• Journal of the Korean institute of surface engineering
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• v.54 no.3
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• pp.112-118
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• 2021

Dy³⁺- and Eu³⁺-codoped BaWO₄ phosphors for white light-emitting diode were synthesized with different activator ions via a solid-state reaction process. The structural, morphological, and optical properties of the BaWO₄:Dy³⁺,Eu³⁺ phosphors were investigated as a function of Eu³⁺ concentration at a fixed concentration of Dy³⁺ ions. XRD patterns exhibited that all the synthesized phosphors had a tetragonal system, irrespective of the concentrations of Dy³⁺ and Eu³⁺ ions. The excitation spectra of the synthesized phosphors were composed of three intense bands centered at 251, 355, and 393 nm and several weak peaks. For the BaWO₄:Dy³⁺,Eu³⁺ phosphors synthesized with 1 mol% of Eu³⁺, the emission spectra under ultraviolet excitation at 393 nm showed two strong blue and yellow bands at 485 and 577 nm corresponding to the ⁴F_9/2⁶H_15/2 and ⁴F_9/2⁶H_13/2 transitions of Dy³⁺ ions, respectively and several weak bands in the range of 600-700 nm resulting from the 4f transitions of Eu³⁺ ions. As the concentration of Eu³⁺ ions increased, intensities of the blue and yellow emission bands gradually decreased while those of the red emissions increased rapidly and the energy transfer efficiency from Dy³⁺ to Eu³⁺ ions was 95.3% at 20 mol% of Eu³⁺. The optimum white light emission with x=0.363, y=0.357 CIE 1931 chromaticity coordinates was obtained for the sample doped with 5 mol% Dy³⁺ and 1 mol% of Eu³⁺.

• Journal of Navigation and Port Research
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• v.44 no.6
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• pp.453-459
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• 2020

A sea trial of the speed performance test is the one of the most important means of verifying a ship's performance, and the International Organization for Standardization established a standard for this test in 2015. Environmental disturbances such as wind and waves are always present under real sea conditions, however, so it is impossible to accurately estimate delivered horsepower under ideal conditions. These disruptive influences also make it difficult to evaluate the positive effect of recently developed energy-saving devices. In this study, uncertainty analysis of improved speed performance was carried out using Monte Carlo simulation to confirm the energy-saving efficiency of a ship equipped with an air-lubrication system. The findings showed the average power saving to be 3.2%, with the expanded uncertainty of ± 2.7% at a 95% confidence level (k=2).

• Korean Chemical Engineering Research
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• v.60 no.1
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• pp.151-158
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• 2022

Iron and nitrogen coordinated carbon catalyst (Fe-N-C) is the most promising non-precious metal catalyst (NPMC) studied to alternate the Pt-group oxygen reduction reaction (ORR) catalyst. In this work, Fe/N/C type catalysts are prepared by four different nitrogen precursors; N, N, N', N'-tetramethylethylenediamine (TMEDA), 1,2-ethylenediamine (EDA), m-dicyanobenzene (DCB), dicyandiamide (DCDA) which can chelate a transition metal; In addition, the catalysts conducted the pyrolysis process at four different temperatures of 700, 800, 900, 1000 ℃ to investigate the ORR activities depend on pyrolysis temperature and to find an appropriate temperature. The characterizations of catalysts were investigated by scanning electron microscope-energy dispersive X-ray spectrometer (SEM-EDS), X-ray diffraction (XRD), and element analysis (EA). The electrocatalytic activity was measured by ORR polarization, also the electron transfer number was calculated from the slope of the K-L plot. The FeNC-EDA-800 which were prepared at pyrolysis temperature of 800 ℃ with EDA showed better ORR activity than the other catalysts.

• Membrane Journal
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• v.32 no.3
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• pp.173-180
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• 2022

Presence of ammonia in drinking water is very toxic to human health. Soluble ammonia contaminates ground water due to activities such as the use of fertilizer in crop, industrial effluents and burning of fossil fuel. Even low concentration of ammonia present in water will damage aqua environment such as marine organism. Membrane technology is an important process to remove ammonia from effectively from water. Flat sheet membrane, membrane contactor and membrane distillation are some of the methods used for water purification from ammonia. Membrane contractor is an efficient process in which ammonia is removed through liquid-gas or liquid-liquid mass transfer without change of phase unlike membrane distillation. However, the cost of ammonia removal in this method is high due to maintenance of very high pH. Zeolite has excellent ion exchange ability that enhances its ability to interact with ammonia and adsorb from wastewater. Mixed matrix membranes containing zeolite enhance the efficiency of ammonia adsorption and separation from wastewater. In this review the above discussed issues are summarized in detail.

• Journal of Digital Convergence
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• v.19 no.11
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• pp.365-371
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• 2021

In this study, The Virtual Power Plant (VPP) solution platform considered in this study minimizes the cost and investment risk associated with the construction of power generation and transmission facilities. In addition, it includes a Demand Response (DR) program operation function to meet consumers' electricity demand. With the introduction of VPP, it is possible to provide more eco-friendly and efficient power by responding to changes in consumer load in real time through existing generators and DR programs without large-scale facility investment in power generation and transmission/distribution sectors. In order to link the communication device to the solar power and ESS linkage device, it is necessary to transmit data in the control/state between the device device and the edge system and develop an IoT device and interworking platform (OneM2M).

• Resources Recycling
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• v.31 no.5
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• pp.59-66
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• 2022

To investigate the rate-determining step of nickel, cobalt and copper electrowinning, experiments were conducted by varying the electrolyte temperature and agitation speed using a rotating disc electrode. Analyzing the rate-determining step by calculating the activation energy in the electrowinning process, it was found that nickel electrowinning is controlled by a mixed mechanism (partly by chemical reaction and partly by mass transport), cobalt is controlled by chemical reaction, and copper is controlled by mass transfer. Electrowinning of nickel, cobalt and copper was performed by varying the electrolyte temperature and agitation speed, and the comparison of the current efficiencies was used the determine the rate-determining step.

• Korean Chemical Engineering Research
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• v.61 no.1
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• pp.52-57
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• 2023

This study is a basic research for the development of high performance flexible electrode material. To enhance its electrochemical property, CuO nanoparticles (CuO NPs) were introduced and dispersed on surface of CNT fiber through electrochemical deposition method. The CNT fiber/CuO NPs electrode was fabricated and applied to electrochemical non-enzymatic glucose sensor. Surface morphology and elemental composition of the CNT fiber/CuO NPs electrode was characterized by scanning electron microscope (SEM) with energy dispersive X-ray spectrometry (EDS). And its electrochemical characteristics were investigated by cyclic voltammetry, electrochemical impedance spectroscopy and chronoamperometry. The CNT fiber/CuO NPs electrode exhibited the good sensing performance for glucose detection such as high sensitivity, wide linear range, low detection limit and good selectivity due to synergetic effect of CNT fiber and CuO NPs. Based on the unique property of CNT fiber, CuO NPs were provide large surface area, enhanced electrocatalytic activity, efficient electron transport property. Therefore, it is expected to develop high performance flexible electrode materials using various nanomaterials.

• Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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• 2021.10a
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• pp.194-198
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• 2021

LoRa is a physical layer technology that is designed to provide a reliable long-range communication with introducing CSS and with introducing a loco parentis tree network. Since a leaf can utilize multiple parents at the same time with a single transmission, PDR increases logarithmically as the number of gateways increases. Because of the ALOHA-like MAC of LoRa, however, the PDR degrades even under the loco parentis tree topology similarly to the single-gateway environment. Our proposed method is aimed to achieve SDMA approach to reuse the same frequency in different areas. For that purpose, it elaborately controls each TxPower of the senders for each message in concurrent transmission to survive the collision at each different gateway. The gain from this so-called capture effect increases the capacity of resource-hungry LPWAN. Compared to a typical collision-free controlled-access scheme, our method outperforms by 10-35% from the perspective of the total count of the consumed time slots. Also, due to the power control mechanism in our method, the energy consumption reduced by 20-40%.

• The Journal of the Korea institute of electronic communication sciences
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• v.19 no.2
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• pp.355-360
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• 2024

In this paper, in implementing a 4-coil resonant wireless power transmission system, we studied the discharge phenomenon that occurs at the end of the transmitting resonance coil. Resonant wireless power transmission consists of a power supply coil, a transmitting resonance coil, a power receiving resonance coil, and a load coil. The transmitting resonance coil serves to amplify the magnetic field generated from the power supply coil and transmits it to the front receiving resonance coil. When a high current flows through the power supply coil in order to transmit large power, a high voltage is induced at the end of the transmitting resonance coil. It causes line-to-line discharge. Line-to-line discharge phenomenon damages the transmitter case and renders the transmitter unusable. Therefore, in order to eliminate this line-to-line discharge phenomenon, the voltage induced in the transmitting resonance coil that causes line-to-line discharge was analyzed and a solution was proposed.

• Composites Research
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• v.37 no.3
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• pp.155-161
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• 2024

Boron nitride nanotubes and carbon nanotubes are the most representative one-dimensional nanostructures, and have received great attention as reinforcement for multifunctional composites for their excellent physical properties. The two nanotubes have similar excellent mechanical stiffness, strength, and heat conduction properties. Therefore, the reinforcing effect of these two nanotubes is greatly influenced by the properties of their interface with the polymer matrix. In this paper, recent comparative studies on the reinforcing effect of boron nitride nanotubes and carbon nanotubes through experimental pull-out test and in-silico simulation are summarized. In addition, the conflicting aspect of the two different nanotubes with structural defects in their side wall is discussed on the viscoelastic damping performance of nanocomposites.