• Journal of The Korean Association For Science Education
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• v.25 no.2
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• pp.88-97
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• 2005

The purpose of this study was to investigate explanations of science textbooks and science teachers' conceptions related to freezing point depression phenomenon. Seven kinds of middle school science textbooks and five kinds of high school chemistryII textbooks were analyzed for the purpose. The teachers' conceptions were searched by a questionnaire developed in this study. The subjects were 146 science teachers. The explanation types of science textbooks were divided into two; 'Description of the phenomenon' and 'Vapor pressure lowering'. The explanations in most of middle school science textbooks and high school chemistryII textbooks belong to 'Description of the phenomenon' and there was no explanation of the reason. The graphs related to depression of freezing point were diverse, too. Most of the science teachers also did not have scientific conception. The percentage of the teachers who thought that the cause of freezing point depression was blocking of solute in solution was high. But the teacher could not find meaningful relation the 'Blocking of solute' explanation represented for elevation of boiling point with depression of freezing point. It is insisted that entropy concept is need to explain depression of freezing point phenomenon in this study.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.16 no.3
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• pp.1594-1599
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• 2015

The world car industry is in an era of internal combustion engines in the past 100 years of environmental, energy and IT is eco-friendly, high-tech cars technologies are bringing an era of change. Until now, the study of new technologies in automobile research and development has been focused on. The car's new technology development is also important, but it's cutting-edge technology is used in the car before the car's performance, and became an important point in the customer experience improvement problems. New technology development, as well as effective for existing technology applied is also important. This study was to determine the effects of temperature and the performance of automobile engine and determine the cause of the content in accordance with the type(tap water, distilled water, underground water) of anti-freeze and water that is contained in the automotive engine cooling water for the effective application of the anti-freeze. In the freezing point of the coolant -10, -20, -30, -40, $-50^{\circ}C$ dynamo performance test was conducted with the numerical analysis. Water (distilled water) were measured at the reference point peak performance 71.112, 99.622hp freezing $-10^{\circ}C$.

• Journal of the Korean Geographical Society
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• v.41 no.5 s.116
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• pp.513-526
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• 2006

The timing and extent of glaciations during the Late Quaternary in the South Shetland Islands, West Antarctica were defined using field mapping, geomorphic analysis and radiocarbon dating. Landforms of glacial erosion and deposition, in particular subglacial meltwater channel erosion, suggest that at least three glaciations occurred during the late Quaternary within the study region. During the global LGM, glacial troughs (such as Maxwell Bay and Admiralty Bay) were overdeepened by an ice stream moving south from $an\sim1000m-thick$ ice cap centered on the present-day continental shelf to the north. This ice was responsible for the subglacial meltwater channel erosion, and glacial polished and striated bedrock on the Fildes Peninsula. The recent local glaciations occurred about 2,000 years ago and during Little Ice Age (LIA). During these glaciations, glaciers were less extensive than the previous one and less erosive as a cold-based ice

• Journal of the Korean Geotechnical Society
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• v.39 no.11
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• pp.53-62
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• 2023

The characteristics of unfrozen water content in frozen soils significantly impact the thermal, hydraulic, and mechanical behavior of the ground. A thorough analysis of the unfrozen water content characteristics of the target subsoil material is crucial for evaluating the stability of frozen ground. This study conducted indoor experiments to measure the freezing point and unfrozen water content of sandy soil while considering pore water salinity. Utilizing the experimental data, we introduced a novel empirical model to conveniently estimate the unfrozen water retention curve. Furthermore, the validity of the unfrozen water retention curve was assessed by comparing the experimental data with the results of a simulation model that utilized the proposed empirical model as input data.

• Journal of The Korean Association For Science Education
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• v.25 no.5
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• pp.555-562
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• 2005

This study investigated the effects of cooperative learning environments in conceptual change instruction upon students' conception, achievement, learning motivation, attitude toward science instruction, and perception of involvement. Two classes of 8th graders at a co-ed middle school were assigned to the treatment and the comparison groups. They were taught about density, boiling point, freezing point, and solubility for 11 class hours. The treatment group's learning environment involved cooperative conceptual change instructions while the comparison group's environment incorporated individual conceptual change instructions. Mann-Whitney test results revealed that the scores of the conception and achievement test for the treatment group were significantly higher than those for the comparison group. The perceptions of involvement for the treatment group were more positive than those for the comparison group. The scores of the learning motivation test for the treatment group were found to be significantly higher than those for the comparison group based on a two-way ANCOVA analysis. However, attitudes toward science instruction were not found to be significantly different between the two groups.

• Journal of Korean Elementary Science Education
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• v.32 no.2
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• pp.206-224
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• 2013

The purpose of this study is to investigate the elementary pre-service teachers' conceptions on 'the freezing point depression' focusing on the survey from a National University of Education. Eighteen pre-service teachers who had completed high school Chemistry II coursework were selected to participate in the study. Participants answered a four question survey to measure their scientific knowledge and conceptions of this phenomenon. Each answer was qualitatively analyzed to determine whether they have 'scientific conceptions' or 'quasi-scientific conceptions' or 'misconceptions'. The results from the study are as follows: First, it was showed that none of the eighteen participants had 'scientific conceptions', six had 'quasi-scientific conceptions' and eight had 'misconceptions' about the caused effect when $CaCl_2$ is scattered on the ice. Second, it was found that three participants had 'scientific conceptions', eight had 'quasi-scientific conceptions' and two had 'misconceptions' for the second survey question. Third, ten out of eighteen participants demonstrated 'scientific conceptions' about the phenomenon of salt water freezing. Fourth, only three of eighteen participants illustrated appropriate 'scientific conceptions' for the fourth survey question. Fifth, of all participants, none answered more than three questions correctly, and only three participants answered any combination of two questions correctly. Based on the findings of this study, five explanatory models were developed. And the models were proposed for pre-service teachers to enhance their understanding of the freezing point depression phenomenon.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2010.11a
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• pp.795-796
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• 2010

Interest has been increasing worldwide in Fischer-Tropsch synthesis (F-T) as a method of producing synthetic liquid fuels from biomass. Hydroisomerization of $C_7-C_{15}$ paraffins applies to production of diesel fuel with high cetane number and improved cold flow properties, such as viscosity, pour point and freezing point. The commercial products such as fuel jet produced from F-T synthesis should have low freezing and pour points. In this study, our major aim is to develop a catalyst for hydroisomerization of synthesis-oil for bio-jet fuel. Effects of zeolites and platinum loading on hydroisomerization of dodecane were investigated as a model reaction in a batch reactor.

• Journal of the Korean Institute of Gas
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• v.17 no.4
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• pp.9-17
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• 2013

Butanethiol is known as a typical odorant with hydrogen sulfide, methyl mercaptan, methyl sulfide, but on the physical and chemical properties and biological hazard assessment, including inhalation toxicity data are very scarce. Butanethiol as a colorless transparent liquid, and has physic-chemical characteristics with flash point as $-23^{\circ}C$ and strong fire risk, boiling point $84-85^{\circ}C$, vapor pressure 80.71 mmHg ($25^{\circ}C$), freezing point $-140.14^{\circ}C$. From whole body exposure with SD rats, the $LC_{50}$ is above 2,500 ppm (9.22mg/L), and then it is classified as the acute toxic chemical (inhalation) category 4 according to the governmental notification No. 2012-14.

• Clean Technology
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• v.24 no.2
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• pp.112-118
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• 2018

Thermo-responsive polymers that exhibit phase transition in response to temperature change can be used as materials for smart windows because they can control solar light transmission depending on the outside temperature. The development of thermo-responsive polymers for smart windows that can be used over a wide temperature range is desirable. To obtain high performance smart windows materials, three-dimensional thermo-responsive poly(N-isopropylacrylamide) (PNIPAm) gels were prepared by free radical polymerization from monomer N-isopropylacrylamide, N, N'-methylenebis acrylamide (MBAm) as a crosslinking agent, ammonium persulfate (APS) as a strong oxidizing agent/tetramethylene diamine as a catalyst, and a mixture of two solvents (water/glycerol). This study examined the effect of glycerol content on the lower critical solution temperature (LCST), freezing temperature and the solar light transmittance of crosslinked PNIPAm gel films. The LCST and freezing temperature of PNIPAm gel films were found to be significantly decreased from 34.3 and $6.3^{\circ}C$ to 28.2 and $-6.5^{\circ}C$ with increasing glycerol content from 0 wt% to 10 wt%, respectively. It was found that the transparent PNIPAm gel films at $25^{\circ}C$ (temperature < LCST) were converted to translucent gels at higher temperature ($45^{\circ}C$) (temperature > LCST). These results suggested that the crosslinked PNIPAm gel materials prepared in this study could have high potential for application in smart glass materials.

• Journal of Korean Society of Forest Science
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• v.98 no.1
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• pp.115-124
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• 2009

New strain needs to maintain desirable characteristics for long term when it was bred, but in lapse of time it degenerates into a bad condition. Therefore the influence of temperature on the viability and survival rates of Lentinula edodes strains were examined after cryopreservation. Also, liquid nitrogen preservation for L. edodes has been proved to be one of the most reliable method. However, a mechanical damage of strain is inevitable during cryopreservation of the fungus because the fungus is very sensitive to stress of cooling rate in the freezing process. So we tried to find out state change of L. edodes with a programmable freezer. L. edodes strains were preserved at $-20^{\circ}C$, $-80^{\circ}C$ and $-196^{\circ}C$ for 50 days. At $-20^{\circ}C$, its mycelial growth became extinct. When thawed, the growth of mycelia which were preserved at $-80^{\circ}C$ was fastest. Attempts were made to investigate viability of L. edodes strains after freezing at $-80^{\circ}C$ and $-196^{\circ}C$, respectively. As the result, more than 90% showed high survival rate of strains tested at $-80^{\circ}C$ and $-196^{\circ}C$. Mycelial growth between apical and basal parts of colony after freezing preservation for 50 days was compared. At apical and basal parts, the survival rates showed 100% at $-80^{\circ}C$, but 98% and 94% at $-196^{\circ}C$, respectively. We confirmed that the ice crystal formation temperatures of L. edodes strains were $-6.0^{\circ}C$ for Sanlim 1, $-5.5^{\circ}C$ for the Sanlim 2, $-4.0^{\circ}C$ for the Sanlim 3 and $-15.5^{\circ}C$ for the Sanzo 302. These results indicated that L. edodes strains showed completely different responses to the ice crystal formation. We knew the fact that even the same species, especially L. edodes, they displayed completely different responses to the same freezing condition. Also, this has nothing to do with the connection between temperature type and freezing point. And a protocol was tried to minimize state change of L. edodes strains using programmable freezer when they are frozen, but it was not effective on them.