• Korean Chemical Engineering Research
• /
• v.47 no.1
• /
• pp.31-37
• /
• 2009

A zwitterionic surfactant shows not only detergency but also mildness effect since it shows characteristics of a nonionic or an anionic surfactant above an isoelectric point, while showing characteristics of a cationic surfactant below an isoelectric point. Therefore, a zwitterionic surfactant can serve as a dual function surfactant by a single molecule through the interconversion of cleaning and softening effects depending on pH variations of the aqueous solution. In this study, physical properties of betaine surfactant such as CMC, surface tension, interfacial tension, contact angle and viscosity were measured and phase behavior study was performed. Also dual function characteristics of betaine zwitterionic surfactant were investigated by measuring an isoelectric point using QCM(quartz crystal microbalance) and zeta potential measurement. The CMC of betaine surfactant was near $10^{-4}mol/L$ and the surface tension at CMC was about 32 mN/m. The interfacial tension between 1 wt% aqueous solution and n-decane measured by spinning drop tensiometer at pH 2~10 resulted in an increase in interfacial tension until pH 5 and a decrease with pH after 5 and equilibration time showed the similar trend with an increase in pH. The isoelectric point of betaine surfactant measured by QCM experiment was found to exist between 3.0 and 3.3, which is the same as the result determined by zeta potential measurement.

• Applied Chemistry for Engineering
• /
• v.20 no.1
• /
• pp.9-14
• /
• 2009

A zwitterionic surfactant shows not only detergency but also softening effect since it shows characteristics of a nonionic or an anionic surfactant above an isoelectric point, while showing characteristics of a cationic surfactant below an isoelectric point. Therefore, a zwitterionic surfactant can serve as a dual function surfactant by a single molecule through the interconversion of cleaning and softening effects depending on pH of the aqueous solution. In this study, the dual function characteristics of an amine oxide zwitterionic surfactant were investigated by measuring the zeta potential and the isoelectric point using quartz crystal microbalance (QCM). In addition, the physical properties of an amine oxide surfactant such as critical micelle concentration, surface tension, interfacial tension, contact angle and viscosity were measured and phase behavior study was also performed. The isoelectric point of an amine oxide surfactant determined by zeta potential measurement was near 7.35 and that obtained by QCM experiment was about 7.4, where both results were found to be close to the value reported in the literature.

• Applied Chemistry for Engineering
• /
• v.27 no.3
• /
• pp.291-298
• /
• 2016

In this study, zwitterionic surfactants were added to liposome systems at different pH conditions to understand the effect of surfactants on liposome characteristics. For this purpose, amine oxide surfactants having different hydrocarbon chain lengths were synthesized and the structure of the resulting product was elucidated by using $^1H$ NMR, $^{13}C$ NMR, and FT-IR. In addition, the physical properties of newly synthesized surfactants such as critical micelle concentration (CMC), surface tension and isoelectric point were measured. The stability characteristics of liposome systems including average particle sizes and zeta potentials were measured by varying pH and hydrocarbon chain lengths of an amine oxide surfactant. Effects of the pH and hydrocarbon chain length of an amine oxide surfactant on fluidity of a liposome membrane were also examined by measuring the deformability and the binding degree between the surfactant and liposome.

• Korean Chemical Engineering Research
• /
• v.50 no.3
• /
• pp.455-463
• /
• 2012

In this study, the measurement of physical properties of ethylene oxide-propylene oxide adducted zwitterionic surfactants were measured such as critical micelle concentration, surface tension, interfacial tension, contact angle, viscosity and foam stability. Also, the dual function characteristics of a zwitterionic surfactant were investigated by determining an isoelectric point, which were obtained using zeta potential measurement and QCM (quartz crystal microbalance) experiments. The isoelectric point of DEP-OSA82-AO zwitterionic surfactant determined by zeta potential measurement was close to that obtained by QCM experiment and both results have shown almost the same trend as that determined by the frictional property measured using an automated mildness tester. In particular, it has been observed that DEP32-OSA82-AO and DEP34-OSA82-AO surfactants provide better softening effect at a pH of acidic or neutral condition than at an alkaline condition. This result indicates that both surfactants act as a cationic surfactant at a pH of acidic or neutral condition and thus provide good softening effect during a rinsing cycle in the detergency process.

• Korean Chemical Engineering Research
• /
• v.50 no.6
• /
• pp.960-968
• /
• 2012

In this study, the measurement of physical properties of 3 different ethylene oxide adducted zwitterionic surfactants were measured such as critical micelle concentration, surface tension, interfacial tension, contact angle, viscosity and foam stability. Also, the dual function characteristics of the zwitterionic surfactants were investigated by determining an isoelectric point, which were obtained using zeta potential measurement and QCM (quartz crystal microbalance) experiments. The isoelectric point of the synthesized zwitterionic surfactant determined by zeta potential measurement was close to that obtained by QCM experiment and both results have shown almost the same trend as that determined by the frictional property measured using an automated mildness tester. In particular, it has been observed that all three surfactants used during this study provide better softening effect at a pH of neutral condition than at an acidic or an alkaline condition. This result indicates that the synthesized surfactants act as a cationic surfactant at a pH of neutral condition and thus provide good softening effect during a rinsing cycle in the detergency process.

• Applied Chemistry for Engineering
• /
• v.23 no.1
• /
• pp.112-118
• /
• 2012

In this study, physical properties of synthesized DE7-OSA82-AO and DEP52-OSA82-AOQ82 zwitterionic surfactants were measured such as critical micelle concentration, surface tension, interfacial tension, contact angle and viscosity. Phase behavior study was also performed. The dual function characteristics of a zwitterionic surfactant were investigated by determining an isoelectric point, which was attained using zeta potential measurements and QCM (quartz crystal microbalance) experiments. The isoelectric point of DE7-OSA82-AO surfactant determined by the zeta potential measurement and QCM experiment was about 7.2 and 7.4, respectively. On the other hand, the isoelectric point of DEP52-OSA82-AOQ82 surfactant determined by the zeta potential measurement and QCM experiment was about 10.9 and 11.0, respectively. The frictional property measured using an automated mildness tester showed that DE7-OSA82-AO surfactant can provide a good softening effect at an acidic or neutral condition. On the other hand, DEP52-OSA82-AOQ82 was found to provide a good softening effect to a fabric surface at a pH below its isoelectric point of 11.

• Applied Chemistry for Engineering
• /
• v.23 no.6
• /
• pp.521-528
• /
• 2012

In this study, we analyzed the physical properties of an ethylene oxide adducted amphoteric surfactant such as critical micelle concentration, surface tension, interfacial tension, contact angle, viscosity and phase behavior. The dual function characteristics of an amphoteric surfactant were investigated by determining an isoelectric point, which were attained using zeta potential measurements and quartz crystal microbalance (QCM) experiments. The isoelectric points of DE3-OSA82-AO, DE5-OSA82-AO and DE9-OSA82-AO surfactant systems determined by zeta potential measurements were 6.97, 6.93 and 7.10 respectively and they are in good agreement with the isoelectric point values measured by QCM experiments. The frictional property measured using an automated mildness tester showed that the DE-OSA82-AO surfactant could provide a good softening effect at neutral condition.

• Journal of the Korean Applied Science and Technology
• /
• v.12 no.1
• /
• pp.47-54
• /
• 1995

Water pollution, which is caused by surfactants, is increased by insolubility and excessive uses of detergents. The detergency properties of nine kinds of amphoteric surfactants derived from imidazoline were investigated and compared with sodium lauryl sulfats(SLS) of petrochemical surfactant by using detergent formulations. Several physico-chemical properties were measured to investigate the effective factors on detergency. From the comparision of these compounds with SLS, it was found that 1-(2-hydroxyethyl)-1- (3-sulfonatedpropyl)-2-undecyl-2-imidazolinum [IV] has the most outstnading characteristics of detergency and various fundamental properties. Therefore, this result is expected to do its environmental stability as a nonpolluting detergent. Detergency process of surfactants were discussed in relation to physico-chemical treatments. Performance improvement on detergency is made work of adhesion to soil as small as possible. Therefore these results show that contamination is easily removed and industrial applications may be respected.

• Applied Chemistry for Engineering
• /
• v.5 no.5
• /
• pp.749-755
• /
• 1994

Imidazoline compounds have been developed in many industrial fields(eg. cosmetic, etc.). These materials can be used in almost all pH ranges and recently its use is successively increased because of nonirritative property. Since the concern of safety has enlarged at industrial application, naturally the use of amphoteric surfactants with new special properties has more. We report general properties of chemical structures of imidazoline surfactants effect.

• Journal of the Korean Applied Science and Technology
• /
• v.31 no.4
• /
• pp.602-611
• /
• 2014

The critical micelle concentration (CMC) of the zwitterionic surfactant of dodecyldimethyl(3-sulfopropyl)ammonium hydroxide(LSB, $CH_3(CH_2)_{11}N^+(CH_3)_2(CH_2)_3SO{_3}^-$) and LSB/Tween-20, LSB/Tween-40, LSB/Tween-80 and LSB/DTAB, LSB/TTAB, LSB/CTAB mixed surfactant systems were determined by using the UV/Vis absorbance method from 284 K to 312 K. And the effects of temperature on the micellization have been measured for the thermodynamic study. The results show that the measured values of gibbs free energy are all negative in the whole measured. The values of enthalpy are positive Tween-20, And negative other surfactants. but the values of entropy are positive in the whole measured temperature region. The results show that all of the thermodynamic parameters are dependent on temperature and alkyl-group's length.