• Applied Chemistry for Engineering
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• v.27 no.6
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• pp.639-645
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• 2016

We herein report efficient triplet-triplet annihilation upconversion (TTA-UC) achieved in various non-toxic and non-volatile vegetable oils as a UC media using platinum-octaethylporphyrin (PtOEP) and 9,10-diphenylanthracene (DPA) as a sensitizer and acceptor, respectively. Green-to-blue UC was readily achieved from PtOEP/DPA solution in vegetable oils with the quantum yield of 8% without any deoxygenation process. The UC efficiency was found to be significantly dependent on the contents of unsaturated hydrocarbon in vegetable oils and viscosity of the solution, as well. Though the Stern-volmer constant and quantum yield in vegetable oils were measured to be lower than those measured in the deaerated organic solvent, the quenching efficiency was still high enough to be 93%. In the sunflower oil, the UC threshold intensity ($I_{th}$) was approx. $100mW/cm^2$, which is far larger than the sunlight intensity, but we believe that the UC achieved in non-toxic and air-saturated media was still highly applicable to nontraditional visualization techniques such as bioimaging.

• Korean Journal of Environmental Agriculture
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• v.24 no.3
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• pp.261-269
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• 2005

To investigate effects of fanning practice and $NO_3-N$ contents of groundwater in intensive horticultural greenhouse area of Yeongnam province, the groundwater samples from 1,370 sites were collected and analyzed. In addition, cultivation year, crops, desalinization methods, amounts of manure application, tube well depth and soil texture with clay contents were observed. Of the investigated sites, 19.7% of shallow groundwater and 1.3% of confined groundwater were exceeded over $10mg/{\ell}$ as the $NO_3-N$ drinking limit value, respectively. $NO_3-N$ concentration in groundwater was highly significantly correlative with clay content $(r=-0.241^{**})$, well depth $(r=-0.228^{**})$ and cultivation duration $(r=0.104^*)$, respectively. In case of desalting crop method being executed for desalinization of greenhouse soil, the $NO_3-N$ value of groundwater was lower than any other desalinization method. The fact that $NO_3-N$ contents of confined groundwater was affected by shallow groundwater was clarified by that $NO_3-N$ contents in shallow were significantly correlative with the confined groundwater $(r=0.532^{**})$.

• Journal of Broadcast Engineering
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• v.22 no.3
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• pp.295-312
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• 2017

Digital video content is the most information-intensive and high-value content. Therefore, it is necessary to protect the intellectual property rights of these contents, and this paper also proposes a watermarking method of digital image for this purpose. The proposed method uses the frequency characteristics of 2-Dimensional Discrete Wavelet Transform (2D-DWT) for digital images and digital watermark on global data without using local or specific data of the image for watermark embedding. The method to insert digital watermark data uses a simple Quantization Index Modulation (QIM) and a multiple watermarking method that inserts the same watermark data in multiple. When extracting a watermark, multiple watermarks are extracted and the final watermark data is determined by a simple statistical method. This method is an empirical method for experimentally determining the parameters in the watermark embedding process. The proposed method performs experiments on various images against various attacks and shows the superiority of the proposed method by comparing the performance with the representative existing methods.

• Korean Journal of Food Science and Technology
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• v.30 no.3
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• pp.660-664
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• 1998

Death of non-growing microorganisms in saline was studied to observe the inhibitory effect of NaCl in foods on the viability of microorganisms. When Leuconostoc mesenteroides LA10, Staphylococcus aureus B31 and Escherichia coli B34 were incubated in McIlvaine buffer with 0, 10, 20, 30% NaCl at $30^{\circ}C$, they survived best at pH 6, 5, 7, respectively. The survival of 5 lactic acid bacteria, 9 other bacteria and 2 yeasts was tested at pH 5, 6, 7 with 10% NaCl. Gram-positive bacteria survived in saline better than Gram-negative bacteria, and lactic acid bacteria and S. aureus survived better than other bacteria. The number of survivors decreased as concentrations of NaCl increased and as pH moved to acidic or alkaline side from the above-mentioned. When L. mesenteroides LA10 was incubated in saline with those materials which are known to protect microorganisms from the killing effect of NaCl, protective effect was not observed.

• Journal of Korean Society of Environmental Engineers
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• v.36 no.6
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• pp.442-450
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• 2014

Concern has grown over a presence of micropollutants in natural water since sulfonamide antibiotic substances such as sulfamethazine, sulfamethoxazole, sulfathiazole have been frequently detected in Nakdong River, Korea. The current work investigates the degradation of the three sulfonamide substances by using quantum chemistry calculations of density functional theory (DFT) and experimental measurement techniques of Fourier transform infrared spectroscopy (FT-IR) and ultraviolet-visible spectrophotometer (UV-VIS). DFT calculations demonstrate that the lowest energy gap between the highest occupied molecular orbital (HOMO) and the lowest unoccupied molecular orbitals (LUMO) lies in sulfanilamide functional group of sulfonamide, implying that the sulfanilamide functional group would be the most active site for ozone oxidation. Also, UV-VIS spectra and FT-IR analysis reveal that 260 nm band originated from sulfanilamide group was absent after ozone oxidation, indicating that a functional group of amine (N-H) was removed from sulfanilamide. Both theoretical and experimental observations agree well with each other, demonstrating the DFT calculation tool can be an alternative tool for the prediction of chemical reactions in purification treatment processes.

• Applied Chemistry for Engineering
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• v.30 no.1
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• pp.88-94
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• 2019

Triplet-triplet annihilation upconversion (TTA-UC) is a photochemical process wherein two or more low-energy photons are converted to a high-energy photon through a special energy transfer mechanism. Herein, we report a strategy to enhance the efficiency of TTA-UC through the light-scattering effect induced by silica microparticles (SM) embedded in polymeric thin films. By incorporating monodisperse uniform silica microparticles with a uniform size of 950 nm synthesized by $St{\ddot{o}}ber$-based seeded growth method into UC polymeric thin films, the UC intensity in the 430-570 nm range was enhanced by as much as 64% when irradiated by 635 nm laser. Analyzing the lifetime of PdTPBP phosphorescence revealed that the presence of SM in the UC layer does not affect triplet-triplet energy transfer (TTET) between sensitizers and acceptors, supporting the enhancement of TTA-UC originated from the light-scattering effect. On the other hand, the incorporation of SM in UC layer is shown to enhance the triplet-triplet annihilation (TTA) efficiency, which results in a 1.5-fold increase of the ${\Phi}_{UC}$, by scattering light source and thus increasing the number of excited photons to be utilized in TTA-UC process.

• Journal of Korean Philosophical Society
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• v.105
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• pp.269-290
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• 2008

The purpose of this paper is to explore the possibility of backwards causation. For study, this paper was divided into four views as follows: The first view was sometimes suggested by the people such as M. Dummett who distinguished observers from behaviors. According to observers' view, backwards causation is impossible, whereas behaviors' view possible. However, in a real or genuine sense, it is incorrect for us to argue for impossibility of backwards causation from the observer aspect. The second view was supported by J. H. Schmidt. He analyzed the possibility of backwards causation in terms of macro and micro level analysis about the causal events. According to micro level analysis, backwards causation is possible, but macro level analysis impossible. Usually the latter makes the former something miraculous. Under the macro level analysis, backwards causation, at first, seems to be miraculous phenomena which belongs to the micro level analysis. The third view had to do with physical equation, and the fourth view physical phenomena, respectively. John Earman argued for the backwards causation by the transformation from Lorentz­-Dirac equation to a second-order integro-differential one in the field of electrodynamic acceleration. His argument was criticized because of his misunderstanding about the relationship between two equations. On the other hand, Phil Dowe defended a version of Reichenbach's own theory about the direction of causation founded on the fork asymmetrical causal relation. However his view was different from Reichenbach's because the former defended the backwards causation model of Bell phenomena in quantum mechanics. On the contrary, Reichenbach put stressed on the priority of cause in the causal process. Subjectivism has recently been defended by H. Price, under the label of perspectivism. According to him, in a certain sense causal asymmetry is not in the world, but is rather a product of our own asymmetric perspective on the world. He also suggested causal net, the symmetry of microphysics, and so on. As mentioned above, there are many kind of suggestions of backwards causation. However none of them replaced objectively the main streams of the direction of causal process. The main stream has been usually defended by pragmatical ground. That is, effects do not precede their causes although causes cannot be without their effects.

• Korea Trade Review
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• v.41 no.3
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• pp.1-25
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• 2016

This study reviews international discussions about the trade-labor linkage and examines the labor chapters of FTAs enforced by the US and the EU from a comparative perspective. Since early 1990s, starting from the NAFTA, the US has included forceable labor provisions in its FTAs and this trend continues to the TPP which was concluded in October 2015. On the other hand, the EU's labor provisions in its FTAs have been composed of promotional elements on labor rights based on cooperations and dialogues. These different features of labor provisions in the US and European FTAs are mainly due to the motives of the FTAs of the US and the EU respectively as well as their domestic situations with regards to domestic law and institutional set-ups. The coordination of labor provisions involves a long-term institutional as well as regulatory convergence which triggers not only economic but also social changes, compared to a relatively short-term effect of tariff elimination. For Korea which has been a FTA partner country both with the US and the EU, it is significant to keep the different characteristics in the labor provisions in mind, particularly in the process of its implementation. Concerning the implementation of Korea-US FTA, it might be problematic if Korean law and its regulatory practice on labor-management relations do not comply with that of the US. The Korea-EU FTA case can also have an indirect impact on Korea's labor laws since it stipulates in its provisions that both parties should have discussions not only within each government but also with the civil communities including NGOs. Thus, Korea should pay more attention to the true meaning in labor provisions of both FTAs in order to promote its firms to be equipped with the right labor-management system in their operations abroad.

• Journal of the Korea Institute of Building Construction
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• v.23 no.5
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• pp.537-546
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• 2023

For the purpose of fire delineation within buildings, steel walls in Korea are mandated to undergo rigorous certification as fire-resistant entities, substantiated via a series of qualitative assessments. Predominantly, these evaluations comprise the fire resistance test paired with supplementary examinations; specifically for steel walls, these encompass the gas hazard and panel bending strength tests. Given the prevalence of semi-noncombustible core materials, gas hazard tests are largely rendered superfluous, pivoting the focus solely onto the panel bending strength test during the certification trajectory. This particular test is designed to gauge the flexural robustness of individual wall panels. An enhanced bending strength is postulated to fortify both the structural integrity and thermal insulation of the wall by mitigating potential deformations. In this scholarly exploration, an analytical deep dive was undertaken into extant, valid certification test datasets. The endeavor aimed to ascertain the depth of correlation between the designated fire resistance metric and the bending strength, the latter being the sole supplementary assessment for steel walls. In distilling the findings, it was discerned that temperature elevations beyond baseline values exhibited no statistically salient linkage with the panel's bending strength.

• Korean Journal of Plant Resources
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• v.37 no.2
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• pp.203-213
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• 2024

In this study, we investigated the growth and physiological responses of Iris laevigata Fisch. to shading treatments in order to suggest optimal light conditions for ex-situ conservation of the northern lineage plants. For this purpose, a control plant receiving full sunlight and different shading treatments (50%, 75%, 95%) were installed, and leaf mass per area, chlorophyll content and fluorescence response, and photosynthetic characteristics were investigated. I. laevigata developed leaves with higher photosynthetic efficiency to adapt to lower light intensity as shading levels increased. Chlorophyll content increased with increasing shading levels, and leaf mass per area decreased with increasing leaf area. The chlorophyll fluorescence responses Fv/Fm and NPQ did not change with shading, and the activity of the carbon fixation system did not differ between treatments. I. laevigata exhibited a light-saturation point equivalent to that of sun plants and maintained photosynthetic capacity similar to that of controls up to 75% shading. The apparent quantum yield of I. laevigata decreased significantly at 95% shading, indicating adaptation to lower light conditions. It seems that the photosynthetic capacity of I. laevigata decreases when grown under 95% shading level compared to full sunlight, and it is judged that the longer the light is restricted by continuous shading, the more unfavorable the growth will be.