• Title/Summary/Keyword: 액화 공정

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Analysis of the Characteristics of Reformer for the Application of Hydrogen Fuel Cell Systems to LNG Fueled Ships (LNG 추진선박에 수소 연료전지 시스템 적용을 위한 개질기의 특성 분석)

  • Lee, Yoon-Ho
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.27 no.1
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    • pp.135-144
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    • 2021
  • In this study, we investigated the characteristics of the process of hydrogen production using boil-of gas (BOG) generated from an LNG-fueled ship and the application of hydrogen fuel cell systems as auxiliary engines. In this study, the BOG steam reformer process was designed using the UniSim R410 program, and the reformer outlet temperature, pressure, and the fraction and consumption of the product according to the steam/carbon ratio (SCR) were calculated. According to the study, the conversion rate of methane was 100 % when the temperature of the reformer was 890 ℃, and maximum hydrogen production was observed. In addition, the lower the pressure, the higher is the reaction activity. However, higher temperatures have led to a decrease in hydrogen production owing to the preponderance of adverse reactions and increased amounts of water and carbon dioxide. As SCR increased, hydrogen production increased, but the required energy consumption also increased proportionally. Although the hydrogen fraction was the highest when the SCR was 1.8, it was confirmed that the optimal operation range was for SCR to operate at 3 to prevent cocking. In addition, the lower the pressure, the higher is the amount of carbon dioxide generated. Furthermore, 42.5 % of the LNG cold energy based on carbon dioxide generation was required for cooling and liquefaction.

Enhancement of Saccharification Yield of Ulva pertusa kjellman for Ethanol Production through High Temperature Liquefaction Process (고압액화공정을 이용한 구멍갈파래의 발효용 알코올 당화수율 증진)

  • Han, Jae-Gun;Oh, Sung-Ho;Choi, Woon-Yong;Kwon, Jung-Woong;Seo, Hyeon-Beom;Jeong, Kyung-Hwan;Kang, Do-Hyung;Lee, Hyeon-Yong
    • KSBB Journal
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    • v.25 no.4
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    • pp.357-362
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    • 2010
  • Green alga, Ulva pertusa kjelmann has been known to be one of the largest pollutants in Korea. Therefore, the efficient pretreatment processes have been required to improve the yields of fermentable sugar. The optimal pretreatment conditions were determined to be $195^{\circ}C$ for 15 min. The sugar yield of glucose and xylose were estimated as 20.5%, and 5.0% respectively, based on theoretical yields. However solid residues were estimated enzymatic digestibility of 90-95% with cellulase loading of 15 FPU/g glucan. This process was proved to generate the low concentration of Hydroxy-Methyl-Furfural (51 ppm), which resulted in ethanol production with 95% of the maximum conversion yield from glucose in the culture of Saccharomyces cerevisiae (ATCC, 24858). This study showed that Ulva pertusa kjellmann can be used as a bioetahnol resource using the high temperature liquefaction process.

Optimization of Demucilage Process of Opuntia ficus-indica var. saboten Fruit using High Hydrostatic Pressure Enzyme Dissolution (고압 효소 액화 장치를 이용한 백년초 점질물 분해 공정의 최적화)

  • Im, Sungbin;Lee, Hyungjae;Shim, Jae-Yong;Kim, Tae-Rahk;Kim, Dae-Ok
    • KSBB Journal
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    • v.30 no.2
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    • pp.63-68
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    • 2015
  • This study aimed to develop and optimize a demucilaging process of Opuntia ficus-indica var. saboten (OFI) fruit to increase its usability as functional food ingredient and food additive. Viscozyme and Novozym 33095 as multienzyme complex having a broad spectrum of carbohydrases and pectolytic enzymes, respectively, were used in enzymatic dissolution along with high hydrostatic pressure liquefaction. To optimize the liquefaction process using high hydrostatic pressure liquefying extractor, response surface methodology with 3-factor central composite design was employed with reaction factors such as temperatures (25, 32, 40, 48, and $55^{\circ}C$), pressures (20, 40, 60, 80, and 100 MPa), and times (15, 30, 45, 60, and 75 min). At optimum conditions ($25^{\circ}C$, 100 MPa, and 58.275 min) for high hydrostatic pressure liquefaction process, the processed OFI fruit juice was predicted to have viscosity at 2.917 poise, partly due to the release of free sugars such as fructose and glucose detected using HPLC-ELSA system. The results above suggests that the OFI fruit juice with decreased viscosity may be used for various manufacturing processes of food, beverage, ice cream, and cosmetics.

A Comparative Study of the Cold Power Generation Systems for LNG Terminal (LNG 인수기지용 냉열발전 시스템 비교 연구)

  • 김동수;박영무
    • Journal of Energy Engineering
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    • v.5 no.1
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    • pp.34-41
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    • 1996
  • The heat of evaporation (cold energy) of LNG is the energy consumed in the production of LNG. This energy amounts to 14% of the NG. In Pyungtak LNG terminal, it is about 96 MW in 1993. In order to utilize the cold energy, the cold power generation systems are investigated: The Rankine cycle using the low temperature energy, the partial expansion cycle using the pressure energy, and the Linde process which is a combined cycle of the Rankine and the partial direct expansion cycle. The commercial simulator, ASPEN Plus, is used. The conceptual design data are obtained from the current facilities of the Pyungtak LNG terminal. The performances of three systems are evaluated. The amount of electric power ranges iron 3 MW to 6MW. The optimum energy efficiency is about 37%. The optimum design conditions are obtained for the partial direct expansion (PDE) cycle. The performance of the PDE cycle is supposed to be comparable to that of the Rankine cycle if the areas of the total heat exchanger of the both cycle are equal.

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A Study on the Microstructure and Mechanical Properties for the Weldment with Variation of Welding Process of the API 5L-X42 Pipeline for Natural Gas Transmission. (천연가스 수송용 API 5L-X42 강관의 용접방법에 따른 용접부의 미세조직과 기계적 특성에 관한 연구)

  • Baek Jong-Hyun;Kim Cheol-Man;Kim Young-Pyo;Kim Woo-Sik
    • Journal of the Korean Institute of Gas
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    • v.2 no.2
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    • pp.34-39
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    • 1998
  • Demand of the clean and convenient natural gas has continuously increased with recognizing of the environment problem since liquefied natural gas was introduced in Korea. Clean fuel natural gas was supplied to each city through high tensile strength pipeline connected by welding. Grades of pipeline were divided into the high and middle pressure according to supply pressure. Pipeline was welded mainly SMA welding process due to its easy handling, the other welding process was adopted according to the constructing condition. We were examined on the microstructure variation and mechanical properties of weld metal for high pressure pipeline, API 5L X-42.

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Determination of the Optimal Operating Condition of the Hamworthy Mark I Cycle for LNG-FPSO (LNG-FPSO에의 적용을 위한 Hamworthy Mark I Cycle의 최적 운전 조건 결정)

  • Cha, Ju-Hwan;Lee, Joon-Chae;Roh, Myung-Il;Lee, Kyu-Yeul
    • Journal of the Society of Naval Architects of Korea
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    • v.47 no.5
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    • pp.733-742
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    • 2010
  • In this study, optimization was performed to improve the conventional liquefaction process of offshore plants, such as a LNG-FPSO(Liquefied Natural Gas-Floating, Production, Storage, and Offloading unit) by maximizing the energy efficiency of the process. The major equipments of the liquefaction process are compressors, expanders, and heat exchangers. These are connected by stream which has some thermodynamic properties, such as the temperature, pressure, enthalpy or specific volume, and entropy. For this, a process design problem for the liquefaction process of offshore plants was mathematically formulated as an optimization problem. The minimization of the total energy requirement of the liquefaction process was used as an objective function. Governing equations and other equations derived from thermodynamic laws acted as constraints. To solve this problem, the sequential quadratic programming(SQP) method was used. To evaluate the proposed method in this study, it was applied to the natural gas liquefaction process of the LNG-FPSO. The result showed that the proposed method could present the improved liquefaction process minimizing the total energy requirement as compared to conventional process.

Comparison of Design Concepts for Four Different Entrained-Bed Coal Gasifier Types with CFD Analysis (CFD 해석을 통한 4종의 건식 분류층 석탄가스화기 설계개념 비교)

  • Yun, Yongseung;Ju, Jisun;Lee, Seung Jong
    • Applied Chemistry for Engineering
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    • v.22 no.5
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    • pp.566-574
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    • 2011
  • Coal gasifier is a key component for achieving high efficiency in integrated gasification combined cycle and indirect coal liquefaction. Although there have been several successful coal gasifiers that were commercially proven, many different design configurations are still possible for a simple and reliable gasifier operation. Four different gasifier design concepts of dry-feeding were compared in terms of residence time, exit syngas temperature and syngas composition. First, cold-flow simulation was applied to pre-select the configuration concepts, and the hot-flow simulation including chemical reactions was performed to compare the concepts at more actual gasifier operating conditions. There are many limitations in applying CFD method in gasifier design, particularly in estimating slag behavior and slag-tap design. However, the CFD analysis proved to be useful in comparing the widely different gasifier design concepts as a pre-selection tool.

Fracture Characteristics of C/SiC Composites for Rocket Nozzle at Elevated Temperature (로켓 노즐목 소재 C/SiC 복합재 고온 파괴 특성)

  • Yoon, Dong Hyun;Lee, Jeong Won;Kim, Jae Hoon;Sihn, Ihn Cheol;Lim, Byung Joo
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.40 no.11
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    • pp.927-933
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    • 2016
  • In a solid propulsion system, the rocket nozzle is exposed to high temperature combustion gas. Hence, choosing an appropriate material that could demonstrate adequate performance at high temperature is important. As advanced materials, carbon/silicon carbide composites (C/SiC) have been studied with the aim of using them for the rocket nozzle throat. However, when compared with typical structural materials, C/SiC composites are relatively weak in terms of both strength and toughness, owing to their quasi-brittle behavior and oxidation at high temperatures. Therefore, it is important to evaluate the thermal and mechanical properties of this material before using it in this application. This study presents an experimental method to investigate the fracture behavior of C/SiC composite material manufactured using liquid silicon infiltration (LSI) method at elevated temperatures. In particular, the effects of major parameters, such as temperature, loading, oxidation conditions, and fiber direction on strength and fracture characteristics were investigated. Fractography analysis of the fractured specimens was performed using an SEM.

Case Study on Optimization of Send-out Operation in Liquefied Natural Gas Receiving Terminal (LNG 터미널 송출 운전 최적화 사례 연구)

  • Park, Chansaem;Han, Chonghun
    • Korean Chemical Engineering Research
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    • v.53 no.2
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    • pp.150-155
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    • 2015
  • Recently, LNG receiving terminals have been widely constructed and expanded for an increase in LNG demand. Selection of the storage tank for send-out and estimation of send-out flow rate have significant influence to process operation and economics. In this study, a send-out flow rate of each storage tank is optimized in order to minimize the total BOG generation rate. Considering a size and characteristic of each storage tanks, BOG flow rates are estimated using a dynamic simulation with varying liquid levels in the tanks. The regression model is developed fitting BOG flow rates and tank liquid levels, which are boil off rate model to predict BOG flow rates with particular level data. The objective function and constraints including required total send-out flow rate and level limit in the tanks are formulated to optimize a send-out flow rate of each tank. This method for optimization of send-out operation is applied to the Incheon LNG receiving terminal considering two scenarios for various liquid levels and maximum and minimum required send-out flow rates. For maximum required send-out flow rate, this method achieves BOG reduction of 9% comparing with assumed conventional operation.

A study on quality assurance and evaluation of uncertainty for the analysis of natural gas (천연가스 분석의 불확도 평가 및 품질 보증을 위한 연구)

  • Woo, Jin-Chun;Kim, Young-Doo;Bae, Hyun-Kil;Lee, Kang-Jin;Her, Jae-Young
    • Analytical Science and Technology
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    • v.19 no.6
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    • pp.490-497
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    • 2006
  • The sources of uncertainty in the analysis of liquified natural gas (LNG) process are evaluated. The uncertainty sources evaluated are the repeatability of measurement, non-linearity of GC, the uncertainty of standard gas used for calibration, difference of gas sampling and deviation after GC calibration and major revealed sources are the non-linearity of GC, the uncertainty of standard gas and the deviation after GC calibration. The determined values and uncertainties of methane and ethane as the major components are $90.0%mol/mol{\pm}1.9%$ (relative and 95% level of confidence) and $6.26%mol/mol{\pm}0.08$ (relative and 95% level of confidence), respectively. The contribution of uncertainty varies depending on the source of uncertainty and gas component. In the case of methane, non-linearity of GC, the uncertainty of standard gas and deviation after GC calibration contribute 0.28%, 0.25% and 0.24% of relative expanded uncertainty, respectively.