• Title/Summary/Keyword: 액화질소가스

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특집:에너지플랜트 및 핵심기자재 기술 - 가스액화플랜트기술

  • Hong, Yong-Ju;Go, Jun-Seok;Kim, Hyo-Bong;Park, Seong-Je
    • 기계와재료
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    • v.24 no.1
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    • pp.26-35
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    • 2012
  • 가스액화플랜트는 질소, 산소, 헬륨 등 고순도의 가스를 효율적으로 저장 및 운송을 위해 가스를 액체로 변환하는 플랜트로, 대표적인 플랜트로는 질소, 산소, 아르곤 등의 가스를 생산하는 공기분리플랜트, 헬륨액화플랜트, 수소액화플랜트, 천연가스액화플랜트 등이 있다. 질소, 산소, 수소 등의 가스는 산업의 전반적인 분야에서 널리 사용되고 있으며, 국내의 경우 철강, 반도체, 디스플레이제조산업 등 가스 다소비 분야의 비약적인 발전에 따라 급격하게 수요가 증가하고 있는 상황이다. 대용량의 가스액화플랜트는 원료로부터 불순물을 제거하고, 팽창 또는 열교환 과정을 통해 가스를 액체로 변환하는 극저온기술로 주로 구성되며, 이와 같은 과정은 압축기, 열교환기, 증류탑, 팽창터빈, 콜드박스 등의 구성요소에 의해 구현된다. 따라서 가스액화플랜트에서 효율적인 극저온의 생성 및 유지는 플랜트의 경제성 제고를 위해 핵심적인 요소이다.

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Biogas upgrading and Producing the Liquefied Bio-methane by Cryogenic Liquefaction Process (바이오가스 고질화와 초저온액화공정을 통한 액화바이오메탄 생산)

  • Shim, Dongmin;Sung, Hyunje;Park, Seongbum;Kim, Nackjoo;Chang, Homyung;Lee, Jaeyoung;Lee, Youngmin;Lee, Woocheul;Oh, Hwasoo
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.246.1-246.1
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    • 2010
  • 본 연구는 바이오가스의 에너지효율성을 높이기 위한 연구로서 바이오가스 정제공정과 초저온액화공정을 통하여 액화바이오메탄을 생산하는 바이오가스 고질화기술개발 연구이다. 바이오가스 정제공정은 탈황, 제습, 흡착, 압축, $CO_2/CH_4$ 분리공정으로 구성하고, 초저온액화공정은 열교환기, $CO_2$ 제거설비, 질소냉매 공급공정으로 구성하여 혐기성소화조에서 발생하는 바이오가스($CH_4$ 농도: 60~65%, $H_2S$: 1,500~2,500ppm)를 $200Nm^3/hr$의 유량으로 인입시켜 액화바이오메탄을 생산하였다. 연구결과, 탈황공정에서는 가성소다 세정법을 이용하여 1,500~2,500ppm으로 인입되는 $H_2S$를 100ppm 이하로 제거한 후, 흡착법을 이용하여 $H_2S$를 완전히 제거하였다. 바이오가스에 포화된 수분은 냉각제습과 흡착제습공정을 통해 Dew point $-70{\sim}-90^{\circ}C$까지 제거하여 안정적으로 $CO_2/CH_4$ 분리공정에 인입시켰다. $CO_2/CH_4$ 분리공정은 흡착방식을 적용하여 $CH_4$ 순도가 95% 이상인 바이오메탄을 생산하였으며, 이때 메탄 회수율은 약 87%이였다. $CO_2$가 분리된 바이오메탄은 초저온액화공정을 이용하여 액화바이오메탄으로 전환시켰다. 이때 초저온액화공정은 Reverse Brayton cycle로 구성하였으며, 냉매로는 질소를 사용하였다. 액화바이오메탄의 생산은 바이오메탄을 등엔트로피과정인 단열팽창을 통하여 $-155{\sim}-159^{\circ}C$의 초저온으로 냉각되는 질소냉매와 열교환기에서 열교환시켜 이루어졌으며 그 생산량은 $3.46m^3$/day(1bar, $-161^{\circ}C$)이었다.

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Study of Cold Gas Propulsion System Utilizing Butane as Liquefied Propellant (부탄을 액화 연료로 사용한 냉가스 추진 시스템에 대한 연구)

  • Kang, Suk-Jin;Kwon, Ky-Beom;Cho, Dong-Hyun;Lee, Sang-Hyun
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.35 no.4
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    • pp.323-328
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    • 2007
  • A direct application of liquefied gas propellants to a typical small satellite cold gas propulsion system was analyzed. Performance of systems using liquefied gas propellant under consideration was compared to that of a nitrogen cold gas propulsion system. Liquefied gas propellant propulsion system's performance, required tank volume, and required propulsion system mass has been calculated at the same mass, volume, and total impulse condition of a typical nitrogen cold gas propulsion system. It was found that the liquefied gas propulsion system has advantages in performance, volume, and mass, compared to a typical nitrogen cold gas system, and can be directly applied to a cold gas propulsion system.

Advanced Dual Refrigerant Expansion Cycle for LNG Liquefaction (천연가스 액화용 이중 냉매 팽창 사이클)

  • Kim, Minki;Kim, Mungyu;Lee, Kihwan;Kim, Hyobin;Lee, Donghun;Min, Joonho;Kim, Jinmo
    • Plant Journal
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    • v.15 no.2
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    • pp.46-55
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    • 2019
  • This paper presents a LNG Liquefaction cycle configuration using two stages of methane expansion (i.e. spliting into two stages as warm & cold to generate an additional inflection point within a cold composite curve) and a single stage of nitrogen expansion to improve the efficiency of the conventional Methane & Nitrogen Expansion Cycle. In comparison with Double Nitrogen Expansion Cycel and Methane & Nitrogen Expansion Cycle, the cycle efficiency has increased approximately from 13.92 and 13.13 to 12.08 kW/ton/day (8~15% efficiency increase). A Life Cycle Cost (LCC) analysis based on Net Present Value (NPV) also show an improvement in therms of project NPV, against a minor increment of a CAPEX.

Design and Analysis for Hydrogen Liquefaction Process Using LNG Cold Energy (LNG냉열이용 수소액화 공정해석 및 설계)

  • Yun, Sang-Kook
    • Journal of the Korean Institute of Gas
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    • v.15 no.3
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    • pp.1-5
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    • 2011
  • For the hydrogen liquefaction, the large amount of energy is consumed, because precooling, liquefaction and ortho/para conversion heats should be eliminated. In this paper the basic design and thermal analysis are carried out to reduce the energy consumption by using LNG cold energy for precooling process in hydrogen liquefaction processes. The LNG cold energy utilization for hydrogen precooling enables not only to get energy saving for liquefaction, but to recover the wasted cold energy to sea water at the LNG terminal. The results show that the energy saving rate for liquefaction using LNG cold energy is almost 75% of current industrial hydrogen liquefaction plant. The demand flow-rate of LNG is only 15T/D for 1T/D hydrogen liquefaction.

Behavior of Liquid Nitrogen in the Cryogenic Storage Tank (초저온액화가스 저장탱크 내에서의 액화질소의 거동)

  • Park Byung Whee;Lee Hyun Chul;Park Doo Seon;Son Moo Ryong
    • Journal of the Korean Institute of Gas
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    • v.2 no.3
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    • pp.37-48
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    • 1998
  • A cryogenic liquid stored in the closed cryogenic tank has been studied at various liquid levels. The change of pressure, temperature, and liquid-vapor ratio in the tank depended on the liquid levels. The various phenomena were shown at different liquid levels as follows: (1) liquid level was increased with condensation of vapor: (2) liquid was vaporized in spite of liquid level going up for a certain initial period and then condensation of vapor occurred at higher pressure; (3) liquid was vaporized without liquid level change; (4) liquid was vaporized with liquid level decreasing. If the tank is full with cryogenic liquid, it is extremely dangerous because of soaring the pressure. Therefore the tank must be filled with $90\%$ liquid according to the safety rules. If the tank was filled with $0\%$ ullage, the pressure increment as high as 80bar during first 5 days. With $90\%$ liquid level, however, the pressure was increased as low as 1.5bar in the same period. No matter what the liquid level is, it is very dangerous if the tank is locked-up with filled cryogenic liquid for a long time.

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Study on Flow behavior of Liquid Nitrogen for Porous Media in Square-section Cylinder (사각 기둥 실린더 내부 다공성 매질에서의 액화질소의 거동에 대한 연구)

  • Choi, Sung Woong;Lee, Woo Il
    • Journal of the Korean Institute of Gas
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    • v.17 no.1
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    • pp.26-34
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    • 2013
  • The multiphase flow analysis related to phase change can be adapted to lots of areas such as evaporation and condensation has many interesting branches due to complicated phenomenon. In this study, the experimental investigation of cryogenic liquid in the porous media with various densities was shown how the cryogenic liquid behaves in the porous structure. For this study, permeability behaviors under different applying pressure of the glass wool with different bulk densities are discussed. Experimental investigation on the behavior of cryogenic liquefied nitrogen in the porous media is conducted. The result was that the non linearity of pressure gradient with location is increased and the permeability is decreased as the bulk density of glass wool increased. Lastly, simulation results with CFD commercial package program are used to realize the cryogenic liquid's flow in porous media to compare the finding with experimental results.

Investigation on Efficiency Improvement of the Nitrogen Expander Cycle : Natural Gas Liquefaction Process for LNG-FPSO (LNG-FPSO(Liquefied Natural Gas-Floating Production Storage and Offloading)용 질소 팽창 사이클의 효율 개선에 대한 연구)

  • Baek, Seung-Whan;Jeong, Sang-Kwon;Kim, Sun-Young
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.22 no.7
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    • pp.442-447
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    • 2010
  • FPSO (Floating Production Strorage and Offloading) method for LNG industry is efficient and facile compared to onshore NG (Natural Gas) treatment facility. Five simple natural gas liquefaction cycles for FPSO are presented and simulated in this paper. SMR (Single Mixed Refrigerant) cycle, SNE (Single Nitrogen Expander) cycle, DNE (Double Nitrogen Expander) cycle, PNE (Precooled Nitrogen Expander) cycle, and PDNE (Precooled Double Nitrogen Expander) cycle are compared. Simple analysis results in this paper show that precooling process and adding an expander in the liquefaction cycle is an effective way to increase liquefaction efficiency.

Numerical analysis of LNG vaporizer heat transfer characteristic in LNG fuel ship (선박용 액화천연가스 기화기의 열전달 특성의 수치해석)

  • Lee, Dae-Chul;Afrianto, Handry;Chung, Han-Shik;Jeong, Hyo-Min
    • Journal of Advanced Marine Engineering and Technology
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    • v.37 no.1
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    • pp.22-28
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    • 2013
  • The heat transfer characteristics of LNG(Liquefied Natural Gas) vaporizer on the ship was performed by numerical simulation to get the optimum NG(Natural Gas) generating condition. The glycol-water was used for heating in LNG vaporizer, and the cooling water of main engine was used as heating souse for glycol-water. This cooling water temperature increases again after recirculating from the main engine, and then it can be used to heat the glycol-water. The numerical analysis results has good agreement with the experimental results by liquid nitrogen for validation. So CFD technique was used to simulate the heat transfer characteristics of LNG vaporizer on the ship. The numerical results show that the operation condition of LNG vaporizer shows NG temperature of $6^{\circ}C$ in the outlet of LNG vaporizer, and the mass flow rates of LNG and glycol-water were showed 0.111 kg/s and 1.805 kg/s, respectively.