• Proceedings of the Korean Vacuum Society Conference
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• 1999.07a
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• pp.54-54
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• 1999

다이아몬드 합성시 질소 첨가는 Cn 화합물의 합성가능성을 비롯하여 다이아몬드의 질소 도핑, 성장 속도 및 결정성 변화 등 다양한 관점에서 중요한 의미를 가지고 있다. 본 연구에서는 다이아몬드의 일반적인 합성조건에서 질소를 첨가하여 합성된 막의 형상 및 상 변화에 대해 고찰하였다. 막은 다이아몬드 전처리시킨 Si 기판위에 microwave plasma CVD 장치를 이용하여 합성하였다. 유입되는 혼합가스(CH4+H2+N2)에서 N2 첨가량을 0-95%까지 변화시켰다. 이때 CH4 농도는 5%로 고정하였고, 합성온도는 90$0^{\circ}C$-115$0^{\circ}C$까지 변화시켰다. 이와 같이 합성된 막의 표면조직 및 성장 두께를 측정하기 위해 주사전자현미경을 이용하였다. 상의 분석은 Raman, XRD 및 TEM 분석을 이용하였으며, 조성분석을 위해 XPS 및 AES를 사용하였다. 질소 첨가량에 따라 합성된 막은 첨가하지 않은 경우에 다이아몬드 결정에서 시작하여 질소첨가에 따라 결정면이 깨지는 것으로 나타났다. 그러나 30%, 45%의 경우는 다시 결정면이 나타났다. 다량의 질소가 첨가되었을 때, 다시 결정면을 보이는 다이아몬드가 합성된 것은 매우 흥미로운 결과이다. 한편 질소와 메탄만의 기체하에서는 다시 결정면이 관찰되지 않았다. 이들 상의 구조는 XRD 및 TED 분석을 통해 모두 다이아몬드로 확인되었다. 기체내의 질소의 첨가에 관계없이 고상내에 질소는 확인되지 않았다. 따라서 이방법에 의한 CN 화합물의 합성은 힘든 것으로 보여진다. 이들 실험 결과를 근거로 온도 및 조성에 따른 기체의 열역학적 계산을 통하여 합성거동과의 연관성을 검토하였다. anode는 매우 높은 충전용량을 갖는데 첫 번째 방전시에 Li2O를 생성하여 비가역적 반응을 나타내고 계속되는 충방전 동안 Li-Sn 합금이 생성되어 2차전지의 가역적 반응을 가능하게 한다. SnO2 는 대기중에서 Li 금속보다 안정하기 때문에 전지의 제작 공정 및 사용 면에서 매우 우수한 물질이지만 아직까지 SnO2 구조적 특성과 전지의 충, 방전 특성에 대한 관계의 규명을 위한 정확한 정설은 제시되고 있지 못하다. 본 연구에서는 TFSB anode 물질로써 SnOx박막을 상온에서 여러 전도성 콜렉터 위에 증착하여 그 충, 방전 특성을 보고하였다. 증착된 SnOx박막의 표면은 SEM, AFM으로 분석하였으며 구조의 분석은 XR와 Auger electron spectroscope로 하였다. 충, 방전 특성을 분석하기 위하여 리늄 foil을 대극과 참조 전극으로 하여 EC:DMC=1:1, 1M LiPF6 액체 전해질을 사용한 Half-Cell를 구성하여 100회 이상의 정전류 충, 방전 시험을 행하였다. Half-Cell test 결과 박막의 구조, 콜렉터의 종류 및 Sn/O비에 따라 서로 다른 충, 방전 거동을 나타내었다.다. 거의 없었다. 5mTorr 일 때가 가장 좋았다.수 있음을 알 수 있었다. 그러므로, RNA바이러스의 하나인 BVDV의 viral replicon을 이용하여 다양한 종류의 포유동물 세포에 유전자 발현벡터로써 사용할 수 있음으로 post-genomics시대에 다양한 종류의 단백질 기능연구에 맡은 도움이 되리라 기대한다.다양한 기능을 가진 신소재 제조에 있다. 또한 경제적인 측면에서도 고부가 가치의 제품 개발에 따른 새로운 수요 창출과 수익률 향상, 기존의 기능성 안료를 나노(na

• Journal of Hydrogen and New Energy
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• v.13 no.3
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• pp.190-196
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• 2002

Ni/MH 박막전지의 전극으로 사용될 수 $Mg_{2}Ni$박막을 스퍼터링방법으로 제조하였다. $Mg_{2}Ni$합금박막은 Mg, Ni타?을 이용하여 동시에 스퍼터링함으로서 제조하였다. KOH 액체전해질 및 $Ni(OH)_2$전극을 이용하여 전기화학실험을 하였다. $Mg_2Ni$ 박막의 초기 싸이클 특성에 미치는 열처리 효과를 조사하기 위하여, $200-550^{\circ}C$로 변화시키면서 진공중에서 열처리를 하였다. 열처리온도가 $300^{\circ}C$ 이하에서는 초기방전용량이 증가하였으며, $400^{\circ}C$ 열처리시에는 활성화시의 방전용량이 약 160mAh/g으로 가장 크게 나타났다.

• Journal of the Korean Electrochemical Society
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• v.21 no.2
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• pp.39-46
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• 2018

Many studies on the electrochemical performance of Li secondary batteries have been obtained using coin-type cells due to the ease of assembly, low cost and ensuring reproducibility. The coin-type cell consists of a case, a gasket, a spacer disk, and a wave spring. These structural features require a greater amount of liquid electrolyte to assemble than other types of cells such as laminated cells and cylindrical cells. Nevertheless, little research has been conducted on the effect of excess liquid electrolytes on the electrochemical performances of Li secondary batteries. In this study, we investigate the effect of different amounts of electrolyte on the coin-type cells. The amount of electrolytes is adjusted to 30 and $100mg\;mAh^{-1}$. Cycle performances at room temperature ($25^{\circ}C$) and high temperature ($60^{\circ}C$) and high voltage are performed to investigate the electrochemical properties of the different amount of electrolytes. In the case of the unit cell including the electrolyte of $30mg\;mAh^{-1}$, the discharging capacity retention characteristic is excellent in comparison with the case of $100mg\;mAh^{-1}$ under the high temperature and high voltage condition. The former shows a larger increase in internal resistance than the latter, confirming that the amount of electrolyte significantly influences the discharge capacity retention characteristics of the battery.

• Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
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• 2002.02a
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• pp.114-118
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• 2002

This paper were investigated discharge characteristics in the Liquid Nitrogen($LN_{2}$) noticed as a cooling medium of high temperature superconductor, and the characteristics of surface discharge and tracking phenomena on the solid insulators of cryocable. In order to investigate the bubbles which have much influence on electric surface discharge in Liquid Nitrogen, knife type electrode and plane electrode was formed oppositely with mode A and B, C configuration. It is considered that these result are fundamental data for electric insulation design of superconductivity and cryogenic application machinery which will be studied and developed in the future.

• Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
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• 2002.02a
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• pp.5-9
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• 2002

In this paper, a relationship between AC discharge progress and the radiated electromagnetic waves was investigated by measuring electromagnetic waves using a biconical antenna and a spectrum analyzer at the atmospheric pressure in L$N_{2}$ . From the results of this study, according to the consideration of the mutual relation between frequency spectrum of the radiated electromagnetic waves and discharge progress, it was confirmed that detecting partial discharge and estimating discharge progress can be possible. It Is considered that these results obtained from this investigation may be used as the fundamental data for diagnosis and prediction of insulation on superconducting and cryogenic power equipments.

• Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
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• 2002.02a
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• pp.237-240
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• 2002

Fiberglass - reinforced plastic (FRP) can have high breakdown puncture strength and has high mechanical strength. So the research of its dielectric properties have been conducted in liquid nitrogen(L$N_{2}$). In this study, we discussed the characteristics of surface flashover on FRP in L$N_{2}$ for applying it to spacer of a superconducting power equipment. We distinguished four types of surface flashover along solid insulator with arrangement of electrodes and tested the surface flashover voltage of each types of electrode arrangement. The type of a electrode set at the back of the insulator showed the worst dielectric property.

• Proceedings of the KIEE Conference
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• 1999.07e
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• pp.2320-2322
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• 1999

This paper was studied on the surface discharge characteristics and tracking phenomena on the solid insulator in liquid nitrogen ($LN_2$) at atmospheric pressure. In order to investigate the bubbles which have much influence on electric surface discharge in liquid nitrogen, Knife type electrode and plane electrode were arranged in different modes(Mode A, Mode B, and Mode C) and investigated for surface discharge and tracking phenomena. In Mode A, by the movement of bubbles tracking damage was formed under the electrodes. The tracking pattern in Mode B was formed along the electrode axis.

• Proceedings of the KIEE Conference
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• 1998.11c
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• pp.956-958
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• 1998

In this study, a relationship between partial discharge and the radiated electromagnetic waves is investigated by measuring electromagnetic waves using a biconical antenna and a spectrum analyzer. The patterns of frequency spectrum of radiated electromagnetic waves measured at the atmospheric pressure in Liquid Nitrogen($LN_2$) during the partial discharges in nonuniform electric field depend on positive DC power. From these points of view. it is considered that these results obtained from this investigation may be used as fundamental data for diagnosis and prediction of insulation on the equipments of superconducting and cryogenic applications.

• The Transactions of the Korean Institute of Electrical Engineers C
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• v.52 no.3
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• pp.123-129
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• 2003

In this paper, a relationship between AC discharge progress and the radiated electromagnetic waves was investigated by measuring electromagnetic waves using a biconical antenna and a spectrum analyzer. The frequency spectrum of the radiated electromagnetic waves were measured at the atmospheric pressure in liquid nitrogen($LN_2$) during partial discharges progressed by AC high voltage in nonuniform electric field. Front the results of this study, a new method was introduced for measurement and analysis of the radiated electromagnetic waves with discharge progress in $LN_2$ Besides. according to the consideration of the mutual relation between frequency spectrum of the radiated electromagnetic waves and discharge progress, it was confirmed that detecting partial discharge and estimating discharge progress could be possible. It is considered that these results obtained from this investigation may be used as fundamental data for diagnosis and prediction of electric insulations about superconducting and cryogenic power equipments.

• Progress in Superconductivity and Cryogenics
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• v.4 no.1
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• pp.105-109
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• 2002

The short-term AC breakdown strength of laminated polypropylene insulating Paper (PPLP) has been studied for cold dielectric of high temperature superconductivity power cables. The design and operating conditions of the electrode system for studying of short-term breakdown strength of one-layer and multi-layer PPLP samples are discussed in liquid nitrogen(LN2) state. The influence of various operating factors (geometry and dimension of electrodes, speed of tested voltage, thickness of test sample) on the value of short-term AC breakdown strength at cryogenic temperature has been established.