• Title/Summary/Keyword: 액체이산화탄소

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Volatile flavor components of Korean ginger(Zingiber officinale Roscoe)extracted with liquid carbon dioxide (액체 이산화탄소 추출법에 의한 생강 (Zingiber officinale Roscoe)의 향기성분)

  • Kim, Myung-Kon;Na, Mun-Su;Hong, Jai-Sik;Jung, Soon-Taek
    • Applied Biological Chemistry
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    • v.35 no.1
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    • pp.55-63
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    • 1992
  • The essential oil of Korean ginger(Zingiber officinale Roscoe) was isolated by liquid carbon dioxide extraction method and fractionated into one hydrocarbon fraction and two oxygenated hydrocarbon fractions by using silica gel column chromatography. The compositions of the resulting oils were investigated by GC and GC-MS spectrometry. Out of 102 identified compounds, 44 were identified by comparing GC retention time and mass spectral data with authentic samples and 58 were tentatively identified according to mass spectral data only. The major compounds of hydrocarhon fraction were $zingiberene,\;{\beta}-sesquiphellandrene,\;{\gamma}-bisabolene,\;{\gamma}-cardinene,\;ar-curcumene$, and those of oxygenated hydrocarbon fractions wee geranal, sesquisabinene hydrate, borneol and zingiberenol. The major compounds of ginger oil were zingiberene, $citronellol+{\beta}-sesquiphellandrene,\;geranial,\;{\gamma}-bisabolene\;and\;ar-curcumene+geranyl\;acetate$, and ginger oil contained higher amounts of sesquiterpene hydrocarbons. The yield of extract was 6.96%.

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Changes of Nutrients in Media and Mycelia on Liquid Spawn Culture of Lentinula edodes (표고 액체종균 배양시 배지와 균사체의 양분변화)

  • Shim, Kyu-Kwang;Yoo, Young-Jin;Koo, Chang-Duck;Kim, Myung-Kon
    • The Korean Journal of Mycology
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    • v.42 no.2
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    • pp.144-149
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    • 2014
  • Lentinula edodes liquid spawn growth under explosive aeration (supplying air with tiny bubbles) and soybean meal addition to liquid culture medium were investigated in terms of mycelial growth and residual free sugar content. The two treatments were effective for homogeneous culturing of mycelial spawn and for separating colonies during multiplication after an exponential growth period without limiting sustaining nitrogen nutrients. The mycelial growth and carbon dioxide concentration were greatest on the 13th day since the inoculation. At 12th day, however, free sugars were almost depleted in the upper part of the liquid medium. Total nitrogen content within precipitated mycelia was the highest at the 13th day. Chitin and sucrose contents in the mycelia were the highest at the 18th day, but ergosterol content became highest at 22 days. These results suggest that Lentinula edodes liquid spawn is ready in 18 days after inoculation.

Working partial pressure of $CO_2$ gas in aqueous solution

  • Kim Dong-Su
    • Resources Recycling
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    • v.14 no.4 s.66
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    • pp.47-52
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    • 2005
  • Carbonate species in aqueous solution play an important role in the determination of chemical properties of water in relation with alkalinity, buffer capacity, biological productivity, and so on. These compounds also have reactive characteristics such as interphasal reactions between solid, liquid, and gas phases. In the absence of solid materials, the total amount and relative abundance of each carbonate species are directly influenced by the partial pressure of $CO_2$ gas in the atmosphere, which in turn significantly affects the properties of aquatic system. In the water/wastewater treatment process along with the wastes treatment and recycling process which occurring in aquatic environment, it is essential to figure out its characteristics for their optimization and one of its most influential features upon these processes is determined by carbonate species. To understand the fundamental aspect of the relationship between the partial pressure of $CO_2$ gas and chemical features of water, especially pH, the working partial pressure of pure $CO_2$ gas that produced by contacting the dry ice with water has been estimated based on equilibrium calculation. The equilibrium constants for the dissociation ot carbonic acid were determined using van't Hoff equation and the distribution diagram of carbonate species according to the pH has been constructed to substantiate the results of equilibrium calculation. The estimated working partial pressure of pure $CO_2$ gas was found to be a function of the concentration of carbonates in solution, which suggesting that Prior evaluation of the working partial pressure of gas is essential for a better understanding of aquatic interactions.

Simulation Model for Dissolution of Liquid $CO_2$ Discharged at Intermediate Depth of Ocean (중층심해에 분사된 액체 이산화탄소 용해 예측모델 개발)

  • 김남진;김종보
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.15 no.9
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    • pp.718-726
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    • 2003
  • Carbon dioxide ocean disposal is one of the promising options to reduce carbon dioxide concentration in the atmosphere because the ocean has vast capacity for carbon dioxide sequestration. However, the dissolution rate of liquid carbon dioxide in seawater must be known in advance in order to estimate the amount of carbon dioxide sequestration in the ocean. Therefore, in the present study, calculations of the solubility, the surface concentration and the dissolution behavior of carbon dioxide when liquid carbon dioxide is released at 1,000m and 1,500m in depth are peformed. The results show that the droplet is completely dissolved below 500 m in depth if the carbon dioxide droplet is released both at 1,000m in depth with the initial droplet diameter of 0.011m or less and at 1,500m in depth with the diameter of 0.016 or less. Also, the surface concentration of carbon dioxide droplet with the hydrate film is about 50% of carbon dioxide solubility at 1,500 m in depth and about 60% of carbon dioxide solubility at 1,000 m in depth.

Decontaminatin Techniques using Liquid/Supercritical $CO_2$ (액체 및 초임계 이산화탄소를 이용한 제염법)

  • 박광헌;김홍두;김학원;고문성;윤청현
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2003.11a
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    • pp.650-654
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    • 2003
  • A major problem of nuclear energy is the production of radioactive wastes. Needs for more environmentally favorable method to decontaminate radioactive contaminants make the use of liqui $d^ercritical $CO_2$ as a solvent medium. In removing radioactive metallic contaminants under $CO_2$ solvent, two methods - use of chelating ligands and that of water in $CO_2$ emulsion-are possible. In the chelating ligand method, a combination of ligands that can make synergistic effects seems important. We discuss about the properties of microemulsion formed by F-AOT and that by non-ionic surfactant. By adding acid in water core, decontamination of metallic parts, soils were possible. The rate of metal surface dissolution to the microemulsion solution was measured by QCM. The possibility of recovering the surfactants after use is also mentioned.ed.

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Numerical Study on the Ocean Sequestration of Liquid $CO_2$ (액체 이산화탄소 해양 고정화에 대한 수치적 연구)

  • Kim Nam-Jin;Chun Won-Gee;Kim Chong-Bo
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.18 no.3
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    • pp.270-278
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    • 2006
  • The idea of carbon dioxide sequestration in the ocean is proposed to be an effective mitigation strategy to counteract potential global warming due to the greenhouse effect. Therefore, in the present study, calculations of the dissolution behavior of carbon dioxide when liquid carbon dioxide is released at 1,000m and 1,500 m in depth. by fixed pipeline are peformed. The results show the liquid $CO_2$ injected in the ocean becomes $CO_2$ bubble at between 350m and 500m in depth, and the injection from a moving ship is a more effective method of dissolution than through a fixed pipeline. It so also noted that the ultimate plume generated from $CO_2$ bubbles repeats expansion and shrinking due to the peeling from a fixed pipeline.

Preliminary Study on Reaction Mechanism for Energy Generation using Hydride and Hydrogen Peroxide (수소화물과 과산화수소를 적용한 에너지 생성 메커니즘 연구)

  • Seo, Seong-Hyeon
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2012.05a
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    • pp.300-303
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    • 2012
  • Global warming has been a serious problem due to excessive emissions of carbon dioxide from the increase of energy consumption. The present study investigates an energy generation mechanism that does not produce carbon dioxide and oxides of nitrogen. A reaction mechanism including sodium borohydride and hydrogen peroxide has been introduced and as a result, thermal energy can be generated from combustion of hydrogen with oxygen. Sodium borohydride dissolved in water reacting with liquid hydrogen peroxide may reveal maximum adiabatic reaction temperature of 1795 K at a mixture ratio of 0.89.

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Control of Nano-Structure of Ceramic Membrane and Its Application (세라믹 멤브레인의 나노구조 제어 및 응용)

  • Lee, Hye-Ryeon;Seo, Bong-Kuk;Choi, Yong-Jin
    • Membrane Journal
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    • v.22 no.2
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    • pp.77-94
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    • 2012
  • Amorphous ceramic membranes have been developed for gas phase separation and liquid phase separation (water treatment, wastewater treatment and separation of organic solvent or compounds) because of their thermal stability and solvent resistance. In this paper, ceramic membranes were categorized by membrane pore size and materials, and summarized for hydrogen separation, carbon dioxide separation, membrane reactor, pervaporation and water treatment with membrane structure and properties.

Study of CO2 Absorption Characteristic and Synthesis of 1-(2-methoxyethyl)-3-methylimidazoLium Methanesulfonate Ionic Liquid (1-(2-methoxyethyl)-3-methylimidazolium Methanesulfonate 이온성 액체 합성 및 CO2 흡수 특성 연구)

  • Jin, Yu Ran;Jung, Yoon Ho;Park, So Jin;Baek, Il Hyun
    • Korean Chemical Engineering Research
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    • v.50 no.1
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    • pp.35-40
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    • 2012
  • In this study, 1-(2-methoxyethyl)-3-methylimidazolium methanesulfonate ionic liquid has been synthesized, characterized and tested with respect to carbon dioxide absorption with the aim to use it as advanced absorbent materials in fossil fuel processing. The ionic liquid was synthesized by a one step method, low cost. The thermal and chemical stability of selected ionic liquid has been investigated by DSC, TGA and the structure was verified by $^1H$-NMR spectroscopy. The solubility of carbon dioxide in the methanesulfonate-based ionic liquids were measured using a high-pressure equilibrium apparatus equipped with a variable-volume view cell at 30, 50 and $70^{\circ}C$ and pressure up to 195 bar. The results show that carbon dioxide solubilities of 1-(2-methoxyethyl)-3-methylimidazolium methanesulfonate increased with pressure increasing and temperature decreasing, and the carbon dioxide absorption capacity showed 27.6 $CO_2/IL$(g/kg) at $30^{\circ}C$, 13 bar.