• Title/Summary/Keyword: 액상탄산화

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An experimental study on preparation of precipitated calcium carbonate using Ca component dissolution characteristics and liquid carbonation by the Industrial byproducts (산업부산물의 Ca 성분 용출 특성 및 액상탄산화 반응을 이용한 침강성 탄산칼슘 제조에 관한 실험적 연구)

  • Lim, Yun-Hui;Lee, Ju-Yeol;Shin, Jae-Ran;Choi, Chang-Sik;Hong, Bum-Ui;Kang, Ho Jong;Park, Byung Hyun
    • Journal of the Korean Applied Science and Technology
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    • v.32 no.1
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    • pp.116-126
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    • 2015
  • The present study utilized a shuttle mechanism of wet chemical absorption using MEA. In addition, industrial by-products containing a large amount of inorganic alkali substances were utilized for wet carbonization process. Chemical pretreatment of industrial by-products extracted calcium ions. ICP result of calcium ion was obtained up to 17,900 ppm(17.9%) by acidic substance. And also, In this work, 94% of recovery rate was obtained using wet MEA absorption process from $CO_2$ flow at the ambient condition. Through the liquid carbonation process, a sludge was fixed with rate of 0.175 mg of $CO_2$ per mg of sludge. It was found from XRD results that the structure of final product was composed of a calcite structure which is general structure of $CaCO_3$.

Study on preparation of precipitated calcium carbonate using recycling water of ready-mixed Concrete (레미콘 회수수를 이용한 침강성 탄산칼슘 제조에 관한 연구)

  • Shin, Jae Ran;Kim, Jae Gang;Kim, Hae Gi;Kang, Ho Jong
    • Journal of the Korean Applied Science and Technology
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    • v.33 no.2
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    • pp.232-238
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    • 2016
  • In this study, a liquid carbonation method was applied for producing precipitate calcium carbonate by liquid-liquid reaction. Also a shuttle mechanism of wet chemical absorption using MEA was utilized. The high concentration $CO_2$(A) and exhaust gas(B) was used for collecting carbon dioxide in the 30% MEA aqueous solution, and $CO_2$ was fixed with rate of 0.35 mg of $CO_2$ per mg of sludge through the liquid carbonation process. It was found from SEM data that calcium carbonate was mainly made up with spherical vaerite with the mixing of a small quantity of calcite.

Study on optimization of liquid carbonation pilot plant (system) using sludge water of ready-mixed concrete (레미콘회수수를 이용한 액상탄산화 Pilot plant(System) 최적화에 관한 연구)

  • Kim, Jae Gang;Shin, Jae Ran;Kim, Hae Gi;Kang, Ho Jong
    • Journal of the Korean Applied Science and Technology
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    • v.33 no.2
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    • pp.239-246
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    • 2016
  • In this study, recycling sludge water of Ready-mixed concrete, and was carried out to optimize the system for recycling of the $CO_2$. The most important process in the liquid phase using a carbonation reaction can be recovered ready-mixed concrete is a process for the $Ca^{2+}$ release. $Ca^{2+}$ concentration of the experiment relative to the pH being lowered by the acidic substance during elution was performed. $CO_2$ was trapped in the MEA solution using a generator flue gas. In ready-mixed concrete can be synthesized $CaCO_3$ up to 11kg/1ton. The resulting $CaCO_3$ analysis results show that it is possible to use paper industry.

A study on the reaction of carbonation in the preparation of lithium carbonate powders (탄산리튬 분말 제조에 있어서 탄산화 반응에 관한 연구)

  • Yang, Jae-Kyo;Jin, Yun-Ho;Yang, Dae-Hoon;Kim, Dae-Weon
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.29 no.5
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    • pp.222-228
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    • 2019
  • In this study, we carried out the experiment to prepare lithium carbonate powder through gas-liquid reactions with a lithium-containing solution and $CO_2$ gas using lithium hydroxide, lithium chloride, and lithium sulfate. Thermodynamically, the carbonation reaction of a lithium-containing solution showed that aqueous reaction of lithium hydroxide occurs spontaneously, but aqueous reactions of lithium chloride and lithium sulfate does not occur spontaneously. In the case of lithium hydroxide solution, the recovery rate of lithium carbonate was 69.8 % at room temperature ($25^{\circ}C$), and increased to 89.4 % at $60^{\circ}C$. In the case of lithium chloride and lithium sulfate solution, lithium carbonate could be prepared using sodium hydroxide as an additive, but the recovery rates were 19.2 % and 16.7 %, respectively.

Flow Regime Transition in Air-Molten Carbonate Salt Two-Phase Flow System (공기-탄산용융염 이상흐름계에서의 흐름영역전이)

  • Cho, Yung-Zun;Yang, Hee-Chul;Eun, Hee-Chul;Kang, Yong
    • Korean Chemical Engineering Research
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    • v.47 no.4
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    • pp.481-487
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    • 2009
  • In this of study, effects of input air velocity(0.05~0.22 m/sec) and molten carbonate salt temperature ($870{\sim}970^{\circ}C$) on flow regime transition have been studied by adopting a drift-flux model of air holdup and a stochastic analysis of differential pressure fluctuations in an air-molten sodium carbonate salt two-phase system(molten salt oxidation process). Air holdup where the flow regime transition begins was determined by air holdup-drift flux plot. The air holdup value which the flow regime transition begins was increased with increasing molten carbonate salt temperature due to the decrease of viscosity and surface tension of molten carbonate salt. To characterize the flow regime transition more quantitatively, differential pressure fluctuation signals have been analyzed by adopting the stochastic method such as phase space portraits and Kolmogorov entropy, The Kolmogorov entropy decreased with an increasing of molten carbonate salt temperature but increased gradually with an increase in an air velocity, however, it exhibited different tendency with the flow regime and the air velocity value which flow regime transition begins was same to the results of drift-flux analysis.

Study on liquid carbonation using the recycling water of ready-mixed concrete (레미콘회수수를 이용한 액상탄산화에 관한 연구)

  • Lim, Yun-Hui;Lee, Ju-Yeol;Choi, Chang-Sik;Hong, Bum-Ui;Park, Jin-Won;Lee, Dae-Young;Park, Byung-Hyun
    • Journal of the Korean Applied Science and Technology
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    • v.30 no.4
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    • pp.770-778
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    • 2013
  • In this study, a liquid carbonation method was applied for producing precipitate calcium carbonate by liquid-liquid reaction. We recycled the recycling water of ready-mixed concrete, one of construction waste for use source of carbonate ion. A supernatant separated from the recycling water of ready-mixed concrete, as a result of ICP analysis of a cation, $Ca^{2+}$ was contained up to 1100 ppm. We used MEA as a $CO_2$ absorbent for the liquid carbonation. A precipitate $CaCO_3$ was produced at more than MEA 20 wt%. The precipitate $CaCO_3$ as a final product was separated and dried. The result of XRD was confirmed the generation of $CaCO_3$ to calcite structure.

A Study on the Synthesis of Potassium Hexatitanate Whisker by the Slow Cooling Calcination Process (서냉 소성법에 의한 육티탄산칼륨 Whisker의 합성에 관한 연구)

  • Lee, Chul-Tae;Choi, Ung-Su;Kim, Young-Myoung
    • Applied Chemistry for Engineering
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    • v.5 no.1
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    • pp.160-175
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    • 1994
  • Fibrous potassium hexatitanate whisker with the size of $ID=0.5{\sim}1{\mu}m$ and length=$100{\sim}1000{\mu}m$ (aspect ratio=100~1000) was produced through the reaction between titanium dioxide and potassium carbonate using the slow-cooling calcination followed by water leaching treatment. The optimum condition for the production of fibrous potassium titanate was calcination temperature of $1100^{\circ}C$ for 5hrs, $TiO_2$ mole ratlo to $K_2CO_3$ of 4.5 and slow-cooling rate of $0.5^{\circ}C/min$ to $860^{\circ}C$. Fibrous crystal are grown by the association between the solid potassium titanate and liquid phase during the slow-cooling process. The Proper water leaching condition for removing of K component was leaching time of 10hrs in boiling water. Pressurizing of the mixture of $K_2CO_3$ and $TiO_2$ to be calcinated became effective on the growth of fibrous crystal.

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A Study on the Performace Evaluation of Antimicrobial Concrete Using Liquid Reinforcing Antibiotics (액상 수밀성 항균제를 사용한 항균 콘크리트의 성능 평가에 관한 연구)

  • Kim, Gyu-Yong;Kim, Moo-Han;Lee, Eui-Bae;Cho, Bong-Suk;Khil, Bae-Su
    • Journal of the Korea Concrete Institute
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    • v.19 no.1
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    • pp.113-120
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    • 2007
  • In this study, researches for the development of antibiotics and antimicrobial concrete were conducted to reduce biochemical corrosion of sewage concrete. First of all, desired performance, such as watertightness, antibiosis, homogeneity, workability and harmlessness, was proposed and performance of antibiotics and antimicrobial concrete were evaluated by them. As results of this study, dispersibility and antibiosis of liquid antibiotics superior to powdery antibiotics. Antibiosis of antimicrobial concrete was verified, and amount of elution of harmful and effective ingredients was little. In workability, setting time of antimicrobial concrete was delayed. Compressive strength and resistance to carbonation of antimicrobial concrete were more increased than ordinary concrete. Also, as little pore volume and closed structure of antimicrobial concrete were observed, watertightness of it was verified. Finally artificial accelerating test for biochemical corrosion was proposed, and its suitability was experimentally proved.

Mobile application-based dietary sugar intake reduction intervention study according to the stages of behavior change in female college students (모바일 어플리케이션 기반 당류 저감화 중재 프로그램의 행동변화단계에 따른 효과 분석 : 일부 여대생 대상 연구)

  • Choi, Yunjung;Kim, Hyun-Sook
    • Journal of Nutrition and Health
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    • v.52 no.5
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    • pp.488-500
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    • 2019
  • Purpose: This study examined the effects of a mobile app-based program to reduce the dietary sugar intake according to the stages of the behavioral change in dietary sugar reduction in female college students. Methods: The program used in this study can monitor the dietary sugar intake after recording the dietary intake and provide education message for the reduction of dietary sugar intake. In an eight-week pre-post intervention study, 68 female college students were instructed to record all the food they consumed daily and received weekly education information. At pre-post intervention, the subjects were asked to answer the questionnaire about sugar-related nutrition knowledge, sugar-intake behavior, and sugar-intake frequency. For statistical analysis, ANOVA and a paired t-test were used for comparative analysis according Precontemplation (PC), Contemplation Preparation (C P), and A M (Action Maintenance) stage. Results: Significant differences were observed in the frequency of snacking, experience of nutrition education, and preference for sweetness according to the stages of behavior change in dietary sugar reduction. After finishing an intervention, the sugar-related nutrition knowledge score was increased significantly in the stages of Precontemplation (PC) and Contemplation Preparation (C P). The score of the sugar intake behavior increased significantly in all stages. The intake frequency of chocolate, muffins or cakes, and drinking yogurt decreased significantly in the PC stage and the intake frequency of biscuits, carbonated beverages, and fruit juice decreased significantly in the C P stage. Subjects in the PC and C P stages had an undesirable propensity in nutrition knowledge, sugar-intake behavior, and sugar-intake frequency compared to the A M stage, but this intervention improved significantly their nutrition knowledge, sugar-intake behavior, and sugar-intake frequency. Conclusion: This program can be an effective educational tool in the stages of PC and C P, and is expected to further increase the usability and sustainability of mobile application if supplemented appropriately to a health platform program.

Agricultural application of natural polymers chitin and chitosan (천연고분자 키틴·키토산의 농업적 활용)

  • Jung, Woo-Jin
    • Food Science and Industry
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    • v.53 no.1
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    • pp.33-42
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    • 2020
  • In accordance with the recent trend of environmentally friendly agricultural policy, product registration of agricultural chitosan among the organic materials has been displayed in various forms such as soil improving agent, crop growth, and pest control. Chitin production industry is expected to bring competitiveness by producing low-quality and low-cost chitin for agriculture, rather than high-quality and high-cost for food, medical products. Since there are various soil microorganisms that can decompose chitin and chitosan in farm soil where crops are produced, it can be applied usefully to agricultural sites suitably for crop growth and pest control using chitin and chitosan as substrates. The purpose of this study is to compare and analyze the registration status of organic materials companies using chitin and chitosan raw materials in the organic materials information system of the NAQS, and to provide an opportunity to further expand the agricultural use of domestic chitin and chitosan.