• Title/Summary/Keyword: 암모니아성 질소

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Ammonia-nitrogen Removal in Sea Water by Using Electrolysis (전기분해법에 의한 해수내의 암모니아성 질소 제거)

  • 이병헌;이제근;길대수;곽순열
    • Journal of Aquaculture
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    • v.10 no.4
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    • pp.435-438
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    • 1997
  • Biological ammonia removal system have been used conventionally for the seawater fish farming. But this process requires long hydraulic retention times and large area. Also it has a trouble of NO3-N accumulation in the system. Therefore, this study was conducted to find out the feasibility of effective nitrogen removal efficiency in the sea water fish farming system by electolysis. As the result, electrolysis system showed a good ammonia and nitrate nitrogen removal and E. coli sterilization efficiencies. Because of the high salinities in the seawater for electron transfer, electrolysis is an effictive water treatment process for seawater fish farming. The relation among ammonia removal efficiency, hydraulic retention time (HRT) and electric wattage (watt) with 10 mm electrod distance isas follow ; log [$NH_4^$+-N(%)]=0.431log(HRT(sec)$\times$Watt)+0.88(r=0.950) And the relation between ammonia removal efficiency and residual chlorine concentration in the seawater is as follow; $$NH_4^+-N(%)=48\cdotlog[Residual\;chlorine(mg/\ell)+28(r=0.892)$$

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Anaerobic Ammonium Oxidation(ANAMMOX) in a Granular Sludge Reactor and its Bio-molecular Characterization (입상 슬러지 반응조 내의 혐기성 암모늄 산화(ANAMMOX) 및 분자생태학적 특성 평가)

  • Han, Ji-Sun;Park, Hyun-A;Sung, Eun-Hae;Kim, Chang-Gyun;Yoon, Cho-Hee;Bae, Young-Shin
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.11
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    • pp.1213-1221
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    • 2006
  • In this study, granular sludge used in an anaerobic process treating brewery waste was inoculated in a laboratory scale of reactor to induce anaerobic ammonium oxidation(ANAMMOX). The reactor was operated with synthetic wastewater, which prepared at 1:1 ratio of $NH_4^+-N$ over $NO_2^--N$. Changes in nitrogen concentration, COD, alkalinity and gas production were analyzed. There are 3 phases of spanning in experimental period according to influent nitrogen concentration. In the Phase 1, each of the concentration of $NH_4^+-N$ and $NO_2^--N$ were increased from 1.91 $gN/m^3{\cdot}d$ to 14.29 $gN/m^3{\cdot}d$. Ammonium nitrogen loading(same as nitrite nitrogen) was 23.81 $gN/m^3{\cdot}d$ in the Phase 2 and 19.05 $gN/m^3{\cdot}d$ in the Phase 3, respectively $NO_2^--N$ has been removed up to 99% during whole period while the removal efficiency of $NH_4^+-N$ was significantly varied. In Phase 2, $NH_4^+-N$ was removed up to 75%. Microorganisms varied temporally through three phases were characterized by 16s rDNA analysis methods. ANAMMOX bacteria were dominantly found in phase 2 when the removal rate of $NO_2^--N$and $NH_4^+-N$ was the highest up to 99% and 75%, respectively. Due to erroneous exposed to air, the removal efficiency of $NH_4^+-N$ was unexpectedly lowered, but ANAMMOX bacteria still existed.

양어장수의 암모니아 제거시 포괄고정화 미생물의 질산화 속도식 도출

  • 이정훈;김병진;서근학
    • Proceedings of the Korean Society of Fisheries Technology Conference
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    • 2001.05a
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    • pp.324-325
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    • 2001
  • 총 암모니아성 질소(TAN)은고밀도 양식에서 한계요소로 작용하는 수질인자 중의 하나이다. 생물학적 암모니아 처리공정의 효율적인 설계를 위해서는 생물반응기의 암모니아 제거속도식을 구하여 처리시스템의 최적 용량을 구하여야 한다. 그러나 현재까지 진행된 고정화 미생물을 이용한 암모니아 제거공정에 대한 연구는 고정화 재질의 특성이나 장치의 운전효율에 대한 것으로 속도식에 대한 연구는 부족하다. (중략)

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Determination optimal ratio of ammonium to nitrite in application of the ANAMMOX process in the mainstream (Mainstream ANAMMOX 공정 적용시 암모니아성 질소 대비 아질산성 질소 비율 도출 연구)

  • Lee, Dawon;Lee, Jiwon;Gil, Kyungik
    • Journal of Wetlands Research
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    • v.23 no.1
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    • pp.60-66
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    • 2021
  • As the concentration of nitrogen in the sewage flowing into the sewage treatment plant increases due to urbanization and industrialization, the degree of adverse effects such as eutrophication and toxicity to the aquatic ecosystem is also increasing. In order to treat sewage containing high concentration of nitrogen, various studies on the biological nitrogen removal process are being conducted. Existing biological nitrogen removal processes require significant costs for supplying oxygen and supplementing external carbon sources. In this respect, as a high-level nitrogen removal process with economic improvement is required, an anaerobic ammonium oxidation process (ANAMMOX), which is more efficient and economical than the existing nitrification and denitrification processes, has been proposed. The purpose of this study is to confirm the stability of the ANAMMOX process in the water treatment process and to derive the ratio of ammonia nitrogen (NH4+) to nitrite nitrogen (NO2-) for the implementation of the mainstream ANAMMOX process. A laboratory-scale Mainstream ANAMMOX reactor was operated by applying the ratio calculated based on the substrate ratio suggested in the previous study. In the initial range, the removal efficiency of NH4+ was 58~86%, and the average removal efficiency was 70%. In the advanced range, the removal efficiency of NH4+ was 94~99%, and the average removal efficiency was 95%. As a result of the study, as the NH4+/NO2- ratio increased, the stability of the mainstream ANAMMOX process was secured, and it was confirmed that the NH4+ removal efficiency and the total nitrogen (TN) removal efficiency increased. As a result, the results of this study are expected to be used as basic data in the application of the ANAMMOX process in the mainstream.

Removal of NH(sub)3-N by Using Immobilized Nitrifier Consortium in PVA[Polyvinyl Alcohol]-I. Effect of Packing Fraction and Aeration Rate on Ammonia Nitrogen Removal (PVA에 고정화된 질화세균군에 의한 암모니아성 질소 제거 I. 충진율 및 공기 유입량이 암모니아성 질소제거에 미치는 영향)

  • 서근학;김병진;오창섭
    • KSBB Journal
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    • v.16 no.3
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    • pp.314-319
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    • 2001
  • A nitrifier consortium immobilized in polyvinyl alcohol was used to remove ammonia nitrogen from synthetic wastewater in an airlift bioreactor. The minimum aeration rates were 0.4, 0.6, 0.8 and 1.0 vvm for 5, 10, 15 and 20% immobilized bead packing volume fraction, respectively. The efficient packing fraction and the aeration rate for ammonia nitrogen removal were 15% and 2.4 vvm, respectively. With a hydraulic retention time of 0.5hr, the removal rate and the efficiency of ammonia nitrogen removal were 1685 g/㎥$.$day and 48% at an influent ammonia nitrogen concentration of 75 g/㎥.

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Effects of Operating Parameters on the Removal Performance of Ammonia Nitrogen by Electrodialysis (전기투석에 의한 암모니아성질소의 제거 시 운전인자의 영향)

  • Yoon, Tae-Kyung;Lee, Gang-Choon;Jung, Byung-Gil;Han, Young-Rip;Sung, Nak-Chang
    • Clean Technology
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    • v.17 no.4
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    • pp.363-369
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    • 2011
  • To evaluate the feasibility of electrodialysis for ammonia nitrogen removal from wastewater, the effects of operating parameters such as diluate concentration, applied voltage and flow rate on the removal of ammonia nitrogen were experimentally estimated. The removal rate was evaluated by measuring the elapsed time for ammonia nitrogen concentration of diluate to reach 20 mg/L. Limiting current density (LCD) linearly increased with ammonia nitrogen concentration and flow rate. The elapsed time was linearly proportional to initial concentration of diluate. Due to relatively large equivalent ion conductivity and ion mobility of ammonia nitrogen, the removal rate increased consistently with flow rate. Increase in the applied voltage gave positive effect to removal rate. From the operation of the electrodialysis module used in this research, the flow rate of 3.2 L/min and 80~90% of applied voltage for LCD are recommended as the optimum operating condition for the removal from high concentrate ammonia nitrogen solution.

Night Soil Treatment by Anaerobic Sequencing Batch Reactor (혐기성 연속 회분식 반응조에 의한 분뇨처리)

  • 허준무;박종안
    • Journal of environmental and Sanitary engineering
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    • v.15 no.2
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    • pp.75-84
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    • 2000
  • 운전 온도 $35^{\circ}C$, 평균 유기물부하 $3.1{\;}kgCOD/m^3/day$ 및 수리학적체류시간 10일에서 혐기성 연속회분식공정에 의한 분뇨처리를 수행하였다. 공정의 평가는 대조 소화조로 완전혼합형의 소화조와 병행하여 수행되었다. 본 실험에서 분뇨는 고농도의 암모니아성 질소와 침전성 고형물을 함유하고 있음에도 불구하고 희석 없이 소화가 가능하였다. 혐기성 연속회분식공정에서 고형물은 급속하게 증가하여 완전혼합형의 대조 소화조에 비하여 소화조내 고형물(biomass)의 농도가 2.4배로 증가하였고, 가스발생량에 있어서도 대조 소화조에 비해 현격한 증가를 보였으며 그 증가율은 205~220%에 달했다. 부가적인 침전 시설이 없이도 혐기성 연속회분식공정의 유출수질이 대조 소화조 보다 높게 나타났는데 상징액 기준으로 휘발성고형물 제거율은 혐기성 연속회분식공정이 대조 소화조 보다 12~14% 높았다. 한편, 혐기성 연속회분식공정의 운전인자로 반응/침강비(R/T ratio)를 조사한 결과 R/T비가 1인 경우가 3의 경우보다 가스발생량, 메탄함량 및 유기물 제거율이 약간 높았으나 큰 차이는 없었다. 위의 실험결과들로부터 혐기성 연속회분식공정은 고농도의 암모니아성 질소와 침전성 유기물을 함유하고 있는 분뇨의 처리에 효과적이고 안정적인 공정으로 판단된다.

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