• Title/Summary/Keyword: 암모니아성 질소

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A Basic Study on the Simultaneous Removal of Ammonium and Nitrate using Zeocarbon (제오카본을 이용한 암모니아성 질소와 질산성 질소 동시 제거에 관한 기초 연구)

  • Kim, Seo-A;Hong, Ji-Sook;Suh, Jeong-Kwon;Kang, Ho;Lee, Jung-Min
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.1
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    • pp.109-114
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    • 2005
  • The objective of this study is to investigate the possibility for water treatment, and to evaluate the efficiency of simultaneous removal of ammonium and nitrate by the surface modified zeocarbon. The surface modification was done by acid treatment using HCl. As a result of modification, strength of the modified zeocarbon was enhanced about 62% higher than that of in original one. This indicates that the modified zeocarbon was suitable for the application of water treatment. In the removal experiments of ammonium and nitrate, the removal efficiency showed about two times higher in the modified zeocarbon and the dependences of pH and temperature were found to be minimized. This indicates that the modified zeocarbon was effective for simultaneous removal of ammonium and nitrate from aqueous solution. Consequently, our results could be used as basic data to design of one-stage ammonium/nitrate simultaneous removal system.

Removal of Low Concentration Ammonia Nitrogen using a Packed Bed Bioreactor Immobilized with Nitrifier Consortium (질화세균을 고정화한 충전층 생물반응기에서 저농도 암모니아성 질소 제거)

  • Lee, Chang-Keun;Kim, Byong-Jin;Lee, Min-Su;Kim, Yong-Ha;Suh, Kuen-Hack
    • Clean Technology
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    • v.13 no.1 s.36
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    • pp.16-21
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    • 2007
  • This study estimated the effect of hydraulic residence time(HRT), influent total ammonia nitrogen(TAN) concentration, temperature and pH in the packed-bed bioreactor using immobilized nitrifiers. Removal rate of ammonia nitrogen was increased with decreasing HRT and the optimum HRT was 0.2 hour when influent TAN was $2g/m^3$. At this point, removal rate was $226.1\;g/m^3{\cdot}day$ and removal efficiency was 88.8%. Removal rate of ammonia nitrogen was Increased with increasing TAN concentration. Removal rate and efficiency of ammonia nitrogen were kept constant at $20{\sim}35^{\circ}C$ and pH $8{\sim}9$ value.

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Removal of Ammonia-Nitrogen Contained in Landfill Leachate by Ammonia Stripping(I) (암모니아 탈기공정을 이용한 침출수의 암모니아성 질소제거(I))

  • Lee, Byung-Jin;Cho, Soon-Haing
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.10
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    • pp.1893-1904
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    • 2000
  • Nitrogen compounds are one of the major pollutants which cause eutrophication problems of the river or lake and red tides problems of the ocean. Currently available technologies for the removal of nitrogen compounds are mostly biological treatment. However, biological treatment is only effective for the wastewater which contains low concentration of nitrogen compounds. Leachate from solid waste landfill or industrial wastewater which contains high concentration of nitrogen can not be effectively treated by most of the currently available biological treatment technologies. With this connection. the objective of this study is to examine the applicability of ammonia stripping technology for the removal of high concentration of ammonia nitrogen compounds of the leachate from solid waste landfill. It can be concluded that ammonia stripping technology which was placed before the biological treatment process was very effective for the removal of high concentration of ammonium compounds. The chemical cost for the ammonia stripping was 16 percent higher than MLE process, so other methods like sludge recycling are needed for the reduction of operation cost. Further details are discussed in this paper.

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Removal of Ammonium and Nitrate Nitrogens from Wastewater using Zeolite (제올라이트를 이용한 수중의 암모니아성 및 질산성 질소 제거에 관한 연구)

  • Kim, Choong Gon
    • Journal of the Korea Organic Resources Recycling Association
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    • v.24 no.1
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    • pp.59-63
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    • 2016
  • The objective of this study lies in identifying the applicability of zeolite for the removal of wastewater ammonium and nitrate nitrogens. To this end, the author tracked adsorption variations as seen with the adsorption removal of wastewater ammonium and nitrate nitrogens. As a result, it was indicated that the maximum adsorption of zeolite acting on the adsorption removal of ammonium nitrogen would reach 120mg/g (weight of ammonium nitrogen divided by that of zeolite), and that Langmuir adsorption isotherm explained the adsorption of ammonium and nitrate nitrogens better than Freundlich adsorption isotherm. This means that zeolite makes ion exchanges with adsorbate for unilayer adsorption. It was also indicated that the removal efficiency of ammonium nitrogen with varying pH would be higher in the order of pH7 > pH5 > pH9 > pH3.

Parameters Affecting Nitrite Accumulation in Submerged Biofilm Reactor (생물막 반응기에서 아질산성 질소의 축척에 미치는 영향인자)

  • Hwang, Byung-Ho;Hwang, Kyung-Yub;Choi, Eui-So
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.10
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    • pp.1789-1797
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    • 2000
  • The objective of this study was to assess parameters affecting nitrite accumulation, which offers advantages in terms of less aeration energy and carbon consumption for denitrification. The influence of the alkalinity to $NH_4{^+}-N$ concentration ratio, pH, FA(free ammonia) concentration and temperature on nitrite accumulation was investigated. The experiment was performed with supernatant from dewatering process of anaerobic digested sludge using a submerged biofilm reactor. The influent contains high strength of ammonium nitrogen and the alkalinity was insufficient for complete nitrification. An increased nitrite accumulation was observed with increase in alkalinity to $NH_4{^+}-N$ concentration ratio. The increase in alkalinity to $NH_4{^+}-N$ concentration ratio has been a maior reason for the high pH value and FA concentration in the reactor. It can be considered that selective inhibition of Nitrobacter can be causes of nitrite accumulation. The nitrite accumulation increased with increment of temperature at fixed alkalinity to $NH_4{^+}-N$ concentration ratio.

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Recycling Water Treatment of Aquaculture by Using Three Phase Fluidized Bed Reactor (삼상유동층 반응기를 이용한 양어장 순환수 처리에 관한 연구)

  • LEE Byung-hun;KIM Jeong-sook;KANG Im-suk
    • Journal of Aquaculture
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    • v.7 no.3
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    • pp.177-187
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    • 1994
  • The objective of the present study were to evaluate nitrification characteristics and determine optimum treatment conditions of three phase fluidized bed reactor for recycling water treatment of aquaculture. When the loading rates were 2.739-0.086kg $COD/m^3/day$ and 1.575-0.128kg $NH_4\;^+-N/m^3/day$, COD and ammonia removal efficiencies were $56.3-94.7\%\;and\; 67.3­92.6\%$, respectively. The maximum removal rates of COD and ammonia were 1200mg/l/day and 488mg/l/day, respectively. Ammonia removal rates were more than $90\%$ beyond 1hr HRT. The ammoniaremoval efficiency was sensitive to the variation of media concentration and air flowrate.

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Ammonia Removal by using RBC in Recirculating Aquaculture System (RBC를 이용한 양어장수 암모니아 제거)

  • KIM Byong-Jin;LIM Sung-Il;SUH Kuen-Hack
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.31 no.5
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    • pp.622-630
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    • 1998
  • Rotating Biological Contactor (RBC) was tested for the removal of total ammonia nitrogen (TAN) by using simulated aquaculture system. RBC performance was evaluated by controlling revolution rate of disk and hydraulic residence tile (HRT). The optimum revolution rate of disk was 4 rpm, As HRT of RBC was increased, TAN removal efficiency of RBC and TAN concentration of rearing water were increased. HRT for maintaining lowest TAN concentration of rearing water was 9.5 minutes and at that condition TAN concentration of rearing tank was $1.03 g/m^3$

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Transformation of Nitrogen in the Form of Nitrate into Ammonia by Electrochemical Reaction (전기화학적 반응을 이용한 질산성 질소의 암모니아성 질소로 전환)

  • Lee, Jae Kwang;Kim, Doyeon;Tak, Yongsug
    • Korean Chemical Engineering Research
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    • v.46 no.5
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    • pp.1013-1016
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    • 2008
  • Nitrogen in the form of nitrate was electrochemically reduced with different cathode materials including Fe, Ni, Cu, and Zn. Zn cathode shows the greatest electrocatalytic activity on the transformation of nitrate ions into ammonia and the $NO_3^-$ removal efficiency has highest value at pH 8.5. Nitrogen in the form of nitrate was initially reduced into nitrite and sequentially, converted into nitrogen inside $NH_3$. Nitrogen in the form of ammonia was completely removed by the reaction with HOCl.

Application of Ferrate (VI) for Selective Removal of Cyanide from Plated Wastewater (도금폐수 중 시안(CN)의 선택적 제거를 위한 Ferrate (VI) 적용)

  • Yang, Seung-Hyun;Kim, Younghee
    • Clean Technology
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    • v.27 no.2
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    • pp.168-173
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    • 2021
  • The treatment of plated wastewater is subject to various and complex processes depending on the pH, heavy metal, and cyanide content of the wastewater. Alkali chlorine treatment using NaOCl is commonly used for cyanide treatment. However, if ammonia and cyanide are present simultaneously, NaOCl is consumed excessively to treat ammonia. To solve this problem, this study investigated 1) the consumption of NaOCl according to ammonia concentration in the alkaline chlorine method and 2) whether ferrate (VI) could selectively treat the cyanide. Experiments using simulated wastewater showed that the higher the ammonia concentration, the lower the cyanide removal rate, and the linear increase in NaOCl consumption according to the ammonia concentration. Removal of cyanide using ferrate (VI) confirmed the removal of cyanide regardless of ammonia concentration. Moreover, the removal rate of ammonia was low, so it was confirmed that the ferrate (VI) selectively eliminated the cyanide. The cyanide removal efficiency of ferrate (VI) was higher with lower pH and showed more than 99% regardless of the ferrate (VI) injection amount. The actual application to plated wastewater showed a high removal ratio of over 99% when the input mole ratio of ferrate (VI) and cyanide was 1:1, consistent with the molarity of the stoichiometry reaction method, which selectively removes cyanide from actual wastewater containing ammonia and other pollutants like the result of simulated wastewater.

Correlation between operation factors and nitritation using anaerobic digester supernatant at ordinary temperature (상온 조건에서 혐기 소화 상징액을 이용한 아질산화 반응과 운전 인자의 상관성 분석)

  • Im, Jiyeol;Gil, Kyungik
    • Journal of Wetlands Research
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    • v.18 no.3
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    • pp.244-249
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    • 2016
  • Anaerobic digester supernatant including high concentrations of nitrogen is recycled to water treatment line and make pollutant load increase in municipal wastewater treatment plant(MWTP). To treat nitrogen in anaerobic digester supernatant is suggested the method of MWTP retrofit. In this study, the lab scale reactor was operated about 200 days using supernatant of anaerobic digester. The results could draw operation condition that ammonium nitrogen removal efficiency more than 90% and nitrite conversion efficiency over 70%. Correlation between operation efficiency and operation factors was analyzed based on the operation results. Ammonium nitrogen remove efficiency and nitrite conversion efficiency were related to solid retention time (SRT), ammonium nitrogen load and ammonium nitrogen loading per unit mixed liquer suspended solid (MLSS). Results of this study can be used effective data on nitritation of supernatant of anaerobic digester, and be expected to increase availability of nitritation.