• Title/Summary/Keyword: 알칼리-실리카 반응

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A Feasibility Study on the Application of Ferrosilicon By-Product in Concrete to Replace Silica Fume (콘크리트 내 실리카퓸을 대체하기 위한 페로실리콘 산업부산물의 활용 적절성에 대한 연구)

  • Kim, Hansol;Cho, Won Jung;Ann, Ki Yong
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.4
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    • pp.413-422
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    • 2019
  • A ferrosilicon (FS) by-product was applied into a cementitious binder in concrete substituting the ordinary Portland cement (OPC). The original material characteristic of FS is very identical to silica fume (SF) regarding chemical composition and physical properties such as specific surface area and specific gravity. Therefore, the FS and SF concrete or mortal of which 10% of the material was replaced to total binder weight were fabricated to evaluate the feasibility of using F S as a binder, and the comparative information of OPC, FS and SF concrete was given. The hydration characteristic of FS concrete was analyzed using X-ray diffraction analysis. The FS concrete was beneficial in compressive strength, resistivity against chloride ingress and reducing porosity considering performance of OPC concrete but the advantage was less than using SF. A possibility of alkali-silica expansion was found out from the FS concrete due to the agglomerated size of the silica particles.

An Experimental Study on the Alkali-Silica Reaction of Crushed Stones (Part4: The Application of the JIS Rapid Test Method to the Several Domestic Reactive Aggregates) (쇄석골재의 알칼리-실리카 반응에 관한 실험적 연구 (제4보: 국내산 반응성 골재에 JIS 신속법 적용가능성))

  • 차태환;조원기;조일호;노재호;이양수;정재동;윤재환
    • Proceedings of the Korea Concrete Institute Conference
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    • 1994.10a
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    • pp.447-450
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    • 1994
  • The chemical method and mortar-bar method for identification of the susceptibility to Alkali-Aggregate Reaction (AAR) was established as KS method by referencing the ASTM methods. However, the chemical method requires skilled chemical engineers and aggregates are tested in very severe condition, and on the other hand, the mortar-bar method needs a long time of 3 or 6 months. Judging from this circumstance that the use of crushed stones are increased due to the shortage of natural aggregates, the development and standardization of a new rapid test method is considered essential. The purpose of this paper is to research for the possibility to apply the rapid method, instead of the chemical method and the mortar-bar method with using the several domestic crushed stones.

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Effects of Content of Reactive Aggregate on Alkali-Silica Reaction Expansion (반응성 골재의 혼입량이 모르타르의 알칼리-실리카 반응 팽창에 미치는 영향)

  • Lee Ju Hyun;Jun Ssang Sun;Um Jang Sub;Jin Chi Sub
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.11a
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    • pp.435-438
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    • 2005
  • The effect of content of reactive aggregate on alkali-silica reaction was investigated through the ASTM C 1260 method. The replacement proportions of fine aggregate by reactive aggregate were 25, 50, 75 and $100\%$, respectively. Reactive aggregate and fine aggregate(non-reactive aggregate) used are a metamorphic rock and andesite rock, respectively. The results indicate that the mortar-bar containing $25\%$ replacement of fine aggregate by reactive aggregate shows the lowest expansion but expansion in excess of $0.1\%$ at 16 days, which can distinguished between deleterious and potentially reactive. Although content of reactive aggregate is a small amount, it can cause detrimental expansion due to alkali-silica reaction.

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Asymmetric Catalytic Activity of Mesoporous Mordenite containing Polymeric Chiral Salen Complexes in the Mesopore System (폴리머 키랄 살렌을 함유한 메조세공 모더나이트의 비대칭 촉매 활성)

  • Guo, Xiao-Feng;Kim, Yong-Suk;Kawthekar, Rahul B.;Kim, Geon-Joong
    • Applied Chemistry for Engineering
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    • v.20 no.3
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    • pp.279-284
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    • 2009
  • The formation of mesoporous pores in the microporous mordenite crystals was performed by controlled silica extraction on alkaline treatment. Inner tunable mesopore size could be controlled by changing the concentration of alkaline solution. The pore structure of mordenite zeolite was studied by instrumental analysis after alkaline-treatment. To obtain the cage type mesopores, Ti-coating on the ourside mordenite crystals before alkaline treatment was investigated to be the most effective. Polymeric chiral salen Co (III) complexes were successfully encapsulated in mesoporous mordenite zeolite by "ship-in-a-bottle" method. The heterogeneous catalyst could be applied in asymmetric ring opening of epichlorohydrine by water. It showed very excellent enantioselectivity with a high yield in the catalysis.

Application of Fly Ash Concrete in the Pavement (시험시공을 통한 플라이애쉬 콘크리트 포장 적용 특성)

  • Hong, Seung-Ho;Lee, Byung-Duk;Han, Seung-Hwan
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.701-704
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    • 2008
  • The case of failure of Alkali-silica reaction (ASR) on the cement concrete pavement was reported in Korea. In the United States America, the fly ash has less than 10 percent Cao reported that prevent expansion by ASR. Most of all fly ash in Korea have less than 10 percent CaO, therefore it is similar ASTM F fly ash in the USA. Crushed aggregates of the test section had expansion behavior by potential ASR that the ASTM C 1260 test method tested expansion 0.17 percent during 14 days. The test section of concrete pavement used crushed aggregate was constructed that fly ash have 20 percent weight of cementitious materials to prevent expansion by ASR. This study was performed flexural strength test for elapsed days and durability by freeze-thaw test. It was shown that flexural strength was increased elapsed days and good performed freeze-thaw test. This study shown that fly ash concrete pavement was good performance in the test section.

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The Effect of the Residual Mortar of Recycled Concrete Aggregate on Alkali Silica Reaction (순환/재생골재의 잔류 모르타르 성분이 알칼리 실리카 반응성에 미치는 영향 평가)

  • Kim, Jeonghyun;Kim, Namho;Yang, Sungchul
    • International Journal of Highway Engineering
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    • v.17 no.4
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    • pp.19-24
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    • 2015
  • PURPOSES : The objective of this study is to evaluate the effect of the residual mortar of recycled concrete aggregate on the expansion behavior during alkali silica reaction (ASR). METHODS: In order to evaluate the net effect of residual mortar on ASR expansion behavior, two aggregate samples with the same original virgin aggregate source but different residual mortar volumes were used. ASTM C1260 test was used to evaluate the ASR expansion behavior of these two aggregates and the original virgin aggregate. RESULTS: The greater the amount of residual mortar in recycled concrete aggregates, the less is the induced ASR expansion. Depending on the amount of residual mortar in recycled concrete aggregate, the ASR expansion of recycled concrete aggregate may be less than half of that of the original virgin aggregate. CONCLUSIONS: The residual mortar of recycled concrete aggregate may lead to the under estimation of the ASR expansion behavior of the original virgin aggregate.

The Effect of Ground Granulated Blast Furnace Slag Replacement on Alkali -Silica Reaction (고로슬래그 미분말 치환에 따른 알칼리-실리카 반응 팽창 저감효과)

  • Kim Ji Hyun;Jun Ssang Sun;Um Jang Sub;Jin Chi Sub
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.11a
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    • pp.431-434
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    • 2005
  • The effect of ground granulated blast furnace slag to prevent detrimental expansion due to alkali-silica reaction was investigated through the ASTM C 1260 method. This method is one of the most commonly used method because results can be obtained within 16 days. Reactive aggregate used is a metamorphic rock. The replacement ratios of portland cement by ground granulated blast furnace slag were 0, 15, 25, 35 and 55 percent, respectively. The results indicate that 35 percent replacement of portland cement by ground granulated blast furnace slag seems to be effective to reduce alkali-silica reaction expansion under this experimental conditions.

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The Effect of Fly Ash Replacement on Alkali - Silica Reaction (플라이 애쉬 치환에 따른 알칼리-실리카 반응의 팽창저감 효과)

  • Kim Jung Eun;Jun Ssang Sun;Seo Ki Young;Jin Chi Sub
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.11a
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    • pp.185-188
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    • 2004
  • The effect of fly ash to prevent detrimental expansion due to alkali -silica reaction was investigated through the ASTM C 1260 method that is one of the most commonly used method because results can be obtained within about 16 days. Reactive aggregate used is a netamorphic rock and sedimentary rock. The replacement proportions of portland cement by fly ash were respectively 0, 5, 10, 15, 25 and 35 percent. Expansion of mortar bars due to alkali-silica reaction decreased with the increase of fly ash content. The results show that the expansion due to alkali-silica reaction is dramatically reduced in the presence of high volume fly ash. When the fly ash content examine from all angles (strength and a flow), the replacement proportions of fly ash is about $25\%$ in order to control on expansion.

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Characteristics of Alkali-Silica Reaction Product of Mortar Bar by ASTM C 1260 Test (ASTM C 1260 시험 콘크리트 시편의 알칼리-실리카 반응 생성물 특징)

  • Hong, Seung-Ho;Yun, Kyong-Ku
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.11a
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    • pp.541-544
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    • 2006
  • This study was performed to proof expansion effect of the mortar bar due to Alkali-silica Reaction (ASR) by ASTM C 1260 test. Recently, the failure case of cement concrete pavement by ASR was reported in Korea. Cement concrete structures are caused crack by ASR. The service life of cracked cement concrete structures by ASR will be shorted. In this study, crushed the slate rock producted Chungcheongnamdo Boryeong was caused 0.3% expansion at 14 days due to ASR by ASTM C 1260 test. The particular spectrum showed that the ASR gel was analyzed contents included Si, Na, K, and Ca by EDX (electron dispersive X-ray spectrometer). It was verified that the crushed aggregate was caused expansion by ASR in Korea.

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Mechanical Properties and ASR Behavior of Recycled Glass Fine Aggregate Mortar Mixed with Mineral Admixture (혼화재를 혼입한 순환유리잔골재 모르타르의 역학적 특성과 ASR 거동)

  • Eu, Ha-Min;Kim, Guy-Yong;Park, Jun-Young;Sasui, Sasui;Choi, Byung-Cheol;Nam, Jeong-Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2023.05a
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    • pp.195-196
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    • 2023
  • In this study, the mechanical properties, alkali-silica reaction(ASR) expansion and residual mechanical properties after ASR of waste glass fine aggregate(GS) mortar according to mineral mixture were evaluated. As a result, it was found that the mineral mixture reduces the ASR expansion. However, mechanical properties and residual mechanical properties have decreased.

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