• Title/Summary/Keyword: 알칼리제

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Effect of Alkaline Activator and Curing Condition on the Compressive Strength of Cementless Fly Ash Based Alkali-Activated Mortar (시멘트를 사용(使用)하지 않은 플라이애시 알칼리 활성(活性) 모르타르의 압축강도(壓縮强度)에 미치는 알칼리 활성제(活性劑) 및 양생조건(養生條件)의 영향(影響))

  • Kang, Hyun-Jin;Ryu, Gum-Sung;Koh, Kyung-Taek;Kang, Su-Tae;Park, Jung-Jun;Kim, Sung-Wook;Lee, Jang-Hwa
    • Resources Recycling
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    • v.18 no.2
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    • pp.39-50
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    • 2009
  • Portland cement production is under critical review due to high amount of $CO_2$ gas released to the atmosphere. Attempts to increase the utilization of fly ash, a by-products from thermal power plant to partially replace the cement in concrete are gathering momentum. But most of fly ash is currently dumped in landfills, thus creating a threat to the environment. Many researches on alkali-activated concrete that does not need the presence of cement as a binder have been carried out recently. Instead, the source of material such as fly ash, that are rich in Silicon(Si) and Aluminium(Al), are activated by alkaline liquids to produce the binder. Hence concrete with no cement is effective in the reduction of $CO_2$ gas. In this study, we investigated the influence of the compressive strength of mortar on alkaline activator and curing condition in order to develop cementless fly ash based alkali-activated concrete. In view of the results, we found out that it was possible for us to make alkali-activated mortar with 70MPa at the age of 28days by using alkaline activator manufactured as 1:1 the mass ratio of 9M NaOH and sodium silicate and applying the atmospheric curing after high temperature at $60^{\circ}C$ for 48hours.

A Experimental Study on the Alkali-Silica Reaction of Crushed Stones (Part 2 : The Influence of the Alkali Content and the Kind of Added Alkali to the Alkali-Silica Reaction) (쇄석 골재의 알칼리-실리카 반응에 관한 실험적 연구( 제 2보 : 첨가알칼리량 및 종류가 알칼리-실리카 반응에 미치는 영향))

  • 이영수;윤재환;정재동;노재호;이양수;조일호
    • Proceedings of the Korea Concrete Institute Conference
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    • 1993.10a
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    • pp.108-112
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    • 1993
  • The term Alkali-Silica Reaction (ASR) is used to describe a reaction between certain siliceous aggregates and hydroxyl ions present in the pore fluid of a concrete. The ASR is affected by the content of alkali, the particle size and the content of reactive aggregate, water-cement ratio, humidity, temperature and so on. In this paper, the fluence of alkali content and kind of added alkali to the ASR was studied. As a result, the more the content of alkali was increased, the more the mortar-bar was expand and the expansion of mortar-bar was showed differently with the added alkali kinds, The reaction products by ASR were observed by SEM(Scanning Electron Microscope) and analyzed by EDXA(Energy Dispersive X-ray Analysis) also and showed a gel composed of alkali(Na+, K+), silica and calcium.

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A Fundamental study on the Characteristics of Zeolite Cement Mortar (제올라이트 시멘트 모르타르의 재료적 특성에 관한 기초 연구)

  • Jo, Byung-Wan;Kang, Suk-Won;Park, Seung-Kook;Choi, Ji-Sun
    • Journal of the Korea Concrete Institute
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    • v.23 no.2
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    • pp.203-209
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    • 2011
  • The cement industry is expected to face a major set-back in the near future due to its large energy consumption and $CO_2$ production, causing global warming. In order to overcome these environmental problems, this research has bee carried out to find a cement substitute material. One possible cement substitute material is Zeolite cement. In this study, the materialistic characteristics of Zeolite cement mortar were evaluated. Natural Zeolite cement mortar was prepared using alkali activation (NaOH) instead of water ($H_2O$) to determine achievable strength and appropriate mixing ratio. Based on the mixing ratio, functional material was added to alkali active agent to harden Zeolite mortar to develop a highly functional construction material. The study result showed that pure Zeolite cement mortar achieved compressive strength of 42 MPa in 7 days depending on the mixing amount of alkaline catalyst and the hardening temperature, showing high efficiency and possibility as a new construction material.

Strength and Flowing Properties of Cementless Inorganic Complex Using Alkali Accelerator and Meta-kaolin (메타카올린과 알칼리 자극제를 사용한 무시멘트계 무기복합체의 유동특성 및 강도특성 연구)

  • Lee, Kang-Pil;Kim, Sung-Soo;Lee, Yun-Seong;Lee, Sang-Soo;Song, Ha-Young
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2010.05a
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    • pp.89-90
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    • 2010
  • As a result of physical characteristics of using meta-kaolin and alkali accelerator, it was found that higher curing temperature density is favorable to strength development at early age and the higher the age is, the higher, most of the compressive strength gets. Also, I was shown that more than atmospheric curing, steam curing was favorable for development of compressive strength. When the temperature of curing temperature was higher, most of the compressive strengths were higher. Thus, based on this study, it was understood that environmental-friendly chemically combined concrete using meta-kaolin and alkali accelerator can be utilized without using cement.

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Mechanical Properties of Blast Furnace Slag Fineness Mortar according to Alkali Activator (알칼리 자극제 종류에 의한 고로슬래그 미분말 모르타르의 강도 특성)

  • Kim, Jong-Hee;Kim, Gyu-Yong;Shin, Kyoung-Su;Nam, Jeong-Soo;Koo, Kyung-Mo;Yun, Yong-Sang
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2011.11a
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    • pp.217-218
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    • 2011
  • The advantages of blast-furnace slag concrete may include lower hydration heating velocity, restraint on concrete temperature increase, long-age strength improvement due to latent hydraulic reaction, improved water tightness, and repulsion to chemical erosion. These advantages contribute to the high quality of the blast-furnace slag concrete. However, the blast-furnace slag concrete has its limitations as well. These disadvantages may include retarded setting and elongated retention of mold due to the weak strength of early-age. Nevertheless, much research is currently under way to improve the aforementioned issues. To improve activity of blast furnace slag powder, alkaline irritants has been used. In this study, we analyze effect on activity fineness and rate of substitution of Alkali Activator toward activity.

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Strength properties according to mixing type and ratio Alkali activator of Non-cement matrix using Paper Ash and Polysilicon sludge (폴리실리콘 슬러지와 제지애시를 활용한 무시멘트 경화체의 알칼리자극제 종류 및 혼입율에 따른 강도특성)

  • Sin, Jin-Hyun;Kim, Tae-Hyun;Kim, Heon-Tae;Lee, Dong-Hoon;Lee, Sang-Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2017.05a
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    • pp.173-174
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    • 2017
  • Recently, many experiments using industrial by-products have been going on in Korea and abroad. Most of the studies on blast furnace slag and fly ash have been conducted, and the blast furnace slag based two and three component experiments have been conducted in many places. Therefore, this study is an additional study of research using polysilicon sludge and paper ash, which is a study using existing industrial by-products based on blast furnace slag, as strength properties of alkali activator according to kind and mixing ratio and to obtain basic data do.

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SEM Analysis Property of Non-cement Light-weight Matrix according to Type and Mixing Ratio of Alkali Activator (알칼리자극제 종류 및 혼입율에 따른 무시멘트 경량 경화체의 SEM분석 특성)

  • Shin, Jin-Hyun;Kim, Tae-Hyun;Lee, Dong-Hoon;Lee, Sang-Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2017.11a
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    • pp.161-162
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    • 2017
  • As the use of cement increases with the development of modern society along with the increase of buildings, environmental pollution intensifies and researches on industrial byproducts are continuing. Research on blast furnace slag and fly ash as industrial byproducts is increasing, and research on industrial byproducts such as polysilicon sludge and paper ash used in this study is increasing. Blast furnace slag, which is one of the industrial byproducts, has been widely studied as a material used with cement. However, in this study, we fabricated lightweight matrix of polysilicon sludge and paper ash replaced based on blast furnace slag, and performed SEM analysis.

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Pore Structure and Heat of Microhydration Analysis of Blast Furnace Slag Containing Alkaline Activator (알칼리 자극제 혼입 고로슬래그 미분말의 공극구조 및 미소수화열 분석)

  • Park, Ji-Woong;Park, Hee-Gon;Kim, Woo-Jae;Lee, Gun-Cheol
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2017.11a
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    • pp.20-21
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    • 2017
  • In this study, fundamental properties by pore structure and heat of microhydration test were determined. As a result of pore structure analysis, BS(AA) specimen showed showed the maximum peak value of significantly lower incremental intrusion than the maximum peak value of incremental intrusion at smaller pore size than that of BS. As a result of heat of microhydration test, the maximum heating value was in the order of OPC > BS > BS(AA), and initial drying shrinkage and compressive strength of BS(AA) were expected to be improved.

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A Study on the Physical Property of concrete using Industrial by-product and Alkali Activators (산업부산물과 알칼리 활성제를 사용한 콘크리트의 물리적 특성에 관한 연구)

  • Lee, Sun-Kwan;Kim, Young-Su
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2013.11a
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    • pp.54-55
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    • 2013
  • Recently, The economic growth has increased carbon dioxide emissions. so, It is caused by social problem to environmental damage and human health due to global warming. Accordingly, The method solution is to the amount of cement and to use industrial by-product such as Blast furnace slag, Fly Ash, and Red-mud. Thus, The purpose of this study is to analyze the physical property of concrete with red-mud. So, this study carries out the basic performance test of concrete such as, air content, slump, and compressive strength. In this work test is conducted according to sequence of materials using concrete twin mixer.

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Strength Properties of Blast Furnace Slag-based Hardened Materials with Addition Rate of Alkali Stimulant NaOH (알칼리 자극제 NaOH의 첨가율에 따른 고로슬래그 기반 경화체의 강도 특성)

  • Kyung, Seok-Hyun;Choi, Byung-Cheol;Lee, Sang-Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2019.11a
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    • pp.135-136
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    • 2019
  • Recently, as the interest in environmental issues increases, the construction industry needs to recycle blast furnace slag, circulating fluidized bed Combustion fly ash, etc. to solve industrial by-products, and to develop artificial stone. In this study, the strength characteristics based on blast furnace slag according to the addition rate of alkali stimulant NaOH are investigated. The experimental results showed that the flexural and compressive strengths increased with the addition of alkali stimulants. Based on these results, it will be presented as a basic research data for the manufacture of artificial stone and will be tested later.

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