• Title/Summary/Keyword: 알루미늄 당량

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Combustion Modeling of Nano/Micro Aluminum Particle Mixture (나노-마이크로 알루미늄 혼합 입자의 공기와의 연소 모델링)

  • Yoon, Shi-Kyung;Shin, Jun-Su;Sung, Hong-Gye
    • Journal of the Korean Society of Propulsion Engineers
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    • v.15 no.6
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    • pp.15-25
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    • 2011
  • One dimensional combustion modeling of aluminum combustion behavior is proposed. Combustion model is assumed that region consists as follows ; preheat, reaction, post reaction region. Flame speed as a function of particle size, equivalence ratio for unitary particles and fraction ratio of micro to nano particle size for binary particles were investigated for lean burn condition at 1 atm. Results were compared with experimental data. For unitary particles, flame speed increase as particle size decreases, but opposite trend with equivalence ratio. For binary particles, flame speed increases proportionally as nano particle fraction increases. For flame structure, separated or overlapping flames are observed, depending on the fraction of nano sized particles.

Combustion Characteristics of Al powder with Water Suspension (Al 분말과 Water 혼합물의 연소특성 연구)

  • Ki, Wan-Do;Kim, Kwang-Yeon;Shmelev, Vladimir;Cho, Yong-Ho
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2012.05a
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    • pp.157-162
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    • 2012
  • The basic study for combustion characteristics of micron-sized aluminum powder with water suspension was carried out. Under atmospheric pressure, the combustion characteristics of aluminum powder with water suspension was studied by adjust the equivalent ratio and the density of a mixture which effect on burning rate. Based on atmospheric pressure's result, the device for the combustion characteristics of aluminum powder with water suspension under high-pressure environment was developed. In the pressure range from 2 to 50 atm the effect of pressure to burning rate was same as the case of nano-aluminum with water suspension, but the pressure range from 50 to 70 atm the sharp increase in burning rate was observed. In the experiment of varying the equivalence ratio, the combustion did not proceed in the condition of excess oxidizer (eq = 1.5).

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Development of combustion test device for study of aluminum powder combustion (알루미늄 분말 연소시험을 위한 장치 개발)

  • Hwang, Yong-Seok;Lee, Ji-Hyung;Lee, Kyung-Hun;Kim, Kwang-Yun;Lee, Sung-Woong;Yeo, Tae-Min
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2011.11a
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    • pp.548-553
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    • 2011
  • The device for studying combustion characteristic of aluminum powder and water was developed. The device has ability to adjust temperature, pressure, and equivalent ratio to some specified value which effect on combustion characteristic of aluminum and water mixture. Methane combustor, water supply device, aluminum powder feeder, and linear combustor are assembled to aluminum combustion test device. Each device has the ability to supply matter to combustor on steady and quantitatively controlled manner and test sequence specified by user can be automatically controlled. The combustion of aluminum powder was observed when integrated device was operated normally.

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Recovery of Platinum Group Metals from the Leach Solution of Spent Automotive Catalysts by Cementation (자동차(自動車) 폐촉매(廢觸媒)의 침출액(浸出液)으로부터 시멘테이션에 의한 백금족(白金族) 금속(金屬)의 회수(回收))

  • Kim, Min-Seuk;Kim, Byung-Su;Kim, Eun-Young;Kim, Soo-Kyung;Ryu, Jae-Wook;Lee, Jae-Chun
    • Resources Recycling
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    • v.20 no.4
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    • pp.36-45
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    • 2011
  • The recovery of platinum group metals (PGMs) from the leach solution of spent auto-catalyst and the wash solution of the leach residue was investigated in the laboratory scale experiments by the cementation process using metal powders as the reductant. In this study, the effect of Al, Mg and Zn powders on the cementation process was particularly examined. Aluminum powder was selected as the most suitable reductant for the cementation of PGMs. At the cementation time of 10 minute under the aluminium stoichimetric amount of 19.3 and the reaction temperature of $50{\sim}60^{\circ}C$, the recovery of platinum group metals from the leach solution of the spent auto-catalyst was found to be 99.3%, 99.4%, 90.2% for Pt, Pd and Rh, respectively. Under the same conditions with the aluminium stoichimetric amount of 45, the recovery of platinum group metals from the wash solution of the leach residue of spent catalyst was observed to be 97%, 97% and 90% for Pt, Pd and Rh, respectively. In addition, it was possible to upgrade the platinum group metals in the precipitates obtained from the cementation process by about 10% through the removal of metal impurities by the nitric acid leaching at ambient temperature.

Recovery Process of Vanadium from the Leaching Solution of Salt-Roasted Vanadate Ore (바나듐광 염배소물 수침출 용액으로부터 바나듐 회수공정 고찰)

  • Yoon, Ho-Sung;Heo, Seo-Jin;Park, Yu-Jin;Kim, Chul-Joo;Chung, Kyeong Woo;Kim, Rina;Jeon, Ho-Seok
    • Resources Recycling
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    • v.31 no.2
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    • pp.40-48
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    • 2022
  • In this study, the effects of solution components were investigated in the recovery of vanadium as ammonium metavanadate from vanadium-ore-salt roasting-water leaching solution. The vanadium-containing solution is strongly alkaline (pH 13), so the pH must be lowered to 9 or less to increase the ammonium metavanadate precipitation efficiency. However, in the process of adjusting the solution pH using sulfuric acid, aluminum ions are co-precipitated, which must be removed first. In this study, aluminum was precipitated in the form of an aluminum-silicate compound using sodium silicate, and the conditions for minimizing vanadium loss in this process were investigated. After aluminum removal, the silicate was precipitated and removed by adjusting the solution pH to 9 or less using sulfuric acid. In this process, the concentration and addition rate of sulfuric acid have a significant influence on the loss of vanadium, and vanadium loss was minimized as much as possible by slowly adding dilute sulfuric acid. Ammonium metavanadate was precipitated using three equivalents of ammonium chloride at room temperature from the aluminum-free, aqueous solution of vanadium following the pH adjustment process. The recovery yield of vanadium in the form of ammonium metavanadate exceeded 81%. After washing the product, vanadium pentoxide with 98.6% purity was obtained following heat treatment at 550 ℃ for 2 hours.

EVALUATION OF RADIOPACITY AND DISCRIMINABILITY OF VARIOUS FIBER REINFORCED COMPOSITE POSTS (수종의 섬유 강화 레진 포스트의 방사선 불투과도와 식별도 평가)

  • Lee, Eun-Hye;Choi, Hang-Moon;Park, Se-Hee;Kim, Jin-Woo;Cho, Kyung-Mo
    • Restorative Dentistry and Endodontics
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    • v.35 no.3
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    • pp.188-197
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    • 2010
  • The purpose of this study was to compare radiopacity and radiographic discriminability of various FRC-Posts. Six FRC-Posts were investigated ; 1) FRC Postec Plus (Ivoclar Vivadent AG, Schaan, Liechtenstein), 2) Snowlight (Carbotech, Lewis center, OH, USA), 3) Dentin Post (Komet Brasseler, Lamgo, Germany), 4) Rely-X Fiber Post (3M ESPE, St.paul, MN, USA), 5) D.T.-Light Post (BISCO, Schaumburg, IL,USA), 6) Luxapost (DMG, Hamburg, Germany) The radiographs of each post with a reference 1 mm / 2 mm aluminum step-wedge was taken using digital sensor. The optical density were calculated by gray value of $10{\times}10$ pixel and compared in mm Al equivalent at five points. Six maxillary incisors of similar radiopacity were used. Radiographs of posts in Mx. incisors of lingual side of dry mandible were taken. We showed radiographs and asked the questionnaire to 3 radiologists, 3 endodontists, 3 general practitioners. The questionnaire was comprised of choices of the highest, lowest radiopaque individual post and the choices of best discriminable post at apical, coronal area. The following results were obtained. 1. Each post system showed various radiopacity. 2. There was change of discriminability between each post and simulated specimens regardless of examiner. Although each post showed various radiopacity, the difference of radiopacity did not affect on discriminability.

Effects of Vanadate Solution Property on the Precipitation of Ammonium (Meta, Poly)Vanadate (바나데이트 수용액 특성이 암모늄(메타, 폴리)바나데이트 침전에 미치는 영향)

  • Ho-Sung Yoon;Seo Jin Heo;Yujin Park;Rina Kim;Chul-Joo Kim;Kyeong Woo Chung;Hong In Kim
    • Resources Recycling
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    • v.32 no.3
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    • pp.26-37
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    • 2023
  • Good control of the solution pH and temperature is required to recover vanadium from the water leaching solution of vanadium ore after sodium roasting. However, such adjustments could lead to aluminum-vanadium and sodium-vanadium co-precipitation, which greatly affects the efficiency of vanadium recovery. In this study, a process that can increase the efficiency of vanadium recovery as ammonium metavanadate [NH4VO3] and ammonium polyvanadate [(NH4)2V6O16·H2O] was investigated by examining the characteristics of vanadium-containing aqueous solutions during precipitation. The aluminum content of vanadium-containing water leaching solutions has a great effect on the loss of vanadium when the pH of the aqueous solution is adjusted to 9. Therefore, a process to minimize aluminum leaching is also required. In this study, ~99% or more of vanadium present in vanadium-containing aqueous solutions was precipitated and recovered as NH4VO3 by adding 3 equivalents of ammonium chloride relative to the vanadium content at pH 9 and room temperature. (NH4)2V6O16·H2O was precipitated from the aluminum-vanadium coprecipitates generated during the pH-adjustment of the aqueous solutions to 9 by dissolving the coprecipitate in the solutions at pH 2.5 and controlling their sodium content to 2,000 mg/L or less. Approximately, 98% or more of the available (NH4)2V6O16·H2O could be precipitated and recovered from a solution with a vanadium content of 2,200 mg/L and a sodium content of 1,875 mg/L at pH 2.5 by adding approximately 3 equivalents of ammonium chloride relative to the vanadium content at 95℃ or higher. The overall process could precipitate and recover, approximately 91% or more of the total vanadium in the water leaching solution as NH4VO3 and (NH4)2V6O16·H2O.

A study on assessment of bone mass from aluminum-equivalent image by digital imaging system (디지털 영상 시스템을 이용한 알루미늄 당량화상에 의한 골량 측정에 관한 연구)

  • Kim Jin-Soo;Choi Eui-Hwan;Kim Jae-Duk
    • Journal of Korean Academy of Oral and Maxillofacial Radiology
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    • v.27 no.1
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    • pp.87-97
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    • 1997
  • The purpose of this study was to evaluate the method for quantitative assessment of bone mass from aluminum-equivalent value of hydroxyapatite by using digital imaging system consisted of Power Macintosh 7200/120, 15-inch color monitor, and GT-9000 scanner with transparency unit. After aluminum-equivalent image made from correlation between aluminum thickness and grey scale, the accuracy of conversion to mass from aluminum-equivalent value was evaluated. Measured bone mass was compared with converted bone mass from aluminum-equivalent value of hydroxyapatite block by correlation formula between aluminum-equivalent value of hydroxyapatite block and hydroxyapatite mass. The results of this study were as follow; 1. Correlation between aluminum thickness and grey level for obtaining aluminum-equivalent image was high positively associated(r²=0.99). Converted masses from aluminum-equivalent value were very similar to measured masses. There was, statistically, no significant difference(P<0.05) between them 2. Correlation between hydroxyapatite aluminum-equivalent and hydroxyapatite mass was shown to linear relation (r²=0.95). 3. Converted masses from aluminum-equivalent value of 3 dry mandible segments were similar to measured masses. The difference between the exposure directions was not significantly different(P<0.05).

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Reconvery of Platinum Group Metals from Spent Automotive Catalysts by Hydrochloric Acid Leaching (自動車 廢觸媒로부터 鹽酸浸出에 의한 自金族 金屬의 回收)

  • Lee, Jae-Chun;Jeong, Jin-Ki;Kim, Min-Seuk;Kim, Byung-Su;Kim, Chi-Kwon
    • Resources Recycling
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    • v.13 no.5
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    • pp.28-36
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    • 2004
  • The extraction of platinum group metals such as Pt, Pd and Rh from spent automobile catalyst has been investigated by leaching in HCl solutions using $HNO_3$ or NaOCl as a oxidant. The effect of type and amount of oxidant, reaction time and pulp density on the extraction of platinum group metals was examined. Platinum group metals were recovered by the cementation method using aluminum as a reducing agent. The extraction ratio was higher when NaOCl was used as a oxidant. The optimum leaching conditions were obtained to be: HCl 8 M, the amount of NaOCl 1.4 mole, leaching temperature $90^{\circ}C$, leaching time 180 minutes, pulp density 400g/L. Under the optimum conditions, the extraction of Pt, Pd and Rh were 96.1%, 93.6% and 77.3%, respectively. With the addition of 2.0g of aluminum which corresponds to 28 equivalent the reduction were 98% for Pt. 98.8% for Pd and 65.3% for Rh, respectively.