• Title/Summary/Keyword: 아레니우스 방정식

Search Result 18, Processing Time 0.027 seconds

A Study of 60-Year Lifetime of Class 1E Cables in the Nuclear Power Plants (원자력 발전소 전기1급 케이블의 60년 사용에 대한 고찰)

  • Jin Sug Il;Bae Jang Ho
    • Proceedings of the KIEE Conference
    • /
    • summer
    • /
    • pp.418-420
    • /
    • 2004
  • 전기1급 케이블의 활성화에너지, 가속노화온도 및 가속노화시간 둥을 이용하여 아레니우스(Arrhenius) 방정식에 근거한 케이블 정격온도 및 실제 사용 가능한 운전온도에서 이론적 수명을 계산하고, 정격온도 이외에서의 허용전류를 계산하였다. 또한, 정격온도를 어느 정도 낮추어 사용하면 표준원전에서 기 검증된 전기1급 케이블을 차세대원전 설계수명인 60년간 사용이 가능한지 계산 및 정격온도 감소 적용시 전력케이블 설계영향 둥을 고찰해 보았다.

  • PDF

A Study on Cable Lifetime Evaluation Based on Characteristic Analysis of Insulation Resistance by Acceleration Factor of the Arrhenius Equation (아레니우스 방정식의 가속인자를 만족하는 절연저항특성 분석에 의한 케이블 수명평가 연구)

  • Um, Kee-Hong;Lee, Kwan-Woo
    • The Journal of the Institute of Internet, Broadcasting and Communication
    • /
    • v.14 no.5
    • /
    • pp.231-236
    • /
    • 2014
  • With the development of industry these days, the demand for electric power increases and the larger capacity for power transfer is required. The scales of facilities should become larger; and the relative systems are required to operate with a higher degree of reliability. Therefore, stabilization of electric power systems is an important issue. The high degree of reliability required in the process of production and supply of electric power is an essential part of industrial society. Accident such as blackouts causes a hugh amount of economic losses to the high-tech industrial society dependent upon electric power. In this paper, in order to determine a stable operation of high-voltage power cable, used as a unique means of delivering electric power generated at a power station, we figure out the time rate of change of insulation resistance following a decay accelerating factor Arrhenius equation. With the data from the insulation resistance, we can determine the lifetime of power cable in operation.

Evaluation of Material Properties due to Thermal Embrittlement in CF8M Cast Austenitic Stainless Steel (CF8M 주조 오스테나이트 스테인리스강의 열취화에 따른 재료물성치 평가)

  • Kim, C.;Park, H.B.;Jin, T.E.;Jeong, I.S.;Seok, C.S.;Park, J.S.
    • Proceedings of the KSME Conference
    • /
    • 2003.04a
    • /
    • pp.131-136
    • /
    • 2003
  • CF8M cast austenitic stainless steel is used for several components such as primary coolant piping, elbow, pump casing, and valve bodies in light water reactors. These components are subject to thermal aging at the reactor operating temperature. Thermal aging results in spinodal decomposition of the delta-ferrite leading to increased strength and decreased toughness. In this study, three kinds of the aged CF8M specimen were prepared using an artificially simulated aging method. The objective of this study is to summarize the method of estimating ferrite contents, Charpy impact energy and J-R curve, and to evaluate the thermal embrittlement of the CF8M cast austenitic stainless steel piping used in the domestic nuclear power plants.

  • PDF

Kinetic Analyses on Thermal Degradation of Epoxy Based Adhesive for Packaging Application (센서 패키지용 고분자 접착제의 열화 거동 분석)

  • Kim, Yeong K.;Lee, Yoon-Sun
    • Journal of the Microelectronics and Packaging Society
    • /
    • v.24 no.1
    • /
    • pp.67-73
    • /
    • 2017
  • An analysis of thermal degradation of epoxy based adhesive performed by thermogravimetry tests are presented in this study. Six different heating rates were employed for the weight change measurements. Based on the data, an Arrhenius type modeling equation was developed by calculating activation energies and proportional constants, and $n^{th}$ polynomial function was adopted to predict the weight change rates. The prediction results by the modeling was compared with the data using the average activation energy. It was found that the activation energy at the each heating rate was not same due to the different degradation kinetics, especially at the high heating rate. To overcome this pitfall, a new approach using exponential function series was introduced and employed. The calculation results showed very good agreements with the test data regardless of the heating rates.

A Study on Train Control System Accelerated Stress Modeling (열차제어시스템 가속 스트레스시험 모델링에 관한 연구)

  • Shin, Duc-Ko;Lee, Jae-Ho;Lee, Kang-Mi
    • Proceedings of the KSR Conference
    • /
    • 2006.11b
    • /
    • pp.624-630
    • /
    • 2006
  • This paper studies a modeling to demonstrate predicted reliability of the train control system components by performing an accelerated stress test. There are two tests for demonstrating predicted reliability; test run at the whole system level, and accelerated life test and accelerated stress test at the component level. In this paper, we imposed accelerated stress on the system and studied the train control system modeling for the accelerated stress test, which demonstrates predicted reliability according to whether or not the equipment is operating. Reliability of train control system consisting of electronic components varies drastically according to temperature so we considered the Arrhenius equation and the activation energy of electronic components. We also used reliability modeling with weighted average and calculated time necessary to complete the accelerated stress test on train control system.

  • PDF

Rheological Properties of Gelatinization of Rice Starch (쌀 전분 호화중의 리올로지 특성)

  • Lee, Shin-Young;Cho, Hyung-Yong;Kim, Sung-Kon;Lee, Sang-Kyu;Pyun, Yu-Ryang
    • Korean Journal of Food Science and Technology
    • /
    • v.16 no.3
    • /
    • pp.273-278
    • /
    • 1984
  • Changes in rheological properties of rice starch-water systems during the gelatinization were evaluated with the tube viscometer at temperatures between 50 and $85^{\circ}C$ and for the concentrations ranging from 3-5% rice starch. The flow consistency index increased exponentially with time at a particular temperature while being linearly dependent upon the concentration. The gelatinization rate measured by rheological method followed Arrhenius type equation. The value of activation energy of gelatinization for 5% rice starch was about 25 kcal/g mol.

  • PDF

Numerical Investigation of Deformation of Thin-walled Tube Under Detonation of Combustible Gas Mixture (가연성 연소 가스의 데토네이션에 의한 얇은 관 변형 모델링)

  • Gwak, Mincheol;Lee, Younghun;Yoh, Jai-Ick
    • Transactions of the Korean Society of Mechanical Engineers B
    • /
    • v.39 no.1
    • /
    • pp.11-19
    • /
    • 2015
  • We present the results of a multi-material numerical investigation of the propagation of a combustible gas mixture detonation in narrow metal tubes. We use an experimentally tuned one step Arrhenius chemical reaction and ideal gas equation of state (EOS) to describe stoichiometric $H_2-O_2$ and $C_2H_4-O_2$ detonations. The purely plastic deformations of copper and steel tubes are modeled using the Mie-Gruneisen EOS and Johnson-Cook strength model. To precisely track the interface motion between the detonating gas and the deforming wall, we use the hybrid particle level-sets within the ghost fluid framework. The calculated results are validated against the experimental data because the results explain the process of the generation and subsequent interaction of the expansion wave with the high-strain-rate deformation of the walls.

Comparison of Measured and Calculated Carboxylation Rate, Electron Transfer Rate and Photosynthesis Rate Response to Different Light Intensity and Leaf Temperature in Semi-closed Greenhouse with Carbon Dioxide Fertilization for Tomato Cultivation (반밀폐형 온실 내에서 탄산가스 시비에 따른 광강도와 엽온에 반응한 토마토 잎의 최대 카복실화율, 전자전달율 및 광합성율 실측값과 모델링 방정식에 의한 예측값의 비교)

  • Choi, Eun-Young;Jeong, Young-Ae;An, Seung-Hyun;Jang, Dong-Cheol;Kim, Dae-Hyun;Lee, Dong-Soo;Kwon, Jin-Kyung;Woo, Young-Hoe
    • Journal of Bio-Environment Control
    • /
    • v.30 no.4
    • /
    • pp.401-409
    • /
    • 2021
  • This study aimed to estimate the photosynthetic capacity of tomato plants grown in a semi-closed greenhouse using temperature response models of plant photosynthesis by calculating the ribulose 1,5-bisphosphate carboxylase/oxygenase maximum carboxylation rate (Vcmax), maximum electron transport rate (Jmax), thermal breakdown (high-temperature inhibition), and leaf respiration to predict the optimal conditions of the CO2-controlled greenhouse, for maximizing the photosynthetic rate. Gas exchange measurements for the A-Ci curve response to CO2 level with different light intensities {PAR (Photosynthetically Active Radiation) 200µmol·m-2·s-1 to 1500µmol·m-2·s-1} and leaf temperatures (20℃ to 35℃) were conducted with a portable infrared gas analyzer system. Arrhenius function, net CO2 assimilation (An), thermal breakdown, and daylight leaf respiration (Rd) were also calculated using the modeling equation. Estimated Jmax, An, Arrhenius function value, and thermal breakdown decreased in response to increased leaf temperature (> 30℃), and the optimum leaf temperature for the estimated Jmax was 30℃. The CO2 saturation point of the fifth leaf from the apical region was reached at 600ppm for 200 and 400µmol·m-2·s-1 of PAR, at 800ppm for 600 and 800µmol·m-2·s-1 of PAR, at 1000ppm for 1000µmol of PAR, and at 1500ppm for 1200 and 1500µmol·m-2·s-1 of PAR levels. The results suggest that the optimal conditions of CO2 concentration can be determined, using the photosynthetic model equation, to improve the photosynthetic rates of fruit vegetables grown in greenhouses.

Modeling of a Pervaporation Process for Concentrating Hydrogen Peroxide (과산화수소 농축을 위한 투과증발공정 모델링)

  • Nguyen, Huu Hieu;Lee, Sung Taek;Choi, Soo Hyoung
    • Korean Chemical Engineering Research
    • /
    • v.49 no.5
    • /
    • pp.560-564
    • /
    • 2011
  • The objective of this study is to propose a mathematical model for a pervaporation process for concentrating hydrogen peroxide. The process was developed by NASA, which consists of a shell and membrane tubes, where a liquid hydrogen peroxide solution flows in the shell, and a sweep gas flows in the tubes countercurrent to each other. The liquid retentate is concentrated as more water molecules permeate and evaporate through the membrane than hydrogen peroxide. For this process, a mathematical model has been developed in the form of a system of nonlinear partial differential algebraic equations based on a sorption-diffusion mechanism for permeation, an Arrhenius relationship for the temperature dependency of the permeate flux, and mass and momentum balances for the liquid concentrations and flows in the membrane module. The dynamic behavior of the concentration of hydrogen peroxide in the retentate side has been simulated by solving a simplified version of the proposed model, and the result is compared with the experimental data reported in the NASA patent.

Char Oxidation Characteristics of High Ash Coal in Drop Tube Furnace (고회분탄의 촤 산화 반응 특성 연구)

  • An, Ke-Ju;Lee, Byoung-Hwa;Kim, Sang-In;Kim, Man-Cheol;Kim, Seung-Mo;Jeon, Chung-Hwan
    • Transactions of the Korean Society of Mechanical Engineers B
    • /
    • v.37 no.4
    • /
    • pp.405-413
    • /
    • 2013
  • The char oxidation characteristics of high ash coal were experimentally investigated at several temperatures (from 900 to $1300^{\circ}C$) for 4 types of coals (Gunvor, Glencore, Noble, and ECM) under atmospheric pressure in a drop tube furnace (DTF). The char reaction rate was calculated from the exhaust gas concentrations (CO and $CO_2$) using FT-IR, and the particle temperature was measured using the two-color method. In addition, the activation energy and pre-exponential factor for high ash coal char were calculated based on the Arrhenius equation. The results show that as the ash content increases, the particle temperature and area reactivity decreases. This is because in high ash coal, the large heat capacity of the ash, ash vaporization, and relatively low fixed carbon content of ash suppress combustibility during char oxidation. As a result, the higher ash content of coal leads to high activation energy.