• Title/Summary/Keyword: 아레니우스 모델

Search Result 31, Processing Time 0.026 seconds

Accelerated Life Test Using Structural Analysis of a Helicopter Accumulator (헬기용 축압기의 구조해석에 의한 가속 수명시험)

  • Lee, Geon-Hui;Hur, Jang-Wook
    • Journal of the Korean Society of Manufacturing Process Engineers
    • /
    • v.19 no.6
    • /
    • pp.67-72
    • /
    • 2020
  • Life tests are essential in reducing the catastrophic damage caused by the accidents of large machinery such as aircraft and ships. However, life tests are challenging to implement due to the high costs and time required to test the life of large machinery parts. Therefore, it is advantageous and convenient to apply accelerated life test techniques for key components to reduce costs and time. In fact, extensive research has already been conducted on these techniques. However, recently, there have been cases in which an experimental value was applied to the shape parameter of the Weibull distribution used in the reliability test, but the test time was not significantly reduced. Therefore, in this paper, the shape parameters are estimated from the probability density function of the Weibull distribution for the analysis of an accelerated life test for bladder accumulators, which are core components of military helicopters. The test time was derived based on the number of samples and confidence level by substituting it into the test time equation. Next, the accelerated life test time was calculated using the steady-state test time with an acceleration factor obtained from the Arrhenius model. The steady-state life test required approximately 15,000 H, whereas the accelerated life test time for one sample at 100 ℃ was 34% shorter than that of the steady-state life test.

Numerical Investigation of Deformation of Thin-walled Tube Under Detonation of Combustible Gas Mixture (가연성 연소 가스의 데토네이션에 의한 얇은 관 변형 모델링)

  • Gwak, Mincheol;Lee, Younghun;Yoh, Jai-Ick
    • Transactions of the Korean Society of Mechanical Engineers B
    • /
    • v.39 no.1
    • /
    • pp.11-19
    • /
    • 2015
  • We present the results of a multi-material numerical investigation of the propagation of a combustible gas mixture detonation in narrow metal tubes. We use an experimentally tuned one step Arrhenius chemical reaction and ideal gas equation of state (EOS) to describe stoichiometric $H_2-O_2$ and $C_2H_4-O_2$ detonations. The purely plastic deformations of copper and steel tubes are modeled using the Mie-Gruneisen EOS and Johnson-Cook strength model. To precisely track the interface motion between the detonating gas and the deforming wall, we use the hybrid particle level-sets within the ghost fluid framework. The calculated results are validated against the experimental data because the results explain the process of the generation and subsequent interaction of the expansion wave with the high-strain-rate deformation of the walls.

A Study of Life about Naturally Aged Nitrocellulose by Storage (자연 노화된 니트로셀룰로오스의 수명에 관한 연구)

  • Kim, Dong-seong;Jin, Hong-Sik
    • Journal of the Korea Academia-Industrial cooperation Society
    • /
    • v.21 no.11
    • /
    • pp.595-601
    • /
    • 2020
  • During the safety inspection of nitrocellulose-made explosive containers stored for more than 10 years, cracks were found in the containers. Therefore, a failure cause analysis test was performed. First, the cause of failure through the failure tree analysis was conducted to select the factors that influenced failure. The changes in the properties of the container caused by the acceleration of the reaction were found to be the cause of the failure by confirming the influence on the environment and internal/external factors that may occur during storage. To confirm this, environmental tests, such as thermal shock test and vacuum thermal stability test, were performed using a naturally aged container to analyze the cause of failure, and an accelerated aging test was performed to reproduce the failure. Through this, the chemical reaction was accelerated by heat and charge, as in the result of the fault tree analysis, and it was confirmed that the physical properties of the container were changed. In addition, the service life of the container was estimated using the Arrhenius model for the storage life due to thermal aging.

저온 플라즈마 반응기에서의 수정충돌주파수를 이용한 실리콘 나노 입자 형성 모델링

  • Kim, Yeong-Seok;Kim, Dong-Bin;Kim, Hyeong-U;Kim, Tae-Seong
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2014.02a
    • /
    • pp.217.1-217.1
    • /
    • 2014
  • 반도체 및 디스플레이 산업은 많은 공정들에서 저온 플라즈마 반응을 이용한다. 특히 소자 제작을 위한 실리콘 박막의 증착은 저온 플라즈마 공정의 주요 공정이다. 하지만 실리콘 박막을 합성하는데 있어서 저온 플라즈마에서 형성되는 실리콘 나노 입자는, 오염입자로써 박막의 특성을 악화시켜 소자생산 수율을 악화시키는 주요 원인이 되고 있다. 따라서 플라즈마에서 입자 형성의 원인이 되는 화학반응 및 입자들의 성장 매커니즘에 대한 연구는, 1980년대 플라즈마 공정에서 입자 합성이 보고된 이래 공정의 최적화를 위해 꾸준히 연구되어왔다. 이러한 매커니즘의 연구들은, 플라즈마 화학반응에 의해 실리콘 입자 핵을 만들어 내는 과정과 입자들이 충돌에 의해 성장해가는 과정으로 나눠진다. 플라즈마 화학 반응 과정은 아레니우스 방정식에 의해 정의된 반응계수를 이용하여 플라즈마 내 전자와 이온, 중성 화학종들이 전자 온도와 전자 밀도, 챔버 온도 등에 의해 결정되는 현상을 모사한다. 또한 이 과정에서 실리콘을 포함하는 화학종들의 반응에 의해 핵이 생성 되가는 양상을 모사한다. 생성된 핵은 충돌에 의해 입자가 성장해 가는 과정의 가장 작은 입자로써 이용된다. 입자들이 성장해가는 과정은 입자들이 서로 충돌하면서 다양한 입경의 입자로 분화되어가는 현상을 모사한다. 이 과정에 의해 다양한 입경분포로 분화된 입자들은 플라즈마 내 전자에 의해 하전되며, 이러한 하전 양상은 입경에 따라 다른 분포를 보인다. 본 연구에서는 입자의 하전 분포를 고려하여, 입자들의 성장의 주요 원인인 입자간의 충돌을 대표하는 충돌주파수를 수정하는 방식을 채택하여 보다 정밀한 입자 성장 양상을 모델링하였다. Inductively coupled plasma (ICP) 타입의 저온 플라즈마 반응기에서 합성된 입자들을 Particle Beam Mass Spectrometer (PBMS)와 Scanning Electron Microscope (SEM)를 이용하여 입경분포를 측정한 데이터와 모델링에 의해 계산된 결과를 비교하여 본 모델의 유효성을 검증하였다. 검증을 위해 100~300 mtorr의 챔버 압력 조건과 100~350 W의 입력 전력 조건들을 달리하며 측정한 결과와 계산한 데이터를 조건별로 비교하였다.

  • PDF

Failure Mechanism and Long-Term Hydrostatic Behavior of Linear Low Density Polyethylene Tubing (선형저밀도 폴리에틸렌 튜빙의 파손 메커니즘과 장기 정수압 거동)

  • Weon, Jong-Il;Chung, Yu-Kyoung;Shin, Sei-Moon;Choi, Kil-Yeong
    • Polymer(Korea)
    • /
    • v.32 no.5
    • /
    • pp.440-445
    • /
    • 2008
  • The failure mechanism and failure morphology of linear low density polyethylene (LLDPE) tubing under hydrostatic pressure were investigated. Microscopic observations using video microscope and scanning electron microscope indicate that the failure mode is a brittle fracture including cracks propagated from inner wall to outer wall. In addition, oxidation induction time and Fourier transform infrared spectroscopy results show the presence of exothermic peak and the increase in carbonyl index on the surface of fractured LLDPE tubing, due to thermal-degradation. An accelerated life test methodology and testing system for LLDPE tubing are developed using the relationship between stresses and life characteristics by means of thermal acceleration. Statistical approaches using the Arrhenius model and Weibull distribution are implemented to estimate the long-term life time of LLDPE tubing under hydrostatic pressure. Consequently, the long-term life time of LLDPE tubing at the operating temperature of $25^{\circ}C$ could be predicted and also be analyzed.

Study of Aging and Performance About Separation Devices Has Been Stored (장기 보관된 분리장치의 성능 및 노화에 관한 연구)

  • Kim, Dong-seong;Jin, Hong-Sik
    • Journal of the Korean Society for Aeronautical & Space Sciences
    • /
    • v.49 no.7
    • /
    • pp.565-572
    • /
    • 2021
  • In this study, a study on the performance and aging of explosive bolts stored for a long time among pyrotechnic mechanical devices(PMD) used as separation devices in the defense field is conducted. For this, explosive bolts that had been installed in the weapon system for about 10 years are secured. Performance and life extension test procedures are established based on the AIAA Standard and MIL-STD. Before performance evaluation, non-functional tests are performed to check whether external changes or failures occurred. Next, circuit inspection and X-ray tests are conducted to check the failure in internal circuits and structures. After that, performance test is carried out to confirm the operation of the samples that passed the non-functional test. Through this test, separation of bolt and separation time are measured, and some samples are tested after a high temperature storage test to confirm the remaining life and the possibility of extension. Finally, the remaining life and reliability are predicted based on the results of the test and the Arrhenius model to identify remaining shelf life and reliability depend on time.

Comparison of Measured and Calculated Carboxylation Rate, Electron Transfer Rate and Photosynthesis Rate Response to Different Light Intensity and Leaf Temperature in Semi-closed Greenhouse with Carbon Dioxide Fertilization for Tomato Cultivation (반밀폐형 온실 내에서 탄산가스 시비에 따른 광강도와 엽온에 반응한 토마토 잎의 최대 카복실화율, 전자전달율 및 광합성율 실측값과 모델링 방정식에 의한 예측값의 비교)

  • Choi, Eun-Young;Jeong, Young-Ae;An, Seung-Hyun;Jang, Dong-Cheol;Kim, Dae-Hyun;Lee, Dong-Soo;Kwon, Jin-Kyung;Woo, Young-Hoe
    • Journal of Bio-Environment Control
    • /
    • v.30 no.4
    • /
    • pp.401-409
    • /
    • 2021
  • This study aimed to estimate the photosynthetic capacity of tomato plants grown in a semi-closed greenhouse using temperature response models of plant photosynthesis by calculating the ribulose 1,5-bisphosphate carboxylase/oxygenase maximum carboxylation rate (Vcmax), maximum electron transport rate (Jmax), thermal breakdown (high-temperature inhibition), and leaf respiration to predict the optimal conditions of the CO2-controlled greenhouse, for maximizing the photosynthetic rate. Gas exchange measurements for the A-Ci curve response to CO2 level with different light intensities {PAR (Photosynthetically Active Radiation) 200µmol·m-2·s-1 to 1500µmol·m-2·s-1} and leaf temperatures (20℃ to 35℃) were conducted with a portable infrared gas analyzer system. Arrhenius function, net CO2 assimilation (An), thermal breakdown, and daylight leaf respiration (Rd) were also calculated using the modeling equation. Estimated Jmax, An, Arrhenius function value, and thermal breakdown decreased in response to increased leaf temperature (> 30℃), and the optimum leaf temperature for the estimated Jmax was 30℃. The CO2 saturation point of the fifth leaf from the apical region was reached at 600ppm for 200 and 400µmol·m-2·s-1 of PAR, at 800ppm for 600 and 800µmol·m-2·s-1 of PAR, at 1000ppm for 1000µmol of PAR, and at 1500ppm for 1200 and 1500µmol·m-2·s-1 of PAR levels. The results suggest that the optimal conditions of CO2 concentration can be determined, using the photosynthetic model equation, to improve the photosynthetic rates of fruit vegetables grown in greenhouses.

Models for Hydration Heat Development and Mechanical Properties of Ultra High Performance Concrete (초고성능 콘크리트의 수화발열 및 역학적 특성 모델)

  • Cha, Soo-Won;Kim, Ki-Hyun;Kim, Sung-Wook;Park, Jung-Jun;Bae, Sung-Geun
    • Journal of the Korea Concrete Institute
    • /
    • v.22 no.3
    • /
    • pp.389-397
    • /
    • 2010
  • Concrete has excellent mechanical properties, high durability, and economical advantages over other construction materials. Nevertheless, it is not an easy task to apply concrete to long span bridges. That's because concrete has a low strength to weight ratio. Ultra high performance concrete (UHPC) has a very high strength and hence it allows use of relatively small section for the same design load. Thus UHPC is a promising material to be utilized in the construction of long span bridges. However, there is a possibility of crack generation during the curing process due to the high binder ratio of UHPC and a consequent large amount of hydration heat. In this study, adiabatic temperature rise and mechanical properties were modeled for the stress analysis due to hydration heat. Adiabatic temperature rise curve of UHPC was modeled superposing 2-parameter model and S-shaped function, and the Arrhenius constant was determined using the concept of equivalent time. The results are verified by the mock-up test measuring the temperature development due to the hydration of UHPC. In addition, models for mechanical properties such as elastic modulus, tensile strength and compressive strength were developed based on the test results from conventional load test and ultrasonic pulse velocity measurement.

A Study on the Accelerated Life Test for the Estimation of Licorice Durability in Cosmetics (화장품 중 유용성감초추출물의 유통기한 예측을 위한 가속수명 시험연구)

  • Lee, So-Mi;Joo, Kyeong-Mi;Park, Jong-Eun;Jeong, Hye-Jin;Chang, Ih-Seop
    • Journal of the Society of Cosmetic Scientists of Korea
    • /
    • v.33 no.3
    • /
    • pp.197-201
    • /
    • 2007
  • Oil soluble licorice extract(licorice extract) is an officially approved cosmetic component as a whitening ingredient in Korea. The durability of licorice, during which the whitening effect can be maintained in optimum condition, must be accurately defined. Since the cosmetics durability under real condition is relatively longer than its development time. It is needed to predict the real durability interval from the experimental measurement under simulated operating conditions. We analyzed the relationship between the licorice lifetime and the high temperature condition by using Arrhenius equation. We have established the constant stress test with temperature of $50^{\circ}C$, $55^{\circ}C$, and $60^{\circ}C$ condition, within which no formulation change of licorice products is expected for the accelerated stress test. In this paper, the lifetime of licorice in cosmetics was defined as time period for its 10% contents reduction. We observed that the lifetime of licorice is 580 h at $50^{\circ}C$, 319 h at $55^{\circ}C$ and 166 h at $60^{\circ}C$. Using the above experimental data, we obtained the equation for the relationship between the licorice lifetime and temperature as follows; log(lifetime)=-35.0243 + 1.15322$\times$(11604.83/temperature). From this equation, the lifetime of licorice at $25^{\circ}C$ can be estimated as 26 months. The estimated result was verified by measuring full lifetime of licorice. In fact, there was no significant difference between the estimated lifetime and real measurement within 95 % significance level. This study can be applied to other useful cosmetic components for the fast estimation of the exact durability.

Accelerated Life Prediction on Tensile Strength of Oil Resistance HNBR (내유성 HNBR 고무의 인장강도 성능에 대한 가속수명예측)

  • Kim, Kyung Pil;Lee, Yong Seok;Yeo, Yong Heon
    • Journal of the Korea Academia-Industrial cooperation Society
    • /
    • v.21 no.11
    • /
    • pp.233-238
    • /
    • 2020
  • Although the interest in NBR has been increasing due to the recent developments of the aerospace sector, there are few reports on HNBR's aeronautical oil, particularly evaluations of the accelerated life of harsh factors. In this study, the tensile strength was adopted as a performance evaluation factor to evaluate the accelerated life of HNBR used in the aviation field. The accelerated stress factor affecting the performance-aging characteristics was defined as temperature. The acceleration stress factor was determined to be temperature, and the result of measuring the tensile strength change over time. The sample for the acceleration condition was taken out of the oven for a certain period and left at room temperature for 24 hours. The dumbbell type 3 specimens were manufactured according to the standard specified in KS M 6518 and were measured the tensile strength, a factor in accelerated life evaluations. The activation energy was 0.895, and the shape parameter was 1.152 using the Arrhenius model. The characteristic life obtained from the tensile strength of the HNBR specimen immersed in aviation oil at 20℃ was 272,256 hours; the average life was 258,965 hours, and the B10 life was 38,624 hours.