• Economic and Environmental Geology
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• v.17 no.2
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• pp.101-107
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• 1984

This paper describes dipole-dipole apparent resistivity responses from near-surface cavities in otherwise homogeneous earth materials. In applying the dipole-dipole resistivity method to the problem of locating and delineating subsurface cavities, it is important to know apparent resistivity responses not only for conductive bodies but also for resistive ones. Dipole-dipole apparent resistivities for these bodies are calculated by the numerical modeling technique using an integral equation solution. The magnitude and pattern of apparent resistivity is highly dependent on the ratio of body resistivity to background resistivity. In conductive bodies, the largest anomaly of apparent resistivity appears at the outside of the body. In resistive bodies, however, the position of the largest anomaly coincides with the location of the body. The field results gathered at Okinawa, Japan in 1978 showed that peak anomalies occurred at the locations of air-filled cavities.

• Elastomers and Composites
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• v.18 no.2
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• pp.51-59
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• 1983

The dielectric properties of polymers are very important when investigating the molecular structure of polymers. The characteristics of the dielectric absorption in vulcanized natural rubber were studied in frequency ranging from 10[KHz] to 32[MHz] at the temperature of 25[$^{\circ}C$]. As a result of the study, it has been confirmed that natural rubber vulcanized below 4phr leads to two kinds of dielectric losses due to the interfacial polarization and the dipole polarization by sulfur, and of above 7[%] was only a loss due to the dipole polarization by sulfur. Futhermore, the dielectric loss maximum $tan{\delta}$ spectrum, removed to the low frequency in accordance with increasing sulfur, depends greatly on sulfur. The volume resistivity of $10^{7}{\sim}10^{11}[{\Omega}{\cdot}cm}]$, regardless of whether the crosslinking of rubber is weakened by sulfur, was observed.

• Journal of the Korean Chemical Society
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• v.25 no.2
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• pp.61-66
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• 1981

A method for calculation of the contribution of $\pi$ bonding molecular orbitals to the dipole moments for octahedral [M(III)$A_3B_3$] type complexes has been developed [M(III) = Ti(III), V(III), Cr(III), Fe(III) or Co(III); A = O or N; B = N, S or Cl]. The contribution of ${\pi}$ bonding molecular orbitals to the dipole moments is found to be smaller than that of ${\sigma}$ bonding molecular orbitals but this contribution may not be negligible even for chelate complexes in which delocalization of ${\pi}$ electron is assumed. The calculated dipole moments (u = $u_{\sigma}$ + $u_{\pi}$) are closer to the experimental values than those for the case where only ${\sigma}$ bonds are assumed to be formed.

• Journal of the Korean Chemical Society
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• v.22 no.5
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• pp.295-303
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• 1978

The dipole moments for octahedral [Co(III)-$O_3N_3$], tetrahedral [M(II)-$O_2N_2$] and square planar [M(II)-$O_2N_2$] types complexes are calculated by the expansion method for spherical harmonics using the valence basis sets for the central metal ion and the single basis set orbital ($2p_z$) for ligands. The calculated dipole moments for these complexes are in agreement with the experimental values.

• Analytical Science and Technology
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• v.28 no.3
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• pp.187-195
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• 2015

The heat of sublimation (HOS) is an essential parameter used to resolve environmental problems in the transfer of organic contaminants to the atmosphere and to assess the risk of toxic chemicals. The experimental measurement of the heat of sublimation is time-consuming, expensive, and complicated. In this study, quantitative structural property relationships (QSPR) were used to develop a simple and predictive model for measuring the heat of sublimation of organic compounds. The population-based forward selection method was applied to select an informative subset of descriptors of learning algorithms, such as by using multiple linear regression (MLR) and the support vector machine (SVM) method. Each individual model and consensus model was evaluated by internal validation using the bootstrap method and y-randomization. The predictions of the performance of the external test set were improved by considering their applicability to the domain. Based on the results of the MLR model, we showed that the heat of sublimation was related to dispersion, H-bond, electrostatic forces, and the dipole-dipole interaction between inter-molecules.

• Geophysics and Geophysical Exploration
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• v.5 no.2
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• pp.108-117
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• 2002

We have introduced a new approach to obtain the conductivity information of subsurface using Cagniard impedance over two-dimensional (2-D) model in the presence of horizontal magnetic dipole source with the frequency range of $1\;kHz\~1\;MHz$. Firstly, we designed the method to calculate the apparent resistivity from the ratio between horizontal electric and magnetic fields, Cagniard impedance, considering the source effects when the plane wave assumption is failed in finite source EM problem, and applied it to several numerical models such as homogeneous half-space or layered-earth model. It successfully provided subsurface information even though it is still rough, while the one with plane wave assumption is hard to give useful information. Next, through analyzing Cagniard impedance and apparent resistivity considering source effect over 2-D models containing conductive- or resistive-block, we showed that the possibility of obtaining conductivities of background media and anomaly using this approach. In addition, the apparent resistivity considering source effect and phase pseudosections constructed from Cagniard impedance over the isolated conductive- and resistive block model well demonstrated outlines of anomalies and conductivity distribution even though there were some distortions came from sidelobes caused by 2-D body.

• The Journal of Engineering Geology
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• v.29 no.3
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• pp.223-236
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• 2019

Resistivity surveys can identify the distribution of geological units and structures (including fragmented fault zones), the extent of weathered and modified geological strata, and the characteristics of groundwater. This study aims to analyze the underground sedimentary layers and geological structures near the Nari and Albong Basins of Ulleung-do, Korea, focusing on six survey lines to identify the spatial trends in subsurface resistivity. A modified dipole array method (D method) was employed, combining resistivity results obtained by existing dipole array methods (A and C methods). The modified method provides optimal analysis of the cross-section of underground resistivity, and shows a clear boundary between a low-resistivity zone (${\leq}500{\Omega}{\cdot}m$) of sedimentary layers and weak zones, and a high-resistivity zone (${\geq}5,000{\Omega}{\cdot}m$) of volcanic rock (trachyandesite). The estimated average thickness of the sedimentary layers is 50~100 m for the Albong Basin and 100~200 m for the Nari Basin. An anomaly zone, different from the weak zone in the bedrock, is identified as a caldera fault, and the low-resistivity zone extends from the surface down to the lowest survey depths.

• Journal of the Korean Geophysical Society
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• v.1 no.1
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• pp.41-50
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• 1998

Schlumberger soundings, dipole-dipole survey and electrical conductivity mappings were carried out inside and in front of the entrance of the Okmyung waste landfill in August, 1997 and January, 1998. Inside and in front of the landfill, 11 and 4 electrical soundings and 1 dipole-dipole survey were carried out, respectively. Electrical conductivities were measured at 164 points along the 4 lines in front of the entrance of the landfill. Interpretations of survey data show that low resistivity zones of 0.3∼3 Ωm extend down to 65 m depth from the surface in the 6th landfill, which indicates subsurface contamination by leachate and leachate level at 3∼6 m depth from the surface. In the 9th landfill, low resistivity zones below 2 Ωm appear at 11∼15 m depth from the surface, which indicates a very slim chance of subsurface contamination. On the other hand, electrical surveys and electrical conductivity mappings reveal low resistivities at shallow depths in front of the entrance of the landfill, indicating a high possibility of contamination of weathered zone in this area. It appears that southern part of this area close to the 6th landfill is more contaminated by leachate.

• 한국지구물리탐사학회:학술대회논문집
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• 2000.09a
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• pp.112-131
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• 2000

In spite of its many strong points, pole-pole electrode configuration is not often used for ground electrical resistivity survey except for bore hole survey as normal logging and for archaeological investigation. Above all, poor spatial resolution of pole-pole survey may be responsible for this. But recent experiences so far gained by the present authers lead them to think that pole-pole survey can be at least a viable means of reconnaissance survey in near-surface conductive environment and an effective interpretational scheme may augment its resolution. As well known, a response of any other electrode configuration is a linear combination of pole-pole responses. Based on this principle of linear superposition and the principle of reciprocity, the other 'responses' can be derived with simple additions and subtractions of pole-pole responses. Though such responses are not always correct due to the adverse effects of noises, combined with the potential decay curves, they can be helpful to interprete better pole-pole survey data especially in connection of the resolution. This can be comparable to the use of the first or second derivatives of gravity and magnetic intensity surveys.

• Geophysics and Geophysical Exploration
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• v.5 no.1
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• pp.23-32
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• 2002

Capacitively-coupled resistivity (CCR) system is known to be very useful where galvanic contact to earth is impossible, such as the area covered with thick ice, snow, concrete or asphalt. This system injects current non-galvanically, i.e., capacitively to earth through line antenna and measures potential difference in a same manner. We derived geometric factor for two types of antenna configuration and presented the method of processing and converting the data obtained with CCR system suitable to conventional resistivity inversion analysis. The CCR system, however, has limitations on use at conductive area or electrically noisy area since it is very difficult to inject sufficient current to earth with this system as with conventional resistivity system. This causes low SM ratio when acquiring data with CCR system and great care must be taken in acquiring data with this system. Additionally the uniform contact between line antennas and earth is also crucial factor to obtain good S/N ratio data. The CCR method, however, enables one to perform continuous profiling over a survey line by dragging entire system and thus will be useful in rapid investigation of conductivity distribution in shallow subsurface.