• Title/Summary/Keyword: 실리케이트

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A Basic Study on the Strength Development Characteristics of Calcium Silicate Cement(CSC) Mixed Mortar according to Carbonation Curing Conditions (칼슘실리케이트 시멘트(CSC) 혼입 모르타르의 탄산화 양생 조건에 따른 강도발현 특성에 관한 기초적 연구)

  • Kim, Young-Jin;Ryu, Dong-Woo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2023.05a
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    • pp.141-142
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    • 2023
  • In this study, the strength development characteristics of calcium silicate cement mixed mortar according to carbonation hardening conditions were evaluated. As a result of measuring the compressive strength, the strength increased according to the carbonation hardening time, and the strength increase rate was higher for the specimen with a CO2 concentration of 20%.

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Setting Time and Compressive Strength Gains of Glycocalix Coating Materials with Silica-based Accelerating Agents (실리케이트계 급결제를 혼입한 글라이코 캘릭스 코팅재의 응결시간 및 압축강도 발현 특성)

  • Jeong, Yun-Ji;Yoon, Hyun-Sub;Yang, Keun-Hyeok
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.8 no.1
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    • pp.105-111
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    • 2020
  • The present study examined the effect of the silica-based accelerating agents on the setting time and compressive strength gain of biomimetic glycocalix coating materials that has been developed for protecting the substrate of concrete exposed to chemical and microbiological attacks. The accelerating agent contents varied from 10mL/L to 40mL/L in the mixtures of glycocalix coating materials determined for shotcrete and lining techniques. Test results showed that the setting time of coating materials containing accelerating agents was affected by the contents of the bacteria carrier. When the accelerating agent content was 40mL/L, the final setting time was 80 minutes for shotcrete mixtures and 318 minutes for lining mixtures. Meanwhile, the compressive strength gain of coating materials with accelerating agents tended to be lower than that of counterpart materials without accelerating agents.

Effect of annealing temperature on surface properties of chemical solution derived silicate fiber (화학적 용액법으로 제조한 실리케이트 섬유의 표면 특성에 미치는 열처리 온도의 영향)

  • 황규석;김상복;이영환;장승욱;오정선;안준형;김병훈
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.13 no.5
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    • pp.217-221
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    • 2003
  • In this work, chemical-solution derived silicate fibers were prepared by mixing tetraethyl orthosilicate, ethanol, distilled water, and hydrochloric acid in order to investigate surface roughness of fiber. Silicate fibers were drawn by using a viscous solution after evaporation at $80^{\circ}C$. The dried gel fibers were finally annealed at $1000^{\circ}C$, $1100^{\circ}C$, $1200^{\circ}C$ and $^1300{\circ}C$ for 60 min in dried air (flow rate = ∼200 ml/min). The crystallinity of the heat-treated silica fiber was analyzed by the X-ray diffraction $\theta$-2$\theta$ scan. A field emission-scanning electron microscope and an atomic force microscope were used to evaluate surface properties. The silicate fiber annealed at $1300^{\circ}C$ showed high value of root mean square roughness and had a relatively inhomogeneous surface structure.

Synthesis and Property of Colorless Polyimide and Its Nanocomposite for Plastic Display Substrate (유연성 디스플레이 기판 소재용 투명성 폴리이미드의 합성 및 그의 나노복합화에 대한 연구)

  • Ma Seung Lac;Kim Yong Seok;Lee Jae Heung;Kim Jung Su;Kim Insun;Won Jong Chan
    • Polymer(Korea)
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    • v.29 no.2
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    • pp.204-210
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    • 2005
  • We describe a colorless, transparent polyimide films for plastic display substrate which should have heat resistance, roll-to-roll processability and low CTE (coefficient of thermal expansion) property. Colorless polyimides were synthesized from 3,3',4,4'-oxydiphthalic anhydride (ODPA) 4,4'-(hexafluoroisopropylidene)diphthalic anhydride (6FDA) and diamines such as sulfonyldianiline, aminophenoxybenzene (TPE-p, TPE-q, TPE-r) and bis[4-(3-aminophen oxy)phenyl] sulfone (m-BAPS). Their optical properties were measured by UV spectrophotometer, colormeter and hazemeter. We prepared polyimide/organophilic layered silicate nanocomposite to improve dimension stability. These colorless polyimide films showed UV transmittance by the level upper $89\%$, at 440 nm and excellent optical property having the value under yellow index (YI)=7. In addition, polyimide nanocomposite films also showed an improvement of CTE value as decreased according to the amount of layered silicate contents.

A Study on the Preparation of Polyimide/Clay Nanocomposites (폴리이미드/Clay 나노복합재료의 합성에 관한 연구)

  • 이충언;배광수;최현국;이정희;서길수
    • Polymer(Korea)
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    • v.24 no.2
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    • pp.228-236
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    • 2000
  • The preparation of organophilic clay from Na$^{+}$-MMT was achieved by intercalation of alkylammonium bromide. The dispersed organophilic clay in NMP was then added to the solution of polyamic acids (BPDA-PPD, BTDA-ODA/ MPD) in NMP. After curing at 30$0^{\circ}C$, thin films of the polyimide/clay nanocomposite were prepared. The results of X-ray diffraction (XRD) shelved that the d-spacings of dried polyamic acid (PAA)-clay complexes increased in proportion to the chain length of the onium ion and patterns of two kinds of PAA-clay complexes were similar. The d-spacings of approximately 13.2 $\AA$ for the polyimide/clay nanocomposites were independent of the initial onium ion chain length and the species of PAA. From the study of XRD and transmission electron microscopy (TEM), we found layered silicates were dispersed in polyimide matrix and the resultants were intercalated nanocomposites. TGA result showed thermal stability of polyimide nanocomposite improved a little more than the pure polyimide. From the result of dynamic mechanical property, we found that the storage modulus of the nanocomposites had increased by 1.2-1.8 times of the pure polyimides.s.

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Study on Performance of Lithium-Silicate Permeation and Changing Prosity Structure according to Water Content (수분의 함수율에 따른 공극구조의 변화와 리튬실리케이트의 침투성)

  • Kim, Kwang-Ki;Moon, Hyung-Jae;Kim, Jeong-Jin;Park, Soon-Jeon;Lee, Joo-Ho;Jung, Sang-Jin
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.769-772
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    • 2008
  • Pores can become factors of reducing the capacity of concrete by being path of degradation factors and moisture can fill up pores inside of concrete, so evaluating the effect of unidirectional permeability due to moisture on pore structure of concrete structure is very important. Therefore, the change of pore structure in cases of 0%, 40%, 60%, 80% and 90% humidity being maintained on test specimens and in case of Lithium Silicate, which is chemical compound, being coated were evaluated. As a result, the condensation due to moisture could be confirmed since unidirectional permeability was decreased and the density of Pore Structure was improved as the percentage of water content was being increased. And, solution-type Lithium Silicate fills up pores of sizes around 1$\mu$m in the condition of carrying water and improves the density but the range of capacity improvement due to osmosis will be limited according to functional conditions.

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