• Journal of the Korean Academy of Esthetic Dentistry
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• v.25 no.2
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• pp.79-87
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• 2016

Single visit monolithic restoration can be proceed with digital workflow which consist of intraoral scanning, dental CAD(computer aided design) and restoration milling with CAM(Computer aided manufacturing). While zirconia has more than 900MPa of flexural strength compared with 400MPa for lithium disilicate, shortened fabricating time of lithium disilicate is considered to be a better choice for fabricating single visit full contour monolithic restoration. However, new zirconia materials which are TZI C(Dentsply Sirona) and LUXEN Enamel(Dental Max), new induction heating method of sintering furnace, and new sintering protocols for MoSi2 heating elements sintering furnace offer significantly reduction of full contour monolithic zirconia restoration fabrication time with greater translucency. These new developments lead single visit zirconia restoration in reality.

• Journal of the Korea Concrete Institute
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• v.27 no.3
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• pp.265-272
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• 2015

In this study, a method to reduce temperature rise due to hydration in mass concrete is investigated. It is to use retarder (glucose) for reducing heat of hydration and to use calcium silicate hydrate (C-S-H) for compensating the retardation effect due to its role as a nucleation seed. For this purpose, the temperature rise of cement paste due to hydration was measured and the effect of using both C-S-H and glucose on setting and 28-day compressive strength of mortar specimens was investigated. According to the experimental results, using C-S-H and glucose caused the reduction in the maximum temperature but accelerated the time to reach the maximum temperature compared to that of retarded cement paste using glucose. In addition, using C-S-H and glucose did not show significant effect on 28-day compressive strength of mortar specimens, indicating that the method shown in this study can be a successful alternative to control maximum temperature rise in mass concrete.

• Polymer(Korea)
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• v.28 no.2
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• pp.177-184
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• 2004

Polymer-clay nanocomposite containing the low amounts of clay shows improved physical, mechanical properties. In this study, allyl ester prepolymer was synthesised by reactions of the diallyl terephthalate monomers and the 1,3-butanediol monomers. Nanocomposites of allyl ester prepolymer and the two kinds of the organically layered silicate were prepared by using the intercalation method as well as the in-situ polymerization method using. By varying the amount of clay content, curing conditions, and feeding conditions. the nanocomposite was studied using X-ray diffraction. From XRD results, allyl ester-Cloisite 30 B nanocomposite made by the in-situ polymerization method shows better exfoliation behavior compared with the intercalation method. It can be said that the transesterification reaction between functional groups (-OH) of intercalant and monomers results in the increased gallery distance. Also mechanical and thermal properties indicate that the dispersity of clay is an important factor for improving physical properties of the nanocomposite.

• Membrane Journal
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• v.16 no.2
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• pp.85-105
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• 2006

Poly(lactic acid) is a linear aliphatic thermoplastic polyester, produced by the ring-opening polymerization of lactides and the lactic acid monomers, which are obtained from the fermentation of sugar feed stocks, corn, etc. PLA has high mechanical, thermal plasticity, fabric-ability, and biocompatibility, So PLA is a promising polymer far various end-use applications. In recent time, the intercalation of polymers from either solution or the melt in the silicate galleries of clay is the best technique to prepare nanocompoiste material which often exhibit remarkable improvement of mechanical, thermal, optical and physicochemical properties when compared with the pure polymer or conventional composites. Layered silicate is naturally abundant, economic, and more importantly benign to the environment.

• Applied Chemistry for Engineering
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• v.19 no.4
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• pp.452-456
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• 2008

Mesoporous silicate materials have been used as adsorbents due to the advantage of high specific surface area and regular mesopores. In this study, conventional mesoporous silicates (MCM-41, and SBA-15) were utilized as adsorbents for gaseous benzene, one of volatile organic compounds. In the results of the breakthrough curves of gaseous benzene, SBA-15 showed a higher benzene adsorption capacity in adsorption condition of this study. Especially, compared to benzene adsorption of zeolite X, that of SBA-15 was higher by a factor of 2.7. With increasing adsorption temperature, adsorption capacity for benzene of SBA-15 was decreased rapidly. This indicates that benzene adsorbed weakly on SBA-15.

• Journal of the Korea Institute of Building Construction
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• v.20 no.5
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• pp.425-432
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• 2020

The appearance of Korean traditional roof tiles is beautiful and excellent in water resistance, fire resistance and durability, but a high sintering temperature of 1,200℃ or higher is required. Therefore, due to the economical and heavy weight problem, the current trend is to use different roof finishing materials than Korean traditional roof tiles. By adding nanoaluminosilicate to clay and kaolin, which are the materials of the clay roof tiles, the sintering temperature is sintered at a low temperature of 1,000℃ or less, and the optimal mixing and material process is designed to satisfy the characteristics required as a Korean traditional roof tile. The results of this study again demonstrate the superiority of Korean traditional tiles with roof finishing materials using nanoaluminate. The properties of Korean traditional roof tiles that satisfy the criteria of KS F 3510 by applying fire resistance of natural minerals and nanoparticle technology to flexural strength of 2800N, Bulk specific gravity of 2.0g/㎤ and absorption rate of less than 10.0%, through which and researched materials development.

• Journal of the Mineralogical Society of Korea
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• v.20 no.4
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• pp.247-253
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• 2007

The effect of heat treatment and acid leaching of siliceous mudstone on the purity of silica precursors, such as sodium silicate and silicic acid, was studied. As well as the temperatures for the heat treatment of siliceous mudstone, the concentrations of hydrochloric acid and sulfuric acid were varied to achieve the highest content of silicon in the precursors while minimizing energy and chemical consumption. It was found that the optimum conditions were achieved at the heat treatment temperature of $600^{\circ}C$ and hydrochloric acid of 1.56 M. The relative concentrations of silicon in the synthesized sodium silicate and silicic acid were as high as 99.2 and 99.5%, respectively.

• Journal of the Korea institute for structural maintenance and inspection
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• v.28 no.3
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• pp.59-65
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• 2024

In this study, in order to improve the mechanical properties and durability of asphalt mixtures, a modifier (CSM, Cationized Silicate Modifier) was applied to asphalt to derive optimal mixing ratio conditions. Design of asphalt mixture using modified asphalt binder was conducted, and moisture resistance and dynamic stability were evaluated for optimal mixing conditions. The evaluation results showed that it exceeded the standards stipulated in the relevant guidelines, and as a result of conducting a water permeability test on the optimal mixing condition, it was confirmed that impermeable performance was secured. As a result of examining the noise reduction performance through field test, a noise reduction performance of about 10 dB was secured compared to before paving. It will be necessary to secure reliability through continuous noise generation evaluation in the future.

• Journal of the Korean Applied Science and Technology
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• v.33 no.3
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• pp.441-448
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• 2016

Heavy metal removal study is conducted from synthetic waste water by reduction and oxidation(redox) reaction of Cu-Zn metal alloy and adsorption reaction of aluminium silicate. Heavy metal whose ionization tendency is smaller than zinc are reducted in an aqueous solution, and the concentration of ionized zinc is reduced by adsorption reaction. The average diameter of metal alloy micro fiber is about $200{\mu}m$, and the surface area is wide enough to get equilibrium in a single cycle treatment. A single cycle treatment of redox reaction of Cu-Zn metal alloy, could remove 100.0 % of Cr(III), 98.0 % of Hg, 92.0 % of Sn and 91.4 % of Cu respectively. An ionization tendency of chromium is very close to zinc, but removal efficiency of chromium by redox reaction is significant. This result shows that trivalent chromium ion is expected to generate hydroxide precipitation with $OH^-$ ion generated by redox reaction. Zinc ion generated by redox reaction is readily removed by adsorption reaction of aluminium silicate in a single cycle treatment. Other heavy metal components which are not perfectly removed by redox reaction also showed very high removal efficiency of 98.0 % or more by adsorption reaction. Aluminium ion is not increased by adsorption reaction of aluminium silicate. That means heavy metal ion removal mechanism by adsorption reaction is turned out to be not an ion exchange reaction, but an adsorption reaction.

• Journal of the Korea Concrete Institute
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• v.16 no.1 s.79
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• pp.70-78
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• 2004

Although set accelerating agents are used generally in New Austrian Tunneling Method, the standards for test methods and quality of set accelerating agents are not prescribed domestically. In this study, the proprieties of the various standards and the characteristics of set accelerating agents for shotcrete were evaluated. The alkali contents of set accelerating agents based on silicate, aluminate and cement were higher than those of alkali-free ones. From the result, it is thought that the quality control of aggregate should be enhanced and that the number of test cycle of alkali-aggregate reaction should be increased. The setting times of cement paste with set accelerating agents based on silicate and alkali-free ones were different largely with mixing methods. Compressive strength of mortar with set accelerating agents based on silicate, aluminate and cement at one day satisfied the specifications of Korea Concrete Institute. However, the strength ratio compared to control mix at 28 days showed as $50{\~}65\%$ except for the alkali-free set accelerating agents. As a results of setting time and strength test, the establishment of domestic standards that can reflect the characteristics of materials and construction methods of tunnels and that can increase quality of set accelerating agents is required immediately.