• Analytical Science and Technology
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• v.26 no.2
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• pp.154-163
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• 2013

The maximum residue limits of pyrimisulfan is set as 0.05 mg/kg in rice in 2011, so very reliable and sensitive analytical method for pyrimisulfan residues is required for ensuring the food safety of pyrimisulfan residues in agricultural products. In this study, a rapid and sensitive analytical method was developed and validated using liquid chromatography electrospray ionization tandem mass spectrometry (LC-MS/MS) for the determination of herbicide pyrimisulfan residues in agricultural products. Average recoveries of pyrimisulfan ranged from 88.7 to 99.3% at the spiked level of 0.005 mg/kg and from 90.1 to 94.2% at the spiked level of 0.05 mg/kg, while the relative standard deviation was less than 10%. Linear range of pyrimisulfan was between 0.01~1.0 ${\mu}g/mL$ with the correlation coefficient ($r^2$) 0.999 and limit of quantification was 0.005 mg/kg. The results of method validation were satisfied Codex guideline. The results revealed that the developed and validated analytical method is possible for pyrimisulfan determination in agricultural product samples and will be used as an official analytical method.

• Proceedings of the Korea Water Resources Association Conference
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• 2011.05a
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• pp.332-332
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• 2011

하천 유사량 특성 분석은 하천유역 내의 수리구조물 설계 및 유지관리, 하천개수 및 하도의 안정, 홍수터 관리, 저수지 설계 및 운영 등 수자원 개발 및 관리를 위한 하천계획의 필요한 요소 중 하나이며 현장 측정에서 분석까지 정밀한 일련의 과정을 통해서 알아낼 수 있다. 본 연구에서는 6개 지점(여주, 왜관, 진동, 공주, 나주, 구례2)에 대해 유사량 특성 분석을 수행하였다. 부유사량은 강우가 집중되는 홍수기(왕복수심적분법; D-74측정장비 / 표면채취법)를 중심으로 측정하였고 하상토의 경우는 Grab Sampler(60L), 선격자법 등을 이용하여 홍수기 전 후로 2회 채취하였다. 채취된 시료는 특성에 따라 여과법(부유사농도), BW관법(부유사입도분포), 체분석법(하상토입도분포)으로 분석하였으며, 이를 통해 산정된 평균 부유사농도, Oden Curve와 입도분포곡선 및 수리량(수위, 유속, 측정수심, 수면폭, 수면경사, 수온)등의 자료를 이용하여 총유사량(Modified Einstein 방법)을 추정하였다. 본 연구 결과는 다음과 같다.: 1) 유량-부유사량 및 총유사량 관계: 유량-부유사량의 관계에 있어 대체적으로 일관된 경향성이 나타났으며 총유사량과의 관계 역시 부유사량과 비슷한 경향성을 보임. 일부 성과의 경우, 총유사량과의 관계에 있어 Modified Einstein 조건의 불충족(자갈하상재료 또는 저유속)으로 부유사량과 동일추정이거나 추정불가 및 이상치가 나타남. 2) 유량-부유사량 특성: 전체적으로 루프현상을 보이며 초기 강우 사상에서는 더 많은 유사량이 발생하는데 이는 초기 강우에 의해 유사 이송이 활발하게 이루어지는 일반적인 특성임. 또한 수위 상승-하강에 따른 부유사량 자료가 더욱더 확보된다면 수위 상승과 하강부로 구분하여 분석하는 것도 의의가 있을 것으로 판단됨. 3) 유량-유사량관계식 개발: 개발된 관계식은 총유사량이 아닌 부유사량으로 개발되었으며, 측정성과들 간의 상관계수가 0.9723(구례2 지점) ~ 0.8490(나주 지점)으로 분석됨. 또한 개발된 관계식에 대한 신뢰도 분석을 실시하지 않았기 때문에 적용 시에는 주의가 요구됨.

• Progress in Medical Physics
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• v.20 no.4
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• pp.308-316
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• 2009

To achieve the accurate evaluation of given absorbed dose from output dose of linear accelerator photon beam through investigate the characteristics of LiF:Mg,Cu,P TLD powder. This experimental TL phosphor is performed with a commercial LiF:Mg,Cu,P powder (Supplied by PTW) and TL reader (LTM, France). The TLD was exposed to 6 MV X rays of linear accelerator photon beam with range 15 to 800 cGy in blind dose at two hospitals. The dose evaluation of TLD was through the experimental algorithms which were dose dependency, dose rate dependency, fading and powder weight dependency. The glow curve has shown the three peaks which are 110, 183 and 232 degrees of heating temperature and the main dosimetric peak showed highest TL response at 232 high temperature. In this experiments, the LiF:Mg,Cu,P phosphor has shown the 2.5 eV of electron trap energy with a second order. This experiments guided the dose evaluation accuracy is within 1% +2.58% of discrepancy. The TLD powder of LiF:Mg,Cu,P was analyzed to dosimetric characterists of electron captured energy and order by glow shape, and dose-TL response curve guided the accuracy within 1.0+2.58% of output dose discrepancy.

• Fire Science and Engineering
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• v.23 no.2
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• pp.55-61
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• 2009

This study has been carried on the transient phenomenon protection system to become fire alarm system control unit of high reliance which can be protected from transient phenomena for surge or transient overvoltage, and constructed engineering base that can develop transient phenomenon protection system by proving performance of protection system in a experimental. This study developed 1 step and 2 step protection system that can be protected from transient phenomenon with process thesis and theory for development of transient phenomenon protection system. It established engineering data construction and a source technology that can develop transient phenomenon protection system as gets satisfied result and test with all performance condition that present in fire protection law and connection regulation.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.10 no.3
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• pp.39-47
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• 1990

The generation of artificial accelerograms considering the characteristic of earthquakes in the Korean peninsula for a time history analysis of structures is accomplised by the stochastic method. The engineering data such as a representative shape of envelope function and an effective duration are investigated from the instrumental records. The maximum ground acceleration value is based on seismic zoning map which are constructed for the Korean peninsula. The acceleration-time histories are generated for two different types of earthquake motions and two types of soil conditions. In the study, the maximum ground acceleration value of 0.2 g and effective durations of 24 seconds are used. The validity of the artificial accelerograms is obtained by the comparison with the required envelope functions and the design response spectrum.

• Journal of Applied Biological Chemistry
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• v.53 no.1
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• pp.25-30
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• 2010

This paper describes a simultaneous method for the determination of two aminoglycosides (neomycin and gentamicin) using solid phase extraction followed by liquid chromatograph-mass spectrometry. The extract was applied to an WCX and HLB solid phase extraction cartridge. The cartridges were washed with water and methanol, and analytes were eluted with TCA buffer-acetonitrile mixture. The aminoglycosides were separated by ion-pairing reversed phase mode prior to ESI-LC/MS. Under the conditions applied neomycin was almost separated from all the gentamicin compounds. No interfering peaks from endogenous compounds of matrix were noted at the elution position of the analytes. Recoveries of neomycin fortified at levels of 0.25, 0.5, 1.0 and 2.0 mg/kg seafood samples ranged from 92 to 115%. Recoveries of gentamycin fortified at levels of 0.05, 0.1, 0.2, 0.4 mg/kg seafood samples ranged from 99 to 116%. Method detection limits in four seafood sample matrices were between 0.002 and 0.033 mg/kg.

• Journal of the Korean Society of Food Science and Nutrition
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• v.34 no.4
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• pp.549-556
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• 2005

Response surface methodology (RSM) was applied in steaming and roasting processes of Polygonatum odoratum roots in order to monitor hypoglycemic components and sensory property. In steaming and roasting processes based on the central composite design with variations in steaming time $(60\~180\;min)$, roasting temperature $(110\~150^{\circ}C)$ and roasting time $(10\~50\;min)$, coefficients of determinations $(R^2)$ were 0.8691 (p<0.05), 0.8253 (p<0.l0), 0.8727 (p<0.05), 0.8706 (p<0.05) and 0.8316 (p<0.10) in soluble solid, stigmasterol, $\beta-sitosterol$, hypoglycemic component (total), and overall acceptability, respectively. The maximum value of soluble solid was $71.47\%$ in 65.24 min of steaming time, $126.93^{\circ}C$ of roasting temperature and 37.58 min of roasting time. The maximum value of hypoglycemic component (total) was $764.10\;{\mu}g/g$ in 107.76 min, $117.78^{\circ}C$ and 14.70 min. Meantime, the maximum value of overall acceptability was 6.89 in 126.04 min, $115.79^{\circ}C$ and 43.93 min. The predicted values in optimum conditions for hypoglycemic components and sensory property were in good agreement with experimental values.

• Journal of Conservation Science
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• v.30 no.4
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• pp.467-480
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• 2014

This study was focused on measurement methods for stone cultural heritages by analyzing Ultrasonic (P-wave) velocity variations according to the water content and anisotropy of rocks. As a result of analyzing of rock properties, the water content and saturation degree were rapidly changed at the beginning of drying and then showed exponential curve which their rates of change gradually decreased. However, P-wave velocity and its rate of change maintained constant values after natural drying of 10 hours. Therefore, the ultrasonic measurement for stone cultural heritages should be performed after natural drying of 10 hours considering the weather and moisture conditions. In addition, the highest values of anisotropy coefficient exhibited in granite and limestone, and indirect method was insensitive to anisotropy compared to direct method. However, all rocks remained anisotropy by indirect method. Accordingly, ultrasonic measurement considering various directions is required. The research results will contribute to customized non-destructive testing and precise diagnosis for lithological characteristics of stone cultural heritage.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.40 no.4
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• pp.371-381
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• 2020

The failure mode of concrete reinforced with FRP is defined as the concrete crushing and the fiber rupture and the definition of limit state is a slightly different according to the design methods. It is relatively difficult to predict of FRP reinforced concrete because the mechanical properties of fibers are quite depending on its of fibers. The design code by ACI440 committee, which has been developed mainly on GFRP having low modulus of elasticity, is widely used, but the applicability on other FRPs of this code has not been sufficiently verified. In addition, the ultimate and serviceability limit state based on the ACI440 are comparatively difficult to predict the behavior of member with the 0.8~1.2 𝜌_b because crushing and rupturing failure can be occurred simultaneously is in this region of reinforcement ratio, and predicted deflection is too sensitive according to the loading condition. Therefore, in this study, reliability and convenience of the prediction of structural performance by design methods such as ACI440 and MC90 concept, respectively, were examined through the experimental results and literature review of the beam and slab with the reinforcement ratio of 0.8 ~ 1.4. As a result of the analysis, it can be applied to the FRP reinforced structure in the case of the simple moment-curvature formula (LIM-MC) of Model Code, and the limit state design method based on the EC2 is more reliable than the ultimate strength design method.

• The Korean Journal of Pesticide Science
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• v.15 no.2
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• pp.149-159
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• 2011

Bentazone is benzothiadiazole group herbicide, and used to foliage treatment. This herbicide have already been widely used for cereals and vegetables planting in worldwide. This experiment was conducted to establish a determination method for bentazone residue in crops using HPLC-UVD/MS. Bentazone residue was extracted with acetone (adjusted pH 1 with phosphoric acid) from representative samples of five raw products which comprised hulled rice, soybean, apple, green pepper, and Chinese cabbage. The extract was diluted with saline water, and dichloromethane partition was followed to recover bentazone from the aqueous phase. Florisil column chromatography was additionally employed for final clean up of the extract. The bentazone was quantitated by HPLC with UVD, using a YMC ODS AM 303 ($4.6{\times}250$ mm) column. The crops were fortified with bentazone at 3 levels per crop. Mean recovery ratio were ranged from 82.0% for a 0.2 mg/kg in apple to 97.9% for a 0.02 mg/kg in Chinese cabbage. The coefficients of variation were ranged from 0.5% for a 0.02 mg/kg in soybean to 9.7% for a 0.02 mg/kg in Chinese cabbage. Quantitative limit of bentazone was 0.02 mg/kg in representative five crop samples. A LC/MS with selected-ion monitoring was also provided to confirm the suspected residue. Therefore, this analytical method was reproducible and sensitive enough to determine the residue of bentazone in agricultural commodities.