• Elastomers and Composites
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• v.47 no.1
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• pp.9-17
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• 2012

Herein, life time prediction based on the deterioration of physical properties of chloroprene rubber (CR)aged by heat and seawater was performed. CR samples were experienced an accelerated test at $80^{\circ}C$, $100^{\circ}C$, $120^{\circ}C$ for heat aging, and $40^{\circ}C$, $60^{\circ}C$, $80^{\circ}C$ for seawater aging for 20,000 hrs. The change in tensile strength, maximum elongation,hardness was measured. As a result, the decrease in elongation was a major factor causing failure. The life time estimated using an Arrhenius model was 125 years at $23^{\circ}C$ for thermal aging and 9 years at $23^{\circ}C$ for seawater aging. SEM and elemental analysis reveal that cracks were generated and the content of oxygen was increased for CR agined by seawater. FT-IR spectrum shows the new C-O and C = O bonds were generated by the chemical reaction with seawater. Also, the glass transtion temperature was increased and the thermal decomposition was decreased by seawater aging.

• Proceedings of the Korean Nuclear Society Conference
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• 1998.05b
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• pp.305-311
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• 1998

최근들어 고려된 LBB(Leak Before Break) 적용요건중 동적파괴시힘 절차에는 울진 3&4호기 이후 파단전누설개념이 적용되는 배관이 탄소강으로 제작될 경우. 이 배관이 Dynamic Strain Aging (DSA)에 의해 파괴저항치가 감소되지 않는다는 것이 정량적으로 입증되지 않는 한, 동 배관의 파괴 물성치 결정시 DSA의 영향이 고려되어야 하며, DSA 영향을 평가하기 위해서는 동적과괴시험이 수행되어야 함을 요건화 하고 있다. 본 연구에서는 DSA 효과에 의한 파괴저항(J-R) 특성의 저하가차세대원전 원자로냉각재배관 파단전누설개넘(LBB) 적용시 설계 안전여유도에 영향을 미치지 않는 정도임을 평가하는데 있다. 따라서 ASME Section III에서 탄소강으로 분류하고 있는 강종별 파괴인성 변화를 고찰하고, 차세대원전 주냉각재배관 재료인 SA508 Class la의 최대 파괴인성 감소치를 예측하여, 울진 3&4호기에서 측정된 엘보우용 SA516-Gr.70 강의 DSA 영향 평가 결과와 비교 분석하여 차세대원전 주냉각재배관의 DSA영향을 평가하였다. 도출된 결론으로는 DSA 영향을 고려한 SA508 Class la의 J 및 dJ/dA 값은 극히 보수적으로 추정할 때 50% 이상 감소하는 것으로 예측된다. 이러한 DSA 영향을 고려하였을 경우 배관재 모재의 파괴인성치는 Weld-SAW의 J/T 값 수준으로 감소하였다. 그러나 현 LRB 해석이 가장 낮은 J/T값을 갖는 Weld-SAW Auto의 균열길이 2a인 J/T선도에 의거하여 수행되고 있다는 점을 고려한다면 비록 DSA가 배관재에 영향을 주는 가장 보수적인 값(J 및 dJ/dA값을 50% 이상)을 사용한다고 하더라도 차세대원전 LBB 적용에 문제가 되지 않음을 알 수 있다. 즉 차세대원자로 주냉각재배관에 LBB를 적용하는데는 DSA 영향은 상대적으로 중요하지 않다는 결론을 얻었다. 표면에 수소화물이 농축되어 있는 hydride layer가 형성됨을 관찰하였으며 ～5,000ppm 이상의 경우에는 수소화물의 방향성이 random하였으며 특히, ZIRLO$^{TM}$ 시편의 경우에서는 원주방향으로 길게 이어진 수소화물과 기계적 성질에 치명적인 반경방향의 수소화물이 평행하게 배열된 것을 관찰하였다.하였을 때는 Li$_2$O의 첨가에 의해 치밀화가 주로 일어났고, 반면에 $N_2$-7vol.%H$_2$ 분위기에서 소결하면 Li$_2$O의 첨가에 의해 작은 기공은 소멸되고 큰 기공이 생성되었다.지나치게 모국어의 영향만 강조하고 다른 요인들에 대해서는 다분히 추상적인 언급으로 끝났지만 이 분석을 통 해서 배경어, 목표어, 특히 중간규칙의 역할이 괄목할 만한 것임을 가시적으로 관찰할 수 있 다. 이와 같은 오류분석 방법은 학습자의 모국어 및 관련 외국어의 음운규칙만 알면 어느 학습대상 외국어에라도 적용할 수 있는 보편성을 지니는 것으로 사료된다.없다. 그렇다면 겹의문사를 [-wh]의리를 지 닌 의문사의 병렬로 분석할 수 없다. 예를 들어 누구누구를 [주구-이-ν가] [누구누구-이- ν가]로부터 생성되었다고 볼 수 없다. 그러므로 [-wh] 겹의문사는 복수 의미를 지닐 수 없 다. 그러면 단수 의미는 어떻게 생성되는가\ulcorner 본 논문에서는 표면적 형태에도 불구하고 [-wh]의미의 겹의문사는 병렬적 관계의 합성어가 아니라 내부구조를 지니지 않은 단순한 단어(minimal $X^{0}$ elements)로 가정한다. 즉, [+wh] 의미의 겹의문사는 동일한 구성요 소를 지닌 병렬적 합성어([$[W1]_{XO-}$ $[W1]_{XO}$ ]$_{XO}$)로

• Journal of the Korean Society for Nondestructive Testing
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• v.21 no.3
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• pp.288-298
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• 2001

There has been a growing interest in thick composite materials especially for primary structures. Fiber waviness is one of the manufacturing defects frequently encountered in thick composite structures and affects the mechanical properties such as stiffness and strength significantly. Therefore, nondestructive evaluation technique that can detect fiber waviness of thick composite is very important for the integrity of structures. In this study, efforts were made to understand ultrasonic wave propagation in thick composites with uniform fiber waviness by adopting the ray and plane wave theories. Both theoretical and experimental investigations were conducted to understand the wave propagation in thick composites with uniform fiber waviness. The experiments were conducted on specially fabricated thick composite specimens with various degrees of uniform fiber waviness using the conventional through-transmission method to verify the predicted results. The experimental results showed good agreement with the theoretical predictions.

• Journal of the Korean Society for Nondestructive Testing
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• v.33 no.2
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• pp.193-197
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• 2013

In this study, ultrasonic nonlinear characteristics in the heat-treated aluminum alloy have been evaluated. The nonlinearity of ultrasonic wave has been measured as the acoustic nonlinear parameter ${\beta}$, depending upon the amplitude ratio of the second-order harmonic and the fundamental frequency component of ultrasonic wave propagating through the materials. The parameter ${\beta}$ measurement has been carried out with the reflected signals from the back-wall of specimens at the same plane using the contact-type transducers. The heat-treatment, aging, has been achieved at $300^{\circ}C$ for various durations in the range of 1 to 50 hours. The tensile strength and elongation are obtained by the tensile test and then compared with the parameter ${\beta}$. There is a peak of the acoustic nonlinear parameter ${\beta}$ on 5 hours aging and the ${\beta}$ decreases thereafter, exhibiting closed relations with tensile strength and elongation. Also, the heat-treatment time showing peak in the parameter ${\beta}$ was identical to that showing severe change in the ${\sigma}-{\varepsilon}$ curve. These results suggest that the acoustic nonlinear parameter ${\beta}$ can be used for monitoring the strength variations with aging of aluminum alloys.

• Journal of the Microelectronics and Packaging Society
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• v.21 no.3
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• pp.25-29
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• 2014

Plasma organic thin film for PCB surface finish is a potential replacement of the conventional PCB finishes because of environment-friendly process, high corrosion-resistance and long shelf life over 1 year. In this study, solder joint properties of the plasma organic surface finish were estimated and compared with OSP surface finish. The plasma surface finish was deposited by chemical vapor deposition from fluorine-based precursors. The thickness of the plasma organic coating was 20 nm. Sn-3.0Ag-0.5Cu (SAC305) solder was used as solder joint materials. From a salt spray test, the plasma organic coating had higher corrosion resistance than the OSP surface finish. The spreadability of SAC305 on plasma organic coating was higher than that on OSP surface finish. SEM and TEM micrographs showed that the interfacial microstructure of the plasma surface finish sample were similar to that of the OSP sample. Solder joint strength of the plasma finish sample was also similar to that of the OSP finished sample.

• The korean journal of orthodontics
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• v.39 no.5
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• pp.320-329
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• 2009

Objective: The aim of this study was to evaluate the effect of metal primers and thermocycling on shear bond strength between the orthodontic bracket and gold alloy. Methods: For this study, 80 specimens made of dental gold alloy were divided into 8 groups based on the combination of metal primers (none, Alloy primer, Metaltite, V-primer) and thermocycling (with and without thermocycling). Shear bond strength testing was performed with a universal testing machine. Bond failure sites were classified by a modified ARI (Adhesive Remnant Index) score. Results: All metal primer treated groups showed a significantly higher shear bond strength than the only sandblasting treated group without thermocycling (p < 0.05). There were no significant differences on shear bond strength in the groups with thermocycling (p > 0.05). Bond failure sites of the metal primer treated group without thermocycling occurred at gold alloy/adhesive interface, whereas there were no differences on bonding failure sites in the groups with thermocycling. Conclusions: These findings suggest that using metal primer on gold alloy enhances the initial bracket bond strength. But, this effect was not shown with thermocycling.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2018.06a
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• pp.116-116
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• 2018

부식은 재료와 사용 환경과의 상호작용에 의한 결과로서 일반적으로 두께의 감소와 균열의 발생 및 파손 등의 문제로 나타난다. 특히 사용환경 중에서 해수 분위기는 금속의 부식에 가장 유리한 조건이다. 따라서 해양환경 중 항만이나 조선 및 해양 산업 등에 많이 이용되는 강 구조물은 이에 대응하기 위하여 도장방식이나 음극방식을 사용하고 있다. 여기서 음극방식은 피방식체를 일정전위로 음극 분극하는 원리로써 외부전원을 인가하거나 비전위의 금속을 전기적으로 연결하여 방식하는 방법이다[1]. 한편, 해수 중에서 이와 같은 원리로 음극방식 할 경우에는 피방식체인 강재표면에 부분적으로 칼슘 또는 마그네슘 화합물 등의 생성물이 부착하는 현상을 볼 수 있게 된다. 이와 같이 수산화마그네슘($Mg(OH)_2$)및 탄산칼슘($CaCO_3$)을 주성분으로 하여 석출되는 석회질 피막(calcareous deposits)은 피방식체에 유입되는 음극방식 전류밀도를 감소시켜 주거나 물리적 장벽의 역할을 함으로써 외부의 산소와 물 등 부식환경으로부터 소지금속을 보호한다[2]. 그러나 석회질 피막은 소지금속과의 결합력, 막의 균일한 분포, 내식성 및 제작시간의 단축 등 해결해야 할 과제가 있다. 또한 여러 가지 환경 조건 등의 영향을 받아 그 피막의 형성 정도도 가늠하기 어렵기 때문에 음극방식 설계 시 그 정도에 따른 영향을 고려-반영하기가 곤란하다. 따라서 본 연구에서는 석출속도, 밀착성 및 내식특성을 향상시키기 위해 전착프로세스를 통해 해수 중 기체를 용해시켜 석회질 피막을 제작하고 막의 결정구조 제어 및 특성을 분석-평가하였다. 본 연구에 사용된 강 기판(Steel Substrate)은 일반구조용강(KS D 3503, SS400)을 사용하였으며, 외부전원은 정류기(Rectifier, xantrex, XDL 35-5T)를 사용하여 3 및 $5A/m^2$의 조건으로 인가하였다. 양극의 경우에는 해수에 녹아있는 이온 이외에 다른 성분들이 환원되는 것을 방지하기 위해 불용성 양극인 탄소봉(Carbon Rod)을 사용하였다. 이때 석출속도, 밀착성 및 내식특성 향상을 위해 해수에 주입한 기체의 양은 0.5 NL/min였으며, 기판 근처에 고정하여 음극 부근에서의 반응을 유도하였다. 각 조건별로 제작된 막의 표면 모폴로지, 조성원소 및 결정구조 분석을 실시하였으며, 석회질 피막의 밀착성과 내식특성을 평가하기 위해 규격에 따른 테이핑 테스트(Taping Test, ISO 2409)와 3 % NaCl 용액에서 전기화학적 양극 분극 시험을 진행하여 제작된 막의 내구성과 내식성을 분석-평가하였다. 시간에 따른 전착막의 외관관찰 결과 전류밀도의 증가와 함께 상대적으로 많은 피막이 형성되었고, 용해시킨 기체에 의해 더 치밀하고 두터운 피막이 형성됨을 확인할 수 있었다. 성분 및 결정구조 분석 결과 $Mg(OH)_2$ 성분의 Brucite 및 $CaCO_3$ 성분의 Calcite 및 Aragonite 구조를 확인하였으며, 용해시킨 기체의 영향으로 $CaCO_3$ 성분의 Aragonite 구조가 상대적으로 많이 검출되었다. 밀착성 및 내식성 평가를 실시한 결과 해수 중 용해시킨 기체에 의해 제작한 시편의 경우 견고하고 화학적 친화력이 높은 Aragonite 결정이 표면을 치밀하게 덮어 전해질로부터 산소와 물의 침입을 차단하는 역할을 하여 기체를 용해시키지 않은 3 및 $5A/m^2$ 보다 비교적 우수한 밀착성 및 내식 특성을 보이는 것으로 사료된다.

• The Journal of Engineering Geology
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• v.17 no.3
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• pp.435-443
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• 2007

This study shows the prediction of the engineering properties of weathered zone bearing corestones through the engineering geological surveys and the scale model test in the laboratory. The window survey and the observation on the borehole core were peformed on three natural slopes in corestones area in order to analyse the distribution pattern and the geometrical properties of corestones. Natural corestones were crushed and abrased for the scale model test into less than 5 mm in maximum-2mm in average by the scale reduction ratio based on the size of natural corestones and the specimen size. Scale model tests were carried out on soil and plaster model specimens with different corestone content ratio - 0%, 10%, 20%. The direct shear test on soils shows that shear strength is increased by the increase of corestone content ratio. The increase of cohesion is, however, more important factor to the shear strength of soil for 20% corestone content ratio due to interlocking of crushed corestone particles. The plaster model test shows a tendance of increase of UCS and modulus of elasticity with increase of corestone content. The variation ratio of specimen property by change of corestone content ratio in plaster model test was applied to in situ properties in order to estimate the properties of weathered zone bearing corestones. So it could be predicted that the increase of corestone content to 10% and to 20% produce about 18% and 30% UCS's increase respectively.

• The Journal of Korean Academy of Prosthodontics
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• v.34 no.4
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• pp.746-754
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• 1996

The purpose of this study was to evaluate the fracture strength of porcelain laminate veneer with various lingual extention length when incisal restoring. Sixty recently extracted, intact maxillary incisors were used and stored in a physiologic saline solution from the time of extraction. Seating form was preparation at the labial surface of each tooth with a water-cooled round diamond bur. Standard block was formed with 32 gauge and 24 gauge wax at tooth labial and lingual surface. Lingual extention length differed according to each group. (group I : 0.5mm, group II : 1 mm, group III : 2mm, group IV : 0mm) All tooth specimens were impressioned with examix(GC Inc., Japan). Refractory cast were maked with refractory die material(Ceramco Inc., U.S.A.) Laminate porcelain (Ceramco II Veneer porcelain, Ceramco Inc., U.S.A.) was condensed in refractory die cast and baked according to the manufacturer's recommendations. Each surface was contoured with low speed diamond bur according to guide block. All porcelain specimens were sandblasted and ultrasonically cleaned in distlled water for 3 minutes. Then, all porcelain specimen were etched with 8% hydrofluoric acid for 5 minutes. Sixty specimens were bonded with composite resin cement(Choice Porcelain Veneer System, Bisco Inc., U.S.A.) according to manufacture's directions. The fracture loads of the specimen were measured by Instron universal testing machine. The mean values of fracture loads for the groups were statistically compared by Duncan's multiful range test. The result were as follows : Mean fracture strengths of each group were 86.95Mpa in no lingual extention group, 44.98Mpa in 0.5mm lingual extention group, 27.47Mpa in 1mm lingual extention group, 19.61Mpa in 2mm lingual extention group. There was a statistically significant difference between all group(p<0.01).

• The Journal of Korean Academy of Prosthodontics
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• v.47 no.3
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• pp.342-347
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• 2009

Statement of problem: when using resin for class II restoration, micoleakage by instrumentation can be regarded as the primary negative characteristic. A review of the available literature suggests that using flowable resin as liner to decreased microleakage. Purpose: The aim of this study was to determine the influence of the nanofilled flowable resin lining on marginal microleakage after load cycling in class II composite restoration fillings using nanofiller resin. Material and methods: 24 extracted premolars were prepared with class II cavity. F group was restored the nanofilled resin with the nanofilled flowable resin as liner. NF group was restored the nanofilled resin only. After restoration, an experiment was performed on 2 groups using a 300N load at 104, 105 and 106 cycles. Prior to and before each load cycling, it was gauged length on total marginal microleakage, axial marginal microleakage and buccal, gingival, lingual marginal microleakage. Data were analyzed with the Mann-Whitney test & Kruskal-Wallis test. Results: There were statistically significant differences between 2 groups and between individual groups. (P <.05) The result showed less microleakage in teeth restored by the nanofilled resin, which was lined by the nanofilled flowable resin. Conclusion: There was significant reduction in microleakage when the nanofilled flowable resin lining was placed underneath the nanofilled resin in class II composite restoration fillings.