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Degradation of Humic Acid and Formation of Formaldehyde in PEROXONE Processes (PEROXONE(Ozone/Hydrogen Peroxide)공정에서의 부식산 분해 및 포름알데히드의 생성)

  • Kim, Kei Woul;Rhee, Dong Seok
    • Analytical Science and Technology
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    • v.14 no.1
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    • pp.80-87
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    • 2001
  • This research was studied the action of the coupling ozone-hydrogen peroxide on aqueous humic acid. PEROXONE process is enhanced the generation of hydroxyl radicals which is effective for degradation of organic matters. Therefore the changes of $UV_{254}$ and TOC were investigated through the change of concentrations, injection time of $H_2O_2$, initial pH of aqueous humic acid and concentrations of radical savenger as $HCO_3{^-}$ in the PEROXONE processes. And the GC/ECD was used to detect the formaldehyde formed by ozonation of humic acid. From the experimental results, concentrations and injection time of $H_2O_2$ and initial pH in solution in the PEROXONE processes were very important for enhancing the efficiency of degradation in humic acid. The results indicated that removal efficiency of TOC was the highest when concentration of $H_2O_2$ was 5mg/L, injection time of $H_2O_2$ was 5 minutes and initial pH in solution was 10.5. And presence of alkalinity in solution was reduced the efficiency of treatment. The formaldehyde were formed less PEROXONE processes than only ozone. When initial pH in solution were changed from 3.5 to 10.5, the formaldehyde were formed highest concentration at pH 5.

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Analysis of Hydraulic Characteristics for the Design Parameters of Culvert Outlet Facilities in Detention Pond (저류지 암거방류시설 설계인자의 수리학적 특성 분석)

  • Lee, Jae Joon;Jang, Joo Young;Lee, Hoo Sang;Jang, Hyun Min
    • 한국방재학회:학술대회논문집
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    • 2011.02a
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    • pp.213-213
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    • 2011
  • 근래 이상기후에 의한 강우량 증대와 도시화에 따른 첨두유출량의 증대 및 도달시간의 단축은 기존의 유수지만으로 도시홍수를 대처하는데 그 한계점에 다다르게 되었다. 1990년대에 들어 각종 우수유출 저감시설의 활용으로 이상의 문제를 해결하고자 하는 노력들이 시작되었으며, 현재 신규개발지에 저류지와 같은 우수유출저감시설 설치를 법제도적으로 의무화 하고 있어, 전국적으로 천여개소의 저류지가 시설되어 있거나 계획 중에 있다. 저류지는 개발로 인해 증가된 첨두유출량을 개발전의 상태로 저감시키기 위하여 임시 또는 상시 저류하거나 저류능력 이상의 유출량에 대해서는 암거방류시설을 통해 하류부의 하천 또는 하도로 방류시키는 역할을 수행하는 수공구조물로서 일반적으로 저류지 계획 및 설계는 첨두유출량 증가분에 대해 초점을 맞추고 있을 뿐 방류시설에 대한 구체적인 설계는 이루어지지 않고 있는 실정이다. 또한 현재 국내에는 저류지 방류시설로 주로 사용되는 암거에 관한 설계규정이나 기법은 미미한 상태로, 한국도로공사(1991)에서 발표한 "도로배수계획"을 이용하고 있으며, 이는 미국 연방도로국(FHWA, 1985)에서 발표한 설계기법을 그대로 인용하고 있다. 즉, 지형 또는 현장 여건에 따라 암거 흐름의 8형식 중 하나의 형식으로 결정하고, 그 형식에 따라 관련도표를 이용한 시산법 또는 도식해법을 적용하여 유입부 상류수위를 산정함으로써 암거설계가 이루어진다. 하지만 이러한 암거설계 방식은 도로 배수암거에 적합한 것으로 저류지 배수암거에 적용하기에는 무리가 있다고 본다. 따라서, 본 연구에서는 저류지의 일반적인 특성상 암거흐름 8형식 중 Class-II군의 암거 상류부 수위가 잠수된 조건 즉, 평상시 저류지가 일정수위 이상의 저류량을 유지하고 있는 상태에서 저류지 암거방류시설의 대표적인 설계인자인 암거직경, 암거경사, 암거경사, 하류단 수위조건의 변화에 따른 상류부 수위변화를 유량별로 분석해 보았다. 방류 암거의 개수를 고려하기 위하여 암거상류부 수위와 암거직경의 관계해석 시 암거단면적을 이용하여 분석하였으며, 각각의 유량별로 상류부 수위와 암거단면적의 관계를 회귀식으로 제시하였다. 암거상류부 수위와 암거경사의 관계를 분석한 결과 암거경사가 5~20%로 변화할 때 암거상류부 수위의 변화는 2~5%정도의 매우 작은 변화를 보임을 확인할 수 있었으며, 암거길이의 경우는 해석 조건의 특성상 상류부 수위에 영향이 전혀 나타나지 않았다. 암거상류부 수위와 암거하류단 수위의 관계에서 암거상류부 수위는 암거하류단 수위가 암거직경과 퇴사위 높이의 합보다 암거하류단의 수위가 높아지는 시점부터 암거하류단 수위에 비례해서 증가되는 결과를 알 수 있었다.

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Level of Obstructive Sleep Apnea of Patients with Ischemic Cardio-cerebrovascular Disease and Affecting Factors (허혈성 심뇌혈관질환자에서 폐쇄성 수면무호흡증 정도 및 영향요인)

  • Kim, Sun Hwa;Hwang, Seon Young
    • The Journal of the Korea Contents Association
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    • v.18 no.4
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    • pp.114-127
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    • 2018
  • This study aimed to investigate the levels of Obstructive Sleep Apnea (OSA), health behavior and sleep quality and to examine the predictors of OSA in patients with ischemic cardio-cerebrovascular disease. 141 patients who were admitted to the vascular unit were recruited and surveyed using structured questionnaires. Saturation of Peripheral Oxygen (SpO2) was measured at three time points using a pulse oximeter. Data were analyzed using SPSS/WIN 20.0. The mean age of the subjects was $64.4{\pm}11.1$ years and 61% was men. The 21.3%(n=30) of the subjects were classified as high-risk for OSA by the cut point and 71.6%(n=101) had low sleep quality. OSA high-risk group showed significant difference in SpO2 in the middle of sleep (p=.006) and at the end of sleep (p=.004) compared to the low-risk group. Multiple logistic regression analysis showed that perceived frequent snoring, smoking, obesity, lack of exercise among health behavior were found as predicting factors on OSA. OSA or persistent snoring should be recognized as a cardiovascular risk factor in the cardiovascular nursing practice. In addition to early treatment of OSA, education and counseling should be provided to patients and their family for prevention of secondary recurrence.

Effect of Gamma Irradiation on the Expression of Gene Endoding Metalloprotease in Vibrio vulnificus (감마선 조사가 vibrio vulnificus의 Metalloprotease 유전자 발현에 미치는 영향)

  • Jung, Jin-Woo;Lim, Sang-Yong;Joe, Min-Ho;Yun, Hye-Jeong;Hur, Jung-Mu;Kim, Dong-Ho
    • Microbiology and Biotechnology Letters
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    • v.36 no.1
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    • pp.6-11
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    • 2008
  • To check the microbiological safety with respect to increased virulence of surviving pathogens after irradiation, in this study, the transcriptional change of vvp gene encoding metalloprotease, which is one of the typical virulence factors of Vibrio mulnificus, was monitored by real-time PCR during the course of growth cycle after reinoculation of irradiated Vibrio. When V. vulnificus was exposed to a dose of 0.5 and 1 kGy, the lag period before growth resumption of sub-cultures became longer than non-irradiated counterpart as increase of irradiation dose. In the case of non-irradiated culture, the transcription of vvp was significantly activated at 15 h after inoculation, when bacterial growth reached the stationary phase, and the highest level of pretense activity (686 U/mL) was measured at the same time. Interestingly, vvp expression of irradiated Vibrio was turned up earlier than non-irradiated Vibrio during the mid log phase of growth, whereas these rapid induction of vvp expression from irradiated cells didn't result in an increase of metalloprotease production. When Vibrio was irradiated at 0.5 and 1 kGy, the protease activities peaked at 18 h after inoculation and the levels of activities were lower 1.2- and 1.4-fold, respectively, compared to the non-irradiated counterpart. Results from this study indicate that gamma radiation is not likely to activate the virulence ability of surviving Vibrio.

A Study on the Contents for Operation of Tunnel Management Systems Using a View Synthesis Technology (영상정합 기술을 활용한 터널관리시스템의 운영 효율성 제고를 위한 콘텐츠 연구)

  • Roh, Chang-gyun;Park, Bum-Jin;Kim, Jisoo
    • The Journal of the Korea Contents Association
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    • v.16 no.6
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    • pp.507-515
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    • 2016
  • In South Korea, there are a large number of tunnels because of the mountainous terrain, and to overcome this characteristics, lengths of tunnels are more longer than existing tunnels. The need to improvement current tunnel management contents is giving rise for accidents in tunnel section is continuously increased although lots of efforts to reduce the accidents. Conventionally, disaster prevention have been focused on the Tunnel Management Systems, tunnel operators generally tend to depend on CCTV images for most contents of detailed traffic flow managing. In this paper, investigation about current Tunnel Management Systems contents using IPA survey was conducted, and Priority Improvement Contents(Accident Situation Management Support, 2nd Accident Management Support, Traffic Flow Monitoring), which importance are high, but satisfaction are low, are deducted. Also, CCTV images, lack intuitive understanding, are judged as a main cause of low satisfaction of those contents. To overcome those limitations of the existing Tunnel Management Systems, this study sought to develop a technology for the synthesis of road images to derive traffic information from synthesis images, and the contents improvement stragegy is established. Tunnel operators-oriented satisfaction survey on new contents was carried out, and scored 4.2 on a 5-point scale. This has confirmed that the availability of new contents and at this stage, with pushing ahead of long-tunnels and undersea tunnels construction, politic applications are expected.

Dispersion of Particle Pulse in Human Lung Airway (인체기관지내의 입자펄스 확산 실험)

  • 이진원;이동엽;추경호
    • Journal of Biomedical Engineering Research
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    • v.19 no.5
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    • pp.511-518
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    • 1998
  • In order to develop the aerosol bolus technique which is thought to be a potential tool for probing geometries or abnormalities of small airways, an experimental system of measuring fast time variations of particle concentration in the inhaled and exhaled breathing air was developed. The system generates monodisperse sebacic acrid particles of 1 micron size and 1.2 of geometric standard deviation in high concentration of $10^8$ particles/cc, delivers a short pulse of particles at the controlled instant during inhalation using a solenoid valve, and measures the fast change of particle concentration in using the laser light scattering. Successful operation of the generator and the measuring system was confirmed by smooth concentration profiles in inhalation. It was also confirmed that maintaining a constant breathing rate is essential to stable outputs and any disturbance in flow rate near the mode (maximum concentration) induces a large number of spurious peaks in the exhalation. Experimental data without strict control of breathing flow rate showed a substantial amount of scatter. The measured results showed an improvement in scatter over the existing results. When compared with theoretical predictions from 1-D convective diffusion equation and other experiments, general characteristics of dispersion for several penetration depths showed a good agreement, but there exists some difference in absolute values, which is attributed to the difference in body conditions. Improvements are needed in the theory, especially in relation to correcting for the effect of breathing flow rate.

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Analysis on Pre-service Early Childhood Teachers' Stage of Concerns about Software Education According to the Concerns-Based Adoption Model (예비유아교사의 소프트웨어 교육에 대한 관심도 분석: 관심중심수용모형(CBAM)을 중심으로)

  • Jung, Ji-Hyun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.7
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    • pp.431-440
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    • 2017
  • This study surveyed pre-service early childhood teachers' level of concern about software education on the assumption that software education will be introduced into early childhood education in the future. It was shown that the pre-service early childhood teachers' level of concern about software education is the highest at stage 0(95%) and that they have a high level of informative, personal and managerial concern. Thus, a non-user pattern was mostly indicated. However, compared to the typical non-user pattern, their personal and informative level of concern is slightly higher. A 'tailing up' phenomenon to stage 6(refocusing) was shown. Hence, a pattern aspect close to critical non-user appeared to some extent. A difference in the significant level of concern was shown at all stages, except for managerial concern, according to the need for awareness, the appearance of a future implementation plan, and technology efficacy level. Based on this outcome, it was proposed that teacher training in early childhood software education should be made available as part of the educational activity connected with the Nuri Curriculum, since this would be more suitable for young children's developmental level than the early childhood software education, including coding education, etc., currently found in private institutions.

Effects of Association and Imagery on Word Recognition (단어재인에 미치는 연상과 심상성의 영향)

  • Kim, Min-Jung;Lee, Seung-Bok;Jung, Bum-Suk
    • Korean Journal of Cognitive Science
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    • v.20 no.3
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    • pp.243-274
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    • 2009
  • The association, word frequency and imagery have been considered as the main factors that affect the word recognition. The present study aimed to examine the imagery effect and the interaction of the association effect while controlling the frequency effect. To explain the imagery effect, we compared the two theories (dual-coding theory, context availability model). The lexical decision task using priming paradigm was administered. The duration of prime words was manipulated as 20ms, 50ms, and 450ms in experiments 1, 2, and 3, respectively. The association and imagery of prime words were manipulated as the main factors in each of the three experiments. In experiment 1, the duration of prime words (20ms) which is expected to not activate the semantic context enough to affects the word recognition was used. As a result, only imagery effect was statically significant. In experiment 2, the duration of prime word was 50ms, which we expected to activate the semantic context without perceptual awareness. The result showed both the association and imagery effects. The interaction between the two effects was also significant. In experiment 3, to activate the semantic context with perceptual awareness, the prime words were presented for 450ms. Only association effect was statically significant in this experimental condition. The results of the three experiments suggest that the influence of the imagery was at the early stages of word recognition, while the association effect appeared rather later than the imagery. These results implied that the two theories are not contrary to each other. The dual-coding theory just concerned imagery effect which affects the early stage of word recognition, and context-availability model is more for the semantic context effect which affects rather later stage of word recognition. To explain the word recognition process more completely, some integrated model need to be developed considering not only the main 3 effects but also the stages which extends along the time course of the process.

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Effects of air pollutants on the weathering of stone cultural properties in Gyeongju (경주지역 석조문화재 풍화에 미치는 대기오염물질의 영향)

  • Jung, Jong-Hyeon;Jung, Min-Ho;Choi, Won-Joon;Seo, Jung-Ho;Hwang, In-Jo;Shon, Byung-Hyun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.11 no.2
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    • pp.597-603
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    • 2010
  • The amount of pollutants from stationary sources of businesses classified into 1-3 type in Gyeongju was found to be 0.70 ton/yr for PM-10, 13.95 ton/yr for $SO_2$, and 37.12 ton/yr for NOx ; with respect to area sources, 1.02 ton/yr for PM-10, 13.44 ton/yr for $SO_2$, and 21.10 ton/yr for NOx ; and with respect to mobile sources 963.91 ton/yr for PM-10, 1415.02 ton/yr for $SO_2$, and 5612.70 ton/yr for NOx. This study surveyed the concentration distribution of PM-10, $SO_2$, and NO2 in the air in around Gyeongju and Pohang, and found that high concentration was mainly distributed around Pohang Steel Industrial Complex and the around of mobile sources. In Gyeongju area, $SO_2$ was predicted to increase from 0.002 ppm in 2006 to 0.005 ppm in 2015, and that of $NO_2$ was predicted to increase from 0.004 ppm to 0.010 ppm during the same period. At this point, practicing guidelines to reduce air pollutants and management plan for environmental pollutants should be devised, and also practicing and management programs to protect the stone cultural properties from environmental pollutants and other chemical, physical, and biological factors should be actively introduced.

Analysis of the Change in Density of Development And Environmental Restrictions Conflict Prediction in Pyeongchang (개발 밀도의 변화 분석과 환경규제 갈등 예측 -평창을 사례로-)

  • Bae, Sun-Hak
    • Journal of the Korean association of regional geographers
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    • v.15 no.2
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    • pp.282-291
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    • 2009
  • This research predicts the spatial discord which relates with a restriction using 1915 and 2005 spatial data. In this research, difference of relative spatial density is measured and predicted the discord which relates with an environmental restriction in Pyeongchang. First, research area Pyeonchang's relative crowding degree of the building was strengthened from 1915 to 2005. When classifies a change type, formed the strong hold with new regulation and grew types and at the strong hold where contiguous concentration is progress types, general the influence weakening types and the change almost nil types. The next is the result which analyzes the long and short terms discord for the environmental restriction which is forecast from the research area. That is forecast with the fact that the discord between of development and preservation will be big with long and short terms in Jinbu-Myeon, Pyeongchang-Eup city center angles and 31 national road circumferences. And in Daegwanryeong-Myeon the discord is big short-term but with the fact that the discord will be weakened long-term. Bangrim-Myeon, now the discord is weak but the discord will be strengthened long-term. This result could be applied with fundamental data for weakening the spatial discord of the area.

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