• Title/Summary/Keyword: 시안

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Immobilization Metallocene Inside Surface-functionalized Nanopore of Micelle-Templated Silica and its Ethylene Polymerization (표면 기능화된 Micelle-Templated Silica 나노세공 내 메탈로센 담지 및 에틸렌 중합)

  • Lee, Jeong-Suk;Yim, Jin-Heong;Ko, Young-Soo
    • Polymer(Korea)
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    • v.36 no.1
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    • pp.111-116
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    • 2012
  • A functionalization of mesoporous materials with organosilane was carried out via a post-synthesis grafting method and $(n-BuCp)_2ZrCl_2$/methylaluminoxane (MAO) as subsequently immobilized on the functionalized mesoporous materials for ethylene polymerization. Organosilanes having amine, cyano or imidazoline group such as $N$-[(3-trimethoxysilyl)propyl]ethylenediamine (2NS), 4-(triethoxysilyl)butyronitrile (1NCy), 1-(3-triethoxysilylpropyl)-2-imidazoline (2NIm) were used for the surface functionalization of mesoporous materials. In the SBA-15/2NS/$(n-BuCp)_2ZrCl_2$ catalyst preparation, the amount of MAO in feed increased with an decrease in the Zr content of the supported catalyst, and Al content in the supported catalyst increased. The ethylene homopolymerization activity of SBA-15/2NS/$(n-BuCp)_2ZrCl_2$ dramatically increased as the amount of MAO in feed increased. Furthermore, when the immobilization time was 6 hrs, SBA-15/2NS/$(n-BuCp)_2ZrCl_2$ showed the highest activity. The activities of supported 2NS-, 1NCy-, 2NIm-functionalized catalysts decreased in the following order, SBA-15/2NS/ > SBA-15/2NIm/ > SBA-15/1NCy/$(n-BuCp)_2ZrCl_2$. 2NS and 2NIm which have two amine groups per silane molecule were shown to interact with $(n-BuCp)_2ZrCl_2$ strongly compared to 1NCy which has one amine group. Thus, the activities increased with an increase in the nitrogen and the Zr content of the supported catalysts.

Diaspora and National policy - Focusing on Russian Diaspora and chinese Diaspora (디아스포라와 국가정책 - 러시안 디아스포라와 차이니즈 디아스포라를 중심으로)

  • Chun, Byung Kuk
    • Cross-Cultural Studies
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    • v.26
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    • pp.123-144
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    • 2012
  • In the modern society in which globalization and localization proceed simultaneously, diversified and rapid migration of diaspora makes a new from of boundary off the frame of the state and the nation. This new border accompanies cultural change and racial mixture; retains ethnic conflict, the gap between rich and poor, alienation and discrimination, as well as power conflict; and extends its influence. Nowadays, the countries all over the world including Korea face problem of Diaspora in numerous forms. And each country takes an approach to the problem of the diaspora in the aspects of their society, culture and political technology. This implies that most countries, without understanding the new form of border which is alive and dynamic, define and conceptualize the diaspora in the frame of one state and one nation to carry forward the policies accordingly, resulting in inequal, incomplete and awkward homogenization. This study aimed to explore the identity of the diaspora, the core for the problem solving. Of course, studies about the identity of the diaspora have been continued until today and many great outcomes have been achieved. Nevertheless, this study aimed to explore the identity of the diaspora and the national policies which have a close interrelationship with it. It is because the study ultimately aimed to highlight the interrelationship between the destination countries, Russia and China, and the diaspora, through the definition and the classification of Russian diaspora and Chinese diaspora and the analysis of the national policies about that. However, the intention was not to distinguish superiority through the comparison of the polices about the diaspora between two countries, but to focus on the diversity of the identity of the diaspora through defining each different diaspora and paralleling the policies. Second, the reason for looking into the diaspora policies of these two countries is because it is judged the changes in the diaspora policies of each country is one of the active factors for the changes in the identify of the diaspora of each country and it is the basic research for the study on the identity of the diaspora. New migration of diaspora changes the identity of the state, and the state makes the policies and enforce the policies, resulting in the influence on the diaspora. This interaction acts as the growth factor for the new boundary. The causes of Russian diaspora and Chinese diaspora show apparent 'differences'. In parallel with this, the policies about the diaspora in Russia and China arouse 'differences' to the diaspora. The variation of the identity of the diaspora made by these differences will suggest other viewpoints on the diaspora, and these viewpoints will become the foundation for solving the problem of the diaspora in the present times.

Characterizing the Structure of China's Passenger Railway Network Based on the Social Network Analysis(SNA) Approaches : Focused on the 2008, 2013, and 2018 Railway Service Data, Respectively (사회 네트워크 분석 방법론에 기초한 중국의 여객 철도 네트워크 특성 분석 : 2008년, 2013년, 2018년 운행 데이터를 중심으로)

  • Zhao, Pei-Song;Lee, Jin-Hee;Lee, Man-Hyung
    • The Journal of the Korea Contents Association
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    • v.19 no.10
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    • pp.685-697
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    • 2019
  • The study aimed to analyze the structure of China's passenger railway network in the years of 2008, 2013, and 2018, respectively. At the same time, it tried to investigate its derivative impact on the patterns of Chinese urban network. The analytical tool was based on the NetMiner4.0. In order to measure network characteristics of China's passenger railway network, it primarily focused on the degree centrality, betweenness centrality, and closeness centrality. First of all, the higher degree centralities, with a few exceptions, were observed in BeiJing, ShangHai, GuangZhou, WuHan, XiAn, ChengDu, HaErBin, and ShenYang over a decade. In contrast, the higher betweenness centralities were recorded in cities of higher development potential including WuLuMuQi, GuiYang, ShenYang, and KunMing. The closeness centrality analyses confirmed the fact that most metropoles like BeiJing, ShangHai, and GuangZhou kept the highest train accessibility during the same research period. At the same time, the opening up of a new stretch of high speed railway network has consecutively strengthened connectivity between BeiJing and TianJin. Owing to unprecedented development of railway traffic and its extensive operations, this study believes that Chinese major cities, without interruption, would pursue a series of urban policy alternatives geared towards railway stations-oriented networking and competitively try to extend their network ranges.

Finite Element Analysis(fem) of The Fixed Position of the Velcro Band for the 3D Print Wrist Brace made using the Dicom File (CT Dicom 파일을 이용하여 제작한 3D Print 손목보호대용 Velcro band 고정위치의 유한요소해석(FEM))

  • Choi, Hyeun-Woo;Seo, An-Na;Lee, Jong-Min
    • Journal of the Korean Society of Radiology
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    • v.15 no.5
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    • pp.585-590
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    • 2021
  • Wrist braces are being used for patients with wrist trauma. Recently, many studies have been conducted to manufacture custom wrist braces using 3D printing technology. Such 3D printing customized orthosis has the advantage of reflecting various factors such as reflecting different shapes for each individual and securing breathability. In this paper, the stress on the orthosis by the number and position of Velcro bands that should be considered when manufacturing a 3D printing custom wrist brace was analyzed. For customized orthosis, 3D modeling of the bone and skin regions was performed using an automatic design software (Reconeasy 3D, Seeann Solution) based on CT images. Based on the 3D skin area, a wrist orthosis design was applied to suit each treatment purpose. And, for the elasticity of the brace, a wrist brace was manufactured with an FDM-type 3D printer using TPU material. To evaluate the effectiveness according to the number and position of the Velcro band of the custom 3D printed wrist brace, the stress distribution of the brace was analyzed by the finite element method (FEM). Through the finite element analysis of the wrist orthosis performed in this study, the stress distribution of the orthosis was confirmed, and the number and position of the orthosis production and Velcro bands could be confirmed. These experimental results will help provide quality treatment to patients.

Study of the Effect of the Transmittance of a Diffuser Plate on the Optical Characteristics of High-power Quantum-dot Illumination (확산판의 투과율이 고출력 양자점 조명의 광특성에 미치는 영향에 대한 연구)

  • Kim, Hye-Rin;You, Dong Geun;You, Jae Hwan;Jang, Jun Won;Choi, Moo Kyu;Hong, Seung Chan;Ko, Jae-Hyeon;Joe, Sung-Yoon;Kim, Yongduk;Park, Taehee;Ko, Young Wook
    • Korean Journal of Optics and Photonics
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    • v.32 no.5
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    • pp.220-229
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    • 2021
  • The optical characteristics of high-power direct-lit white light-emitting diode (LED) lighting were investigated, where a quantum dot (QD) film was adopted to enhance the color-rendering index (CRI). The transmittance of the diffuser plate and the concentration of the QD film were varied in this study. The color coordinates and the correlated color temperature (CCT) did not show any appreciable change, while the CRI values increased slightly as the transmittance of the diffuser plate decreased. The investigated optical properties were nearly independent of the viewing angle, and the luminance distribution was close to Lambertian. The CCT decreased from approximately 6000 K to approximately 4000 K as the concentration of the QD film increased from 0 to 7.5 wt%, which was due to the enhanced red component in the emission spectrum. The CRI increased to approximately 95 for some optical configurations of the lighting. These results demonstrate that glare-free, color-changeable, high-rendering LED lighting can be realized by using a combination of a diffuser plate of appropriate transmittance and a red QD film.

Analysis of Emotions of Anti-Korea and Anti-Japan in International Soccer Games of Korea vs. Japan (한국과 일본 간 축구경기와 반일·반한 감정의 관계)

  • Lee, Jong-Kil;Lee, Kong-Joo;Yang, Jae-Sik
    • Journal of Digital Convergence
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    • v.17 no.2
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    • pp.463-473
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    • 2019
  • This study aimed to investigate the relationship between soccer games of Korea vs. Japan and emotions of anti-Japan and anti-Korea, empirically. For that, this study selected 2,400 comments from Naver and 5CH where people could write their SNS comments on EAFF E-1 football championship 2017. The study results got by frequency analysis and one-way ANOVA were as follows. First, Korean showed amity with own team and hostility to the opponents, and stronger hostility toward Japan. Japanese showed hostility to own team, and it was especially strong when vs. Korea. Second, Korean showed stronger hostility toward Japan than others. Japanese showed stronger hostility to own team when vs Korea. From those results, this study could conclude that soccer games of Korea vs. Japan could be a field to express those emotions rather than effect on the emotions of anti-Korea and anti-Japan. By the empirical method of this study on the emotions of anti-Japan and anti-Korea unlike advance studies, this could receive favorable evaluation.

The Brand Identity Design Evaluation Using EEG Measurement (뇌전도를 활용한 브랜드 아이덴티티 디자인 평가)

  • Han, Yu-Rim;Kim, Da-Sol;Han, Ji-Ae;You, Sicheon
    • Smart Media Journal
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    • v.7 no.4
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    • pp.106-113
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    • 2018
  • Brand identity (BI) is a key asset that affects consumers' psychological cognition of products and services. In the initial planning stage of the BI design development for a company, a unique approach strategy is required. In the final evaluation stage, a reasonable design evaluation method involving potential consumers needs to be prepared. However, conventional brand identity design evaluation processes tend to depend on the results of surveys, and in many cases it is impossible to be free from the distorting phenomenon of survey respondents' psychological manifestation which is often revealed in the process of the surveys. In this context, this research has explored whether the method of utilizing EEG data of the subjects along with the conventional survey method of preference could be helpful in the process of evaluating the brand identity design. To achieve that, we correlated the subject's preference survey results with the subject's EEG data. 'Attractiveness' and 'concentration' were used as variables. As a result, it was found that there was a high correlation between the results of preference survey on 'attractiveness' and the results of 'EEG' on 'concentration'. Therefore, in addition to the existing conventional qualitative evaluation methods, we confirmed that design evaluation methods using EEG are useful for evaluating tacit knowledge objects such as the BI design.

Surface Reflectance Retrieval from Satellite Observation (OMI) over East Asia Using Minimum Reflectance Method (위성관측 오존계에서 최소 반사도법을 이용하여 동아시아 지역의 지면반사도 산출)

  • Shin, Hee-Woo;Yoo, Jung-Moon;Lee, Kwon-Ho
    • Journal of the Korean earth science society
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    • v.40 no.3
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    • pp.212-226
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    • 2019
  • This study derived spectral Lambertian Equivalent Reflectance (LER) over East Asia from the observations of Ozone Monitoring Instrument (OMI) onboard polar-orbit satellite Aura. The climatological (October 2004-September 2007) LER values were compared with the surface reflectance products of OMI or MODerate resolution Imaging Spectroradiometer (MODIS) in terms of the atmosphere-environment variables as follows: wavelength (UV, visible), surface properties (land, ocean), and cloud filtering. Four kinds of LER outputs in the UV and visible region (328-500 nm) were retrieved based on the averages of lowest (1, 5, and 10%) surface reflectance values as well as the minimum reflectance. The average of the lowest 10% among them was in best agreement with the OMI product: correlation coefficient (0.88), RMSE (1.0%) and mean bias (-0.3%). The 10% average and OMI LER values over ocean were 2% larger in UV than in visible, while the values over land were 1% smaller. The LER variability on the wavelength and surface property was highest (~3%) in the condition of both land and visible, particularly in the ice-cap and desert regions. The minimum reflectance values over the oceanic and inland sample areas overestimated the MODIS product by 1.4%. This high-resolution MODIS observations were effective in removing cloud contamination. The relative errors of the 10% average to MODIS were smaller (-0.6%) over ocean but larger (1.5%) over land than those of the OMI product to MODIS. The reduced relative error in the OMI product over land may result from additional cloud filtering using the Landsat data. This study will be useful when retrieveing the surface reflectance from geostationary-orbit environmental satellite (e.g., Geostationary Environment Monitoring Spectrometer; GEMS).

Recombinant Production and Antimicrobial Activity of an Antimicrobial Model Peptide (Uu-ilys-CF) Derived from Spoon Worm Lysozyme, Uu-ilys (개불 라이소자임 유래 항균성 모델 펩타이드(Uu-ilys-CF)의 재조합 단백질 생산 및 항균 활성)

  • Oh, Hye Young;Go, Hye-Jin;Park, Nam Gyu
    • Journal of Life Science
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    • v.31 no.1
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    • pp.83-89
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    • 2021
  • Uu-ilys, an i-type lysozyme from spoon worm (Urechis unicinctus), is an innate immune factor that plays an important role in the defense against pathogens. It also possesses non-enzymatic antibacterial activity. Thus, there is a possibility to develop an antimicrobial model peptide from Uu-ilys. In this study, we report the design, production, and antibacterial activity of an Uu-ilys analog that exhibits antibacterial activity. The Uu-ilys structure was fragmented according to its secondary structures to predict the regions with antimicrobial activity using antimicrobial peptide (AMP) prediction tools from different AMP databases. A peptide containing the C-terminal fragment was predicted to exert antimicrobial activity. The chosen fragment was designated as an Uu-ilys analog containing the C-terminal fragment, Uu-ilys-CF. To examine the possibility of developing an AMP using the sequence of Uu-ilys-CF, recombinant fusion protein (TrxA-Uu-ilys-CF) was produced in an expression system that was heterologous. The produced fusion protein was cleaved after methionine leaving Uu-ilys-CF free from the fusion protein. This was then isolated through high performance liquid chromatography and reverse phase column, CapCell-Pak C18. The antibacterial activity of Uu-ilys-CF against different microbial strains (four gram-positive, six gram-negative, and one fungal strain) were assessed through the ultrasensitive radial diffusion assay (URDA). Among the bacterial strains tested, Salmonella enterica was the most susceptible. While the fungal strain tested was not susceptible to Uu-ilys-CF, broad spectrum antibacterial activity was observed.

Control Effect of Botanical Pyrethrum to Polyphagotarsonemus latus (Banks) (Acari: Tarsonemidae) in Green Perilla (잎들깨에서 차먼지응애에 대한 천연 피레스럼 방제효과)

  • Seo, Youn-Kyung;Chae, Eui-Soo;Ann, Seoung-Won;Choi, Yong-Seok
    • Korean journal of applied entomology
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    • v.59 no.4
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    • pp.421-425
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    • 2020
  • We investigated an ecologically-sensitive method to control Polyphagotarsonemus latus in a green perilla polyvinyl house using concentrated pyrethrum. The survival rates of Polyphagotarsonemus latus nymphs and adults to 2%, 4%, and 6% pyrethrum 3 days after spraying were 58.1%, 27.5%, and 22.7% respectively, and 73.4%, 37.3%, and 30.6% at 5 days after spraying. These results show that the most effective control occurred using 6% pyrethrum. To investigating the densities of P. latus on a 1 cm diameter leaf-disk of green perilla, we sprayed the leaf every 10 days from May 10 with 6% pyrethrum 1,000 times and milbemectin EC 2% 1,000 times. The period chosen was one where the incidence of P. latus could be predicted. The density was kept low during the treatment period. However, if leaf damage had already occurred from P. latus, the density could not be decreased by spraying 1 or 2 times each week where milbemectin EC 2% was used, but the population could be reduced when sprayed 3 times. Therefore, in order to effectively control P. latus in green perilla greenhouses, it is important to begin treatment at an early stage when P. latus are first observed.