• Korean Journal of Mineralogy and Petrology
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• v.34 no.3
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• pp.169-176
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• 2021

This study aimed to fundamentally understand structural changes of zeolite under pressure and in the presence of different pressure-transmitting media (PTM) for application studies such as immobilization of heavy metal cation or CO₂ storage using pressure. High-pressure X-ray powder diffraction study was conducted on the zeolite-W (K_6.4Al_6.5Si_25.8O₆₄× 15.3H₂O, K-MER) to understand linear compressibility and the bulk moduli in different PTM conditions. Zeolite-w is a synthetic material having the same framework as natural zeolite merlinoite ((K, Ca_0.5, Ba_0.5, Na)₁₀ Al₁₀Si₂₂O₆₄× 22H₂O). The space group of the sample was identified as I4/mmm belonging to the tetragonal crystal system. Water, carbon dioxide, and silicone-oil were used as pressure-transmitting media. The mixture of sample and each PTM was mounted in a diamond anvil cell (DAC) and then pressurized up to 3 GPa with an increment of ca. 0.5 GPa. Pressure-induced changes of powder diffraction patterns were measured using a synchrotron X-ray light source. Lattice constants, and bulk moduli were calculated using the Le-Bail method and the Birch-Murnaghan equation. In all PTM conditions, linear compressibility of c-axis (𝛽^c) was 0.006(1) GPa^-1 or 0.007(1) GPa^-1. On the other hand, the linear compressibility of a(b)-axis (𝛽^a) was 0.013(1) GPa^-1 in silicone-oil run, which is twice more compressible than the a(b)-axis in water and carbon dioxide runs, 𝛽^a = 0.006(1) GPa^-1. The bulk moduli were measured as 50(3) GPa, 52(3) GPa, and 29(2) GPa in water, carbon dioxide, and silicone-oil run, respectively. The orthorhombicities of ac-plane in the water, and carbon dioxide runs were comparatively constant, near 0.350~0.353, whereas the value decreased abruptly in the silicone-oil run following formula, y = -0.005(1)x + 0.351(1) by non-penetrating pressure fluid condition.

• Journal of Animal Environmental Science
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• v.16 no.3
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• pp.227-236
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• 2010

This study was conducted to develop an measuring system and method for fermentation degree of liquid swine manure by visible ray. The constituent changes of liquid swine manure were examined. pH gradually increased with time, but EC gradually decreased. Malodor strength decreased gradually with aeration treatment with time. Control needed more time to decrease malodor strength than aeration treatment. In aeration treatment, there was no germination of seeds (radish, chinese cabbage) up to 6 weeks and germination rate at 15th week was over 50%. However, in control, there was no germination up to end of experiment. Circular chromatography method showed that there was change after 10th week in aeration treatment but there was no change up to end of experiment in control. As a result, the fermentation degree of liquid swine manure would have relations among pH, EC, germination rate, malodor concentration, and reaction of circular chromatography. The simple analytical instrument for liquid swine manure consisted of a tungsten halogen and deuterium lamp for light source, a sample holder, a quartz cell, spectrometer for spectrum analyzer, a malodour measuring device, a software, etc. Results showed that the simple analytical instrument that was developed can approximately predict the fermentation degree of liquid swine manure by visible ray. Generally, the experiment proved that the simple analytical instrument was reliable, feasible and practical for analyzing the fermentation degree of liquid swine manure.

• Journal of Soil and Groundwater Environment
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• v.7 no.4
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• pp.77-86
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• 2002

Surfactant enhanced in-situ soil flushing was performed to remediate the soil and groundwater at an oil contaminated site, where had been used as a military vehicle repair area for 40 years. A section from the contaminated site (4.5 m $\times$ 4.5 m $\times$ 6.0 m) was selected for the research, which was composed of heterogeneous sandy and silt-sandy soils with average $K_d$ of 2.0$\times$$10^{-4}$cm/sec. Two percent of sorbitan monooleate (POE 20) and 0.07% of iso-prophyl alcohol were mixed for the surfactant solution and 3 pore volumes of surfactant solution were injected to remove oil from the contaminated section. Four injection wells and two extraction wells were built in the section to flush surfactant solution. Water samples taken from extraction wells and the storage tank were analyzed on a gas-chromatography (GC) for TPH concentration in the effluent with different time. Five pore volumes of solution were extracted while TPH concentration in soil and groundwater at the section were below the Waste Water Discharge Limit (WWDL). The effluent TPH concentration from wells with only water flushing was below 10 ppm. However, the effluent concentration using surfactant solution flushing increased to 1751 ppm, which was more than 170 times compared with the concentration with only water flushing. Total 18.5 kg of oil (TPH) was removed from the soil and groundwater at the section. The concentration of heavy metals in the effluent solution also increased with the increase of TPH concentration, suggesting that the surfactant enhanced in-situ flushing be available to remove not only oil but heavy metals from contaminated sites. The removal efficiency of surfactant enhanced in-situ flushing was investigated at the real contaminated site in Korea. Results suggest that in-situ soil flushing could be a successful process to remediate contaminated sites distributed in Korea.

• Journal of the Korean GEO-environmental Society
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• v.11 no.9
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• pp.55-60
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• 2010

This study are carried out to an lab model tests to develop a construction method that solidifies high-water content cohesive soil by using filter type drain and vacuum pressure, and that stabilizes the ground by accelerating horizontal drain at incline or in tunnel. The calibration chamber was designed within length of 1.5m and height of 50cm, and a drainage hole for preconsolidation, a switchgear and a piezometer were installed at the bottom part of the chamber. Also, a settlement gage was installed at the top part so that it can measure the settlement by time. The calibration ground basis was made in a form of thin layer from kaolinite and bentonite in 9:1 ratio stirred at 130% water content condition. A filter type drain was installed at chamber center and a vacuum pressure of 0.8MPa was applied through a hose linked to the cap at the top part, then, the settlement was measured in every 1 hour interval. After experiment, the moisture contents were measured by position, then, verified the increase of solidity of the ground through a triaxial compression test on undisturbed profile. After 11 days from the effective date, it was observed that the settlement decreased by maximum 35mm and the water content ratio was reduced by 38% at most while the solidity of the ground increased by 5~8 times greater than before preconsolidation.

• Proceedings of the Korean Society for Agricultural Machinery Conference
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• 2017.04a
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• pp.8-8
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• 2017

본 연구는 로타리 작업에 따른 105마력급 농업용 트랙터의 소요동력을 분석하기 위하여 수행되었다. 소요동력 측정 시스템은 차축 토크미터, PTO 토크미터, 주/보조 유압센서, 데이터 수집장치를 이용하여 구성하였다. 시험에 사용된 트랙터는 동양물산 105 HP급 트랙터 (S07, TYM, Korea)이며, 작업기는 로타베이터 (SW 230GL, Sungwoo Industrial Co. Ltd, Korea)를 사용하였다. 포장시험은 전라북도 부안군에 죽림길에 위치한 $4,000m^2$ ($100m{\times}40m$) 크기의 경작지 2곳에서 수행하였다. 포장시험 시 작업 단수는 주행단수 L3단 (2.38 km/h)에서 PTO 단수 1단 (540 rpm)과 2단 (750 rpm)으로 설정하였고, 로타리 작업 시 경심은 13 cm 조건에서 실시하였다. 트랙터 작업은 동양물산의 성능시험 업무를 맡고 있는 숙련된 작업자가 숙달된 방법으로 수행하였다. 포장시험지의 토양환경은 임의의 15곳에서 채취한 시료를 이용하여 토성, 함수율, 원추 관입지수에 대하여 미국 농무부 (USDA)법을 기준으로 분석하였다. 토양환경 분석 결과 토성은 Sandy loam (사양토), 평균 함수율은 35.15%, 평균 원추관입지수는 1,562 kPa로 나타났다. PTO 1단 작업 시 트랙터의 평균 소요동력은 차축, PTO, 주 유압, 보조 유압에 대하여 각각 1.8, 54.0, 1.3, 그리고 1.1 hp로 나타났다. PTO 2단 작업 시 트랙터의 평균 소요동력은 차축, PTO, 주 유압, 보조 유압에 대하여 각각 1.2, 79.4, 1.2, 그리고 1.0 hp로 나타났다. PTO 1단 작업 시 소요동력의 합은 58.2 hp로, 정격 마력 (105 hp) 대비 55.43 % 사용한 것으로 나타났으며, PTO 2단 작업 시 소요동력의 합은 82.8 hp로, 정격 마력 대비 78.85% 사용한 것으로 나타났다. PTO 1단 대비 2단에서는 PTO를 제외한 차축, 주 유압, 보조 유압의 소요동력이 감소하였으나, PTO에서 약 1.47배로 크게 증가하여 전체적으로 소요동력이 증가한 것으로 나타났다. 향후 다양한 작업기 및 작업 단수에 따른 소요동력을 분석하여 농업용 트랙터의 모든 부하 조건에 대한 데이터베이스 구축에 관한 연구를 수행할 예정이다.

• Korean Journal of Environmental Agriculture
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• v.29 no.3
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• pp.266-272
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• 2010

The present study was carried out to assess exposure & risk for Korean by total and inorganic As intake through agricultural products. Total arsenic analysis was performed using microwave device and ICP-MS. 50% MeOH extraction and anion-exchange HPLC-ICP-MS method has been used to determine arsenic species. 329 samples covering 20 kinds of agricultural products were collected from various retail outlets and markets across Korea. The concentration of total As was in the range of 0.001~0.718 mg/kg, while inorganic and organic arsenic species in all samples was not determined. For risk assessment, probable daily intake was calculated and compared with provisional tolerable weekly intake (PTWI, 15 ${\mu}g$/kg b.w./week for inorganic arsenic) established by JECFA. The median daily exposure to total and inorganic As by intake of agricultural products except rice was ranged 0.0002~0.012, 0.0001~0.001 ${\mu}g$/kg b.w./day, corresponding to 0.01~0.5%, 0.002~0.1% of PTWI, respectively. The median level of total and inorganic As intake through rice was 0.603 and 0.041 ${\mu}g$/kg b.w./day, and 28.1% and 1.9% of PTWI, respectively. Therefore, the level of overall exposure to arsenic for Korean through agricultural products was below the recommended JECFA levels, indicating of least possibility of risk.

• Journal of the Korean Society of Radiology
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• v.11 no.3
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• pp.123-129
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• 2017

Compton suppression apparatus using the Compton scattering response, by inhibiting part of the spectrum Compton continuum Compton continuum in the area of the peak analysis of the gamma rays that enables a clearer device. In order to find out the geometry structure of high-purity germanium detector(HPGe) -NaI(TI) and to optimize the effect of movement, Monte Carlo simulation was used to grasp the behavioral characteristics of Compton suppression and compare several layout structures. And applied to the cylinder beaker used for the environmental measurement by using the efficiency according to the distance. For the low-energy source such as 81 keV, the Compton continuum is scarcely developed and the suppression effect is also insignificant because the scattering cross-section of the Compton effect is relatively low. In the spectrum for the remaining energy, it can be seen that the Compton continuum part is suppressed in a certain energy range. Compton suppression effect was not significantly different from positional shift. average reduction factor(ARF) value was about 1.08 for 81 keV and about 1.23 for 1332.4keV energy at the highest value. It can be seen that suppression over the Compton continuum region of the energy spectrum is a more appropriate arrangement. Therefore, it can be applied to various environmental sample measurement through optimized structure.

• Journal of Animal Environmental Science
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• v.17 no.3
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• pp.155-162
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• 2011

This study was conducted to suggest the measurement procedure and to build up national greenhouse gas inventory database of animal agricultural sector by assessing methane and nitrous oxide emissions according to IPCC guidelines for national greenhouse gas inventory report in order to correspond to the Climate Change Convention. Ten house-made steady-state Half dome floating chambers were used to collect air samples emitted from slurry stored in the pit under the slat. Those chambers were spread out in order that air samples might represent the whole area of slurry under the slat. Fresh air was pumped into the chambers by $5{\sim}9{\ell}/min$ and air inside the chambers was sampled by $1{\ell}/min$. Surplus air by the higher flow rate of fresh air than sampling flow rate was passed through a hole on the top of chambers. Nitrous oxide fluxes measured from 10 locations would be negligible as concentrations between background air and sampled air from the chambers were within the error range. However, mean $CH_4$ fluxes were $0.15{\sim}1.02mg/m^2{\cdot}s$. The application of continuous greenhouse gas measurement techniques would be preferred if the patterns of greenhouse gas emissions are considered.

• Journal of Korean Society of Environmental Engineers
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• v.34 no.5
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• pp.316-325
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• 2012

In this study, we suggested adequate control technology by analyzing emission process and main chemical of VOC/HAPs generated from four paint factories in Busan area. And we estimated whether Kapok fiber, which is a natural material, can be commercially used for an absorbent by testing adsorption ability. As a result of this sturdy, above 60% of VOC/HAPs was volatilized and dispersed inside the working place without conducting control system of facilities during manufacturing paints. Concentration profile of VOC/HAPs, which is volatile naturally outside the factories, is surveyed above 70% at Toluene, Ethylbenzene, and Xylene. And a result of evaluation of odor attribution level about the component whose Odor Threshold is known, it is estimated that major cause material of A, B, C factories is Toluene and that of D factory is m/p-Xylene. And that result presented design arguments such as facilities specifications, activated carbon filling volume, and replace cycle of activated carbon as control technology. Also, that result presented emission process improvement such as adsorption of central-controlled ventilation device, installation of inlet flenge, and potable cleaning process. The rate of pollutant adsorption of Kapok fiber, which is natural material, is indicated about 91.9%, 66.7%. That result validated the possibility as replacement of activated carbon.

• Journal of the Korean Society of Marine Environment & Safety
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• v.23 no.1
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• pp.98-103
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• 2017

In this study, contributes to improving the state of this problem using cavitation by ultrasonic energy to reduce fuel costs, which take up a considerable part of ship operation costs, by making the use of on-board blended fuel oil more stable. An experiment simulating on-board blending methods was completed. Fuel (M.G.O & MF-180) was mixed at a volume ratio of 0.25:0.75 and, 0.75:0.25, and the effect of ultrasonic energy on blended fuel oil was examined after applying ultrasonic energy to blended fuel oil using an ultrasonic treatment unit. With the results, we confirmed the blending problem reported by vessels and residual carbon was reduced by up to 28.4%. In addition, based on the results for reduction of residual carbon content and dispersion stability, it was confirmed that the collapse pressure of the cavity due to the ultrasonic energy was effective to atomization of fuel particle and the temporary availability of mixed fuel containing a heavy fuel increased.