• Title/Summary/Keyword: 스크린 인쇄

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Fabrication and Electrical Properties of Ni-Mn-Co-Fe Oxide Thick Film NTC Thermistors (Ni-Mn-Co-Fe 산화물 후막 NTC 서미스터의 제조 및 전기적 특성)

  • Park, Kyeong-Soon;Bang, Dae-Young;Yun, Sung-Jin;Choi, Byung-Hyun
    • Journal of the Korean Ceramic Society
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    • v.39 no.10
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    • pp.912-918
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    • 2002
  • Ni-Mn-Co-Fe oxide thick films were coated on an alumina substrate by screening printing technique. The microstructure and electrical properties of the thick films, as a function of composition and sintering temperature, were investigated. The components of the NTC thick films sintered at 1150${\circ}C$ were distributed homogeneously. On the other hand, in the case of the NTC thick films sintered at 1200 and 1250${\circ}C$, Co element was distributed homogeneously, but Ni, Mn and Fe elements were distributed heterogeneously, resulting in the formation of Ni rich and Mn-Fe rich regions. All the thick film NTC thermistors prepared showed a linear relationship between log resistance (log R) and the reciprocal of absolute temperature (1/T), indicative of NTC characteristics. At a given NiO and $Mn_3O_4$ content, the resistance, B constant and activation energy of $(Ni_{1.0}Mn_{1.0}Co_{1-x}Fe_x)O_4$ (0.25${\le}$x${\le}$0.75) and $(Ni_{0.75}Mn_{1.25}Co_{1-x}Fe_x)O_4$ (0.25${\le}$x${\le}$0.75) thermistors increased with increasing $Fe_2O_3$ content.

Effect of Cathode Porosity on the Cathodic Polarization Behavior of Mixed Conducting LSCF(La0.6Sr0.4Co0.2Fe0.8O3) (혼합전도체 LSCF(La0.6Sr0.4Co0.2Fe0.8O3) 양극의 기공률에 따른 양극분극 특성)

  • Yun, Joong-Cheul;Lee, Jong-Ho;Kim, Joosun;Lee, Hae-Weon;Kim, Byong-Ho
    • Journal of the Korean Ceramic Society
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    • v.42 no.4
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    • pp.251-259
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    • 2005
  • In order to characterize the influence of the reaction-site density on the cathodic polarization property of LSCF, we chose the porosity of LSCF as a main controlling variable, which is supposed to be closely related with active sites for the cathode reaction. To control the porosity of cathodes, we changed the mixing ratio of fine and coarse LSCF powders. The porosity and pore perimeter of cathodes were quantitatively analyzed by image analysis. The electrochemical half cell test for the cathodic polarization was performed via 3-probe AC-impedance spectroscopy. According to the investigation, the reduction of oxygen at LSCF cathode was mainly controlled by following two rate determining steps; i) surface diffusion and/or ionic conduction of ionized oxygen through bulk LSCF phase, ii) charge transfer of oxygen ion at cathode/electrolyte interface. Moreover, the overall cathode polarization was diminished as the cathode porosity increased due to the increase of the active reaction sites in cathode layer.

Fabrication of Small SOFC Stack Based on Anode-Supported Unit Cells and Its Power Generating Characteristics (음극지지형 단전지를 사용한 소형 SOFC 스택의 제조 및 출력특성)

  • Jung, Hwa-Young;Kim, Woo-Sik;Choi, Sun-Hee;Kim, Joosun;Lee, Hae-Weon;Ko, Haengjin;Lee, Ki-Chun;Lee, Jong-Ho
    • Journal of the Korean Ceramic Society
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    • v.41 no.10 s.269
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    • pp.777-782
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    • 2004
  • In this research, $5\times5cm^2$ unit cells were fabricated via liquid condensation process and uniaxial pressing followed by the screen printing of electrolyte and cathode layer. The SOFC stack was assembled with unit cells, gasket-type sealant and metal interconnect. The stack was designed to have a single column with internal-manifold and cross-flow type gas-channels. The SOFC stack produced 15 W, which is $50\%$ of the maximum power being expected from the maximum power density of the unit cell. Controlling factors for the proper operation of the SOFC stack and other designing factors of stack manifold and gas channels were discussed.

Creation of the Fashion Design in Roy Lichtenstein's Works (로이 리히텐슈타인의 작품을 통한 패션디자인 창작)

  • Jeon, Yong-Ok
    • Archives of design research
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    • v.20 no.1 s.69
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    • pp.287-296
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    • 2007
  • Since the beginning of the 20th century, the art has developed its artistic qualities in exercising an influence on the creative elements of the fashion. In this sense, the fashion is one of many methods of which given time's arts, their compositions, and elements can be expressed, recognized, and experienced. In this study, artworks of Roy Lichtenstein, who took the leading, active role of pop artist have been studied. The purpose of this study is to present practical application of the art and aesthetic and artistic application of clothing by studying and applying the factors of Roy's paintings. The conclusion through actual designing is as follows: First, Lichtenstein interested with the characteristic of print media. He combined the image of commercial technique with the traditional painting by using Ben-day dots. Second, he reduces his form and color to the simplest possible elements. Third, by applying Lichtenstein's works to fashion design, we can make creative and aesthetic fashion works. Fourth, his Ben-day dots and stripe was applied to variant dots and stripe pattern in the fashion design. Roy Lichtenstein is expected to continually affect modern fashion and also fashion of the future. Furthermore Lichtenstein's works are expected to be further studied under various methods and ways, and those aesthetic characteristics would be developed and expressed more in fashion design under various perspectives.

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Properties of Thick Films Prepared with $V_2O_5$-doped Ferrite Pastes ($V_2O_5$ 도핑한 페라이트 페이스트 후막 특성)

  • 제해준;김병국;박재환;박재관
    • Korean Journal of Crystallography
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    • v.12 no.2
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    • pp.70-75
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    • 2001
  • The purpose of this study is to investigate the effect of V₂O/sub 5/ addition on physical and magnetic properties of NiCuZn ferrite for multi-layer chip inductors. NiCuZn ferrite pastes doped with 0, 0.1, 0.3 and 0.5 wt% V₂O/sub 5/ were prepared and samples of ferrite sheets were prepared by the screen printing method. They were sintered at 870, 880, 890 and 900℃, and then their physical and magnetic properties were analyzed. After sintering at 870℃, the sintered density of the ferrite sheet doped with 0.5wt% V₂O/sub 5/ showed the highest value to 5.08g/cm³due to the best densification by the liquid phase sintering, while the microstructures of ferrite sheets doped with 0.1 and 0.3 wt% V₂O/sub 5/ showed and inhibited grain growth. Irrespective of the sintering temperature, the initial permeability of ferrite sheet doped with 0.5 wt% V₂O/sub 5/ was highest and after sintering beyond 880℃, the quality factor of 0.3 wt% V₂O/sub 5/-doped sample appeared to be highest.

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Effects of Particle Size on Properties of PZT -Based Thick Films (입자 크기가 PZT계 압전 후막의 물성에 미치는 영향)

  • 김동명;김정석;천채일
    • Journal of the Korean Ceramic Society
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    • v.41 no.5
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    • pp.375-380
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    • 2004
  • Pb(Ni$\_$1/3/Nb$\_$2/3/)O$_3$-PbZrO$_3$-PbTiO$_3$ thick films were screen-printed on platinized alumina substrates and fired at 800-1000$^{\circ}C$. Two kinds of powders with different particle size were prepared by attrition and ball milling methods. Effects of particle size of starting material on the microstructure and electrical properties of the thick films were investigated. Average particle size of attrition milled-powder (0.44 ${\mu}$m) was much smaller than that of ball milled-powder (2.87 ${\mu}$m). Average grain size of the thick film prepared from attrition-milled powder was smaller than that of the thick film prepared from ball-milled powder at the sintering temperature of 800$^{\circ}C$. However, the difference in average particle size became smaller with increasing the sintering temperature. Thick films prepared from attrition-milled powders showed more uniform and denser microstructures at all firing temperatures. Thick films prepared from attrition-milled powders had better electrical properties at the firing temperature above 900$^{\circ}C$ than thick films prepared from ball-milled powders. Dielectric constant, remanent polarization and coercive field of the thick film prepared from attrition-milled powders and fired at 900$^{\circ}C$ were 559, 16.3 ${\mu}$C/cm$^2$, and 51.3 kV/cm, respectively.

Fractionation of KOCC by Froth-Flotation(IV)- (부상부유처리에 의한 국산 골판지 고지의 분급(IV))

  • 여성국;윤혜정;류정용;김용환;신종호;송봉근;서영범
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2000.11a
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    • pp.40-40
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    • 2000
  • 우리나라의 제지산업은 천연펄프 자급능력이 20% 내외로서 낮은 실정이며 주원료의 7 70% 이상을 수입펄프와 고지에 의존하는 원료수급의 불균형이 심화된 상태이다 .. 1999년도 제지통계에 의하면 골판지 원지로 사용되는 라이너지와 골심지의 연간 생산량이 각각 169만 톤과 88만톤을 점유하여 국내 전체 지류생산량 887만톤의 약 29%를 점하고 있다. 이처럼 국내 제지산업에서 큰 비중을 차지하는 골판지 원지는 주로 국내에서 발생되는 고지를 원료 로 하여 생산되고 있어 환경친화적인 지류라 할 수 있다. 그러나, 국산 골판지 고지( Korean O Old Corrugated Container)의 경우 골판지 고지 이외에 각종 인쇄고지와 기타 산업용지가 혼합된 최하급지로서, 고지 재생 시 여러 가지 많은 제한요소를 지니고 있다. 국산 골판지 고지는 거듭된 재생처리로 인하여 미세분의 함량이 전체 지료의 절반에 달할 만큼 많으며, 아울러 섬유가 각질화됨에 따라 재생처리가 거듭될수록 그러한 미세분의 형성이 더욱 조장 되고 있다. 일반적으로 크기 75µm 이하의 무기질 및 단섬유를 일걷는 미세분은 골판지 원지 의 초지시 습지필의 탈수를 저해하여 생산성을 저하시키는 요인이 되어 왔다. 이러한 문제 를 해결하기 위해 선진국에서는 골판지 고지를 스크린 또는 클리너 둥으로 정선 처리하여 장단섬유를 분급한 다음, 장섬유분을 선택적으로 고해하여 종이의 강도를 향상시키는 기술 이 개발되어 적용돼 왔으나, 이러한 기술은 우리 나라와 같이 장섬유 보다 미세분 함량이 많은 저급의 골판지 고지를 주원료로 삼는 골판지 원지의 강도 개선에 큰 효과를 거둘 수 없는 기술이라고 판단된다. 이는 기존의 섬유 분급 처리는 고급 고지의 경우에는 효과적이 나 저급의 혼합고지를 100% 재활용하여 구성되는 국산 골판지의 생산 시에 적용하기에는 5 50-60%에 이르는 미세분이 포함되어 분리의 대상이 섬유장이 다른 펼프 섬유라기 보다는 미세섬유를 펄프섬유로부터 분리하는 것이 필요하기 때문이다. 이러한 문제점을 극복하기 위해서는 기포의 수력학적 포집작용을 이용하여 고농도의 미세분을 선택적으로 분급시키는 부상부 유 분급처리방법을 적용하였다. 이 방법은 미세분의 농축을 위한 부가적인 처리가 필요치 않으며, 분급에 천공을 이용하지 않기 때문에 분급처리 시 천공의 plugging 문제가 발생되 지 않는다는 장점도 가지고 있다. 미세분 분급을 위한 최적의 부상부유 조건은 장섬유의 응 집을 촉진하면서 미세분은 그러한 응집체에 포함되지 않은 상태로 자유로이 부상하여 걷혀 지는 경우이다. 응집거동을 조절하기 위한 시도로서 부상부유 처리시 유량을 달리한 실험결 과에 의하면 유량이 낮을수록 장섬유 손실이 줄고 미세분이 선택적으로 포집되나 전체 부상 부유 리젝트의 양이 줄어드는 문제점이 있었다. 이에 본 실험에서는 장섬유의 응집에 영향 하는 또 다른 인자로서 지료의 농도를 증가시키면서, 미세분의 부상부유를 촉진시키도록 유 량을 증가시키는 조건으로 부상부유 처리에 의한 미세분 분급효율을 증가시키고자 하였다.

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Gas Sensing Properties and Mechanism of the $\textrm{SnO}_2-\textrm{In}_2\textrm{O}_3$ System Prepared by Coprecipitation Method (공침법으로 제조된 $\textrm{SnO}_2-\textrm{In}_2\textrm{O}_3$ 계의 가스감응특성 및 감응기구)

  • Yun, Gi-Hyeon;Im, Ho-Yeon;Gwon, Cheol-Han;Yun, Dong-Hyeon;Kim, Seung-Ryeol;Hong, Hyeong-Gi;Lee, Gyu-Jeong
    • Korean Journal of Materials Research
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    • v.8 no.9
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    • pp.813-818
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    • 1998
  • Ultrafine powders of $\textrm{In}_{2}\textrm{O}_{3}$-doped $\textrm{SnO}_{2}$ were synthesized by a coprecipitation method and the effects of pH value and the amount of In2Q addition on particle size were investigated. The influence of pH value on particle size could be negligible, whereas the amount of $\textrm{In}_{2}\textrm{O}_{3}$ has influenced on particle size and specific surface area. The gas sensitivity to hydrocarbOn($\textrm{C}_{3}\textrm{H}_{8}$, $\textrm{C}_{4}\textrm{H}_{10}$) increased with $\textrm{In}_{2}\textrm{O}_{3}$ addition and reached a maximum at 3wt.% addition. From the results of impedance analysis and I-V characteristics. it was showed that the agglomeration structure of particles and the boundaries between agglomerates were the important factors to determine the gas sensing mechanism.

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Synthesis of SiO2/Ag Core-shell Nanoparticles for Conductive Paste Application (SiO2/Ag 코어-쉘 나노입자의 합성 및 전도성 페이스트 적용)

  • Sim, Sang-Bo;Han, Jong-Dae
    • Applied Chemistry for Engineering
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    • v.32 no.1
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    • pp.28-34
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    • 2021
  • SiO2/Ag core-shell nanoparticles were synthesized by combining modified Stöber process and reverse micelle method using acetoxime as a reducing agent in water/dodecylbenzenesulfonic acid (DDBA)/cyclohexane reverse micells. The SiO2/Ag core-shells were studied for structure, morphology and size using UV-visible spectroscopy, XRD, SEM and TEM. The size of a SiO2/Ag core-shell could be controlled by changing the [water]/[DDBA] molar ratio (WR) values. The size and the polydispersity of SiO2/Ag core-shells increased with increase of the WR value. The resultant Ag nanoparticles exhibit a strong surface plasmon resonance (SPR) peak at 430 nm over the amorphous SiO2 nanoparticles. The SPR peak shifted to the red side with increase in nanoparticle size. Conductive pastes with 70 wt% SiO2/Ag core-shell were prepared, and the pastes were coated on the PET films using a screen-printing method. The printed paste film of the SiO2/Ag core-shell showed higher surface resistance than the commercial Ag paste in the range of 460~750 µΩ/sq.

Core-shell TiO2/Ag Nanoparticle Synthesis and Characterization for Conductive Paste (전도성 페이스트용 코어-쉘 TiO2/Ag 나노입자의 합성 및 특성 연구)

  • Sang-Bo, Sim;Jong-Dae, Han
    • Applied Chemistry for Engineering
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    • v.34 no.1
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    • pp.36-44
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    • 2023
  • Core-shell TiO2/Ag nanoparticles were synthesized by a modified sol-gel process and the reverse micelle method using acetoxime as a reducing agent in water/dodecylbenzenesulfonic acid (DDBA)/cyclohexane. The structure, shape, and size of the TiO2/Ag nanoparticles were investigated using X-ray diffraction (XRD), UV-visible spectroscopy, scanning electron microscope (SEM), transmission electron microscope (TEM), and thermogravimetric analysis (TGA). The size of TiO2/Ag nanoparticles could be controlled by changing the [water]/[DDBA] molar ratio values. The size and the polydispersity of TiO2/Ag nanoparticles increased when the [water]/[DDBA] molar ratio rose. The resultant Ag nanoparticles over the anatase crystal TiO2 nanoparticles exhibited a strong surface plasmon resonance (SPR) peak at about 430 nm. The SPR peak shifted to the red side with the increase in nanoparticle size. Conductive pastes with 70 wt% TiO2/Ag nanoparticles were prepared, and the pastes were coated on the PET films using a screen-printing method. The printed paste films of the TiO2/Ag nanoparticles demonstrated greater surface resistance than conventional Ag paste in the range of 405~630 μΩ/sq.