• Journal of the Korea Concrete Institute
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• v.28 no.3
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• pp.349-356
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• 2016

This report presents the results of an investigation on the early strength development of pastes high volume slag cement (HVSC) activated with different concentration of sodium carbonate ($Na_2CO_3$). The ordinary Portland cement (OPC) was replaced by ground granulated blast furnace slag (GGBFS) from 50% to 90% by mass, the dry powders were blended before the paste mixing. The $Na_2CO_3$ was added at 0, 2, 4, 6, 8 and 10% by total binder (OPC+GGBFS) weight. A constant water-to-binder ratio (w/b)=0.45 was used for all mixtures. The research carried out the compressive strength, ultrasonic pulse velocity (UPV), water absorption and X-ray diffraction (XRD) analysis at early ages(1 and 3 days). The incase of mixtures, V5 (50% OPC + 50% GGBFS), V6 (40% OPC + 60% GGBFS) and V7 (30% OPC + 70% GGBFS) specimens with 6% $Na_2CO_3$, V8 (20% OPC + 80% GGBFS) and V9 (10% OPC + 90% GGBFS) specimens with 10% $Na_2CO_3$ showed the maximum strength development. The results of UPV and water absorption showed a similar tendency to the strength properties. The XRD analysis of specimens indicated that the hydration products formed in samples were CSH and calcite phases.

• Journal of the Korea Concrete Institute
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• v.27 no.1
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• pp.65-73
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• 2015

This study discussed the pozzolanic properties of calcined sewage sludge (CSS) according to calcination and fineness conditions. The chemical and mineralogical analysis of CSS according to calcination temperature and time were carried out and compared with that of the existing pozzolanic materials such as fly-ash, blast furnance slag and meta-kaolin. Various mortars were made by mixing those CSS and $Ca(OH)_2$ (1:1 wt. %), and their compressive strength and hydrates according to experimental factors such as fineness of CSS and curing age were also investigated in detail. The results show clearly the potentiality of calcined sewage sludge (CSS) as an admixture materials in concrete, but the CSS should be controlled by calcination temperature and time, and fineness etc. In this experimental condition, the calcination temperature of $800^{\circ}C$, calcination time of 2 hours and fineness of $5,000cm^2/g$ were optimum conditions in consideration of the mechanical properties and economic efficiency of CSS. The compressive strength of CSS mortars was higher than that of fly-ash mortars and blast furnace slag mortars, especially at the early ages. Then, the utilization of CSS in construction fields was greatly expected.

• Korean Journal of Mineralogy and Petrology
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• v.33 no.1
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• pp.19-28
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• 2020

Ranciéte is a hexagonal phyllomanganate mineral containing random Mn(IV) vacancies with hydrated Ca²⁺ cations charged balanced as interlayer cations. Its Mn²⁺ analogue is called takanelite, and ranciéite and takanelite are regarded as end-members of a solid solution series of (Ca²⁺,Mn²⁺)Mn₄O₉·nH₂O. Because the minerals are found as very small particles associated with other minerals, the crystal structures of the solid solution series have yet to be defined. In this research, we conducted classical molecular dynamics (MD) simulations of ranciéite and takanelite by varying the Mn²⁺/Ca²⁺ interlayer cation ratio to find relations between the interlayer cations and mineral structures. MD simulation results of chalcophanite group minerals are compared with experimental results to verify our method applied. Then, lattice parameters of ranciéite and takanelite models are presented along with detailed interlayer structures as to the distribution and coordination of cations and water molecules. This study shows the potentials of MD simulations in entangling complicated phyllomanganates structures.

• Journal of the Korea Concrete Institute
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• v.15 no.2
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• pp.305-313
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• 2003

The setting and hardening of concrete is accompanied with nonlinear temperature distribution caused by development of hydration heat of cement. Especially at early ages, this nonlinear distribution has a large influence on the crack evolution. As a result, in order to predict the exact temperature history in concrete structures it is required to examine thermal properties of concrete. In this study, the coefficient of air convection, which presents thermal transfer between surface of concrete and air, was experimentally investigated with variables such as velocity of wind and types of form. From experimental results, the coefficient of air convection was calculated using equations of thermal equilibrium. Finally, the prediction model for equivalent coefficient of air convection including effects of velocity of wind and types of form was theoretically proposed. The coefficient of air convection in the proposed model increases with velocity of wind, and its dependance on wind velocity is varied with types of form. This tendency is due to a combined heat transfer system of conduction through form and convection to air. From comparison with experimental results, the coefficient of air convection by this model was well agreed with those by experimental results.

• Journal of the Korea Concrete Institute
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• v.15 no.2
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• pp.314-322
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• 2003

Pipe cooling method is widely used for reduction of hydration heat and control of cracking in mass concrete structures. However, in order to effectively apply pipe cooling systems to concrete structures, the coefficient of flow convection relating the thermal transfer between inner stream of pipe and concrete must be estimated. In this study, a device measuring the coefficient of flow convection was developed. Since a variation of thermal distribution caused by pipe cooling has a direct effect on internal forced flows, the developed testing device is based on the internal forced flow concept. Influencing factors on the coefficient of flow convection are mainly flow velocity, pipe diameter and thickness, and pipe material. Using experimental results from the developed device, the coefficient of flow convection was calculated. Finally, a general prediction model was proposed by theoretical procedures. The proposed prediction model is able to estimate the coefficient of flow convection with flow velocity and material properties of pipe. From comparison with experimental results, the coefficient of flow convection by this model was well agreed with those by experimental results.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.21 no.1
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• pp.6-14
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• 2011

The re-crystallization process for recovering granular crystalline gypsum from phospho-gypsum have proposed. The process consists of two stages; at the first stage, needle-like fine gypsum is recovered with under-product of 325 mesh wet screening after the speedy hydration of dehydrated phospho-gypsum, and at the second stage, granular crystalline gypsum is recovered with upper-product of 325 mesh wet screening after dehydration and re-crystallization of the needle-like fine gypsum in $Na_2SO_4$ solution. This paper is mainly focused on the influence of dehydration time, cooling speed of temperature and re-crystallization temperature on the recovery of granular crystalline gypsum. And the re-crystallization velocity of needle-like fine gypsum at room temperature and the variation of $Ca^{2+}$ concentration of gypsum slurry during over all re-crystallization process were also discussed.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.27 no.1
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• pp.47-56
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• 2017

In this study, the higher temperature thermal property of the fly ash-blast furnace slag system Geopolymer including alumina aggregate was investigated whether that Geopolymer will be or not useful as thermal-resistant construction materials. Under every mixing conditions, the crack on the surface of hardened body was not observed up to $800^{\circ}C$ and it corresponded with fact that level of changes was not significant before and after heating process. Residual compressive strength is most high when mixing Blast-Furnace Slag ratio is 60 wt% until temperature reaches $800^{\circ}C$. The major hydrates of hardened body of Geopolymer; amorphous halo pattern between $20{\sim}35^{\circ}$ (2theta) and mullite ($3Al_2O_3{\cdot}2SiO_2$) and quartz ($SiO_2$) was found during the experiment. Amorphous halo pattern was a aluminosilicate gel generated by geopolymeric polycondensation and it was found that the halo pattern of aluminosilicate gel was preserved up to $800^{\circ}C$. The patterns of aluminosilicate gel disappeared from $1,000^{\circ}C$ and crystal phases like gehlenite, calcium silicate, calcium aluminum oxide, microcline was observed with the increase of exposure temperature.

• Journal of Korean Tunnelling and Underground Space Association
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• v.22 no.6
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• pp.669-680
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• 2020

In Korea, fireproof performance is evaluated through a series of fire-resistance tests for important structures, and the performance standard follows the guidelines suggested by ITA. The fireproof duct slab manufactured by combining the slab and the fireproof material with a precast method is effective in that it can eliminate the construction time of the fireproof material. In this study, a series of fire resistance tests was performed on the fire test specimens under the RWS fire scenario in order to secure the fire resistance performance of the precast fireproof duct slab. As a result of the test, it was found that the fireproof performance was secured when the thickness of the fireproof material was 30 mm or more. In both fireproof materials and concrete, the rate of temperature change initially increased, then decreased, and then increased again, and the temperature at the inflection point was measured as 110℃ for all fireproof materials and concrete. It is judged that this occurs when the C-S-H (CaO-SiO₂-H₂O) generated by the hydration reaction in both the fireproof material and concrete is dehydrated.

• Journal of the Korea Institute of Building Construction
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• v.10 no.5
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• pp.113-119
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• 2010

Fire resistance and field tests for high-strength concrete(HSC) of 80MPa were carried out to evaluate whether or not it shows the same material properties even in the field condition of being mass-produced and supplied. As a result, it was found that fire resistant HSCs containing composite fiber(NY, PP) of 0.075% have great resistance to fire and spalling. In the field test, before the pumping air contents, slump flow, U-box, L-flow, compressive strength, gap of hydration temperature of interior and exterior of specimen and placing ratio per hour satisfied the required properties of HSC. However, after the pumping of HSC, as slump flow and L-flow were slightly less than required criterion, they need to be improved. In terms of hydration temperature of HSC, it was found to satisfy the related criterion. Packing ability as well as placing ratio per hour of HSC, which was about $44m^3$, show outstanding results. If slump flow of developed ternary HSC is improved after the pumping it can be useful for the construction of high-rise buildings.

• Journal of the Korea Institute of Building Construction
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• v.18 no.5
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• pp.439-446
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• 2018

The PHC pile has been increasingly used due to its implementation of the top-base method, which is advantageous in high penetration rate and bearing capacity reinforcement. Typically, when a PHC pile is manufactured, high-strength mixed materials are mainly used to enhance the compressive strength. However, recent studies have been conducted to utilize ground granulated blast-furnace slag (GGBS) in terms of economic efficiency. For this reason, this study manufactured PHC pile considering the replacement ratio and curing conditions of GGBS instead of high-strength mixed materials, and further investigated the engineering properties of the PHC pile. According to the experimental results, the compressive strength of GGBS-replaced PHC pile increased by steam curing, and particularly, PHC pile with 20% replacement of GGBS under $80^{\circ}C$ steam curing condition showed a compressive strength of approximately 84MPa. Furthermore, the experimental results confirmed that more hydration products were generated under the $80^{\circ}C$ steam curing condition than that under the $20^{\circ}C$ steam curing condition, which would affect the higher density of the PHC pile as well as the increase in the compressive strength.