• Title/Summary/Keyword: 수화물

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Decomposition Characteristics of 4-Chlorophenol Treated in Fe2O3 Supported γ-Alumina Catalyst and O3 (Fe2O3/γ-Al2O3 세라믹촉매와 오존을 이용한 4-클로로페놀의 분해특성)

  • 박병기;이정민;서동수
    • Journal of the Korean Ceramic Society
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    • v.41 no.6
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    • pp.485-492
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    • 2004
  • We prepared cylindrical y-alumina pellets using amorphous alumina and pore generating agent. The pellets were immersed in an aqueous solution of the mixture of Fe(NO$_3$)$_3$ㆍ9$H_{2}O$ and $CH_3$COOH. They were then hydrothermally treated at 20$0^{\circ}C$ for 3 h in autoclave, dried and calcined. For the application of environmental catalyst for its, we investigated the decomposition characteristics of 4-chlorophenol and the initiation characteristics of OH' conversion action in $O_3$ environment with or without the Fe$_2$O$_3$ supported ${\gamma}$-alumina catalyst and $O_3$ molecule.

Analysis of Internal Structure in Alkali-Activated Fire Protection Materials Using Fly ash (플라이애시를 활용한 알칼리 활성화 내화성 마감재의 내부구조 분석)

  • Song, Hun;Chu, Yong-Sik;Lee, Jong-Kyu
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.4
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    • pp.104-112
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    • 2012
  • This study involves investigating the correlation between variation of internal structure and heating temperature of alkali-activated fire protection materials using fly ash. Dehydration and micro crack thermal expansion occur in cement hydrates of cementitious materials heated by fire. Internal structure difference due to both the dehydration of cement hydrates and pore solution causes and influences changes in the properties of materials. Also, this study is concerned with change in microstructure and dehydration of the alkali-activated fire protection materials at high temperatures. The testing methods of alkali-activated fire protection materials in high temperature properties are make use of TG-DSC and mercury intrusion porosimetry measurements. The study results show that the alkali-activated fire resistant finishing material composed of potassium hydroxide, sodium silicate and fly ash has the high temperature thermal stability. These thermal stability is caused by the ceramic binding capacity induced by alkali activation reaction.

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Investigation on Factors Influencing Creep Prediction and Proposal of Creep Prediction Model Considering Concrete Mixture in the Domestic Construction Field (크리프 예측 영향요인 검토 및 국내 건설현장 콘크리트 배합을 고려한 크리프 예측 모델식 제안)

  • Moon, Hyung-Jae;Seok, Won-Kyun;Koo, Kyung-Mo;Lee, Sang-Kyu;Hwang, Eui-Chul;Kim, Gyu-Yong
    • Journal of the Korea Institute of Building Construction
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    • v.19 no.6
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    • pp.503-510
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    • 2019
  • Recently, construction technology of RC structures must be examined for creep in concrete. The factors affecting the creep prediction of concrete and the results of creep in domestic construction field were reviewed. The longer the creep test period and the higher the compressive strength, the higher the creep prediction accuracy. The higher the curing temperature, the higher the initial strength development of the concrete, but the difference in the creep coefficients increased over time. Based on the results of creep evaluation in the domestic construction field and lab. tests, a modified predictive model that complements the ACI-209 model was proposed. In the creep prediction of real members using general to high strength concrete, the test period and temperature should be considered precisely.

Analysis of the characteristics of polymer multi-layers by using quartz crystals (수정진동자를 이용한 고분자 누적막의 특성분석)

  • Kim, Ki-Young;Kim, Jong-Min;Kwon, Young-Soo;Lee, Burm-Jong;Chang, Yong-Keun;Kim, Jong-Deuk;Chang, Sang-Mok
    • Journal of Sensor Science and Technology
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    • v.3 no.2
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    • pp.3-10
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    • 1994
  • The use of preformed polymers and their cross-linking has been attempted in order to improve the intrinsic fragility of monolayers and Langmuir-Blodgett(LB) films. The evaluation of the characteristics of the LB multi-layer by using an AT-cut quartz crystal has been also attempted. This study reveals that the polyether pendants of 2C18VE3 lie at the air-water interface at low surface pressures and are forced down into the subphase when the monolayers are compressed. This characteristic behavoir of the pendant polyethers is very clear on aqueous poly allyl amine(PAA) and is also observeable on saturated aqueous NaCl and $CaCl_{2}$. And the characteristics of LB multi-layers could be evaluated by using AT-cut quartz crystal in situ.

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Decomposition Characteristics of Aniline Treated in Fe2O3 Supported γ-Alumina Catalyst and O3 (Fe2O3γ-Al2O3 세라믹촉매와 오존을 이용한 아닐린의 분해특성)

  • Park, Byung-Ki;Suh, Jeong-Kwon;Lee, Jung-Min
    • Journal of the Korean Ceramic Society
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    • v.42 no.4
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    • pp.237-244
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    • 2005
  • We prepared the cylindrical $\gamma-alumina$ pellets of 5 mm in diameter and 10 mm in average length using amorphous alumina and pore generating agent. The pellets were immersed in an aqueous solution of the mixture of $Fe(NO_{3})_{3}{\cdot}9H_{2}O$ and $CH_{3}COOH$. They were then hydrothermally treated at $200^{\circ}C$ for 3 h in autoclave, dried and calcined. For the application as an environmental catalyst, we investigated the decomposition characteristics of aniline and the initiation characteristics of $OH^{\cdot}$ conversion action in $O_{3}$ environment with or without the $Fe_{2}O_{3}$ supported y-alumina catalyst and $O_{3}$ molecule.

Temperature Distribution and It's Contribution to Self-equilibrium Thermal Stress in Bridge (교량 단면 내 온도분포에 따른 자체평형 열응력 해석)

  • Kwak, Hyo-Gyoung;Kwon, Se-Hyung;Ha, Sang-Hee
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.24 no.5
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    • pp.531-542
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    • 2011
  • The time-dependent temperature distribution across the section in bridges is determined on the basis of the three-dimensional finite element analyses and numerical time integration in this study. The material properties which change with time and thermal stress of concrete are taken into account to effectively trace the early-age structural responses. Since the temperature distribution is nonlinear and depends upon many material constants such as the thermal conductivity, specific heat, hydration heat of concrete, heat transfer coefficients and solar radiation, three representative influencing factors of the construction season, wind velocity and bridge pavement are considered at the parametric studies. The validity of the introduced numerical model is established by comparing the analytical predictions with results from previous analytical studies. On the basis of parametric studies for four different bridge sections, it is found that the creep deformation in concrete bridges must be considered to reach more reasonable design results and the temperature distribution proposed in the Korean bridge design specification need to be improved.

A Study on Crack Control of Tunnel Lining Concrete with Large Section (대단면 터널 라이닝 콘크리트의 균열저감 연구)

  • Kim, Wan-Young
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.509-512
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    • 2008
  • The lining concrete of water tunnel is a much capability to occur crack due to drying shrinkage and vibrator compaction etc. Because of crack of concrete induce structural problem and decrease durability of concrete, it is need to reduce crack of concrete. In this an Analytical study to analyze the effect of curing of concrete and compaction on the lining concrete. As the results, it was found that control of construction condition into curing of concrete and compaction improve on construction efficiency of the lining concrete.

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Drying Shrinkage of Ultra High Strength Steel-Fiber Reinforced Cementitious Composites (초고강도 강섬유 보강 시멘트 복합체의 자기수축 모델식에 관한 연구)

  • Kang, Su-Tae;Park, Jong-Sup;Joh, Chang-Bin;Park, Jung-Jun;Koh, Gyung-Taek;Kim, Byung-Suk
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.725-728
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    • 2008
  • Most of shrinkage is mainly caused by autogenous shrinkage in Ultra high strength steel-fiber reinforced cementitious composites(UHSFRC). water to binder ratio is very low, about 0.2. It occurs faster hydration and cause a large amount of autogenous shrinkage in early ages. the large autogenous shrinkage can cause harmful cracks in a structure and deteriorate the designed structural performance. therefore it is very important to predict the autogenous shrinkage accurately. The study about the autogenous shrinkage of UHSFRC was carried out in this paper. through comparing with JSCE recommendations for UHSFRC, it was found out that UHSFRC in this study showed higher autogenous shrinkage than that of JSCE. And Applicability of early proposed models by some researchers was also investigated. the analytical results let us know that Miyazawa's model showed the best agreement with the experimentally obtained autogenous shrinkage of UHSFRC.

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An Experimental Study on the Durability of Concrete adding MgO-Type Expansive Agent (MgO를 혼합한 콘크리트의 내구특성 평가에 관한 실험적 연구)

  • Kim, Tae-Sang;Jang, Bong-Seok;Jung, Sang-Hwa;Kim, Joo-Hyung
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.397-400
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    • 2008
  • MgO powder-mixed concrete, expanded at the lower temperature around $850{\sim}1000$ degree celcius, might have long-term expansibility, which could remunerate for the contraction of concrete with delayed expansion, and through the process, the crack resistance of mass concrete might be improved. Currently used expandable concrete additive has three different types : CSA, CaO and MgO. In this study, therefore, such tests as carbonation, chloride diffusivity, freezing-thawing resistance and sulfate resistance after 56 days' curing were implemented and compared the results with the concrete with no MgO mixed to evaluate the durability of 5% MgO-mixed concrete after longer period of time. The degree of hydration for the MgO-mixed cement paste was analyzed after 1 day, 3 days, 7 days, 28 days, and 56 days using SEM, XRD, DSC.

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A Study on Properties of Ultra High Strength Concrete of above 100MPa (100MPa급 이상의 초고강도 콘크리트의 자기수축 특성에 관한 연구)

  • Lee, Sang-Ho;Kim, U-Jae;No, Hyeon-Seung;Lee, Jae-Sam;Lee, Han-Seung
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.677-680
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    • 2008
  • The autogenous shrinkage of HPC is important in that it can lead the early cracks in concrete structures. The purpose of the present study is to explore the autogenous shrinkage of HPC with cellulose fiber and expansive additive and to derive a realistic equation to estimate the autogenous shrinkage model of that. For this purpose, comprehensive experimental program has been set up to observe the autogenous shrinkage for various test series. Major test variables were the quantity of expansive additive and cellulose fiber. Water-cement ratio is fixed with 13%. The autogenous shrinkage of HPC is found to decrease with increasing expansive additive and cellulose fiber. A prediction equation to estimate the autogenous shrinkage of HPC was derived and proposed in this study. The proposed equation shows reasonably good correlation with test data on autogenous shrinkage of HPC.

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