• Journal of Soil and Groundwater Environment
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• v.27 no.1
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• pp.31-38
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• 2022

The common algae and industrial waste, chlorella and red mud, were co-pyrolyzed in carbon dioxide condition to fabricate iron-biochar composite. In order to investigate the direct effect of chlorella and red mud in the syngas generation and the property of biochar, experiments were performed using mixture samples of chlorella and red mud. The evolution of flammable gasses (H₂, CH₄, CO) was monitored during pyrolysis. The produced biochar composite was employed as a catalyst for persulfate activation for methylene blue removal. BET analysis indicated that the iron-biochar composite mainly possessed meso- and macropores. The XRD analysis revealed that hematite (Fe₂O₃) contained in red mud was transformed to Fe₃O₄ during co-pyrolysis. The composite effectively activated persulfate and removed methylene blue. Among the composite samples, the composite fabricated from the mixture composed of 1:2 chlorella:red mud showed the best performance in syngas generation and methylene blue removal.

• Journal of Soil and Groundwater Environment
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• v.29 no.2
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• pp.1-10
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• 2024

With industrial development, the inevitable increase in both organic and inorganic waste necessitates the exploration of waste treatment and utilization methods. This study focuses on co-pyrolyzing lignin and red mud to generate metalbiochar, aiming to demonstrate their potential as effective adsorbents for water pollutant removal. Thermogravimetric analysis revealed mass loss of lignin below 660℃, with additional mass loss occurring (>660℃) due to the phase change of metals (i.e., Fe) in red mud. Characterization of the metal-biochar indicated porous structure embedded with zero-valent iron/magnetite and specific functional groups. The adsorption experiments with 2,4-dichlorophenol and Cd(II) revealed the removal efficiency of the two pollutants reached its maximum at the initial pH of 2.8. These findings suggest that copyrolysis of lignin and red mud can transform waste into valuable materials, serving as effective adsorbents for diverse water pollutants.

• Journal of the Korean Geophysical Society
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• v.6 no.3
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• pp.139-153
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• 2003

Subsurface information is one of the most important factors in the archaeological excavation. To obtain the information on the underground, geophysical prospecting is becoming a popular method. This study is on the small rocky islands located 200m away from the shoreline of Gampo, Gyeongju city, Korea. According to the historical records and field surveys, it was revealed as the tomb of King Munmu of Shilla Dynasty. However, the questions and debates, such as whether it is really the tomb of King Moonmu or not, and whether it is a buried place or not, are still remains, in addition to the incompletion of precise surveying and scientific studies. The scope of this study contains the researches on the above problems and debates using the geophysical and geological methods and techniques. The rocky islands around the submerged Tomb of King Moonmu is composed of granite, and sag exists inside of the islands. Sea water enters through the east groove by wave and is drained to the west slot by hydraulic gradient, since west slot is 15cm lower than the east. Sag inside of the islands is believed to be extended and widened from pre-existed sinkage by applying tools like chisel in the joints and cracks. It is concluded that the submerged megalith inside of sag was from the rock block which was developed by joints. Geophysical surveys reveal that there is no artificial structure or stone/china/steel chest, under the m egalith and rocky island. Researches show that the tomb of King Moonmu was constructed in the small rocky island artificially. However, the evidences show that planners and constructors of the tomb made every possible effort to preserve the natural environment and condition. It is strongly believed that the megalith was sort of alter to sprinkle bone-ash rather than buried place.

• Journal of the Korean Geophysical Society
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• v.7 no.3
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• pp.207-215
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• 2004

As the sea connecting with the East Sea, the Sea of Okhotsk is the most potential area of gas hydrates in the world. In other to examine geophysical structures of gas hydrate-bearing sediments in the Sea of Okhotsk, the CHAOS (hydro-Carbon Hydrate Accumulation in the Okhotsk) international research expedition was carried out in August 2003. In the expedition, high-resolution seismic and geochemical survey was also conducted. Sparker seismic profiles show only diffusive high-amplitude reflections without BSRs at BSR depth. It means that BSR appears to be completely different images on seismic profiles obtained using different frequencies. Many gas chimneys rise up from BSR depth to seafloor. The chimneys can be divided into two groups with different seismic characteristics; wipe-out (WO) and enhanced reflection (ER) chimneys. Different seismic responses in the chimneys would be caused by amount of gas and gas hydrates filling in the chimneys. In hydroacoustic data, a lot of gas flares rise up several hundreds meters from seafloor to the water column. All flares took placed at the depths within gas hydrate stability zone. It is interpreted that gas hydrate-bearing sediments with low porosity and permeability due to gas hydrate filling in the pore space make good pipe around gas chimneys in which gas is migrating up without loss of amount. Therefore, large-scale gas flare at the site on gas chimney releases into the water column.

• Journal of the Korean Society of Propulsion Engineers
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• v.19 no.3
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• pp.9-19
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• 2015

Experimental research on characteristics of particle-laden jet by using a coaxial injector was conducted in order to design fuel and oxidizer injectors of the supercavitation underwater vehicle. $1{\mu}m$ and $42{\mu}m$ particles was simultaneously injected to obtain particle and fluid velocity. Small particles($1{\mu}m$) and large particles represent fluid and fuel characteristics respectively. Small particles, which was processed using PIV algorithms, and one for the large particles processed using PTV algorithms. Fluid phase axial velocity increases according to particle loading ratio increases, and particles are located at the outside of the high vorticity region in a mixing layer of a coaxial injector.

• Journal of the Korean Geotechnical Society
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• v.23 no.1
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• pp.51-65
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• 2007

The purpose of this study is the development and application of a high resolution ultrasonic wave imaging system to detect discontinuity plane in lab-scale rock models. This technique is based on received time series which capture the multiple reflections at interface. This study includes the fundamental aspects of ultrasonic wave propagation in rock mass, the selection of the optimal ultrasonic wave transducer, data gathering, a signal processing, imaging methods, and experiments. Experiments are carried out by the horizontal movement and rotation devices. Experimental studies show the discontinuity is well detected by the horizontal movement and rotation devices under water. Furthermore, the discontinuity and the cavity on the plaster block are identified by the rotation device. This study suggests that the new method may be an economical and effective tool for the detection of the discontinuity on rock mass.

• Korean Journal of Soil Science and Fertilizer
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• v.32 no.1
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• pp.47-56
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• 1999

$^{15}N$-Isotope concentrations of groundwater from l4 wells with different land-use types in Kyonggi Province were measured to investigate the nitrate contamination sources. Water samples were collected monthly from January to December 1997 and analyzed for pH. PC, anions (fluoride, chloride, nitrate, sulfate, inorganic phosphate, and bicarbonate), and canons (calcium, magnesium, potassium, and sodium). For the analysis of the $^{15}N/^{14}N$ ratio as ${\delta}^{15}N$, $N_2$ samples were prepared through Kjeldahl-Rittenberg method and were analyzed using an isotope ratio mass spectrometer (VG Optima IRMS). Reproducibility of the method and precision of the IRMS were below 1.0‰ and 0.1‰, respectively. The ionic composition of each groundwater sample was only slightly different according to the land-use type. The nitrate concentrations of groundwater in cropland or livestock farming areas were higher than those in the residential area. The percentages of nitrate to total anions of groundwater samples from the livestock farming area were higher than those of other areas. The ${\delta}^{15}N$ values of ammonium sulfate, urea, groundwater sample in the non-contaminated area, and water from the animal manure septic tank were -2.7, 1.4, 5.5, and 27.2‰, respectively. Based on the ${\delta}^{15}N$ values, the sources of nitrate could be classified as originated from chemical fertilizers with ${\delta}^{15}N$ values below 5% and as from animal manure or municipal waste with ${\delta}^{15}N$ values over 10‰. In most cases, contamination sources investigated from ${\delta}^{15}N$ values of groundwater samples were correlated with the specific sources according to the land-use types. However, some ${\delta}^{15}N$ values did not matched the apparent land-use types, and there were seasonal variations of ${\delta}^{15}N$ values within the same well. These results suggest that the groundwater quality was affected by two or more contamination sources and the contribution of each source to the groundwater quality varied depending on the sampling season.

• Economic and Environmental Geology
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• v.55 no.1
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• pp.63-76
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• 2022

Dacitic tuffs, 97 to 118 m thick, were recovered from the lower part of the subsurface Seongdongri Formation, Janggi Basin, which was drilled to assess the potential for underground storage of carbon dioxide. The tuffs are divided into four depositional units(Unit 1 to 4) based on internal structures and particle componentry. Unit 1 and Units 3/4 are ignimbrites that accumulated in subaerial and subaqueous settings, respectively, whereas Unit 2 is braided-stream deposits that accumulated during a volcanic quiescence, and no dacitic tuff is observed. A series of analysis shows that mordenite and clinoptilolite mainly fill the vesicles of glass shards, suggesting their formation by replacement and dissolution of volcanic glass and precipitation from interstitial water during burial and diagenesis. Glass-replaced clinoptilolite has higher Si/Al ratios and Na contents than the vesicle-filling clinoptilolite in Units 3. However, the composition of clinoptilolite becomes identical in Unit 4, irrespective of the occurrence and location. This suggests that the Si/Al ratio and pH in the interstitial water increased with time because of the replacement and leaching of volcanic glass, and that the composition of interstitial water was different between the eastern and western parts of the basin during the formation of the clinoptilolite in Units 1 and 3. It is also inferred that the formation of the two zeolite minerals was sequential according to the depositional units, i.e., the clinoptilolite formed after the growth of mordenite. To summarize, during a volcanic quiescence after the deposition of Unit 1, pH was higher in the western part of the basin because of eastward tilting of the basin floor, and the zeolite ceased to grow because of the closure of the pore space as a result of the growth of smectite. On the other hand, clinoptilolite could grow in the eastern part of the basin in an open system affected by groundwater, where braided stream was developed. Afterwards, Units 3 and 4 were submerged under water because of the basin subsidence, and the alkali content of the interstitial water increased gradually, eventually becoming identical in the eastern and western parts of the basin. This study thus shows that volcanic deposits of similar composition can have variable distribution of zeolite mineral depending on the drainage and depositional environment of basins.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.8 no.3
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• pp.225-236
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• 2003

In order to understand the relationship of depositional environment between fluvial and estuarine-embayment in Han River system, including depositional change in main Han River, more than 250 bottom sediment and 70 suspended sediment were analyzed with hydrologic data. Based on the previous data, the study area can be divided into two environment(fluvial and estuarine-embayment) by Singok underwater dam. The gravelly facies occurs in the South and North Han Rivers and sandy and silty facies occupies in the main Han River. Depositional environment of main Han River changed mainly because of limited sediment transport and hydrological condition. In the estuarine-embayment environment, coarse-grained sediments are dominant in tidal channel and of shore whereas fine and poorly sorted sediments are observed in coastal area. During moderate period, relationship between fluvial-estuarine-embayment system is discontinuou s because of flow restriction by artificial construction such as dam and underwater dam, so that each river system characterizes the individual environment. Fluvial and estuarine system is influenced by tide and, thus, transition zone of estuarine- embayment system moves landward. During flooding period, however, each river system is integrated as continuous depositional system by high discharge and, thus, transition zone of fluvial-estuarine-embayment system moves seaward. For further detailed systems about the lower Singok under-water dam, joint research of South-North Korea should be necessary.

• Proceedings of the Korea Society of Environmental Toocicology Conference
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• 1994.05a
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• pp.51-53
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• 1994

담수는 인간의 생존에 필수적인 요소이다. 우리는 매일 일정량의 물을 섭취하고 있으며, 일상에서 직접, 간접적으로 물과 관련되지 않고서는 생활할 수 없다. 지구 표면의 약 70%가 물로서 덮여 있다고는 하지만 인간의 생활에 직접적인 이용가치가 있는 담수(지표수)는 전체 물의 용적의 2%에 지나지 않는다. 한국의 연평균 강수량은 1,274mm로서 세계 연평균 강수량인 970mm보다 많은 편이나 인구 1인당 연간 강수량은 약 3,000m3으로서 세계 평균인 34,000m3의 11분의 1에 지나지 않는다. 수자원총량중 지하침투와 증발에 의해 손실되는 양을 제외한 하천유출량은 전체의 55%인 697억m3으로서 이것이 곧 가용수자원량이다. 그러나 하절기 강우집중도가 높은 우리나라 실정에서는 가용수자뭔량중 수자원총량의 37%가 홍수시 유출되고 실제 이용량은 수자원총량의 18%인 230억m3에 불과하여 인구증가와 함께 수자원의 가치가 더욱 증대하고 있는 실정이다. 더우기 지하수 이용량은 19억m3에 불과함에 따라 우리나라는 실제 이응수자 원량의 90% 이상을 지표수에 의존하고 있으며, 그 중 약 40%가 호소수로 구성되어 있다. 이러한 수자원 이용효율의 취약성으로 인해 제한된 수자원 용량과 생활 및 농공용수의 과수요에 따른 불균형으로 근래 많은 하천이 갈수기나 평수기시 친천화되어 가고 있어 수중생태계에 큰 위협을 주고 있다. 또한 이에 더하여 산업발달과 함께 수질오염원은 양적으로는 물론 질적으로도 증가일로에 있어 기존의 유기 및 중금속 오염물질을 포함해 수많은 신생 유기화합물질이 수계에 유출되고 있으며, 이에 더해 질소 및 인으로 대표되는 영양물질의 유입과다로 국내 대다수의 호수가 부영양화의 새로운 위협에 직 면해 있다. 우리나라에는 적은 유입유량에 큰 저수용량 및 긴 체류시간으로 대표되는 대규모 자연호는 없으며, 대부분이 매단위 강을 막아 형성된 체류시간 1년 이하의 인공호로서 그 중 안동호, 충주호, 대청호 등은 비교적 체류시간이 긴 호소형 인공호로, 팔당호나 기타 대부분의 호수는 체류시간이 짧은 하천형 인공호로 대별된다(Table 1). 이처럼 국내 호소는 국외의 자연 호와는 다른 구조적 특성을 가짐에 따라 부영양화 특성 역시 매우 상이하고, 호소형 인공호와 하천형 인공호간의 차이 역시 현저하여 일률적인 관리대책을 설정하기가 어려운 실정에 있다. 또한 각 호수의 유역특성이 상이함에 따라 호수별로 유역 오염원의 오염부하율이 현저히 달라(Table 2) 호수에 따른 특성적인 유역관리(Lake-specific management)가 요구되고 있다 정상상태(Steady state)가 아닌 국내 호소에 대해 국외 자연호의 인단순모델 (Simple phosphorus budget model)을 그대로 적용하는 것에 다소 무리한 점이 따르나, 평균적인 개념으로 OECD의 유역부하량 및 호소특성에 따른 부영양화 판정모델을 적용한다면, 국내 주요 호수는 모두 부영양 수준에 있다. 또 각 호수별로 부영양화 제어를 위해 요구되는 인의 삭감부하량은 상당량이 되어 현실적으로 관리가 이미 어려운 실정에 와 있다. 호수의 부영양화는 조류 발생으로 이어지며, 그에 따른 폐해는 각종 형태로 나타나는데 대표적으로 이취미 발생이나 유해조류에 의한 독성물질의 배출, 정수처리 과정의 THM 발생등이 주로 문제가 되고 있다. 따라서 국내 호수의 구조적 특성별 부영양화 실태를 파악하고 그에 따른 영향 및 관리방안에 관한 종합적 고찰이 차후 수질관리를 위해 요구되고 있으며, 특히 납조류로 대표되는 유해조류의 독성영향에 관한 연구는 시급한 실정에 있다.