• Proceedings of the Korea Water Resources Association Conference
• /
• 2010.05a
• /
• pp.253-257
• /
• 2010

최근 들어 이상 강우 현상으로 인한 기록적인 집중 강우와 더불어 토지 이용 변화로 인해 탁수의 발생 빈도가 증가하고 있다. 강우 유출로 유입한 탁수는 저수지 내 장기간 체류하면서 하류 하천의 수질 및 수생태계 뿐만 아니라 저수지 내부의 영양단계에도 많은 영향을 준다. 특히, 성층화된 저수지의 경우 높은 영양염류 농도를 포함한 탁수는 밀도류 거동 특성을 보이면서 수평 및 수직 혼합 과정을 거치면서 국부적인 부영양화 현상과 조류의 수화 현상의 원인이 되고 있다. 따라서 대형 저수지의 수질관리에 있어 하천 유입 탁수의 밀도류 해석, 저수지의 수온 성층 구조 변화, 부유입자의 동력학적 해석이 중요한 요소로 부각되어 왔다. 본 연구에서는 소양호를 연구 대상 지역으로 선정하여 2005년과 2007년 수문 사상을 바탕으로 2차원 횡방향 수치 모형을 구축하였다. 수치모형을 통해 수온 성층 구조의 재현성을 확인하였으며, 다양한 탁수 거동 모형을 구축하여 적용성을 평가하였다. 유입수의 SS(Suspended Solid)를 단일 입경으로 가정한 TM-1 모형, SS의 입경분포에 따라 3개의 그룹(SSi)으로 구분한 TM-2 모형, 3개 그룹을 포함하면서 저수지내 탁수 장기화로 인한 탁수 저감 효과를 1차 반응상수로 매개 변수화(유기물 함량($a_0$) ${\times}$ 분해속도(${\lambda}_a$))하여 수정된 지배방정식을 적용한 TM-3 모형을 사용하였다. 각각의 탁수 거동 모형은 2005년과 2007년 수문 조건에서 수온 성층 구조를 잘 재현하였다. TM-1 모형과 TM-2 모형을 비교해보면, 탁수 중심축의 최고 탁도에 대한 예측 성능은 TM-2 모형이 우수한 결과를 나타냈었다. 하지만, 장기 탁수 모의 시 저수지 수중 잔류 SS가 지속적으로 높게 나타나 중층 탁도를 과대평가하는 경향을 보였다. TM-3 모형이 TM-2 모형에 비해 수심별 탁도 분포에 대한 중심축 탁도가 저평가되는 경향을 보였지만 저수지 내 잔류 탁도에 대한 영향 부분에서는 개선된 결과를 나타내었다. 본 연구 결과는 저수지 탁수 밀도류 해석 및 운영 시스템에 활용 될 수 있으며, 선택 취수 설비 등의 수리 구조물의 영향 평가에 활용할 수 있다.

• Applied Chemistry for Engineering
• /
• v.25 no.3
• /
• pp.307-311
• /
• 2014

In this present study, Castanea crenata was found as an excellent biosorbent for the removal capability of copper ions among four different wood wastes (Castanea crenata, Pinus densiflora, Larix kaemoferi and Robinia pseudoacaia). Also, the removal efficiencies of 5, 10, 20, 40 and 50 mg/L copper ions using Castanea crenata from aqueous solution were investigated. The most effective particle size of Castanea crenata for removing 5 mg/L copper ions was found to be $43{\sim}63{\mu}m$. When the concentration of Castanea crenata increased, the removal efficiencies of copper ions were enhanced. In addition, when the 0.8 g/100 mL of Castanea crenata was used for 30 min, the removal efficiencies of 20 and 40 mg/L copper ions were 99% and 85%, respectively. Moreover, the chemical treatment of Castanea crenata with 1 M sodium acetate was required to improve the removal ability for 50 mg/L copper ions. Meanwhile, 1 M hydrochloric acid was selected as the optimal desorption agent with 93% desorption efficiency of copper ions for recycling of modified Castanea crenata. Therefore, these experimental results could be employed as economical and practical engineering data for the development of copper removal processes.

• Journal of Soil and Groundwater Environment
• /
• v.13 no.3
• /
• pp.21-26
• /
• 2008

Nitrate adsorption from aqueous solutions onto zinc chloride ($ZnCl_2$) treated coconut Granular Activated Carbon (GAC) was studied in a batch mode at two different initial nitrate concentrations (25 and 50 mg/L). The rate of nitrate uptake on prepared media was fast in the beginning, and 50% of adsorption was occurred within 10 min. The adsorption equilibrium was achieved within one hour. The mechanism of adsorption of nitrate on $ZnCl_2$ treated coconut GAC was investigated using four simplified kinetic models : the rate parameters were calculated for each model. The kinetic analysis indicated that pseudo-second-order kinetic with pore-diffusion-controlled was the best correlation of the experimental kinetic data in the present adsorption study.

• Membrane Journal
• /
• v.31 no.4
• /
• pp.241-252
• /
• 2021

Rapid industrialization with growing population leads to environmental water pollution. Demand in generation of clean water from waste water is ever increasing by scarcity of rain water due to change in weather pattern. Colorimetric detection of heavy metal present in clean water is very simple and effective technique. In this review membrane based colorimetric detection of mercury (II) ions are discussed in details. Membrane such as cellulose, polycaprolactone, chitosan, polysulfone etc., are used as support for metal ion detection. Nanofiber based materials have wide range of applications in energy, environment and biomedical research. Membranes made up of nanofiber consist up plenty of functional groups available in the polymer along with large surface area and high porosity. As a result, it is easy for surface modification and grafting of ligand on the fiber surface enhanced nanoparticles attachment.

• Journal of the Korean Society of Visualization
• /
• v.19 no.3
• /
• pp.84-91
• /
• 2021

Effervescent tablets generate gas bubbles when chemical reaction occurs between water and tablets. Most of previous studies have been focused on pharmaceutical characteristics of tablets. However, for their applications in disinfectants, cleaners, and pesticides, physical characteristics of bubbles released from the effervescent tablets when they are in water are important. In this study, we experimentally investigated the characteristics of microbubbles generated by an effervescent tablet made of sodium bicarbonate and tartaric acid using PDPA and high-speed camera. Microbubbles were generated using different weights of effervescent tablet as well as in different water temperature. The experimental study shows increase in reaction time, bubble concentration and rise velocity as the weight of effervescent tablet increases from 1 to 20 g. The decrease in average bubble diameter was observed when the temperature of water increased from 25 to 45 ℃. Further, reaction time varies inversely with increase in water temperature, while bubble rise velocity is directly proportional to increase in water temperature. Effervescent table continuously generates the bubble with approximately constant diameter (235 ㎛) in the water. However, bubble concentration and bubble rise velocity decreased over time.

• Korean Chemical Engineering Research
• /
• v.60 no.2
• /
• pp.289-294
• /
• 2022

Oil contained in domestic and industrial wastewater or marine spilled oil gives rise to severe environmental pollution issues such as water pollution and ecosystem destruction. The membrane filtration method as one of representative oil/water separation strategies has technological challenges such as membrane fouling and low separation rate. In this work, we devise a 3D-printed microhydrocyclone for oil/water separation by utilizing a digital lighting processing-based 3D printer. We demonstrate that the 3D-printed microhydrocyclone can effectively separate oil and water phases from oil-in-water emulsion.

• Korean Journal of Ecology and Environment
• /
• v.40 no.2
• /
• pp.318-326
• /
• 2007

Characteristics of organophoshhorus pesticides (OPs) distribution were investigated in Shingu Reservoir, as a shallow eutrophic agriculture reservoir in Korea. In August 2006, IBP, DDVP and dyfonate were detected in the water column of Singu Reservoir, ranging from 1340.7 to 16030.1 ng $L^{-1}$, 58.7 to 127.6 ng $L^{-1}$ and N.D. to 20.3 ng $L^{-1}$, respectively, However, in September 2006, mevinfos, ethoprofos, phorate, chlorfenvinfos, and methidathion were also found in addition to IBP (202.5${\sim}$213.2 ng $L^{-1}$), DDVP (100.7${\sim}$340.6 ng $L^{-1}$) and dyfonate (N.D.${\sim}$25.0 ng $L^{-1})$. Maximum concentrations of OPs were observed at the middle depth in August, which might be related with photo-oxidation. On the other hand, IBP and DDVP among the OPs were detected in suspended particles, suggesting the relatively active adsorption reactivity. The composition of OPs varied temporally on account of the influence of inflow water from its surrounding areas. In the present study, the observed OPs concentrations seem to be not acute toBic levels to aquatic organisms in Shingu Reservoir, considering the standard monitoring levels of U.S. Environmental Protection Agency and Japan Ministry of Environment.

• Korean Journal of Soil Science and Fertilizer
• /
• v.29 no.2
• /
• pp.113-123
• /
• 1996

This experiment was carried out to compare with the physico-chemical properties of granular fused magnesium phosphates which were two domestic products(Pungnong Biryo Industrial Co., LTD and Kyunggi Chemical Industrial Co., LTD) and a imported Chinese product. The changes of pH, distribution of particle size, disintegration in water and in soil, hardness in soil, chemical composition, and dissolution rates in water, in soil and in 2% citric acid solution were investigated. The changes in pH were bigger in Jungmun series(black volcanic soil), in the imported chinese product, and in Jungmun series with the larger quantities applied. The domestic products were lower in pH, calcium, alkalinity and 1/2N-HCl soluble silicate than the Chinese product but total(Aqua regia) soluble phosphate, 2% citric acid soluble phosphate, 1/2N-HCl soluble and 2% citric acid soluble magnesium, and 2% citric acid soluble manganese concentration were similar among the domestic products and the imported product. In particle sizes, Chinese product was the biggest, Kyunggi product was the next, and Pungnong product was the smallest. The changes of disintegration rate in water and in soil were smaller in Pungnong and Kyunggi products at the early days of dissolution, and there were decreased with the order of Kyunggi product> Chinese product> Pungnong product at the latter days. The hardness of the products in soil was the strongest in Kyunggi product, the next was Pungnong product and Chinese product was the weakest so as to hardly measurable. The changing dissolution rates of 2% citric acid soluble phosphate concentration of granular fused magnesium phosphate products were the highest in Kyunggi product and the lowest in Pungnong product at the early days, the three products were dissolved over 90% within 50 days, and there were no clear difference among the products after 70 days of dissolution. The dissolution rates of 2% citric acid soluble phosphate concentration of granular fused magnesium phosphate products in soil were the highest in Pungnong product and Chinese product was the lowest, but they were less than 60% in 100 days of dissolution.

• Journal of the Korean Society of Fisheries and Ocean Technology
• /
• v.36 no.2
• /
• pp.117-125
• /
• 2000

The waveform and spectrum analysis of Tursiops truncatus(bottlenose dolphin) sonar signals were carried out on the basis of data collected during the dolphin show at the aquarium of Cheju Pacificland from October 1998 to February 1999. When greeting to audience, the pulse width, peak frequency and spectrum level from the five dolphins'sonar signals were 3.0ms, 4.54kHz and 125.6dB, respectively. At the time of warm-up just before the show, their figures were 5.0㎳, 5.24kHz and 127.0dB, respectively. During the performance of dolphins, with singing, peak frequency ranged 3.28∼5.78kHz and spectrum level ranged 137.0∼142.0dB. With playing ring, pulse width, peak frequency and spectrum level were 7.0㎳, 2.54kHz and 135.9dB, and when playing the ball, the values were 9.0㎳, 2.78kHz and 135.2dB, respectively. The values determined from the five dolphins during jump-up out of water were : pulse width 2.0㎳, peak frequency 4.50kHz and spectrum level 126.8dB. When they responded to trainer's instructions, the values were 2.25㎳, 248kHz and 148.7dB, respectively, and greeting to audience, the peak frequency and spectrum level were 5.84kHz and 122.5dB. During swimming under water, peak frequency and spectrum level were determined to be 10.10kHz and 126.8dB. It was found that there exited close consistencies in pulse width, frequency distribution and spectrum level between whistle sounds and dolphin's sonar signals. Accordingly, the dolphins can be easily trained by using whistle sound based on the results obtained from the waveform and spectrum of the dolphin's sonar signals.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
• /
• v.8 no.3
• /
• pp.251-261
• /
• 2003

As a part of an on-going project investigating flux of materials in Gomso Tidal Flat, we have monitored temporal and spatial distribution of nitrogen components(TN, PON, DON, DIN) and have sought the relationships with the freshwater input(tidal range, salinity), the biological activities(chlorophyll-${\alpha}$, TP, DIP, silicate) and the resuspended bottom sediment in seawater(SPM) from 1999 to 2000. TN in seawater was 39.05 $\mu\textrm{m}$ol 1$\^$-1/ (31.03∼42.93 $\mu\textrm{m}$ol 1$\^$-1/) without any statistical difference(p<0.05) between the studied periods. Organic nitrogen (DON and PON) occupied 75％, 95％, 73％, and 75％ in April, August, September and November, respectively. DON and PON have been found within the narrow concentration ranges of 11.30∼16.38 $\mu\textrm{m}$ol 1$\^$-1/ and 13.16∼20.04 $\mu\textrm{m}$ol 1$\^$-1/ in spite of severe environmental differences through the studied periods. Dissolved fractions of nitrogen(DON and DIN) occupied 53∼65％ of TN. Only DIN varied with an evident temporal variability: low concentrations(1.325∼1.616 $\mu\textrm{m}$ol 1$\^$-1/) in August and high enrichment(8.377∼14.65 $\mu\textrm{m}$ol 1$\^$-1/) in September. High consumption rate of DIN by phytoplankton and a long-lasted drought probably induced such low concentration of DIN in August. Eventually heavy precipitation probably introduced plenty of new nitrogen sources into Gomso Bay in September. The portion of PON, DON and DIN in the total nitrogen was 40％, 38％ and 22％, respectively. Their contents were in the order of DON>PON>DIN for the year round except PON>DON>DIN only in September. The highest DON portion in August probably due to the active microbial decomposition of organic material in summer. Only in April, some evident negative correlations have been found between chlorophyll-${\alpha}$ and DIN mostly nitrate(-0.64, p<0.01), phosphate(-0.46, p<0.01) and silicate(-0.55, p<0.01). The Si(OH)$_4$/DIN/DIP ratios in the water column suggests the limitation of DIN for the growth of phytoplankton during the dry summer in Gomso Bay, which was the case of August in this work. Even with some difference between the studied periods, the primary factors on the distribution of nitrogen components in seawater overlying the Gomso Tidal Flat have been the tidal range and the freshwater input, but the additional variations were due to the biological activities.