• Title/Summary/Keyword: 수용성 인

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Synthesis and Characterisation of Acrylic-Modified Water-Reducible Alkyd Resin 1. Modification by TMPTA Graft Copolymerization (수용성 아크릴 변성 알키드수지의 합성과 물성 1.TMPTA그라프트 공중합에 의한 변성)

  • Cho, Young-Ho;Noh, Si-Tae
    • Applied Chemistry for Engineering
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    • v.4 no.4
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    • pp.823-829
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    • 1993
  • The basic medium oil modified alkyd resin was synthesized from linseed oil fatty acid(LOFA), phthalic anhydride(PAA), trimellitic anhydride(TMA ), and trimthylol propane(TMP) by condensation polymerization at $230^{\circ}C$. TMPTA modified water-reducible alkyd resins were synthesized with TMPTA graft copolymerization onto the basic resin at $180^{\circ}C$. Acid value of the resin was controlled by the addition of TMA and N,N-Dimethylethanol amino(DMEA) was used as an neutralizing agent to prepare water-reducible alkyd. To evaluate the optimum formulation for anionic alkyd resin, water proofness and water reducibility were estimated from the acid value or TMA contents. The effect of TMPTA on the graft copoymerization of the resin was studied by measuring molecular weight, glass transition temperature(Tg), viscosity, and gel contents. The suitable balance of water proofness and water reducibility of the resin was obtained at range of 5.3~7.0wt.% of TMA contents or 40~50 of acid value of basic resin. The molecular weight, viscosity, and gel contents of water-reducible alkyd resin were increased according to the TMPTA graft copolymerization, but Tg was decreased.

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Study on Physicochemical Properties of Pesticide. (I) Water Solubility, Hydrolysis, Vapor Pressure, and n-Octanol/water Partition Coefficient of Captafol (농약의 물리화학적 특성연구 (I) Captafol의 수용성, 가수분해, 증기압, 옥탄올/물 분배계수)

  • Kim, Jeong-Han;Lee, Sung-Kyu;Kim, Yong-Hwa;Kim, Kyun
    • Applied Biological Chemistry
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    • v.40 no.1
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    • pp.71-75
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    • 1997
  • Important physicochemical properties of captafol [N-(1,1,2,2-tetrachloro-ethylthio)cyclohex-4-ene-1,2-dicarboximide], water solubility, vapor pressure, hydrolysis and octanol/water partition coefficient(Kow) were measured based on the standard EPA and OECD methods. Water solubility of the chemical was 2.24 ppm at $25^{\circ}C$. Half-life by hydrolysis at $25^{\circ}C$ in the buffer solution of pH 3.0, pH 7.0, and pH 8.0 was 77.8 hr, 6.54 hr and 0.72 hr, respectively, demonstrating instability in alkaline solution. The half-life in acid condition was not significantly different by temperature change, however, that in neutral or alkaline solution became shorter at $40^{\circ}C$. Hydrolysis study with a reference compound, diazinon, proved that the experimental method of the present study is reliable. Vapor pressure of captafol, $8.27{\times}10^{-9}$ torr at $20^{\circ}C$, was calculated from the equation, log P=6.94-(4401.6/T) plotted on the experiment results under different temperature conditions, 40, 50, and $60^{\circ}C$. pressure of captafol, the contamination of captafol would not happen easily in environment by vaporization. High Kow value of 1,523 was observed and this might result in bioconcentration through food chain when captafol was exposed. However, affecting human health through aquatic bioaccumulation is not likely to occur due to its rapid hydrolysis in the environment.

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Malignant Gastrointestinal Stromal Tumor of Esophagus - A case report - (식도의 악성 위장관 간질종양 - 1례 보고 -)

  • Kang, Shin-Kwang;Won, Tae-Hee;Ku, Kwan-Woo;Yoon, Soo-Young;Yu, Jae-Hyun;Na, Myung-Hoon;Lim, Seung-Pyung;Lee, Young
    • Journal of Chest Surgery
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    • v.36 no.2
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    • pp.109-112
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    • 2003
  • Stromal tumors of the gastrointestinal tract, especially of the esophagus, are rare. We had a case of malignant gastrointestinal stromal tumor(GIST) of the esophagus. A 46 years old woman was admitted for abnormal mass shadow in the chest radiograph. The mass was originated from the lower thoracic esophagus, and compressed the right lower pulmonary vein and the inferior vena cava. We removed the tumor externally without injuring of the esophageal mucosa via right posterolateral thoracotomy. The tumor was positive for CD 34 and CD 117, and diagnosed malignant CIST of the esophagus.

Immunohistochemical Analysis of the Bullae in Patients with Primary Spontaneous Pneumothorax (원발성 기흉환자 폐기포의 면역조직화학적 분석)

  • 김광호;윤용한;김정택;백완기;김현태;김영삼;손국희;한혜승;박광원
    • Journal of Chest Surgery
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    • v.36 no.2
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    • pp.86-90
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    • 2003
  • Bulla is an air-filled space within the lung parenchyma resulting from deterioration of the alveolar tissue. Molecular mechanism of the formation of the bulla is not well described. Fibroblast growth factor(FGF)-7, bone morphogenetic protein(BMP) receptor, and transforming growth factor(TGF)-$\beta$ receptor are known to have a stimulatory or inhibitory role in the lung formation. We investigated to see if these growth factor or cytokine receptors are involved in the bulla formation by immunohistochemical staining of bullous lung tissues from patients with primary spontaneous pneumothorax. Material and Method: Bullous lung tissues were obtained from 31 patients with primary spontaneous pneumothorax, including 30 males and 1 female from 15 to 39 years old. The bullous tissues were obtained by video-thoracoscopic surgery and/or mini-thoracotomy and fixed in formalin. Blocks of the specimens were embedded with paraffin and cut into 5-6 ${\mu}{\textrm}{m}$ thick slices. The sections were deparaffinized and hydrated and then incubated with primary antibodies against FGF-7, BMP-RII, or TGF-RII. Result: Of the 31 patients, 24 were TGF-RII positive including 18 strong and 6 weak positives. Observation with high magnification showed that strong immunostaining was detected in the boundary region between bullous and normal lung tissues. In contrast, all of the sections were negative with FGF-7 or BMP-RII antibodies. Conclusion: These results suggest that overexpression of TGF- P RII may be involved in the formation of bulla, although further molecular studies are needed to find out more detailed molecular mechanisms.

The Global String Table based Encapsulation Method of XML Metadata for Smart TV (스마트 TV를 위한 전역 문자열 테이블 기반의 효율적인 XML 메타데이터 캡슐화 구조)

  • Oh, Bong-Jin
    • Proceedings of the Korean Information Science Society Conference
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    • 2012.06d
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    • pp.351-353
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    • 2012
  • 최근에 XML은 가독성과 확장성이란 장점 때문에 IPTV나 스마트 TV에서 서비스나 콘텐츠 정보 표현 및 검색을 위한 기술로 많이 사용되고 있다. 특히 TV-Anytime에서 정의한 스키마나 전송 프로토콜을 기본 규격으로 채택하고 필요한 기능을 수용하기 위하여 규격을 확장하는 경향을 보이고 있다. 그러한 장점에도 불구하고 XML은 텍스트 기반으로 정보를 표현함으로써 정보의 양이 커진다는 문제가 존재하고 이를 위하여 다양한 인코딩 방식이 제공되고 있다. 그러나 전송과정에서 문서를 독립된 조각으로 단편화하여 블록단위로 캡슐화하는 과정을 거치면서 인코딩 효율이 급격하게 떨어지게 되는 문제가 발생한다. 본 논문에서는 XML 문서를 캡슐화하는 과정에서 단편화를 통해 감소되는 인코딩 효율을 보완할 수 있는 블록 단위의 문자열 테이블 방식을 제안하고 실험을 통한 성능 분석을 제공하였다.

Grid Voltage and Frequency Control Algorithm using Smart Inverter (스마트 인버터를 이용한 계통 전압 및 주파수 제어 알고리즘)

  • Park, Hwa-Pyeong;Chae, Suyong;Kang, Moses;Bae, Kuk-Yeol;Baek, Jongbok
    • Proceedings of the KIPE Conference
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    • 2020.08a
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    • pp.338-339
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    • 2020
  • 화력 발전에 의한 전력 생산은 환경오염으로 이어지고 이를 극복하기 위해 태양광 발전 혹은 풍력발전과 같은 신재생에너지원을 이용한 전력 생산이 꾸준히 증가하고 있다. 하지만 신재생에너지는 불규칙적인 전력을 생산할 뿐만 아니라 전력 계통의 도선 및 부하의 임피던스에 의해 계통의 전압 및 주파수가 변동한다. 이러한 문제를 극복하기 위해 계통 연계형 스마트 인버터를 사용하여 신재생에너지를 사용함과 동시에 계통의 안전성을 높일 수 있다. 본 논문은 ESS를 사용한 계통 연계형 스마트 인버터의 Voltage-Watt, Voltage-Var 제어 및 Frequency-Watt 제어를 통해 신재생에너지에 의해 발생하는 계통의 문제를 해결하는 제어 알고리즘을 제안한다.

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About the Post-Cinematic Characteristics and Desire Shown in a Film (영화 <파란만장>에 나타난 욕망과 포스트시네마적인 특성에 대하여)

  • Son, Seong-Woo
    • Journal of Korea Entertainment Industry Association
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    • v.13 no.3
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    • pp.121-129
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    • 2019
  • This study aims to focus on the text analysis, production methods of text, and reproduction of production methods, based on a film (2010) taken by mobile devices. As a digital film in which the objects and images have no characteristics of index, this work has the post-cinematic attributes in the aspect of consumers' recipience. This thesis paid attention to the interactions between essential change and production/consumption throughout the whole film culture in the receptive aspect. Just as the main character is a mediator-shaman in the film, this film works as a mediating position of cinematic possibility. In this film, there are different kinds of mediation such as mediation of shaman inside the text, mediation of film in the relationship between text and consumers, and consumers' instrumental desire for others'tool outside the text. Outside the text, this relevant film stimulates the imitation desire of consumer subjects as others. In other words, this is connected to the desire of consumers who aim to create a digital film through mobile devices as an author. This is connected to Simondon's thinking in which such technical objects not only generate new relationships, but also become a revolutionary seed that newly collectivizes human society.

The Effects of the RFID System for Eco-Agricultural Products on Trust and Behavior Intention: Focusing on an Expanded Technology Acceptance Model (친환경농산물 RFID 시스템이 신뢰 및 행동의도에 미치는 영향 : 확장된 기술수용모델(TAM)을 중심으로)

  • Choi, Won-Sik;Kim, Moon-Myoung;Lee, Soo-Bum
    • Culinary science and hospitality research
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    • v.19 no.1
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    • pp.85-102
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    • 2013
  • The purpose of this study is to examine the effect relation of the external variables of the RFID for eco-agricultural products, that of the external variables on TAM approachableness and usefulness, that of TAM approachableness on usefulness, that of TAM as approachableness and usefulness on trust and behavior intention, and the effect of trust on the behavior intention. The subjects of the actual analysis are the ordinary consumers aged 20 and over living in Seoul and Gyeong-gi Province and have the experience of purchasing eco-agricultural products. Total 300 copies of questionnaire were distributed for 14 days from September 24, 2012 until October 7, 2012, and total 278(92.7%) copies of survey materials were used for the final statistical analysis data except some found too strong unequal distribution of the response value or the value unknown at present. In the analysis results of this study, by examining the effects of the external variables of the RFID for eco-agricultural products on TAM's accessibility and usefulness and verifying the causal relationship between TAM's accessibility and consumers' trust and behavioral intent, this study has a sufficient value as an initial study on the RFID for eco-agricultural products. Thus, the results of this in-depth study show that producers and distributors maintaining and providing with safer eco-agricultural products food directly influence service companies' visible achievements.

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Study on Deliver the Core Value to the Regional Differentiation the Development of Co-Branded (지역적 차별화로 핵심가치를 전달하는 공동브랜드 개발에 관한 연구)

  • Kim, Jin-Young
    • Proceedings of the KAIS Fall Conference
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    • 2012.05a
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    • pp.108-111
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    • 2012
  • 본 연구는 지방의 공동브랜드가 난립하고 있는 실정에서 보령머드의 차별성을 살리고, 원래 가지고 있던 고유성을 부각시켜서 시각적으로 이미지를 정립한 과정을 살펴보고자 한다. 공동브랜드의 가치를 높일 수 있도록 제품 이미지에 부합하고 소비자의 요구에 대응할 수 있는 디자인 방안이 제시되어야 한다. 그러나 현 시점에서 많은 공동브랜드가 유사성과 몰개성적인 난립으로 지역생산자에게 만족스러운 결과를 주지 못하는 부분이 크다. 보령머드는 이러한 점을 인식하고 보령머드의 현재 가치를 유지하면서 미래가치를 높일 수 있는 아이덴티티인 머드반지 개발과 적용을 브랜드 관리 차원에서 순차적으로 진행하고 있다. 세계인을 향한 보령머드의 약속을 상징하는 머드반지는 이미지 전달자인 보령과 이미지 수용자인 소비자 사이에 이러한 시각요소를 전달하고 있다.

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A Study on the Effect of Alleolopathy of Vitex negundo var. incisa Leaves Extracts (좀목형 엽 추출물의 Allelopathy에 관한 연구)

  • 서병수;문성필;손정훈
    • Korean Journal of Environment and Ecology
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    • v.15 no.2
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    • pp.173-185
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    • 2001
  • 마편초과의 좀목형 엽에 함유된 물질의 allelopathy 효과를 구명하기 위해 수용성 엽 추출액, 메탄올 엽 추출액, 엽 분말과 토양과의 혼화된 pot에 각각 상치, 이탈이란라이그라스, 개솔새, 억새 종자를 발아실험하여 발아억제물질을 분석한 결과는다음과 같다. 1. 좀목형 엽 분말을 증류수에 각각 24, 48, 72 시간 침지 후 추출물에 상치, 이탈리안라이그라스, 개솔개, 억새 종자를 파종한 후의 발아율은 각 처리구마다 대조구마다 높은 발아억제를 보였고, 48시간 침지시에는 각각 26.9%, 58.8%, 6.6%, 22.2%의 발아율을 보여 강한 발아억제현상르 보였다. 2. 좀목형 엽 분말을 메탄올 75%에 24, 48시간 침지 후 추출물에 이탈리아라이그사스, 개솔새, 억새 종자를 파종한 후의 발아율은 48시간 추출액때 각각 33.3%, 15.4%, 7.7%를 보여 48시간 수용성 추출액과 24시간 메탄올 추출액보다 강한 발아억제효과가 있었다. 3. 좀목형 엽 분말과 Vermiculite를 1: 99.5: 95, 10:90, 20:80(w/w)으로 구분한 pot에 공시수종을 파종한 결과 엽 분말의 비율이 높을수록 발아억제효과가 컸으며, 엽 분말이 20%인 경우 발아된 부분의 건중량의 비율은 실험구와 대조구간에 비교한 발아율의 비율보다 훨씬 낮아 생장억제효과가 있는 것으로 나타났다. 4. Column chromatography의 TLC를 이용하여 최종 7 fraction을 찾고 생물검정 결과, 5, 6번 fraction에 강한 활성을 나타냈다. 5. UV 와 IR분광분석 결과 UV 분광분석은 256 nm과 336nm에서 흡수 최대를 나타내었으며, 이들은 시르시트시약을 사용하여 검토한 결과 7위에 에테르 결합한 전형적인 플라본류로 추정되었고, IR 분광분석 결과 지방족에 에테르결합이 존재하는 것으로 생각되었다. 6. Py-GC-MS 분석으로부터 5, 6 fraction의 경우 플라본류에 1개의 당이 결합한 배당체 구조이고 B환의 경우 1개 또는 2개 이상의 페놀성 수산기의 존재가 예상되었다.

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