• Title/Summary/Keyword: 수소 함량

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실리콘고무계 및 에폭시수지계 차폐재의 방사선 영향에 관한 연구

  • 조수행;김익수;신영준;도재범;노성기
    • Proceedings of the Korean Nuclear Society Conference
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    • 1997.05b
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    • pp.231-236
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    • 1997
  • 방사성물질의 수송 및 저장용기 등에 사용되는 실리콘고무계 및 수소 첨가된 비스페놀-A형 에폭시수지계 중성자 차폐재들의 인장강도, 압축강도, 비중, 무게, 수소함량 등에 방사선이 미치는 영향을 검토하였다. 방사선 조사선량의 증가에 따라 실리콘고무계 중성자 차폐재(KNS-101 및 102)들의 인장강도, 압축강도, 비중 등이 증가하는 경향을 나타내었으며, 차폐재의 무게는 거의 변화가 없었으나, 수소함량은 약간 감소하는 경향을 나타내었다. 또한 에폭시수지계 중성자 차폐재(KNS-201 및 202)들의 인장강도 및 압축강도는 0.1 MGy까지는 방사선 조사선량의 증가에 따라 증가하다가 0.1MGy 이상에서는 감소하는 경향을 나타내었으며, 조사선량의 증가에 따른 차폐재들의 비중, 무게 및 수소함량은 크게 변하지 않는 것으로 나타났다.

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Characterization of Arthrospira platensis Cultured in Nano-bubble Hydrogen Water (나노기포 수소수에서 배양한 Arthrospira platensis 특성 확인)

  • Seo, Ji-Hye;Choi, Soo-Jeong;Lee, Sang-Hoon;Lee, Jae-Hwa
    • Applied Chemistry for Engineering
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    • v.26 no.4
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    • pp.421-426
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    • 2015
  • Arthrospira platensis (A. platensis) has been used in various fields including dietary supplements as it contains a high protein content and large amounts of unsaturated fatty acids. In addition, it has some pigments such as phycocyanin, myxoxanthophyll and zeaxanthin and thus has been used as a food additive and antioxidant substance. Nano-bubble hydrogen is to dissolve more than the saturation solubility in water by injecting the hydrogen gas in the nano-bubble hydrogen water. The nano-bubbles are known to possess higher antioxidant properties in addition to anticancer effects. In this paper, Arthrospira platensis was cultured in both a normal medium with distilled water and nano-bubble hydrogen water medium and their properties were compared. The cell growth and the content of chlorophyll and carotenoid in the nano-bubble hydrogen water was 15% higher than that of the control. The level of phycocyanin in nano-bubble hydrogen water was also 7% higher than that of the control. However, there were little differences in the lipid content between the nano-bubble and control. To determine the content of the antioxidants, the level of flavonoid and polyphenol were measured. The level of flavonoid in nano-bubble hydrogen water was found to be more than 70% increased when comparing to that of the control, while the level of polyphenol was similar to each other.

Effect of Nano Bubble Oxygen and Hydrogen Water on Microalgae (나노기포 산소수 및 수소수가 미세조류 배양에 미치는 영향)

  • Choi, Soo-Jeong;Kim, Young-Hwa;Jung, In-Ha;Lee, Jae-Hwa
    • Applied Chemistry for Engineering
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    • v.25 no.3
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    • pp.324-329
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    • 2014
  • Microalgae Nannochloropsis oculata (N. oculta) and Chlorella vulgaris (C. vulgaris) are important sources for biodisel because of the high content of neutral lipids. Stable nano bubble is maintained for a long time and therefore it is possible for use in biotechnology. In this study, effects of nano bubble oxygen or hydrogen water on the microalgae growth were characterized. The cell growth in nano bubble water was similar to that of control, and the total lipid content was rather low. But, chlorophyll content of N. oculata grown in nanno bubble oxygen and hydrogen water increased 54% and 30%, and increased 59%, 39% in C. vulgaris. Carotenoid content also increased 21%, 25% in N. oculata and 49%, 29% in C. vulgaris grown in nano bubble oxygen and hydrogen water. From these results, nano bubble water seems to enhance the photosynthetic capacity of microalgae.

Analysis of Parameters for the Off-Site Dose Calculation Due to HTO, oBT, and Radioactive Carbon Ingestion (국내 원자력발전소 주변 삼중수소 및 $^14C$ 섭취선량 평가 경로인자 분석)

  • 이갑복;정양근;방선영;엄희문
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2004.06a
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    • pp.361-367
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    • 2004
  • For assessment of tritium and radiocarbon ingestion dose to off site individuals, water, hydrogen, and carbon content of main farm produce of Korea were investigated to replace the existing data in K-DOSE60, the Offsite Dose Calculation Manual (ODCM) of Korea Hydro & Nuclear Power Co. Ltd, (KHNP). Main items and weighting factors of farm produce were determined with the nationwide food intake data in 2001, 2002. Main farm produce were sampled around Kori, Wolsong, Ulchin, Younggwang nuclear power sites, Content of each produce was multiplied by weighting factor and summed up to make the weighted mean group value For grains, water, hydrogen, and carbon content was not much different from the existing data currently used in K-DOSE60, but root vegetables had 3.5 times more hydrogen, and leafy vegetables and fruits had 0.7∼1.3 times more or less water, hydrogen, and carbon contents than K-DOSE60.

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Performance and Emission Comparisons of a SI Engine Fueled by Syngas with Varying Hydrogen Content (합성가스 연료의 수소 함량 변화가 SI 엔진의 연소특성에 주는 영향)

  • Park, Seung-Hyun;Lee, Sun-Youp;Park, Cheol-Woong;Lee, Jang-Hee
    • Journal of the Korean Institute of Gas
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    • v.15 no.2
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    • pp.63-68
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    • 2011
  • As an effective utilization of biomass, organic wastes and coal, attention has been made to use syngas to a reciprocating engine to generate power. However, significant component variation of syngas depending upon origin and gasification conditions, and its lower heating value than that of LPG and CNG can create difficulties in stable engine operation. Thus it is necessary to address these issues in order to successfully develop power generation engines. As a primary step to resolve these problems, effects of H2 content variation in syngas on engine performance and emission characteristics were discussed in this study. The results show that as H2 % in syngas increases, more stable combustion was achieved with retarded MBT spark timing and engine efficiency becomes maximum with syngas of 10% H2. In addition, NOx emission increased while THC emission decreased as H2 % rises in the syngas.

Tritium concentration in rain with seasonal variation (계절에 따른 강우중 삼중수소 함량변화)

  • Yoon, Yoon-Yeol;Kim, Kyeong-Ja;Lee, Kil-Yong;Ko, Kyung-Seok
    • Analytical Science and Technology
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    • v.23 no.2
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    • pp.161-164
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    • 2010
  • The concentration of the tritium in precipitation from 2007 to 2009 has been analyzed for using tracer of groundwater study. The samples were collected monthly at Daejeon. The tritium concentrations in precipitation were ranged from 4.2 TU to 18.6 TU. The contents were higher at spring and fall season and lower at summer and winter season. The weighted average tritium content in precipitation was $7.85{\pm}0.46\;TU$.

A Study on the Deposition of DLC Films from $CH_4-CO_2$ Gas Mixture by PECVD Method ($CH_4-CO_2$혼합가스로부터 PECVD법에 의한 DLC 박막 증착에 관한 연구)

  • Jin, Eok-Yong
    • Korean Journal of Materials Research
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    • v.6 no.3
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    • pp.324-332
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    • 1996
  • DLC 박막을 RF 플라즈마 화학증착법(PECVD)을 이용하여 CH4와 CO2기체로부터 합성하였다. 증착압력, CH4와 CO2가스의 조성비, 바이어스 전압(-VB) 등의 증착조건 변화에 따른 증착속도는 증착층의 두께를 알파스텝으로 측정하여 결정하였으며, 박막의 구조 변화에 따른 증착속도는 증착층의 두께를 알파스텝으로 측정하여 결정하였으며, 박막의 구조 변화는 FTIR 분광분석을 이용하여 분석을 행하였다. 이 연구로부터 얻은 실험 결과는 다음과 같다: 1) 증착속도는 증착압력 및 바이어스 전압의 증가에 따라 증가한다. 2)바이어스 전압 300V이상에서, CO2량 증가는 순증착속도를 증가 시킨다. 3) 순수한 CH4가스를 사용할 경우에는 바이어스전압(-VB)이 증가함에 따라 박막내 수소의 함량과 sp3/sp2비는 감소하는 경향을 나타낸다. 4)증착압력이 증가함에 따라 박막내 수소함량은 증가하며, sp3/sp2비는 감소한다. 5)50mTorr의 증착압력에 증착시, CH4-+Co2 혼합가스에서 이산화탄소의 부피분율에 따라서는 박막내 수소함량은 감소하며, sp3/sp2비는 증가한다.

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Investigation of the corrosion properties of as extruded Mg5Sn(1-4)Zn ternary alloy (Mg5Sn(1-4)Zn 삼원계 압출재의 부식저항성 연구)

  • Ha, Heon-Yeong;Kim, Seong-Gyeong;Gang, Jeon-Yeon;Im, Chang-Dong;Yu, Bong-Seon
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2012.11a
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    • pp.15-15
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    • 2012
  • Mg(1-4)Zn 이원계 압출재 및 Mg5Sn(1-4)Zn 삼원계 압출재의 부식거동을 3.5 % NaCl 용액에서 다양한 전기화학기법을 이용하여 평가하였다. 이원계 합금에 대한 연구결과, Zn 함량 증가에 따라 Mg 모재의 부동태화가 촉진되었고 동시에 수소발생속도가 증가하였으며 그 결과 부식전위의 상승이 관찰되었다. 그러나 Zn 함량 증가에 따른 부동태화 효과보다 수소발생 증가 효과가 우세하므로 결과적으로 Zn 함량 증가에 따라 부식속도는 증가하였다. Mg5Sn(1-4)Zn 삼원계 합금에 대한 부식시험 결과, Mg5Sn2Zn 합금이 가장 낮은 부식속도 및 우수한 부동태화를 나타내었으며 이는 합금원소 Sn의 수소발생속도 감소효과와 합금원소 Zn의 부동태화 효과의 상호작용에 의한 것으로 사료된다.

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Effect of Additive Gas on the Bonding Structure of a-C:H Films Deposited by rf PECVD (rf PECVD법으로 증착된 a-C:H 박막의 결합구조에 미치는 보조가스의 영향)

  • Song, Jae-Jin;Kim, Seong-Jin
    • Korean Journal of Materials Research
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    • v.9 no.11
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    • pp.1088-1094
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    • 1999
  • 본 연구에서는 rf PECVD(13.56MHz)법을 이용하여 $CH_4$가스에 소량의 보조가스($O_2$$N_2$)를 혼합하여 a-C:H 박막을 얻었다. 이렇게 얻어진 박막의 증착속도는 rf power 증가에 따라서 증가하다가 200W에서는 다시 감소하였으며, 산소와 질소가스의 유량이 증가함에 따라 감소하였다. FT-IR분석으로 계산된 박막내의 수소함량은 rf power 증가와 산소 및 질소첨가량의 증가에 따라 감소하였다. 산소가스 첨가 시에는 C=O 결합이 생성되며, 질소가스 첨가 시에는 C=N 결합이 생성됨을 FT-IR 분석을 통하여 알 수 있었다. 이와 같이 산소와 질소를 보조가스로 첨가할 경우에 스퍼터링 효과로 박막내의 수소함량 감소와 더불어 a-C:H 박막의 구조 변화를 일으킬 수 있을 것으로 생각된다. Raman 분석결과 산소와 질소를 첨가함에 따라서 I(sub)D/I(sub)G비가 증가하였고, D line과 G line의 위치가 높은 파수 쪽으로 이동하였으며, D line의 폭은 넓어지는 반면에 G line의 폭은 감소됨을 보였다. 이것은 산소와 질소의 첨가로 박막내의 수소함량 감소, 결합각의 disorder 감소 및 micro-crystallite 흑연의 형성에 의한 것이라고 판단된다.

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Study of the hydrogen concentration of SiNx film by Fourier transform infrared spectroscopy (Fourier transform infrared spectroscopy를 이용한 SiNx박막의 수소농도 연구)

  • Lee, Seok-Ryoul;Choi, Jae-Ha;Jhe, Ji-Hong;Lee, Lim-Soo;Ahn, Byung-Chul
    • Journal of the Korean Vacuum Society
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    • v.17 no.3
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    • pp.215-219
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    • 2008
  • The bonding structure and composition of silicon nitride (SiNx) films were investigated by using Fourier transform infrared spectroscopy (FT-IR). SiNx films were deposited on Si substrate at $340^{\circ}C$ using a conventional PECVD system. The compositions of Si and N in SiNx films were confirmed by using Rutherford backscattering spectroscopy (RBS) and photoluminescence (PL) analysis. The surface morphology of SiNx films was also analyzed by using atomic force microscopy (AFM). It was found that the contents of NH(at. %) is the reverse related with those of SiH corresponding to the result of FT-IR. we conclude that a quantitative analysis on SiNx films can be possible through a precise detection of the contents of H in SiNx films with a FT-IR analysis only.