• Title/Summary/Keyword: 수소 재순환

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The Ejector Design and Test for 5kW Molten Carbonate Fuel Cell (5kW 용융탄산염 연료전지 이젝터 설계 및 시험)

  • Kim, Beom-Joo;Kim, Do-Hyung;Lee, Jung-Hyun;Jung, Sang-Chun;Lee, Sung-Yoon;Kang, Seung-Won;Lim, Hee-Chun
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.05a
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    • pp.53-56
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    • 2008
  • An ejector is a fluid machinery to be utilized for mixing fluids, maintaining vacuum, and transporting them. The Ejector is applied for a variety of industrial fields such as refrigerators and power plants. It is adopted to recycle anode off gas safely in 5kW Molten Carbonate Fuel Cell system of KEPRI(Korea Electric Power Research Institute). The ejector is placed at mixing point between the anode off gas and the cathode off gas or the fresh air. In this study, the entrainment ratio is measured according to the diametrical ratio of nozzle to throat. In addition, the performance curve of the ejector and the differential pressure in diffuser is observed.

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High Durability of Stack for Automobile (차량용 스택 고출력 내구성능)

  • Kim, Young-Min;Lee, Jong-Hyun;Yoon, Jong-Jin;Cho, Jang-Ho
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.557-560
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    • 2007
  • The durability of 80 kW class stack module was tested in hydrogen recirculation and non-recirculation systems with the condition of 300Amps (constant current mode) and hydrogen pulse purging (10 seconds close/0.8 seconds open). A localized membrane failure in the interfacial area between membrane and sub-gasket, carbon corrosion in cathode electrode, and Pt dissolution/extraction have been found through the post mortem analysis such as CV, Impedance, SEM, and so on. The main reason of these mechanisms will be discussed in this study.

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A Numerical Study of Diffusion Flames in Supersonic Flow (초음속 유동장 내의 확산 화염에 관한 수치 연구)

  • 김지호;윤영빈;정인석
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 1997.11a
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    • pp.17-17
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    • 1997
  • 극초음속 여객기와 군사용 항공기에 대한 수요가 증가함에 따라서 새로운 개념의 다양한 추진기관이 연구가 진행되고 개발되어 왔다. 초음속 항공기의 속도 영역은 마하 10-20 정도가 되는데 이 속도 한계를 극복하기 위하여 초음속 연소 램제트 엔진(SCRamjet; Supersonic Combustion Ramjet)이 제안되었다. 스크램 제트를 개발하기 위해서는 연료와 산화제의 혼합 효율 문제, 화염의 안정화 문제, 벽면의 냉각에 관한 문제 등 몇 가지 기본적인 문제들을 해결해야 한다. Univ of Michigan에서 실험한 연소기를 모델로 본 연구에서는 연료와 공기의 혼합에 관한 수치 연구를 수행하였다. 다원 혼합기체에 관한 축대칭 Navier-Stokes 방정식을 지배 방정식을 이용하였고 비평형 화학반응식을 고려하였다. 공간 차분에는 유한 체적법을 이용하였다. 대류 플럭스 항은 Roe의 Upwind FDS 기법을 사용하여 차분하였고 점성항에는 중심 차분법을 이용하였다. 시간 적분법으로는 근사 자코비안과 LU분할 기법을 이용한 완전 내재적 방법이 쓰였다. 난류 모델로는 Mentor에 의해 제안된 2 방정식 k-$\varepsilon$/k-$\omega$ 혼합모델을 사용하였다. 유동장이 실험에서의 찍은 사진과 유사한 모습의 충격파 간섭을 수치 모사하였고 수소가 확산되는 모습과 함께 노즐 lip 주위의 재순환 영역에 대해서 살펴볼 수 있었다.

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The Ejector Design and Test for 5kW MCFC System (5kW 용융탄산염 연료전지(MCFC) 이젝터 설계 및 시험)

  • Kim, Beom-Joo;Kim, Do-Hyeong;Lee, Jung-Hyun;Lee, Sung-Yoon;Kim, Jin-Yoel;Kang, Seung-Won;Lim, Hee-Chun
    • Transactions of the Korean hydrogen and new energy society
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    • v.20 no.1
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    • pp.31-37
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    • 2009
  • An ejector is a machine utilized for mixing fluid, maintaining a vacuum, and transporting fluid. The Ejector enhances system efficiency, are easily operated, have a mechnically simple structure, and do not require a power supply. Because of these advantages, the ejector has been applied to a variety of industrial fields such as refrigerators, power plants and oil plants. In this work, an ejector was used to safely recycle anode tail gas in a 5 kW Molten Carbonate Fuel Cell system at KEPRI(Korea Electric Power Research Institute). In this system, the ejector is placed at mixing point between the anode tail gas and the cathode tail gas or the fresh air. Commercial ejectors are not designed for the actual operating conditions for our fuel cell system. A new ejector was therefore designed for use beyond conventional operating limits. In this study, the entrainment ratio is measured according to the diametrical ratio of nozzle to throat in the designed ejector. This helps to define important criteria of ejectors for MCFC recycling.

Performance of a Molten Carbonate Fuel Cell With Direct Internal Reforming of Methanol (메탄올 내부개질형 용융탄산염 연료전지의 성능)

  • Ha, Myeong Ju;Yoon, Sung Pil;Han, Jonghee;Lim, Tae-Hoon;Kim, Woo Sik;Nam, Suk Woo
    • Clean Technology
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    • v.26 no.4
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    • pp.329-335
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    • 2020
  • Methanol synthesized from renewable hydrogen and captured CO2 has recently attracted great interest as a sustainable energy carrier for large-scale renewable energy storage. In this study, molten carbonate fuel cell's performance was investigated with the direct conversion of methanol into syngas inside the anode chamber of the cell. The internal reforming of methanol may significantly improve system efficiency since the heat generated from the electrochemical reaction can be used directly for the endothermic reforming reaction. The porous Ni-10 wt%Cr anode was sufficient for the methanol steam reforming reaction under the fuel cell operating condition. The direct supply of methanol into the anode chamber resulted in somewhat lower cell performance, especially at high current density. Recycling of the product gas into the anode gas inlet significantly improved the cell performance. The analysis based on material balance revealed that, with increasing current density and gas recycling ratio, the methanol steam reforming reaction rate likewise increased. A methanol conversion more significant than 90% was achieved with gas recycling. The results showed the feasibility of electricity and syngas co-production using the molten carbonate fuel cell. Further research is needed to optimize the fuel cell operating conditions for simultaneous production of electricity and syngas, considering both material and energy balances in the fuel cell.

A Study on Characteristics of Wood Pellet Gasification in Two Stage Gasifier (Two Stage Gasifier에서의 우드펠릿 가스화 특성 연구)

  • Lee, Moon-Won;Choi, Sun-Yong;Kim, Lae-Hyun
    • Journal of Energy Engineering
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    • v.19 no.4
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    • pp.240-245
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    • 2010
  • In this study, characteristics of wood pellet gasification was studied using a Two Stage Gasifier which is consisted of pyrolysis reactor and ultra high temperature reformer. The average yields of $H_2$, $CH_4$, CO, $CO_2$ were 16.7, 11.3, 37.2, 26.6 L/mim, conversion rate from biomass to gas was 65% in pyrolysis reactor and gas yields in reformer were 55.4, 0.8, 120.8, 56.8 L/mim, respectively. The hydrogen flow rate from reformer is obtained 360.1 L/hr. The most of $CH_4$ was decomposed from 12.3 to 0.3 vol.% while $H_2$ is from 18.2 to 23.7 vol.% in reformer by methane dry reforming, Boudouard reaction, oxidation and/or steam reforming. The amount of $H_2O$ generated by hydration reaction from reformer was 1111.8 g, its accelerated conversion of $CH_4$ to other products. The conversion rate from $CH_4$ to other Compounds was 97.2%. Cold gas efficiency was 53.2%.

The Effects of EGR and Hydrogen Enriched Gas on Diesel HCCI Engine (디젤 예혼합 압축착화 엔진에서 EGR 및 수소농후가스의 영향)

  • Park, Cheol-Woong;Cho, Jun-Ho;Oh, Seung-Mook
    • Transactions of the Korean Society of Automotive Engineers
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    • v.19 no.1
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    • pp.1-8
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    • 2011
  • In recent years, there has been an interest in early-injection diesel engines as it has the potential of achieving a more homogeneous and leaner mixture close to TDC compared to standard diesel engine. The more homogeneous mixture may result in reduced NOx and soot emissions and higher efficiency in homogeneous charge compression ignition engines. While earlier studies have shown that a reduction in NOx emissions from HCCI engine is possible, there are some significant problems including the control of ignition timing and combustion rate. In order to investigate the effect of EGR and hydrogen enriched gas on combustion characteristics and emissions, an experiments with single cylinder CRDi engine were carried out concerning the formation of various premixed charge, which can achieved by early injection, EGR and hydrogen enriched gas. EGR was not effective to further reduce NOx and PM emissions. It was found that NOx emissions were decreased with an introduction of hydrogen enriched gas and an adequate diesel fuel amount.

Effects of Cooled EGR on Exhaust Emission Characteristics of DI DME Engine (대체에너지 DME를 사용하는 직접분사엔진의 배기특성에 미치는 Cooled EGR의 영향)

  • Pyo, Youngduk;Nam, Sanghoon;Kim, Gangchul;Kim, Youngkil;Lee, Yongjae
    • Transactions of the Korean hydrogen and new energy society
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    • v.14 no.2
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    • pp.138-145
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    • 2003
  • There are high expectations for DME(Dimethyl Ether) as a new alternative fuel for diesel engine. Compared with the conventional diesel engine, nearly zero soot emission and high thermal efficiency have been reported from DME fuelled CI engines. However, higher NOx emission is one of the disadvantages from DME Engines. In the present study, cooled EGR(Exhaust Gas Recirculation) was applied to DME engine modified from conventional Dl diesel engine, and effects of EGR were examined under various EGR temperature. Finally, it was concluded that the cooled EGR is an effective solution to reduce NOx emission from DME engine.

Simluation of PEM Fuel Cell with 2D Steady-state Model (2차원 정상상태 모델을 이용한 고분자전해질형 연료전지의 모사)

  • Chung, Hyunseok;Ha, Taejung;Kim, Hyowon;Han, Chonghun
    • Korean Chemical Engineering Research
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    • v.46 no.5
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    • pp.915-921
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    • 2008
  • In most PEM fuel cell research, effects of cell geometry, physical properties of component such as membrane, carbon cloth, catalyst, etc. and water transport phenomena are key issues. The scope of these research was limited to single cell and stack except BOP(Balance of plant) of fuel cell. The research fouced on the fuel cell system usually neglect to consider detailed transport phenomena in the cell. The research of the fuel cell system was interested in a system performance and system dynamics. In this paper, the effect of the anode recirculation is calculated using the 2D steady-state model. For this work, 2D steady-state modeling and experiments are performed. For convenience of modifying of model equation, not commercial pakage but the in-house algorithm was used in simulation. For an vehicle industry, the analysis of the anode recirculation system helps the optimization of operating condition of the fuel cell.

Effects of Pilot Injection on Low Temperature Diesel Combustion (파일럿 분사가 저온 디젤 연소에 미치는 영향)

  • Han, Sang-Wook;Bae, Choong-Sik
    • Transactions of the Korean Society of Automotive Engineers
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    • v.20 no.3
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    • pp.141-147
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    • 2012
  • A direct injection diesel engine with large amount of exhaust gas recirculation was used to investigate low temperature diesel combustion. Pilot injection strategy was adopted in low temperature diesel combustion to reduce high carbon monoxide and hydrocarbon emissions. Combustion characteristics and exhaust emissions of low temperature diesel combustion under different pilot injection timings, pilot injection quantities and injection pressures were analyzed. Retarding pilot injection timing, increasing pilot injection quantity and higher injection pressure advanced main combustion timing and increased peak heat release rate of main combustion. As a result of these strategies, carbon monoxide and hydrocarbon emissions were reduced. Soot emission was slightly increased with retarded pilot injection timing while the effect of pilot injection on nitrogen oxides emission was negligible under low combustion temperature condition. Spatial distribution of fuel from the spray targeting visualization was also investigated to provide more insight into the reason for the reduction in carbon monoxide and hydrocarbon emissions.