• Title/Summary/Keyword: 수소화염

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A Study on Synthesis of Carbon Nanomaterial as a Material for Eco-ship (친환경 선박용 재료인 탄소나노물질의 합성에 관한 연구)

  • Choi, Jae-Hyuk;Kim, Jae-Hyun;Shin, Woo-Jung;Choi, Jung-Sik;Ryu, Kyoung-Boo;Lee, Sang-Min;Park, Seol-Hyun;Lee, Joo-Hee;Lim, Tae-Woo
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.18 no.5
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    • pp.468-474
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    • 2012
  • In this study, experimental studies were performed for the carbon nanomaterial(CNM) which is catching on as a material for eco-ship. The opposed-flow methane flame was used as a heat source for synthesis of CNM. Ferrocene was used as a catalyst for the synthesis of CNM. These major parameters were $H_2$ mixing rate and sampling positions that synthesize CNMs in opposed-flow diffusion flames. The propensities of CNMs were experimentally determined using SEM and TEM images. The experimental result showed that the amount of CNTs was increased with increasing $H_2$ concentration. It can also be found that the optimal temperature in opposed-flow methane flame for synthesis of CNT was about 1500 K.

Liftoff Mechanisms in Hydrogen Turbulent Non-premixed Jet Flames (수소 난류확산화염에서의 부상 메커니즘에 대한 연구)

  • Oh, Jeong-Seog;Kim, Mun-Ki;Choi, Yeong-Il;Yoon, Young-Bin
    • Journal of the Korean Society of Combustion
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    • v.12 no.2
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    • pp.26-33
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    • 2007
  • To reveal the newly found liftoff height behavior of hydrogen jet, we have experimentally studied the stabilization mechanism of turbulent, lifted jet flames in a non-premixed condition. The objectives of the present research are to report the phenomenon of a liftoff height decreasing as increasing fuel velocity, to analyse the flame structure and behavior of the lifted jet, and to explain the mechanisms of flame stability in hydrogen turbulent non-premixed jet flames. The velocity of hydrogen was varied from 100 to 300m/s and a coaxial air velocity was fixed at 16m/s with a coflow air less than 0.1m/s. For the simultaneous measurement of velocity field and reaction zone, PIV and OH PLIF technique was used with two Nd:Yag lasers and CCD cameras. As results, it has been found that the stabilization of lifted hydrogen diffusion flames is related with a turbulent intensity, which means that combustion occurs at the point where the local flow velocity is balanced with the turbulent flame propagation velocity.

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A numerical analysis on the extinction of hydrogen-oxygen diffusion flames at high pressure (고압하에서 수소-산소 확산화염의 소염 특성에 관한 수치 해석)

  • Son, Chae-Hun;Kim, Jong-Su;Jeong, Seok-Ho;Lee, Su-Ryong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.21 no.9
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    • pp.1174-1184
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    • 1997
  • Extinction characteristics of pure hydrogen-oxygen diffusion flames, at high pressures in the neighborhood of the critical pressure of oxygen, is numerically studied by employing counterflow diffusion flame as a model flame let in turbulent flames in rocket engines. The numerical results show that extinction strain rate increases almost linearly with pressure up to 100 atm, which can be explained by comparison of the chain-branching-reaction rate with the recombination-reaction rate. Since contributions of the chain-branching reactions, two-body reactions, are found to be much greater than those of the recombination reactions, three-body reactions, extinction is controlled by two-body reactions, thereby resulting in the linearity of extinction strain rate to pressure. Therefore, it is found that the chemical kinetic behaviors don't change up to 100 atm. Consideration of the pressure fall-off reactions shows a slight increase in extinction strain rate, but does not modify its linearity to pressure. The reduced kinetic mechanisms, which were verified at low pressures, are found to be still valid at high pressures and show good qualitative agreement in prediction of extinction strain rates. Effect of real gas is negligible on chemical kinetic behaviors of the flames.

Numerical study on extinction and acoustic response of diluted hydrogen-air diffusion flames with detailed and reduced chemistry (상세 및 축소 반응 메커니즘을 이용한 희석된 수소-공기 확산화염의 소염과 음향파 응답 특성에 관한 수치해석)

  • Son, Chae-Hun;Jeong, Seok-Ho
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.21 no.11
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    • pp.1527-1537
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    • 1997
  • Extinction characteristics and acoustic response of hydrogen-air diffusion flames at various pressures are numerically studied by employing counterflow diffusion flame as a model flamelet in turbulent flames in combustion chambers. The numerical results show that extinction strain rate increases linearly with pressure and then decreases, and increases again at high pressures. Thus, flames are classified into three pressure regimes. Such nonmonotonic behavior is caused by the change in chemical kinetic behavior as pressure rises. The investigation of acoustic-pressure response in each regime, for better understanding of combustion instability, shows different characteristics depending on pressure. At low pressures, pressure-rise causes the increase in flame temperature and chain branching/recombination reaction rates, resulting in increased heat release. Therefore, amplification in pressure oscillation is predicted. Similar phenomena are predicted at high pressures. At moderate pressures, weak amplification is predicted since flame temperature and chain branching reaction rate decreases as pressure rises. This acoustic response can be predicted properly only with detailed chemistry or proper reduced chemistry.

Design of a Combustion Chamber for Studying the Combustion Characteristics of Counterflow Flames at Elevated Pressure (압력변화에 따른 대향류 화염 연소특성 연구를 위한 가압 연소실 설계)

  • AHN, YEONG JONG;KU, JAE WON;CHOI, SUN;KOO, JAYE;KWON, OH CHAE
    • Transactions of the Korean hydrogen and new energy society
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    • v.28 no.3
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    • pp.315-321
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    • 2017
  • A combustion chamber is designed and fabricated for studying the combustion characteristics of counterflow flames at elevated pressure and establishing the fundamental combustion database of counterflow flames. The combustion chamber design aims to allow the maximum operating pressure of 11 bar and be able to conduct flame visualization and the measurements of flame extinction limits, flame temperature and combustion emissions at elevated pressure. Preliminary tests for counterflow nonpremixed $CH_4-NH_3-N_2$/air flames at 1-3 bar have been conducted, and the results confirm the proper operation of the designed chamber.

Stability limits of premixed microflames at elevated temperatures (고온에서의 예혼합 초소형 화염의 연소안정한계 연구)

  • Kim, Ki-Baek;Lee, Kyoung-Ho;Hong, Young-Taek;Kwon, Oh-Chae
    • Transactions of the Korean hydrogen and new energy society
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    • v.17 no.2
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    • pp.158-165
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    • 2006
  • In order to provide the database for designing microcombustors, the combustion characteristics of premixed methane and propane air microflames at normal and elevated temperatures and atmospheric pressure generated on a microtube were studied experimentally and computationally. The stability limits of premixed microflames and the propensity of the microflames near the stability limits were experimentally determined, while the structure of the microflame at the fuel-leanest limit was obtained using a two-dimensional CFD simulation with a reduced kinetic mechanism. For all the microflames, the stability limits were observed only in the fuel-rich region. Results also show substantial extension of stability limits with elevated temperature that is realistic condition for micro fuel processing and significant fuel dilution immediately near the tube exit due to a low Peclet number times Lewis number effect.

Chemical Interaction in Downstream Flows of SNG/Air Symmetric Premixed Counterflow Flame (SNG/Air 예혼합 대향류 대칭화염의 후류 유동장에서 화학적 상호작용)

  • KANG, YEONSE;LEE, KEEMAN
    • Transactions of the Korean hydrogen and new energy society
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    • v.29 no.6
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    • pp.668-679
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    • 2018
  • Experimental and numerical data were compared through a counterflow burner for the characteristic of basic flame about SNG- C11. In order to use the numerical mechanism accurately, the validation was carried out at strain rate ($a_g=30$, $120s^{-1}$) and the UCSD model showed satisfactory results. The effective Lewis number of the extinction boundary, and the behavior of extinction for the symmetric flames of the SNG-C11, could be explained through the trend of $Le_V$, and the flame of the extinction condition was inspected by the major species, key radicals and the chemical reaction paths. The interactions phenomenon in the merged flames has chemical reaction path for producing $HO_2$ were generated at stagnation point. It can be expected the one of major factors in interaction phenomenon.

Numerical Study on the NH3/CH4 Symmetric Premixed Counterflow Flames - Part I Characteristics of Extinction Behavior (암모니아/메탄 예혼합 대향류 대칭화염에 관한 수치해석적 연구 - Part I 소화거동의 특성)

  • EUNSEO JIN;KEEMAN LEE
    • Transactions of the Korean hydrogen and new energy society
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    • v.34 no.1
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    • pp.47-58
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    • 2023
  • Experimental data conducted by Colson et al. and numerical data conducted in this study were compared through counterflow flames to understand of the characteristic of basic flame about mixture of ammonia/methane. In order to use the suitable numerical mechanism, the validation was performed using total four mechanisms and the Okafor's mechanism showed satisfactory experimental results. The extinction boundary of the stability map could be explained through the effective Lewis number and the trend of LeD. The extinction behavior of the flame was different under the lean and rich symmetric conditions and it was investigated by the major variables, global strain rate (ag) and mole fraction of ammonia (ΩNH3).

A Study on the Transition of Hydrogen-Air and LPG-Air Explosion to Fire (수소와 액화석유 가스의 공기혼합기의 폭발 후 화재로 전이 연구)

  • Oh Kyu-Hyung;Lee Sung-Eun;Rhie Kwang-Won
    • Journal of the Korean Society of Safety
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    • v.19 no.4 s.68
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    • pp.150-154
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    • 2004
  • Gas explosion characteristics of hydrogen and liquefied petroleum gas(LPG) were measured in 6L cylindrical vessel, and experiment for explosion to fire transition phenomena of the gases were carried out using the 270L vessel. Explosion characteristics were measured using the stain type pressure transducer and explosion to fire transition phenomena was analyzed with the hish-speed camera. Base on the experiment, it was found that explosion pressure was most high slightly above the stoichiometric concentration, and explosion pressure rise rate and flame propagation velocity were proportional to the combustion velocity. And we find that those kind of explosion characteristics affect the explosion-to-fire transition, in addition, explosion flame temperature, flame residence time, are important parameters in explosion-to-fire transition.