• Title/Summary/Keyword: 수소이온 농도

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Medium Constituents for in vitro Multiplication of Chinese Yam (Dioscorea opposita Thunb.) (둥근마(Dioscorea opposita Thunb.)의 기내증식을 위한 배지조건)

  • Jeong, Eun-Ah;Kwon, Soon-Tae
    • Korean Journal of Plant Resources
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    • v.24 no.2
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    • pp.208-213
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    • 2011
  • This study was carried out to determine the effect of medium solidity, salt strength, sugar and nitrogen sources, and pH levels on in vitro multiplication of pathogen-free yam (Dioscorea opposita Thunb.). Liquid medium was more effective in the growth of plant height, fresh weight, and formation of microbulb than the solid medium. Optimal condition for plant fresh weight, growth, and multiplication axillary bud was in 1MS salt strength with 60 $g{\cdot}L^{-1}$ sucrose and half strength of $KNO_3$. Optimal condition for microbulb formation was $\frac{1}{2}$ MS salt strength supplemented with glucose 60 $g{\cdot}L^{-1}$ and half strength of $KNO_3$. The number of leaves and nodes were sharply increased from 2 to 5 weeks, whereas plant fresh weight was steadily increased from 3 to 11 weeks after inoculation. Microbulbs were formed at 2 weeks after inoculation and continuously increased until 12 weeks.

Effect of External Factors on Diastase Activity in Water (각종 요인이 물속의 Diastase 활성에 미치는 영향)

  • Yoon, Bock-Sang;Hyun, Ho-Sup;Paik, Nam-Won
    • Journal of Preventive Medicine and Public Health
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    • v.7 no.1
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    • pp.107-113
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    • 1974
  • Many factors exert an influence on enzyme activity and thus on the rate of reactions that they catalyse. The most important of these factors are pH, temperature, substrate concentration, and the concentration of some inhibitors present. A solution of the enzyme diastase, which breaks down molecules of the polysaccharide starch to the disaccharide maltose by hydrolysis, was provided. Activity of this enzyme was measured by the rate at which starch was removed from the reaction mixture. These experiments were designed to study this reaction rate under varying conditions and the following results were obtained. 1. The range of optimum pH for this enzyme at room temperature was 4.0-7.0 and the optimum pH was 5.0. 2. The range of optimum temperatures for this enzyme at pH 7.0 was $30^{\circ}C-50^{\circ}C$ and the optimum temperature was $40^{\circ}C$. 3. The relationship between the enzyme activity and substrate concentration could be expressed by the Michaelis-Menten equation. The limiting velocity of this enzyme at room temperature and pH 7.0 was $415{\mu}g$ starch removed/ml of reaction mixture/min and $K_m$, Michaelis constant, was $343{\mu}g/ml$. 4. Inhibitors NaCl and $HgCl_2$ blocked this enzyme activity completely at 1% and 0.01% respectively.

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Degree of saturation of $(CaCO_3)$ in the East Sea (동해의 탄산칼슘$(CaCO_3)$ 포화도)

  • Kang, Dong-Jin;Kim, Kyung-Ryul;Lee, Kyung-Eun
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.6 no.4
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    • pp.234-241
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    • 2001
  • The degree of saturation of calcium carbonate in the East Sea was calculated from the data obtained from'99 expedition using R/V Roger Revelle. The calcium concentrations in seawaters were estimated from salinity data, and the carbonate ion concentrations were calculated from total alkalinity and pH data. The results suggest that the crossover from the supersaturation to undersaturation for calcium carbonate occur at the depth of approximately 200-400 m for calcite, and 100-300 m for aragonite. Compared to the Pacific and Atlantic oceans, these levels in the East Sea are shallow due to most likely lower temperature of sea water in this region.

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A Study on the Microflora of Gapcheon, Daejeon in Korea (갑천의 미소생물상에 관한 연구)

  • 심정기
    • Korean Journal of Environmental Biology
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    • v.20 no.4
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    • pp.347-354
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    • 2002
  • Near the Gapcheon, a new suburban city will be developed by the Ministry of Construction and Transportation, and a intracity highway will be constructed by Daejeon Metropolitan City. By these new plans, rapid disruption of environmental conditions near the Gapcheon will be anticipated. The new construction of the city and highway will raise a problem of environmental pollution and disruption of natural status of this area, and will have an adverse influence to environment of the Dunsan area and an industrial complex which are located at the downstream of the Gapcheon. This re-search was conducted on the Gapcheon area, Daejeon (Gasuwongyo to Wonchongyo) from August, 2001 to June, 2002 years. Microorganisms of Gapcheon are three forms, 17 varieties, 105 species, 58 geneva, 31 families, and totalled 125 taxa. And zooidal micro-organisms, one varieties, 16 species, 12 genera, eight families, and totalled 17 taxa. Hydrogen ion concentration of the stream is ranged from 7.10 to 9.98 with great variation, especially high below bridges of Gasuwongyo and Mannyeongyo. The clean water quality of the stream is still maintained very well due to dense distribution of diverse aqua-tic and swamp plants. Furthermore, species diversity of microorganisms in the stream does help to purify the quality of water, and to keep the health of the Gapcheon as natural. More environmentally controlled and continuous efforts to keep the Gapcheon in a natural status and to purify the quality of water should be made by Daejeon Metropolitan City Officials who ave now spending about 6G,5()0 million won for overall conservation plans of the stream (from 1999 to 2003 years).

Solubility of Hydrogen Sulfide and Methane in Ionic Liquids: 1-Ethy-3-methylimidazolium Trifluoromethanesulfonate and 1-Butyl-1-methylpyrrolidinium Trifluoromethanesulfonate (1-Ethyl-3-methylimidazolium trifluoromethanesulfonate와 1-Butyl-1-methylpyrrolidinium trifluoromethanesulfonate 이온성 액체에 대한 황화수소와 메탄의 용해도)

  • Lee, Byung-Chul
    • Korean Chemical Engineering Research
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    • v.54 no.2
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    • pp.213-222
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    • 2016
  • Solubility data of hydrogen sulfide ($H_2S$) and methane ($CH_4$) in two kinds of ionic liquids with the same anion: 1-ethyl-3-methylimidazolium trifluoromethanesulfonate ([emim][TfO]) and 1-butyl-1-methylpyrrolidinium trifluoromethanesulfonate ([bmpyr][TfO]) are presented at pressures up to about 30 MPa and at temperatures between 303 K and 343 K. The gas solubilities in ionic liquids were determined by measuring the bubble point pressures of the gas + ionic liquid mixtures with various compositions at different temperatures using a high-pressure equilibrium apparatus equipped with a variable-volume view cell. The $H_2S$ solubilities in ionic liquid increased with the increase of pressure and decreased with the increase of temperature. On the other hand, the $CH_4$ solubilities in ionic liquid increased significantly with the increase of pressure, but there was little effect of temperature on the $CH_4$ solubility. For the ionic liquds [emim][TfO] and [bmpyr][TfO] with the same anion, the solubility of $H_2S$ as a molality basis was substantially similar, regardless of the temperature and pressure conditions as a molar concentration basis. Comparing the solubilities of $H_2S$ and $CH_4$ in the ionic liquid [emim][TfO], the solubilities of $H_2S$ were much greater than those of $CH_4$. For the same type of ionic liquid, the solubility data of $H_2S$ and $CH_4$ obtained in this study were compared to the solubility data of $CO_2$ from the literature. When compared at the same pressure and temperature conditions, the $CO_2$ solubility was in between the solubility of $H_2S$ and $CH_4$.

Role of Electrode Reaction of Electrolyte in Electrokinetic-Fenton Process for Phenanthrene Removal (동전기-펜턴 공정에서 전해질의 전극반응이 처리효율에 미치는 영향)

  • Park Ji-Yeon;Kim Sang-Joon;Lee You-Jin;Yang Ji-Won
    • Journal of Soil and Groundwater Environment
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    • v.11 no.1
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    • pp.7-13
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    • 2006
  • The effects of electrolytes were investigated on the removal efficiency when several different electrolytes were used to change the electrode reaction in an electrokinetic (EK)-Fenton process to remediate phenanthrene-contaminated soil. Electrical potential gradient decreased initially due to the ion entrance into soil and then increased due to the ion extraction from soil under the electric field. Accumulated electroosmotic flow was $NaCl>KH_2PO_4>MgSO_4$ at the same concentration because the ionic strength of $MgSO_4$ was the highest and $Mg(OH)_2$ formed near the cathode reservoir plugged up soil pore to inhibit water flow. When hydrogen peroxide was contained in electrolyte solution, removal efficiency increased by Fenton reaction. When NaCl was used as an electrolyte compound, chlorine ($Cl_2$) was generated at the anode and dissolved to form hypochlorous acid (HClO), which increased phenanthrene removal. Therefore, the electrode reaction of electrolyte in the anode reservoir as well as its transport into soil should be considered to improve removal efficiency of EK-Fenton process.

A Study on the Optimum Operating Conditions and Effects of Wastewater Characteristics in Electrochemical Nitrogen Removal Process (질소 제거를 위한 전기화학적 처리 공정의 최적 운전조건 및 폐수 성상에 따른 영향에 관한 연구)

  • Sim, Joo-Hyun;Kang, Se-Han;Seo, Hyung-Joon;Song, Su-Sung
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.1
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    • pp.29-34
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    • 2009
  • This study was performed under four operational conditions for nitrogen removal in metal finishing wastewater. The conditions include electrode gap, reducing agent, the recycling of treated wastewater in 1st step and the simultaneous treatment of nitrate and other materials. Result showed that the removal efficiency of $NO_3{^-}-N$ was highest at the electrode gap of 10 mm. As the electrode gap was shorter than 10 mm, the removal efficiency of $NO_3{^-}-N$ decreased due to increasing in concentration polarization on electrode. And, in case that the electrode gap was longer than 10 mm, the removal efficiency of $NO_3{^-}-N$ increased with an increase in energy consumption. Because hydrogen ions are consumed when nitrate is reduced, reducing reaction of nitrate was effected more in acid solution. As 1.2 excess amount of zinc was injected, the removal efficiency of $NO_3{^-}-N$ increased due to increasing in amount of reaction with nitrate. As the effluent from 1st step in the reactor was recycled into the 1st step, the removal efficiency of $NO_3{^-}-N$ increased. Because the zinc were detached from the cathode and concentration-polarization was decreased due to formation of turbulence in the reactor. The presence of $NH_4{^+}-N$ did not affect the removal efficiency of $NO_3{^-}-N$ but the addition of heavy metal decreased the removal efficiency of $NO_3{^-}-N$. As chlorine is enough in wastewater, the simultaneous treatment of nitrate and ammonia nitrogen may be possible. The problem that heavy metal decrease the removal efficiency of $NO_3{^-}-N$ may be solved by increasing current density or using front step of electrochemical process for heavy metal removal.

Antimicrobial Activity and Stability of Tetrasodium Pyrophosphate Peroxidate (과산화피로인산나트륨의 항균성 및 안정성)

  • Lee, Jong-Hoon;Kim, Il-Hwan
    • Korean Journal of Food Science and Technology
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    • v.30 no.5
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    • pp.1040-1044
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    • 1998
  • Tetrasodium pyrophosphate peroxidate can be crystallized as a hydrogen-peroxide-bound salt from the solution of tetrasodium pyrophosphate and hydrogen peroxide. The antimicrobial activity and stability of the compound were tested for the use as a food preservative. It showed antimicrobial activities against several food spoilage microorganisms at the concentration of 0.1% (w/v), and was stable for 80 days in room temperature as a form of 70% hydrogen-peroxide-bound tetrasodium pyrophosphate peroxidate. It was also stable at the boiling temperature but decomposed significantly in the presence of metal ions. The compound can be an effective food preservative at the 0.2% (w/v) concentration, which contains 0.03% (v/v) hydrogen peroxide. The compound could be commercialized if the application area and usage direction as well as the removal method of hydrogen peroxide were developed.

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Recovery of Alumina from Sodium Hydroxide Leaching Solution by Precipitation with Hydrogen Peroxide (수산화나트륨 침출용액으로부터 과산화수소에 의한 침전으로 알루미나 회수)

  • Nguyen, Thi Thuy Nhi;Lee, Man Seung
    • Resources Recycling
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    • v.28 no.4
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    • pp.23-29
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    • 2019
  • In order to recover pure alumina from balck dross, precipiatation experiments were done to the NaOH leaching solution of mechanically activated black dross. In this work, hydrogen peroxide was added to the synthic solution as a precipitating agent. Among some variables, the concentration of $H_2O_2$ and the volume ratio of $H_2O_2$ to solution showed a remarkable effect on the precipitation of aluminum hydroxide. At the optimum conditions, most of the aluminate was precipitated. Calcination of the aluminum hydroxide at $1200^{\circ}C$ led to the formation of ${\theta}$ and ${\alpha}$-alumina. The charactistics of the synthesized activated alumina was measured by XRD and EDS. The average particles size of the alumina was $3.73{\mu}m$.

A Modified Back-Titration Method to Measure Soil Titration Curves Minimizing Exchange Acidity and Dilution Effects (토양 적정곡선 측정을 위하여 교환산도와 희석효과를 최소화한 수정역적정법 제안)

  • Jozefaciuk, G.;Shin, Jae Sung
    • Korean Journal of Soil Science and Fertilizer
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    • v.29 no.4
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    • pp.321-327
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    • 1996
  • A back titration method was suggested to determine the exchangeable acidity of soil originated from exchangeable aluminum and adsorbed hydrogen ion in relation to minimizing its titration error. In this method. soils are treated by neutral salt solution whose concentration is the same as soil solution suspended by distilled water. And then. its pH is adjusted at 3, using 1 N HCl solution and back-titrated by 0.1 N NaOH solution containing 1 N NaCl. The results of the suggested back-titration showed the possibility of practical application with linear relationship to that of standard method.

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