• Journal of Auto-vehicle Safety Association
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• 제6권2호
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• pp.72-77
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• 2014

In the ongoing debates over the need to identify new sources of energy and to reduce the emissions of greenhouse gases. Hydrogen has emerged as one of the most promising alternatives due to its emissions from the vehicle being virtually zero. The governments have identified the development of regulations and standards as one of the key requirements for commercialization of hydrogen-fueled vehicles. Regulations and standards will helpful in overcoming technological barriers to commercialization. Developments of a technique for safety assessment of Hydrogen Fuel Cell Vehicle(HFCV) includes four tasks, research for regulation system and policy, hydrogen safety, vehicle operation safety and protection against high-voltage. The objective is to establish a technique for safety assessment and amend safety standards for HFCV and consequently reflect research results to vehicle management policy. We devised safety standards and evaluation techniques with regard to high-pressure gas and high voltage of hydrogen fuel cell vehicle. Korean Motor Vehicle Safety Standards(KMVSS) for HFCV was amended to June 10, 2014. including the results of the safety assessment technology for high-voltage and hydrogen characteristics.

• Resources Recycling
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• 제7권3호
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• pp.42-51
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• 1998

Hydrogen in atmosphere can easily dissolve in melt of light metal alloys. Increasing demand for recycling of light metal a alloys has, therefore, focused attention on the removal of hydrogen gas, and alloy addition in melt has become an imporLant r refining process. For this purpose behaviors of mixing and hydrogen degassing in impeller agitated refming vessel with/without barnes were investigated. Flow patterns, mixing time behavior and kinetics of degassing in various agitating conditions were analysed in watet model experiments. And, numerical analysis on turbulent flow pattern in impeller agitated vessels was performed.

• Nuclear Engineering and Technology
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• 제17권1호
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• pp.8-15
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• 1985

A model for thermal interactions of debris/water with gas flow from within and below debris bed was presented for severe accident analysis in LWR. The consumption of steam, production of hydrogen in the debris bed, generation of gases from below debris bed and generation of chemical heat are included in the conservation equations. The model has been incorporated in the MARCH code to estimate the gas production due to both metal/oxidation and hot debris/concrete interaction. The results indicate that the hydrogen source can potentially give a significant impact on the containment pressure transient and the conductive heat loss to concrete and the convective gas cooling in the debris bed have a small effect on the debris bed coolability. However, the reheating and melting of the debris particles could be delayed by the interaction of debris with concrete.

• Journal of the Korean Society for Marine Environment & Energy
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• 제14권3호
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• pp.205-211
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• 2011

On board comparison of pH and total alkalinity measurement in seawater was carried out during the JES expedition on R/V Roger Revelle in the East Sea using 550 real seawater samples from the surface to the bottom. Spectrophotometry and potentiometry without liquid junction were compared for pH measurement. The pH values of two methods are generally in a good agreement. Spectrophotometry with a pipette provides higher value compare with the potentiometry in the deep layer, where pH values are lower. However, spectrophotometry without a pipette shows same values with potentiometry within their precision range. The pipetting procedure may remove of $CO_2$ in the sample, which causes increase of pH. Potentiometric titration methods using a closed-cell and an open-cell were compared for the total alkalinity measurement. Values from open cell method are smaller by about 5~10 ${\mu}mol\;kg^{-1}$ than those from closed cell method. This may be caused by the bubble formed in the closed cell during the experiment. Although any analytical method compared in this study for the pH or TA measurement can be applied, special attentions should be paid for satisfactory results.

• Transactions of the Korean hydrogen and new energy society
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• 제25권2호
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• pp.105-113
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• 2014

Performance tests on $Ni/Ce-ZrO_2/Al_2O_3$ catalysts with additives (MgO, $La_2O_3$) were investigated in the combined reforming processes (SCR, ATR, TRM) in order to produce hydrogen and carbon monoxide (it is called "syngas".). The catalyst characterization was conducted using the BET surface analyzer, X-ray diffraction (XRD), SEM, TPR and TGA. The combined reforming process was developed to adjust the syngas ratio depending on the synthetic fuel (methanol, DME and GTL) manufacturing processes. Ni-based catalysts supported on alumina has been generally recommended as a combined reforming reaction catalyst. It was found that both free NiO and complexed NiO species were responsible for the catalytic activity in the combined reforming of methane conversion, and the $Ce-ZrO_2$ binary support employed had improved the oxygen storage capacity and thermal stability. The additives, MgO and $La_2O_3$, also seemed to play an important role to prevent the formation of the carbon deposition over the catalysts. The experimental results were compared with the equilibrium data using a commercial simulation tool (PRO/II).

• Journal of the Korean Institute of Gas
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• 제16권6호
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• pp.87-101
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• 2012

In gas industries, the potential risks of serious accidents have been increased due to high technology application and process complexities. Especially, in case of gas-related accidents, the extent of demage is out of control since gas plants handle and produce combustible, flammable, explosive and toxic materials in large amounts. The characteristics of this kind of disaster is that accident frequency is low, while the impact of damage is high, extending to the neighboring residents, environment and related industries as well as employees involved. The hydrogen gases treated important things and it used the basic material of chemical plants and industries. Since 2000, this gas stood in the spotlight the substitution energy for reduction of the global warming in particular however it need to compress high pressure(more than 150 bar.g) and store by using the special cylinders due to their low molecular weight. And this gas led to many times the fire and explosion due to leak of it. To reduce these kinds of risks and accidents, it is necessary to improve the new safety management system through a risk management after technically evaluating potential hazards in this process. This study is to carry out the quantitative risk assesment for hydrogen filling plant which are very dangerous(fire and explosive) and using a basic materials of general industries. As a results of this risk assessment, identified the elements important for safety(EIS) and suggested the practical management tools and verified the reliability of this risk assessment model through case study of accident.

• Journal of Korean Society of Environmental Engineers
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• 제29권12호
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• pp.1371-1380
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• 2007

Study on the instability of waste plastic's thermal pyrolysis oil was carried out for the purpose of improving its quality. The reaction of pyrolysis oil with ozone changed double bonds into aldehydes and ketone, estimated that HDPE pyrolysis oil contained $\sim45$ wt% 1-alkene type olefins, and PP pyrolysis oil did $\sim73$ wt% olefins, which consisted of $\sim47$ wt% secondary and $\sim20$ wt% primary alkenes. The dark brown color and odor of pyrolysis oil were improved by eliminating double bonds, indicated that they were directly related to unsaturated hydrocarbons. Container test showed that metal can affected oil quality worse than the brown glass bottle. Antioxidant added into pyrolysis oil was consumed up to 90% within $2\sim3$ days and the wt. composition of unsaturated hydrocarbons in pyrolysis oil was not changed within 50 days, inferring that instability of pyrolysis oil due to unsaturated bonds can be stabilized by antioxidants. Adsorption test on silica gel, activated carbon and alumina to remove precipitates in oil produced a good result, but not enough to remove moisture. However, cheap anhydrous sodium carbonate showed the best removal efficiency of moisture as well as precipitates in oil. Therefore the pyrolysis oil quality improvement was accomplished by applying anhydrous $Na_2CO_3$ into the production plant.

• Proceedings of the Korean Society For Composite Materials Conference
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• 한국복합재료학회 2005년도 춘계학술발표대회 논문집
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• pp.25-28
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• 2005

The optical fiber is known for the proper sensor which can accomplish the structural health monitoring, Fiber Bragg Grating sensors are being studied more than any other fiber optic sensors due to good multiplexing capabilities. But because the signal stability of FBG sensors can be influenced by the strain gradient, it needs to analyze signal of FBG sensors. Particularly acoording to strain gradient induced by structural geometry or cracks, the spectrum peak of the FBG sensor signal can be split easily. In this paper, the spectrum analysis of the FBG sensor signal was performed and the region of embedment of FBG sensors was determined in $H_2$ pressure vessel by numerical method.

• Proceedings of the Materials Research Society of Korea Conference
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• 한국재료학회 2003년도 추계학술발표강연 및 논문개요집
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• pp.119-119
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• 2003

탄화규소나 열분해 탄소는 고온 특성 및 화학적인 안정성 이 우수하여 단미 혹은 코팅재로로 소재의 성능을 향상시키기 위하여 에너지 관련 분야, 반도체 치구 분야, 방위산업 및 항공우주 분야와 원자력 분야에서 다양하게 사용된다. 특히 원자력 분야에서는 고온형 원자로의 노심 요소 부품으로 적용 및 개발을 고려하고 있으며, 대표적인 예로 수소생산용 초고온 가스냉각로의 코팅 핵연료 입자를 들 수 있다. 일반적으로 TRISO라 불리는 가스냉각로 핵연료는 구형 $UO_2$ kemel의 주변을 PyC-SiC -PyC의 삼중 코팅층으로 둘러싸는 구조를 하고 있으며, 이 코팅층들은 kernel물질이 분열하는 동안 발생되는 내부 기체 압력을 견디는 압력용기 역할과 기체나 금속 핵분열 생성물들을 가두는 확산 장벽 역할을 하게 된다. 본 연구에서는 구형의 $UO_2$대신 선행연구를 위하여 구형 ZrO$_2$를 이용하여 증착온도나 시간 및 입력기체비 등의 화학증착 변수로 조절하여 SiC 및 PyC을 코팅하고, 각 변수들에 의한 증착층의 거동을 고찰하고자 하였다.

• Proceedings of the KSME Conference
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• 대한기계학회 2007년도 춘계학술대회A
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• pp.23-27
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• 2007

To store hydrogen with high pressure is one of key technologies in developing FCVs (fuel cell vehicles). Especially, metal lined composite structure, which is called Type 3, is expected to effectively stand highly pressurized hydrogen since it has high specific strength and stiffness as well as excellent storage ability. However, it has many difficulties to design Type 3 vessels because of their complex geometry, fabrication process variables, etc. In this study, therefore, optimal design of Type 3 vessels was performed in consideration of such actual circumstances using genetic algorithm. Additionally, detailed finite element analysis was followed for the optimal result.