• 기계와재료
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• v.24 no.1
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• pp.26-35
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• 2012

가스액화플랜트는 질소, 산소, 헬륨 등 고순도의 가스를 효율적으로 저장 및 운송을 위해 가스를 액체로 변환하는 플랜트로, 대표적인 플랜트로는 질소, 산소, 아르곤 등의 가스를 생산하는 공기분리플랜트, 헬륨액화플랜트, 수소액화플랜트, 천연가스액화플랜트 등이 있다. 질소, 산소, 수소 등의 가스는 산업의 전반적인 분야에서 널리 사용되고 있으며, 국내의 경우 철강, 반도체, 디스플레이제조산업 등 가스 다소비 분야의 비약적인 발전에 따라 급격하게 수요가 증가하고 있는 상황이다. 대용량의 가스액화플랜트는 원료로부터 불순물을 제거하고, 팽창 또는 열교환 과정을 통해 가스를 액체로 변환하는 극저온기술로 주로 구성되며, 이와 같은 과정은 압축기, 열교환기, 증류탑, 팽창터빈, 콜드박스 등의 구성요소에 의해 구현된다. 따라서 가스액화플랜트에서 효율적인 극저온의 생성 및 유지는 플랜트의 경제성 제고를 위해 핵심적인 요소이다.

• Transactions of the Korean hydrogen and new energy society
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• v.33 no.6
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• pp.838-844
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• 2022

In this paper, an experimental study was conducted on the energy efficiency ratio of performance for air source heat pump. The energy efficiency ratio presents the operating efficiency of heat pump performance. In order to improve reliability in the energy efficiency ratio test of air source heat pump, the measurement uncertainty of the instrument was estimated. Measurement uncertainty refers to the uncertainty of a measurement, estimates the range in which the expected value of the measurement can be within a certain confidence level, and suggests a range in which the measured representative value is incorrect. The measurement uncertainty for the energy efficiency ratio test of air source heat pump was calculated and the measured results were presented.

• Journal of Internet Computing and Services
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• v.24 no.2
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• pp.47-56
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• 2023

Hydrogen energy is an eco-friendly energy that produces heat and electricity with high energy efficiency and does not emit harmful substances such as greenhouse gases and fine dust. In particular, smart hydrogen energy is an economical, sustainable, and safe future smart hydrogen energy service, which means a service that stably operates based on 'data' by digitally integrating hydrogen energy infrastructure. In this paper, in order to implement a data-based hydrogen charging station demand forecasting model, three hydrogen charging stations (Chuncheon, Sokcho, Pyeongchang) installed in Gangwon-do were selected, supply and demand data of hydrogen charging stations were secured, and 7 machine learning and deep learning algorithms were used. was selected to learn a model with a total of 27 types of input data (weather data + demand for hydrogen charging stations), and the model was evaluated with root mean square error (RMSE). Through this, this paper proposes a machine learning-based hydrogen charging station energy demand prediction model for optimal hydrogen energy supply and demand.

• 한국신재생에너지학회:학술대회논문집
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• 2007.06a
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• pp.598-601
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• 2007

셀룰로오스, 헤미셀룰로오스, 리그닌으로 구성된 목질계 바이오매스를 이용한 가스화의 경우 30%의 리그닌 성분이 열에 안정한 상태인 타르로 형성되면서 가스화 후단공정에서의 정제, 발전 등에 직접 사용하기 어려우며, 가스화 효율을 저하시키는 원인이 된다. 이의 문제 해결을 위하여 본 연구에서는 촉매를 이용한 수증기 개질 반응을 통하여 타르를 합성가스로 개질시킬 수 있는 방법을 모색하기 위하여 다양한 온도, 촉매, 스팀 주입량 및 촉매크기에 따른 전환율, 생성가스 특성을 알아보았다. 타르 대상 물질로는 타르 내 상당부분을 차지하고 있는 톨루엔을 이용하였다. 일반적으로 반응온도, 스팀 주입량이 증가할수록 수소 생성량이 증가하였으며, 지르코니아로 증진된 니켈 촉매의 경우 600$^{\cdot}C$ 에서도 100%의 높은 전환율을 보였다. 일반적인 가스화기에서 배출되는 타르의 농도보다 10배 높은 조건에서도 100%의 높은 전환율을 얻을 수 있었으며, 이를 통하여 실제 공정으로의 적용시에도 후단 공정의 부담을 줄일 수 있는 개질기로 적용 가능할 것으로 보인다.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2014.11a
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• pp.150-150
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• 2014

지구상 존재하는 화석연료의 고갈에 대한 우려와 함께 최근 들어 지구 온난화로 인해 야기되고 있는 심각한 지구환경 문제에 대한 관심이 고조되고 있다. 이산화탄소로 대표되는 지구 온난화를 일으키는 공해물질의 많은 부분이 현재 주에너지원으로 사용되는 화석연료에 기인하기 때문에 이를 대체할 수 있는 청정에너지 개발은 이미 세계적 당면 과제라고 할 수 있다. 그 중, 수소에너지는 청정에너지로써의 역할 뿐만 아니라 에너지 저장매체로써의 기능 또한 담당할 수 있어 주목 받고 있다. 본 연구에서는 텅스텐 광촉매를 사용하여 물을 수소와 산소로 분해 하고자 하였고 C70을 도입하여 분해 효율을 향상시키고자 하였다.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2015.05a
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• pp.102-102
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• 2015

지구상 존재하는 화석연료의 고갈에 대한 우려와 함께 최근 들어 지구 온난화로 인해 야기되고 있는 심각한 지구환경 문제에 대한 관심이 고조되고 있다. 이산화탄소로 대표되는 지구 온난화를 일으키는 공해물질의 많은 부분이 현재 주에너지원으로 사용되는 화석연료에 기인하기 때문에 이를 대체할 수 있는 청정에너지 개발은 이미 세계적 당면 과제라고 할 수 있다. 그 중, 수소에너지는 청정에너지로써의 역할 뿐만 아니라 에너지 저장매체로써의 기능 또한 담당할 수 있어 주목 받고 있다. 본 연구에서는 텅스텐 광촉매를 사용하여 물을 수소와 산소로 분해 하고자 하였고 C70을 도입하여 분해 효율을 향상시키고자 하였다.

• Journal of the Korean Geotechnical Society
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• v.36 no.8
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• pp.17-25
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• 2020

Korea Institute of Civil Engineering and Building Technology has constructed a large scale Dust Thermal Vacuum Chamber to simulate extreme lunar terrestrial environments and to study the Moon as an outposts for space development and exploration. Although a large amount of KLS-1 (Korean Lunar Simulant-1) is required for research, its massive production is practically difficult. This paper describes semi-automatic manufacturing system for massive production of KLS-1 in detail, which is seven times more efficient than manual production. In addition, to increase the similarity with lunar regolith, hydrogen reduction reaction using ilmenite which is one of the minerals was also conducted to simulate nanophase Fe(0) which is the unique property of lunar regolith. As a result, it was found that np-Fe(0) was formed at a temperature of 700℃ or higher, and increased in proportion to the temperature until 900℃.

• Journal of the Korean Institute of Gas
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• v.27 no.3
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• pp.77-83
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• 2023

Energy consumption is increased by rapid industrialization. As a result, climate change is accelerating due to the increase in CO₂ concentration in the atmosphere. Therefore, a shift in the energy paradigm is required. Hydrogen is in the spotlight as a part of that. Currently 95% of hydrogen is fossil fuel-based reforming hydrogen which is accompanied by CO₂ emissions. This is called gray hydrogen, if the CO₂ is captured and emission of CO₂ is reduced, it can be converted into blue hydrogen. There are 3 technologies to capture CO₂: absorption, adsorption and membrane technology. In order to select CO₂ capture technology, the analysis of the exhaust gas should be carried out. The concentration of CO₂ in the flue gas from the hydrogen production process is higher than 20%if water is removed as well as the emission scale is classified as small and medium. So, the application of the membrane technology is more advantageous than the absorption. In addition, if LNG cold energy can be used for low temperature CO₂ capture system, the CO₂/N₂ selectivity of the membrane is higher than room temperature CO₂ capture and enabling an efficient CO₂ capture process. In this study, we will analyze the flue gas from hydrogen production process and discuss suitable CO₂ capture technology for it.

• Journal of the Korean Society of Marine Environment & Safety
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• v.30 no.2
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• pp.239-251
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• 2024

In this study, a hydrogen fuel cell process based on methanol was developed to reduce greenhouse gas emissions. In Case1, the methanol fuel engine system was designed to investigate the emission of exhaust gas when methanol was supplied as fuel instead of gasoline to the engine. In Case2, a hydrogen fuel cell system was designed by adding a methanol reforming system to Case1. This hybrid system produced gray hydrogen and combined the output of the engine and fuel cell to drive the ship. However, gray hydrogen emits carbon in the process of producing hydrogen. To address this problem, a carbon capture and utilization (CCU) system was added to Case3. The CO2 of the flue gas discharged from Case2 was synthesized with gray hydrogen to produce blue methanol. The results of the case studies revealed that the optimal operating conditions were 220 ℃, 500 kPa, SCR = 1.0, and flow ratio = 0.7. The system of Case3 reduced carbon emissions by 42% compared with that Case1. Thus, the hybrid system of Case3 could considerably reduce the ship's CO2 emissions.

• Applied Chemistry for Engineering
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• v.19 no.2
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• pp.209-213
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• 2008

The fixed bed gasification reactor with 1 m hight and 10.2 cm diameter was utilized for the hydrogen production from biomass wastes. Lauan sawdust was used for non-catalytic and catalytic gasification reaction as a sample in the fixed bed reactor. The fixed bed temperature and catalyst are the major variables affecting the process operation. Thus, the effect of fixed bed temperature and the catalysts on gas composition were studied at the temperature range from $400^{\circ}C$ to $700^{\circ}C$. The yield of hydrogen was increased at higher temperature in the fixed bed reaction. Fractions of hydrogen, carbon monoxide and methane gas in the product gas increased when sodium carbonate ($Na_2CO_3$) and potassium carbonate ($K_2CO_3$) catalysts were used. Furthermore, sodium carbonate catalyst was more effective to obtain higher hydrogen yield compared to potassium carbonate catalyst.