• Title/Summary/Keyword: 수소/공기확산화염

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Effects of Addition of Hydrogen and Water Vapor on Flame Structure and NOx Emission In $CH_4$-Air Diffusion Flame (메탄-공기 확산화염에서 수소와 수증기 첨가가 화염구조와 NOx 배출에 미치는 효과)

  • Park, Jeong;Keel, Sang-In;Yun, Jin-Han
    • Journal of Hydrogen and New Energy
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    • v.18 no.2
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    • pp.171-181
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    • 2007
  • Blending effects of hydrogen and water vapor on flame structure and NOx emission behavior are numerically studied with detailed chemistry in methane-air counterflow diffusion flames. The composition of fuel is systematically changed from pure methane and pure hydrogen to the blending fuels of methane-hydrogen-water vapor through the molar addition of $H_2O$. Flame structure is changed considerably for hydrogen-blending methane flames and hydrogen-blending methane flames diluted with water vapor in comparison to pure methane flame. These complicated changes of flame structures also affect NOx emission behavior considerably. The changes of thermal NO and Fenimore NO are analyzed for various combinations of the fuel composition. Importantly contributing reaction steps to thermal NO and Fenimore NO are addressed in pure methane, hydrogen-blending methane flames, and hydrogen-blending methane flames diluted with water vapor.

Flame-Vortex Interaction and Mixing in Turbulent Hydrogen Diffusion Flames with Coaxial Air (동축공기 수소확산화염에서 화염-와류 상호작용 및 혼합)

  • Kim, Mun-Ki;Oh, Jeong-Seog;Choi, Young-Il;Yoon, Young-Bin
    • 한국가시화정보학회:학술대회논문집
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    • 2007.11a
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    • pp.149-154
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    • 2007
  • This study examines the effect of acoustic excitation using forced coaxial air on the flame characteristics of turbulent hydrogen nonpremixed flames. A resonance frequency was selected to acoustically excite the coaxial air jet due to its ability to effectively amplify the acoustic amplitude and reduce flame length and NOx emissions. Acoustic excitation causes the flame length to decrease by 15 % and consequently, a 25 % reduction in EINOx is achieved, compared to a flame without acoustic excitation. Moreover, acoustic excitation induces periodical fluctuation of the coaxial air velocity, thus resulting in slight fluctuation of the fuel velocity. From phase-lock PIV and OH PLIF measurement, the local flow properties at the flame surface were investigated under acoustic forcing. During flame-vortex interaction in the near field region, the entrainment velocity and the flame surface area increased locally near the vortex. This increase in flame surface area and entrainment velocity is believed to be a crucial factor in reducing flame length and NOx emission in coaxial jet flames with acoustic excitation. Local flame extinction occurred frequently when subjected to an excessive strain rate, indicating that intense mass transfer of fuel and air occurs radially inward at the flame surface.

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The Structure of the Axisymmetric turbulent Diffusion Flame -( I ) Flow Measurement in Isothermal Field- (재순환 영역이 있는 축대칭 난류확산화염의 구조 -( I ) 비연소 유동장 측정 결과-)

  • 이병무;신현동
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.8 no.4
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    • pp.328-334
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    • 1984
  • 본 연구에서는 기하학적으로는 물론이며 유동 장체가 축대칭이 되고 재순환 영역이 있는 노즐을 제작하여 우선 연구의 1차 단계로서 연소가 없을 경우 시간 평균 유속 및 난류 성분을 레이져 도플러 유속계로 비교적 정밀히 측정한후, 노즐 유체와 주위공기류와의 시간 평균 혼합특성을 구명하기 위하여 가스크로마토그라프에 의하여 농도 분포를 측정, 모델 검토를 위한 기초 데이타 제공과 실험용으로 채용한 노즐류의 구조를 구명하고저 한다. 특히 노즐유체를 수소/질소 혼합기인 경우와 공기를 사용 한 양 경우를 비교, 검토하므로써 부력효과에 대한 평가를 시도하였다.

Prediction of Isothermal and Reacting Flows in Widely-Spaced Coaxial Jet, Diffusion-Flame Combustor (큰 지름비를 가지는 동축제트 확산화염 연소기내의 등온 및 연소 유동장의 예측)

  • O, Gun-Seop;An, Guk-Yeong;Kim, Yong-Mo;Lee, Chang-Sik
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.20 no.7
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    • pp.2386-2396
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    • 1996
  • A numerical simulation has been performed for isothermal and reacting flows in an exisymmetric, bluff-body research combustor. The present formulation is based on the density-weighted averaged Navier-Stokes equations together with a k-epsilon. turbulence model and a modified eddy-breakup combustion model. The PISO algorithm is employed for solution of thel Navier-Stokes system. Comparison between measurements and predictions are made for a centerline axial velocities, location of stagnation points, strength of recirculation zone, and temperature profile. Even though the numerical simulation gives acceptable agreement with experimental data in many respects, the present model is defictient in predicting the recoveryt rate of a central near-wake region, the non-isotropic turbulence effects, and variation of turbulent Schmidt number. Several possible explanations for these discrepancies have been discussed.

Experimental Study on Flame-Vortex Interactions in Turbulent Hydrogen Non-premixed Flames with Coaxial Air (동축공기 수소확산 화염에서의 화염과 와류의 상호작용 실험연구)

  • Kim, Mun-Ki;Oh, Jeong-Suk;Choi, Young-Il;Yoon, Young-Bin
    • 한국연소학회:학술대회논문집
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    • 2006.10a
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    • pp.86-94
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    • 2006
  • This paper investigates the effects of acoustic forcing on NOx emissions and mixing process in the near field region of turbulent hydrogen nonpremixed flames. The resonance frequency was selected to force the coaxial air jet acoustically, because the resonance frequency is effective to amplify the forcing amplitude and reduce NOx emissions. When the resonance frequency is acoustically excited, a streamwise vortex is formed in the mixing layer between the coaxial air jet and coflowing air. As the vortex develops downstream, it entrains both ambient air and combustion products into the coaxial air jet to mix well. In addition, the strong vortex pulls the flame surface toward the coaxial air jet, causing intense chemical reaction. Acoustic excitation also causes velocity fluctuations of coaxial air jet as well as fuel jet but, the maximum value of centerline fuel velocity fluctuation occurs at the different phases of $\Phi$=$180^{\circ}$ for nonreacting case and $\Phi$=$0^{\circ}$ for reacting case. Since acoustic excitation enhances the mixing rate of fuel and air, the line of the stoichiometric mixture fraction becomes narrow. Finally, acoustic forcing at the resonance frequency reduces the normalized flame length by 15 % and EINOx by 25 %, compared to the flame without acoustic excitation.

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Flame Length Scaling and Structure in Turbulent Hydrogen Non-Premixed Jet Flames with Coaxial Air (동축공기 수소 확산화염의 구조 및 화염길이 스케일링)

  • Yun, Sang-Wook;Oh, Jeong-Seog;Kim, Mun-Ki;Yoon, Young-Bin
    • 한국연소학회:학술대회논문집
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    • 2006.04a
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    • pp.105-110
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    • 2006
  • Many previous works have been performed to provide correlations of flame length, theoretically and experimentally. Most of these results studied were conducted in vertical turbulent flame with no coaxial air condition. The present study analyzes the flame length scaling with coaxial air. In turbulent hydrogen non-premixed jet flames with coaxial air, flame length scaling theoretically proposed so far has been related with the concept of a far-field equivalent source. At high coaxial air to fuel velocity ratio, $U_A/U_F$, however, this scaling theory has some difference with experimental flame length data. This difference is understood to be due to the fact that the theory is based on far-field notion, while the effect of coaxial air on jet flame occurs in the region near the nozzle exit. Therefore, we define effective jet density $P_{eff}$ involving the concept of near-field so that effective jet diameter can be extended to the near-field region. In this condition, we modify the correlation and compare with experimental data.

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Reduction of NOx Emissions in Turbulent Hydrogen Diffusion Flame using Acoustic Excitation (음파가진에 의한 동축공기 수소 확산화염의 NOx 배출저감연구)

  • Kim, Mun-Ki;Han, Jeong-Jae;Yoon, Sang-Wook;Yoon, Young-Bin
    • Journal of the Korean Society of Combustion
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    • v.10 no.1
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    • pp.13-19
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    • 2005
  • Measurements of flame length and NOx emissions have been conducted to investigate the effects of acoustic excitation on flame structure in turbulent hydrogen diffusion flames with coaxial air. When the acoustic excitation of a specific frequency is applied to coaxial air stream, flame length is dramatically reduced, resulting in reduction of flame residence time. Consequently, EINOx could decrease up to 35 % and this shows that acoustic excitation is effective in reducing NOx emissions. Mie scattering technique has been used to visualize the vortex structure induced by acoustic excitation and vortex formation, development and destruction were observed quantitatively. As a result, vortex entrains coflow air into fuel stream and mixing rate between fuel and air is significantly enhanced, which may contribute to reduction of NOx emissions.

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Effect of Pressure on Acoustic Pressure Response and NO Formation in Diluted Hydrogen-Air Diffusion Flames (희석된 수소-공기 확산 화염에서 음향파 응답과 NO 생성에 미치는 압력의 영향)

  • Sohn, Chae-Hoon;Chung, Suk-Ho
    • 한국연소학회:학술대회논문집
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    • 1999.10a
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    • pp.11-20
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    • 1999
  • Acoustic pressure response and NO formation of hydrogen-air diffusion flames at various pressures are numerically studied by employing counterflow diffusion flame as a model flame let in turbulent flames in combustion chambers. The numerical results show that extinction strain rate increases linearly with pressure and then decreases, and increases again at high pressures. Thus, flames are classified into three pressure regimes. Such non-monotonic behavior is caused by the change in chemical kinetic behavior as pressure rises. Acoustic pressure response in each regime is investigated based on the Rayleigh criterion. At low pressures, pressure-rise causes the increase in flame temperature and chain branching/recombination reaction rates, resulting in increased heat release. Therefore, amplification in pressure oscillation is predicted. Similar phenomena are predicted at high pressures. At moderate pressures, weak amplification is predicted. Emission index of NO shows similar behaviors as to the peak-temperature variation with pressure.

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The Predictions on the Structure of Tubulent Hydrogen-Air Diffusion Flame (수소 - 공기 난류확산화염 구조예측에 관한 연구)

  • 신현동
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.7 no.3
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    • pp.328-334
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    • 1983
  • The turbulent hydrogen-air diffussion flame was studied experimentally and theoretically. Laser Doppler anemometer was used to measure the velocity field in the flame. Two mathematical models for the combustion reaction term, which are infinite rate model and finite rate to be derived eddy break-up model, were tested by comparing predictions with experimental data for coaxial turbulent diffusion flame. The agreement between the predictions and the data is, on the whole, very good in the case of employing the finite rate model rather than the infinite rate model. But, it was shown that the finite rate model was practically applicable to the predictions of the turbulent diffussion flame structure.

Simultaneous PIV/OH PLIF Measurements in Hydrogen Nonpremixed Flames with Coaxial Air (PIV/OH PLIF 동시 측정을 이용한 동축공기 수소확산화염의 실험적 연구)

  • Kim, Mun-Ki;Kim, Seung-Han;Yoon, Young-Bin
    • 한국연소학회:학술대회논문집
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    • 2003.12a
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    • pp.115-123
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    • 2003
  • Simultaneous measurements of velocity and OH distribution were made using particle image velocimetry(PIV) and planar laser-induced fluorescence(PLIF) of OH radical in turbulent hydrogen nonpremixed flames with coaxial air. The OH radical was used as an approximate indicator of chemical reaction zone. The OH layer was correlated well with the stoichiometric velocity, $U_s$, instantaneously and on average. In addition, high strain-rate regions almost coincide with the OH distribution. The residence time in flame surface, calculated from the root-mean-square value of the radial velocity, is proportional to $(x/d_F)^{0.7}$. It is found that the mean value of principal strain rate on the OH layer can be scaled with $(x/d_F)^{-0.7}$ and therefore, the product of the residence time and the mean strain rate remains constant over all axial positions.

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