• Title/Summary/Keyword: 수산화물

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Electrochemical Characteristics of LiMn2O4 Cathodes Synthesized from Various Precursors of Manganese Oxide and Manganese Hydroxide (다양한 형태 및 구조의 망간산화물 및 망간수산화물 전구체로부터 합성한 LiMn2O4양극의 전기화학적 특성 연구)

  • Lee, Jong-Moon;Kim, Joo-Seong;Hong, Soon-Kie;Lee, Jeong-Jin;Ahn, Han-Cheol;Cho, Won-Il;Mho, Sun-Il
    • Journal of the Korean Electrochemical Society
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    • v.15 no.3
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    • pp.172-180
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    • 2012
  • The $LiMn_2O_4$ cathodes for lithium ion battery were synthesized from various precursors of manganese oxides and manganese hydroxides. As the first step, nanosized precursors such as ${\alpha}-MnO_2$ (nano-sticks), ${\beta}-MnO_2$ (nano-rods), $Mn_3O_4$ (nano-octahedra), amorphous $MnO_2$(nano-spheres), and $Mn(OH)_2$ (nano-plates) were prepared by a hydrothermal or a precipitation method. Spinel $LiMn_2O_4$ with various sizes and shapes were finally synthesized by a solid-state reaction method from the manganese precursors and LiOH. Nano-sized (500 nm) octahedron $LiMn_2O_4$ showed high capacities of 107 mAh $g^{-1}$ and 99 mAh $g^{-1}$ at 1 C- and 50 C-rate, respectively. Three dimensional octahedral crystallites exhibit superior electrochemical characteristics to the other one-dimensional and two-dimensional shaped $LiMn_2O_4$ nanoparticles. After 500 consecutive charge discharge battery cycles at 10 C-rate with the nano-octahedron $LiMn_2O_4$ cathode, the capacity retention of 95% was observed, which is far better than any other morphologies studied in this work.

Factor Analysis Affecting on the Charterage of Capesize Bulk Carriers (케이프사이즈 용선료에 미치는 영향 요인분석)

  • Ahn, Young-Gyun;Lee, Min-Kyu
    • Korea Trade Review
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    • v.43 no.3
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    • pp.125-145
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    • 2018
  • The Baltic Shipping Exchange is reporting the Baltic Dry Index (BDI) which represents the average charter rate for bulk carriers transporting major cargoes such as iron ore, coal, grain, and so on. And the current BDI index is reflected in the proportion of capesize 40%, panamax 30% and spramax 30%. Like mentioned above, the capesize plays a major role among the various sizes of bulk carriers and this study is to analyze the influence of the factors influencing on charter rate of capesize carriers which transport iron ore and coal as the major cargoes. For this purpose, this study verified causality between variables using Vector Error Correction Model (VECM) and tried to derive a long-run equilibrium model between the dependent variable and independent variables. Regression analysis showed that every six independent variable has a significant effect on the capesize charter rate, even at the 1% level of significance. Charter rate decreases by 0.08% when capesize total fleet increases by 1%, charter rate increases by 0.04% when bunker oil price increases by 1%, and charter rate decreases by 0.01% when Yen/Dollar rate increases by 1%. And charter rate increases by 0.02% when global GDP increases by one unit (1%). In addition, the increase in cargo volume of iron ore and coal which are major transportation items of capesize carriers has also been shown to increase charter rates. Charter rate increases by 0.11% in case of 1% increase in iron ore cargo volume, and 0.09% in case of 1% increase in coal cargo volume. Although there have been some studies to analyze the influence of factors affecting the charterage of bulk carriers in the past, there have been few studies on the analysis of specific size vessels. At present moment when ship size is getting bigger, this study carried out research on capesize vessels, which are biggest among bulk carriers, and whose utilization is continuously increasing. This study is also expected to contribute to the establishment of trade policies for specific cargoes such as iron ore and coal.

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A Study on the Disputable Issues of the Standard Form of Korea Service Contract - Focusing on Liquidated Damage and Minimum Quantity Commitment - (한국 컨테이너 해상화물 표준장기운송계약서 쟁점에 관한 연구 - 손해배상예정액과 최소약정물량을 중심으로 -)

  • Jae-woong Yoon;Yun-seok Hur
    • Korea Trade Review
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    • v.48 no.2
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    • pp.217-243
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    • 2023
  • This study revealed practical implications by analyzing the clauses and disputable issues of the Korea Service Contract. Korea introduced Servcie Contract in the container part since Hanjin Shipping's bankrupcy and distributed the standard form(2019). After that, the standard form was revised during the supply chain crisis(2022). In the standard form, there are clause that require agreement due to conflicting interests of shipper and carrier. Therefore, the main clauses of the standard form were analyzed to derive the practical meaning to the both parties. In addition, in the process of introducing the standard form, the most disputable issues, liquidated damages and minimum quality commitment, were deeply analyzed to explain how shipper and carriers' benefit and loss differ as the clause changes. In conclusion, both parties must set LD at a very reasonable level so that they do not proceed separately with penalty. In addition, 'evenly' is a much more important than quantity for carrier in the establishment of MQC, so extra box option for shipper even during the peak season is needed to accommodate with service contract.

Investigation of Corrosion Minerals from the Remediation for TCE-Contaminate d Groundwater (TCE로 오염된 지하수 정화시 부식 광물에 대한 연구)

  • Moon, Ji-Won;Moon, Hi-Soo;Yungoo Song;Kang, Jin-Kyoo;Yul Roh
    • Journal of the Mineralogical Society of Korea
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    • v.16 no.1
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    • pp.107-123
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    • 2003
  • The objective of this study was to investigate mineral precipitates, which derived from the zero valent iron (ZVI) corrosion during TCE dechlorination and to find the controlling factors in mineral precipitates. A series of column experiemnts were conducted to evaluate the location of ZVI and the effects of electrode arrangements in electro-enhanced permeable reactive barrier (E2PRB) systems. Based on mineralogical study, ZVI samples near the influent port had more lepidocrocite, ferrihydrite or Fe (oxy)hydroxide, and (phospho)siderite while backward samples had more akaganeite, magnetite/maghemite, and intermediate green rust (GR) I and GR II. A suite of mineral distribution was preferabley related to the dissolved oxygen and the increased pH. Controlling factors of mineral precipitates in an E2PRB system were found to be (1) pH, (2) dissolved oxygen, (3) the types of Fe intermediates, and (4) anionic species to form complex strongly.

Lipids of Fresh-Water Cockle, Corbicula elatior (재첩의 지질에 관한 연구)

  • JOH Yong-Goe;PARK Soo-Jin;AHN Cheol-Woo
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.15 no.1
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    • pp.94-98
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    • 1982
  • Present investigation was carried out to clarify chemical characteristics, lipid composition, fatty acid components and the sterol composition of the lipids from the fresh-water cockle, Corbicula slatier. The results obtained are as follows :1) The oil content, iodine value and unsaponifiable matter of the total .lipids were 2.17, 119 and $16.6\%$ respectively. 2) The main components of the total lipids were phospholipids (ahout $43\%$), triglyceride and sterol. 3) The main fatty acids of the total lipids were $C_{16:0}\;(48.4\%),\;C_{14:0}\;(10.0\%),\;C_{18:3}\;(8.3\%),\;C_14:1\;(5.4\%)\;and\;C_{18:1}\;(5.3\%)$. 4) Sterols found were 24-methylenecholesterol ($14.1\%$), $\beta-sitosterol(22.5\%)$, fucosterol ($14.9\%$), isofucosterol (?) ($14.0\%$), $\Delta^7-avenasterol (?)(5.2\%)$ and cholesterol ($2.3\%$).

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Recycling of Waste Egg Shells for Treatment of Laboratory Wastewater containing Heavy Metals (중금속 함유 실험실 폐수처리를 위한 폐달걀껍질의 재활용)

  • Kim, Eun-Ho;Kim, Hyeong-Seok;Seong, Nak-Chang
    • Journal of the Korea Organic Resources Recycling Association
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    • v.7 no.1
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    • pp.13-21
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    • 1999
  • The purposes of this research were to evaluate the character of laboratory wastewater, and to examine the utilization of waste egg shells for neutralization and removal of heavy metals. Waste egg shells are excellent at neutralizing acidic wastewater, because they have alkaline minerals such as calcium. It must be seemed that removal rate of heavy metals were very influenced by adsobent dosage and adsorbate concentrations, because waste egg shells acted as precipitation and adsorption. If we reflected the adsorption capacity(k) and adsorption(1/n) of Freundlich isotherm, we couldn't consider waste egg shells as a good adsorbent. In view of these results, it showed that wastes containing the similar compositions as waste egg shells could utilize the neutralization, precipitation and adsorption of heavy metals in laboratory wastewater.

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Effect of Environmental Factors on the Growth, Glycogen and Hemoglobin Content of Cultured Arkshell, Scapharca broughtonii (서식환경에 따른 피조개 Scapharca broughtonii의 성장과 글리코겐 및 헤모글로빈량의 변화)

  • PARK Mi Seon;LIM Hyun Jeong;KIM Pyoung Joong
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.31 no.2
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    • pp.176-185
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    • 1998
  • For the sustainable production of cultured arkshell Scapharca broughtonii and pre-estimation of the harvest of it, we investigated the relationship between the habitat environmental factors and the physiological conditions of the arkshell in the two experiment sites near the Chinhae Bay, Korea. For the analysis of habitat environmental factors such as temperature, salinity, dissolved oxygen, DIP (dissolved inorganic phosphate), DIN (dissolved inorganic nitrogen), suspended solids and chlorophyll a of bottom water and T-S (total sulfide) and COD (chemical oxygen demand) of surface sediment were measured, To determine physiolosical condition of cultured arkshell, shell length, fatness, glycogen, hemoglobin content and gametogenesis were examined. Water temperature were higher in Woongchon than in Songdo in 1992, and were Higher in Songdo in 1993. Salinity were higher in Songdo than in Woongchon except from January to May in 1992. COD, suspended solids and chlorophyll a content were higher in Songdo than in Woongchon, while the contents of sediment sulfide, DO, DIP and DIN were higher in Woongchon. Based on the environmental assessment, significant factors affecting the growth and physiological condition of arkshell were quantity of food and total sulfide content in the bottom sediment.

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The Estimation of the Value-added Related to Agriculture in Chung-nam's Agribusiness (충청남도 농림수산 관련산업의 농림수산관련 부가가치 추계)

  • Kim, Changhwan;Yoo, Beomsik;Lee, Jongsang
    • Journal of Agricultural Extension & Community Development
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    • v.20 no.2
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    • pp.315-339
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    • 2013
  • This study aims to suggest methods to estimate the agriculture related added value created in the agricultural production sector and the up/downstream agribusiness of Chungcheongnam-do by using the transaction table at producer's price, the domestic transaction table, the wholesale-retail profit table and the freight charge table in the input-output tables, and further aims to estimate regional and industrial agriculture related added values created in the agricultural production sector and the agribusiness of Chungcheongnam-do by using the input-output tables of the year 2005. This thesis suggests the consideration of overall and holistic policy regarding public welfare facilities in healthcare, commission sale market places for fishery products, fishery processing factories, processing factories for medicines, cosmetics, feedstuff, and tobacco leaves and the innovative distribution system with regard to wholesale/retail that Chungnam lacks in. It is also proposed to make comprehensive and cohesive policy to enhance growth and competitiveness of agricultural, forestry and fishery industry.

Hydrothermal Synthesis and Exfoliation of Mg/Al Layered Double Hydroxide with Tailored Aspect Ratio (수열 합성 및 박리에 의한 Mg/Al 층상 이중 수산화물의 종횡비 제어)

  • Hwang, Sung-Hwan;Kim, Donghyun;Kim, Yewon;Jung, Hyunsung
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.30 no.12
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    • pp.822-827
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    • 2017
  • Mg/Al layered double hydroxide with two-dimensional (2D) nanostructures was synthesized by a hydrothermal technique. The morphology and aspect ratio of $Mg_4Al_2(OH)_{14}3H_2O$ were controlled by the concentration and kinds of the hydrolysis agent, and temperature. The aspect ratio of $Mg_4Al_2(OH)_{14}3H_2O$ layered double hydroxides with the 2D hexagonal crystal structure was tailored from about 12.6 to about 45.7. The intercalated $CO{_3}^{2-}$ anions of the synthesized 2D $Mg_4Al_2(OH)_{14}3H_2O$ layered double hydroxides were exchanged to $NO_3{^-}$ anions. The bulk 2D $Mg_4Al_2(OH)_{14}3H_2O$ layered double hydroxides with the increased space between two layers due to the anion exchange were exfoliated in a formamide solution. The aspect ratio of the exfoliated 2D $Mg_4Al_2(OH)_{14}3H_2O$ layered double hydroxides increased to 570.3.

Genesis of Clay Minerals in the Vicinity of Gwangpo Bay, Southern Coast of Korea (광포만 집수유역내에 분포하는 점토광물의 성인에 관한 연구)

  • PARK Maeng-Eon;SONG Yong-Sun;KIM Hee-Joon;KIM Dae-Choul;PAIK In-Sung;CHUNG Sang-Yong;SONG Shi-Tae
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.21 no.4
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    • pp.259-268
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    • 1988
  • Clay deposits in the vicinity of the Gwangpo Bay, southern coast of Korea, occur restrictively in anorthositic masses. Laumontite and meta-halloysite are the predominant clay minerals with iron oxides at the uppermost surface. Chlorite and halloysite occur in deeper zone. Beneath the main clay horizon, but not above, some anorthositic rocks are pervasively altered to quartz, sericite, chlorite, pyrite and montmorillonite along the hydrothermal channels. The hypotheses of hydrothermal and weathering origins of the clay minerals are tested by multi-component equilibrium calculations of the reactions of modified hydrothermal water and rain water with anorthositic rocks at $100^{\circ}C\;and\;25^{\circ}C$, respectively. The calculated mineralogy from the reaction with rain water resembles natural mineral assemblage except for abundance in laumontite. The result implies that the weathering process is the main machanism of the formation of clay deposits in the area.

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