• Title/Summary/Keyword: 수산화물

Search Result 273, Processing Time 0.024 seconds

Preparation of Castable Refractories by Recycling of Aluminum Dross (알루미늄드로스를 재활용한 캐스타블내화물 제조)

  • Park Hyungkyu;Lee Hooin;Lee Jinyoung
    • Resources Recycling
    • /
    • v.12 no.3
    • /
    • pp.46-53
    • /
    • 2003
  • Recycling of aluminum dross is an important issue in the secondary aluminum industries. In this study, aluminum dross generated in the domestic secondary aluminum industry was processed to use it as raw material for producing alumina refractories. Sample dross was classified according to its size. The dross smaller than 1 mm was leached with sodium hydroxide solution to extract the remained aluminum from the dross into the solution. and then aluminum hydroxide precipitate was recovered from the leach liquor. The waste residue in the leaching was washed, dried and roasted. Most remained metallic components in the residue was changed into oxide through the processes. The roasted dross was made into alumina castable refractories by mixing with aggregates and a binder. Bending strength of the tested castable specimen was over $25\;kg/\textrm{m}^2$ and compressive strength over $80\;kg/\textrm{cm}^2$, which satisfied the Korean Standard value respectively. From the results, it was suggested that this process could be applicable to recycling of aluminum dross.

Properties of Porphyran and Hemicellulose extracted with Different extract Solutions and Enzymatic Pretreatments from Porphyra (추출 용매 및 효소 전처리 방법에 따른 포피란과 헤미셀루로오즈의 특성)

  • AN, Se-Ra;KOO, Jae-Geun
    • Journal of Fisheries and Marine Sciences Education
    • /
    • v.29 no.1
    • /
    • pp.108-117
    • /
    • 2017
  • Laver, Porphyra, is distinctive for its high content of proteins and polysaccharides such as porphyran and hemicellulose. The chemical properties of the polysaccharides extracted with different extraction methods such as hot water, dilute acid(pH 4.0) or alkali solution(2N NaOH) were examined to investigate the suitable extraction conditions for porphyran and hemicellulose from laver. For porphyran extraction, dilute acid solution was more preferable to hot water and alkali solution because of its higher 3,6-anhydrogalactose content and lower protein content. However, alkali solution was more suitable to extract the hemicellulose because of higher mannose content indicating the extraction of mannan. To decrease contamination of the polysaccharides with protein, the dried lavers were pretreated with enzymes (Protamex, Flavourzyme, Alcalase, Viscozyme) before hot water extraction. All enzyme pretreatments increased the yield of polysaccharides by compared with control (enzyme unpretreated) and Flavourzyme pretreatment was most effective to decrease protein contamination in the polysaccharide. All viscosities of porphyran solutions pretreated by enzymes were lower compared to the control porphyran solution and showed pseudoplastic behavior with yield stress. In case of alkali extraction of residues obtained after enzyme hydrolysis and hot water extraction, protease pretreatment increased the mannose contents in the polysaccharide while the xylose content was increased by Viscozyme pretreatment.

Fabrication of Mg(OH)2 from Ferro-Nickel Slag (페로니켈 슬래그를 이용(利用)한 수산화(水酸化)마그네슘 제조방법(製造方法))

  • Park, Soo Hyun;Chu, Yong Sik;Song, Hun;Lee, Jong Kyu;Seo, Sung Kwan
    • Resources Recycling
    • /
    • v.22 no.1
    • /
    • pp.42-47
    • /
    • 2013
  • Ferro-Nickel slag is a byproduct of Ferro-Nickel manufacturing process. Ferro-Nickel slag mostly discarded or used as aggregates despite having useful ingredients such as magnesium oxide and silicon oxide. This study tried to extract process for Mg ion using $H_2SO_4$ solution. And remove impurities and get high purity $Mg(OH)_2$ using NaOH. Mg ion was extracted with the Fe ion and other Ferro-Nickel slag composition by $H_2SO_4$ solution. It is important to control the pH because remove impurities and obtain high-purity $Mg(OH)_2$. The impurities were removed by precipitation of the hydroxides. After this process, we added NaOH and high-purity $Mg(OH)_2$ was obtained.

Treatment of high hexavalent chromium plating wastewater (고농도 6가 크롬 도금 폐수 처리)

  • Kang, Chang Duk;Sim, Sang Jun;Hwang, Suk Hoon
    • Clean Technology
    • /
    • v.7 no.1
    • /
    • pp.75-80
    • /
    • 2001
  • In this study, hexavalent chromium (Cr(VI)) plating wastewater in strong acidic condition was treated by reduction and alkalization. Ferrous sulfate ($FeSO_4$), known to reduce Cr(VI) to Cr(III) rapidly at acidic pH, was used as a reductant of Cr(VI). The optimum reduction condition of Cr(VI) was observed at iron to chromium dose ratio of 3:1 by mole concentration. The precipitation of Cr(III) as $Cr(OH)_3$, was achieved by the pH adjustment in the limestone aeration bed. The precipitates were removed less than the upper limit of chromium for effluent at pH over 5.0. The continuous removal of Cr(VI) was performed using the process consisting of reduction vessel, limestone aeration bed, and sedimentation tank coupled with metal screen membrane. As pH was maintained around 5.0 in the limestone aeration bed, insoluble chromic hydroxide flocs was formed continuously. Most chromic hydroxide flocs were filtered by the metal screen membrane with 1450 mesh size, and the treated water to meet the upper limits of chromium for effluent (Cr Conc. 0.25~0.90 mg/l) was obtained in 30 minutes. Periodic backwashing decreased the fouling on the membrane rapidly.

  • PDF

The Effect of Freezing and Filter Cake Drying Process on the Preparation of Ba-Ferrite by Coprecipitation (동결 및 Filter Cake 건조과정이 공침법에 의한 Ba-ferrite제조에 미치는 영향)

  • 이병우;오근호
    • Journal of the Korean Crystal Growth and Crystal Technology
    • /
    • v.1 no.1
    • /
    • pp.100-106
    • /
    • 1991
  • Ba.Fe - hydroxide precipitates were obtained by the variation of pH levelsm, which process was based on the calculated solubility from the solubility product(Ksp). Single phase $BaFe_12O_19$ was synthesized above $790^{\circ}C$. The 98% of theoretical density was obtained in the specimens formed from the filter cake drying and the hand pressing at temperatures $95^{\circ}C$ and $1,100^{\circ}C$ for 2hrs, respectively. The feezing of colloidal coprecipitate suspension formed powders up to several tens of micron size, which led to reduce the filtration time and the consumption of distilled water.

  • PDF

Evaluating Cadmium Ion Removal in Aqueous Solutions and Cytotoxicity Evaluation of Carbon, Synthesized Layered Double Hydroxide, and Multi-wall Carbon Nanotube (활성탄, 합성 층상이중층 수산화물, 카본나노튜브를 이용한 수용액상의 카드뮴의 제거와 흡착제 독성 연구)

  • Kim, Tae-Gyung;Park, Bog-Soung;Jung, Yong-Jun
    • Journal of Korean Society on Water Environment
    • /
    • v.33 no.2
    • /
    • pp.211-218
    • /
    • 2017
  • This experiment was carried out with the purpose of testing cadmium adsorption abilities of multi wall carbon nanotube (MWCNT), activated carbon, and synthesized layered double hydroxide (LDH). In the acidic condition, only MWCNT was effective for removing cadmium ion in the aqueous phase while other adsorbents rarely removed it. The MWCNT and cadmium ion adsorption reactions followed pseudo-first order kinetic. When the initial pH value was neutral (pH = 7), cadmium ion was rapidly removed by MWCNT and activated carbon in 4 hr (100% and 99.2%, respectively). Increasing adsorbent dosages affects the pH evolution and cadmium ion removal (0 to 99%). Cytotoxicity test showed that both MWCNT and LDH has low cytotoxic effects on three kind of human cells (A549, HS-294t, and HT-29).

Mechanical Properties of Epoxy-Modified Mortars and Concretes without Hardener (경화제 무첨가 에폭시 시멘트 모르터 및 콘크리트의 역학적 성질)

  • 조영국;소양섭
    • Magazine of the Korea Concrete Institute
    • /
    • v.8 no.3
    • /
    • pp.157-165
    • /
    • 1996
  • The purpose of this study is to develop the epoxy-modified mortars and concretes without hardener having a good balance between performance and cost. In this study, the epoxy-modified and concretes without and with the hardener are prepared with various polymer-cement ratios, and tested for the mechanical properties of the epoxy-modified mortars and concretes without and with the hardener. From the test results, the epoxy-modified mortars and concretes without the hardener having an excellent mechanical properties are developed at low polymer-cement ratios of 10 to 20% compared with those of conventional epoxy-modified mortars and concretes with the hardener.

Preparation and Characterization of OXI-PAN Based Carbon Fibers Activated by Hydroxides (수산화물에 의해 활성화된 OXI-PAN계 섬유의 제조 및 특성)

  • Moon, Sook-Young;Han, Dong-Yun;Lee, Byung-Ha;Lim, Yun-Soo
    • Journal of the Korean Ceramic Society
    • /
    • v.42 no.7 s.278
    • /
    • pp.469-474
    • /
    • 2005
  • Activated Carbon Fibers (ACFs) are widely used as adsorbents in technologies related to pollution abatement due to their highly porous structure and large adsorption capacity. The porous structure and surface area of ACFs depends strongly on both the activation processes arid the nature .of the precursors. The chemical activation with hydroxides has recently been, of great interest as it permits the preparation of activated carbon fibers with highly developed porosity. In this work, OXI-PAN fiber used as precursor for the preparation of activated carbon fibers by chemical activation with KOH and NaOH. The affects of several activation conditions on the surface properties, pore size distribution and adsorption capacity of Ag ion and Iodine ion on ACFs studied.

Synthesis of (${Ba_{1.3}}{Al_{12}}{O_{19}}$:$Mn^{2+}$) by Ultrasonic Spray Pyrolysis and Effect of Precursor Type on Morphology and Photoluminescence (초음파 분무 열분해법에 의한 바륨 헥사알루미네이트(${Ba_{1.3}}{Al_{12}}{O_{19}}$:$Mn^{2+}$) 제조 및 전구체 종류에 따른 형성과 발광 특성)

  • 김경화;강윤찬;김창해;박희동;최세영
    • Journal of the Korean Ceramic Society
    • /
    • v.38 no.2
    • /
    • pp.173-178
    • /
    • 2001
  • 본 연구에서는 PDP용 녹색 형광체의 대안인 $Ba_{1.3}$A $l_{12}$ $O_{19}$:$Mn^{2+}$ 분말을 초음파 분무 열분해법으로 합성하였으며 활성제인 $Mn^{2+}$의 첨가량과 모체를 구성하는 바륨 및 알루미늄의 전구체 물질들의 조합을 변화시킴으로써 형광체 분말의 형태 및 발광특성을 조절하였다. 최적의 발광 휘도를 나타내는 $Mn^{2+}$의 농도는 0.25몰을 첨가하였을 때이며 녹색 발광 영역인 517nm에서 최대 발광 효율을 나타내었다. 바륨의 전구체 물질로는 초산염, 질산염, 염화물 및 수산화물을 사용하였으며 알루미늄 전구체 물질로는 질산염 및 염화물을 사용하였다. 전구체는 합성된 분말의 형상에 영향을 미치는데 구형을 유지하거나 혹은 뭉치거나 구형이 깨지는 등 전구체 조합에 따라 얻어지는 분말의 형태가 달라졌다. 합성된 형광체 분말들은 일반적인 고상 반응의 온도보다 낮은 열처리 온도인 140$0^{\circ}C$, 5시간 유지에서는 좋은 VUV 발광 특성을 가졌다. 또한 전구체의 조합은 형광체 발광 효율에도 영향을 미치는데 바륨과 알루미늄은 염화물을, 망간은 질산염을 사용하였을 때 가장 좋은 발광 휘도를 나타내었다.다.다.다.

  • PDF

Chemical Analysis of Fly Ashes from Municipal Solid Waste Incinerators (생활폐기물 처리시설 배출 비산재의 조성분석)

  • Jang, Seong-Ki;Choi, Duk-Il;Lim, Chang-Ho;Lee, Jin-Sook
    • Analytical Science and Technology
    • /
    • v.13 no.2
    • /
    • pp.215-221
    • /
    • 2000
  • Analysis of fly ashes from the MSW incinerators was carried out using XRF, ICP-MS and ICP-AES. It was found that the major elements of fly ash were Ca, K, Na, Si, Al, S, Cl and O by the XRF analysis. The XRD spectra showed that the fly ashes were mainly consisted with the chlorides, hydroxides, carbonates and also oxides of former elements. For the determination of minor elements such as Zn, Pb, Cu, Cr, and Cd, we used ICP-AES and ICP-MS after microwave digestion and the results were compared with the result of XRF.

  • PDF