• Title/Summary/Keyword: 수산화나트륨

Search Result 228, Processing Time 0.041 seconds

Fine Structure and Physical Properties of Cotton Fibers and their Fabrics Treated with Liquid Ammonia, NaOH, and NaOH/Liquid Ammonia (액체암모니아, 수산화나트륨, 수산화나트륨/액체암모니아 처리한 면의 미세구조 및 물성)

  • 배소영;이문철;김홍성;이영희;김경환
    • Textile Coloration and Finishing
    • /
    • v.6 no.2
    • /
    • pp.47-54
    • /
    • 1994
  • Cotton fiber, NaOH-mercerized cotton fiber, cotton fabric, and NaOH-mercerized cotton fabric have been treated by liquid ammonia at -33.4$^{\circ}C$. The fine structures, bending properties, tensile strengthes, shrinkages for laundering, and wrinkle recoveries were studied. The treatment of cottons with liquid ammonia brought about the transition of crystal lattice ; transforming cellulose I crystal of original cotton to cellulose I and III crystal, and cellulose II crystal of mercerized cotton to cellulose II and III crystals. The degree of crystallinities were decreased in the order of liquid ammonia>NaOH/liquid ammonia>NaOH-treated cotton. However moisture regain and water absorbency for liquid ammonia-treated cotton were lower than that of NaOH-treated cotton because of a difference in swelling actions of the agents. It seems caused by intermicrofibrillar pores produced in swelling processes. The bending rigidity and bending hysteresis were decreased remarkly by liquid ammonia treatment. Therefore softness and dimensional stability were improved. The liquid amminia and NaOH/liquid ammonia-treated cottons moreover show excellent properties in tensile strength, anti-shrinkage for laundering, and wrinkle recovery.

  • PDF

Dyeing Behavior of Cotton Fibers Treated with Liquid Ammonia, NaOH, and NaOH/Liquid Ammonia (액체암모니아, 수산화나트륨, 수산화나트륨/액체암모니아 처리한 면의 염색성)

  • 배소영;이문철;김홍성;이영희;김경환
    • Textile Coloration and Finishing
    • /
    • v.6 no.3
    • /
    • pp.1-7
    • /
    • 1994
  • Cotton fiber and NaOH-mercerized cotton fiber had been treated by liquid ammonia and were dyed with two direct dyes, C.I. Direct Red 2 and Blue 1. The effect of the treatment on the rate of dyeing, dye adsorption isotherm, and affinity were studied. The rate of dyeing was increased in the order of NaOH-mercerized> NaOH/liquid ammonia-treated > liquid ammonia-treated>Untreated cotton irrespective of kind of dyes. The rate of dyeing for NaOH-treated fiber considerably increased, whereas liquid ammonia-treated or NaOH/liquid ammonia-treated did not because the structural transformation was not enough for the dyes to penetrate easily into the liquied ammonia-treated cottons. The time of half-dyeing was considerably reduced by mercerizing with NaOH, but lengthened by liquid ammonia treatment because of increased equilibrium dye exhaustion especially in dyeing with C.I. Dierect Red 2. In spite of a short time of the ammonia treatment for 4 seconds, the equilibrium exhaustions of both of direct dyes, C.I. Direct Red 2 and C.I. Direct Blue 1, were increased in proportion to internal volume of treated cotton under a condition of fixed affinity.

  • PDF

Compressive Strength and Optimal Mixing Ratio of Alkali Activated Cement Concrete Containing Fly Ash (플라이 애쉬를 활용한 알칼리 활성시멘트 콘크리트의 압축강도와 최적혼합비)

  • Han, Sang-Ho;Park, Sang-Sook;Kang, Hwa-Young
    • Journal of the Korea institute for structural maintenance and inspection
    • /
    • v.11 no.4
    • /
    • pp.152-158
    • /
    • 2007
  • This is a fundamental research to utilize alkali activated cement(AAC) in concrete. The compressive strength of AAC concrete were measured for the various mixing ratios of activator/fly ash, and the mixing ratios of water glass, NaOH, and water among the activators. The mixing ratio of fine and coarse aggregates was maintained constantly. The relationships between the compressive strength and mixing ratios were analyzed to find the optimal mixing ratio of AAC concrete. As the results, the optimal mixing ratio of activator/fly ash in AAC concrete was 0.7, and that of water glass, NaOH, water among the activator was 4.0:1.0:2.5 for the maximum compressive strength.

Dehydration of Alcohol Solutions Through Crosslinked Chitosan Composite Membranes III. Effects of Substrate, Neutralization and Active Layer Thickness on Pervaporation of Water/Ethanol Mixture (가교키토산 복합막을 통한 알콜수용액의 탈수 III. 화학가교시 지지체, 중화에 의한 효과와 이온가교시 활성층두께 변화에 의한 효과)

  • 이영무;남상용;유제강;류경옥
    • Membrane Journal
    • /
    • v.6 no.4
    • /
    • pp.250-257
    • /
    • 1996
  • Surface crosslinked chitosan composite membranes were prepared with glutaraldehyde and surfuric acid. Effects of neutralization for complex between chitosan and acetic acid and of water permeability for substrate membranes on pervaporation performance were investigated. For ionically crosskinked membranes, effect of active layer thickness on separation factor of water/ethanol mixture was studied. With increasing the water permeability of the substrate, the membrane showed an increased separation factor, while it maintained a constant permeate flux. Neutralized chitosan composite membranes revealed a decreased separation factor and a constant permeate flux. When the thickness of the active layer increased, an optimum crosslinking time to achieve higher separation factor shifted to a prolonged times.

  • PDF

Mechanical Properties of the Alkali-Activated Slag Mortar with Gypsum (석고를 혼합한 알칼리 활성화 슬래그 모르타르의 특성)

  • Kim, Tae Wan;Hahm, Hyung Gil
    • Journal of the Korea institute for structural maintenance and inspection
    • /
    • v.16 no.3
    • /
    • pp.109-116
    • /
    • 2012
  • This study investigated the effects of blast furnace slag mortars activated with sodium hydroxide(NaOH) and gypsum in relation to flow, setting time and compressive strength. The parameters in this studied was the gypsum ratio 0 to 50%, 3M and 6M of activator concentration and $20{\pm}2^{\circ}C$ and $35{\pm}2^{\circ}C$ of curing temperatures. The results of flow was increase, setting time was increase as the amount of gypsum increases. But the results of compressive strength was dependent on the gypsum ratio, indicating that the compressive strength increased with the increase of the amount of gypsum until a certain limit, beyond which the strength decreased quickly.

Effects of Ni and Rh on the Structural Changes in Synthesis of the Spinel Type $Fe_3O_4$ (Spinel형 $Fe_3O_4$의 합성시 구조변화에 미치는 Ni 및 Rh의 영향)

  • Park Young Goo
    • Journal of the Korean Institute of Gas
    • /
    • v.2 no.2
    • /
    • pp.40-47
    • /
    • 1998
  • This study describes a synthesis of spinel-type $Fe_3O_4$ for decomposition of carbon dioxide, using $Fe_3O_4$ $7H_2O$ and NaOH, at $40^{\circ}C$ for 20 h. with change of their chemical equivalent ratio from 0.50 to 0.75, 1.00, 1.25 and 1.50, respectively. Addition of 0.1-1.00 mole percentage $NiCl_2,\;RhCl_3$ to the particles of $Fe_3O_4$, Prepared by reacting chemical equivalent ratio 1.00, afforced spinel $Fe_3O_4$. The structure of $Fe_3O_4$ and $NiCl_2,\;RhCl_3$-added $Fe_3O_4$ was investigated with XRD and SEM, respectively.

  • PDF

Simultaneous Removal Characteristics of NOx, SOx from Combustion Gases using Pulse Corona induced Plasma Chemical Processing (PPCP에 의한 연소가스 중 NOx, SOx 동시제거 특성)

  • Park, Jae-Yoon;Koh, Yong-Sul;Jung, Jang-Gun;Kim, Jung-Dal
    • Journal of Korean Society of Environmental Engineers
    • /
    • v.22 no.2
    • /
    • pp.211-216
    • /
    • 2000
  • In this paper, experimental investigations were carried out to remove NOx, SOx simultaneously from a simulated combustion flue gas [$NO(0.02%)-SO_2(0.08%)-CO_2-Air-N_2$] by using a pulse corona induced plasma chemical processing. Discharge domain of wire-cylindrical plasma reactor was separated from a gas flow duct to avoid unstable discharge by aerosol particle deposited on discharge electrode and grounded electrode. The NOx, SOx removal was experimentally investigated by a reaction induced to ammonium nitrate, ammonium sulfate using a low price of aqueous NaOH solution and a small quantity of ammonia. Volume percentage of aqueous NaOH solution used was 20% and $N_2$ flow rate was $2.5{\ell}/min$ for bubbling aqueous NaOH solution. Ammonia gas(l4.82%) balanced by argon was diluted by air and was introduced to a main simulated flue gas duct through $NH_3$ injection system which was in downstream of reactor. The $NH_3$ molecular ratio(MR) was determined based on [$NH_3$] and [$NO+SO_2$]. MR is 1.5. The NOx removal rates increased in the order of DC, AC and pulse, but SOx removal rates was not significantly effected by source of electricity. The NOx removal rate slightly decreased with increasing initial concentration. but SOx removal rate was not significantly affected by initial concentration. The NOx, SOx removal rates decreased with increasing gas flow rate.

  • PDF

A Study on Cementation of Sand Using Blast Furnace Slag and Extreme Microorganism (고로슬래그와 극한미생물을 이용한 모래의 고결화 연구)

  • Park, Sung-Sik;Choi, Sun-Gyu;Nam, In-Hyun
    • Journal of the Korean Geotechnical Society
    • /
    • v.30 no.1
    • /
    • pp.93-101
    • /
    • 2014
  • In this study, a blast furnace slag having latent hydraulic property with an alkaline activator for resource recycling was used to solidify sand without using cement. Existing chemical alkaline activators such as $Ca(OH)_2$ and NaOH were used for cementing soils. An alkaliphilic microorganism, which is active at higher than pH 10, is tested for a new alkaline activator. The alkaliphilic microorganism was added into sand with a blast furnace slag and a chemical alkaline activator. This is called the microorganism alkaline activator. Four different ratios of blast furnace slag (4, 8, 12, 16%) and two different chemical alkaline activators ($Ca(OH)_2$ and NaOH) were used for preparing cemented specimens with or without the alkaliphilic microorganism. The specimens were air-cured for 7 days and then tested for the experiment of unconfined compressive strength (UCS). Experimental results showed that as a blast furnace slag increased, the water content and dry density increased. The UCS of a specimen increased from 178 kPa to 2,435 kPa. The UCS of a specimen mixed with $Ca(OH)_2$ was 5-54% greater than that with NaOH. When the microorganism was added into the specimen, the UCS of a specimen with $Ca(OH)_2$ decreased by 11-60% but one with NaOH increased by 19-121%. The C-S-H hydrates were found in the cemented specimens, and their amounts increased as the amount of blast furnace slag increased through SEM analysis.