• Title/Summary/Keyword: 소성환경

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Recovery of Alumina from the First Calcined Waste Pottery (1차소성 폐도자기로부터 알루미나 회수)

  • 김재용;서완주;이진수;박수길;엄명헌
    • Journal of environmental and Sanitary engineering
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    • v.15 no.1
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    • pp.62-68
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    • 2000
  • This study was investigated to the recovery of alumina from the first calcined waste pottery using alkaline sintering. This study was based on calcination result of a commercial ${\alpha}-Al2_O_3$ with NaOH powder. $NaAlO_2$ was formed by calcination of ${\alpha}-Al_2O_3$ with NaOH and conversion of $NaAlO_2$ from ${\alpha}-Al_2O_3$ was 91.4% at calcination condition ; weight ritio of $NaOH/{\alpha}-Al2_O_3$ 1.5, $800^{\circ}C$, and 90min. The first calcined waste porrery from the manufacturing Procedure of H Ltd. was grinded to 170/270mesh by a ball mill and calcined over $500^{\circ}C$ with NaOH powder. The calcined sample was dissolved in $25^{\circ}C$ water and sodiumaluminosilicate solid was formed. After filtration, the contained aluminum was leached out by dissolving sodiumaluminosilicate solid in 1N HCl. We estimated the efficiency of Al extraction from waste pottery by ICP analysis and NaOH was added to the filtrate and then aluminum compound was precipitated with $Al(OH)_3$ and recovered. The investigation was carried out with the variables ; the calcination temperature($500-900^{\circ}C$), the calcination time(30~90min), and the weight ratio of NaOH/waste pottery(0.5~1.5). The treatment efficiency of the waste pottery and the recovery of Al as 97.9%, 91.9% were obtained under the optimum conditions as followed ; the weight ratio of NaOH/waste pottery was 1.5 and the calcination conditions were $900^{\circ}C$ and 60min.

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Stabilization of As in Soil Contaminated with Chromated Copper Arsenate (CCA) Using Calcinated Oyster Shells (목재방부제(CCA) 오염토양의 소성가공 굴껍질을 이용한 비소 안정화)

  • Moon, Deok-Hyun;Cheong, Kyung-Hoon;Kim, Tae-Sung;Khim, Jee-Hyeong;Choi, Su-Bin;Moon, Ok-Ran;Ok, Yong-Sik
    • Korean Journal of Environmental Agriculture
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    • v.28 no.4
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    • pp.378-385
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    • 2009
  • Arsenic (As) is known to be very toxic and carcinogenic to human beings. Arsenic contaminated soil was collected from a timber mill site at Busan Metropolitan City, Korea, where chromated copper arsenate (CCA) had been used to protect wood from rotting caused by insects and microbial agents. The soil was stabilized using both natural oyster shells (NOS) and calcinated oyster shells (POS). The calcination of natural oyster shells was accomplished at a high temperature in order to activate quicklime from calcite. Two different oyster shell particle sizes (-#10 mesh and -#20 mesh) and curing periods of up to 28 days were investigated. The stabilization effectiveness was evaluated based on the Korean Standard Test (KST) method (1N HCl extraction). The stabilization results showed that the POS treatment was more effective than the NOS treatment at immobilizing the As in the contaminated soils. A significant As reduction (96%) was attained upon a POS treatment at 20 wt% and passed the Korean warning standard of 20 mg/kg ('Na' area). However, an As reduction of only 47% (169 mg/kg) was achieved upon a NOS treatment at 20 wt%. The -#20 mesh oyster shells seem to perform better than the -#10 materials. The scanning electron microscopy (SEM)-energy dispersive X-ray spectroscopy (EDX) results showed that As immobilization was strongly associated with Ca and O in the presence of Al and Si.

3, 4성분계 DSA 전극의 제조와 성능 평가

  • Park, Yeong-Sik;Kim, Dong-Seok
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2008.11a
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    • pp.482-487
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    • 2008
  • 성능이 우수한 다성분계 전극을 개발하기 위하여 Ru를 주 전극성분으로 Pt, Sn, Sb 및 Gd를 보조 전극성분으로 하여 3, 4성분계 전극의 성능과 산화제 생성량 및 전극 표면 분석을 행하여 다음의 결과를 얻었다. 1. 2분 동안 단위 W당 제거된 RhB 농토는 Ru:Sn:Sb=9:1:1 > Ru:Pt:Gd=5:5:1 > Ru:Sn=9:1 > Ru:Sn:Gd=9:1:1 > Ru:Sb:Gd=9:1:1로 나타났다. Ru:Sn:Sb=9:1.1 전극에서 발생하는 free Cl, ClO$_2$ 및 H$_2$O$_2$농도가 다른 전극보다 높은 것으로 나타나 산화제 생성경향과 RhB 분해율과는 상관관계가 있는 것으로 사료되었다. 4성분계 전극 중에서 Ru:Sn:Sb:Gd 전극의 성능이 가장 우수한 것으로 나타났으나 3성분계 전극인 Ru:Sn:Sb=9:1.1 전극보다 성능이 떨어지는 것으로 나타났다. Ru:Sn:Sb=9:1:1 전극에서 생성되는 산화제 농도가 다른 두 종류의 산화제 농도보다 높은 것으로 나타났고 4성분 전극의 경우 Ru:Sn:Sb:Gd 전극의 산화제 농도가 Ru:Sn:Sb:Gd 전극이 높거나 유사한 경우로 나타나 산화제 생성 경향과 RhB분해 능과는 상관관계가 있는 것으로 나타났다. 초기 RhB 분해 속도가 높은 전극의 COD 제거율도 높은 것으로 나타났다. OH 라디칼은 발생하지 않지만 염소계 산화제 농도가 높고 RhB제거율이 높아 Ru를 주 성분으로 한 전극의 RhB분해는 주로 간접 산화작용에 의한 것이며, 개발된 3, 4성분계 산화물 전극은 간접 산화용 전극임을 알 수 있었다. 에칭을 하기 전의 Ti판은 표면이 매끄러운 것으로 나타났으며, 35% 염산으로 에칭한 후의 Ti메쉬는 매우 거친 표면조직을 가지는 것을 관찰할 수 있었다. Ru:Sn:Sb=9:1:1 전극과 Ru:Sn:Sb:Gd 전극의 SEM 사진을 관찰한 결과 두 전극 모두 전극 물질이 균일하게 도포되어 있었으며, 두 전극 모두 열소성을 통해 전극 성분을 코팅할 때 발생하는 "mud crack"이 발생한 것이 관찰되었다 EDX 분석에서 Cl이 관찰되었는데, 전극 성분의 불완전 산화로 인한 비양론적 산화물 때문이며 이는 RhB 분해성능과 관련 있는 것으로 사료되었다.

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A Study on the Mercury Emission Characteristic and Comparison Tests for Applicability of Latest Mercury Measuring Methods - Focus on the Cement Kiln - (시멘트 소성시설에서의 수은 배출특성 및 최신 측정방법 적용성 평가 연구)

  • Kim, Hyung-Chun;Kim, Hee-Jin;Kim, Jong-Hyeon;Kang, Dea-Il;Park, Jung-Min;Kim, Jeong-Hun
    • Journal of Korean Society for Atmospheric Environment
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    • v.33 no.3
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    • pp.241-250
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    • 2017
  • Recently, there has been growing interest in the emission characteristics and behavior of anthropogenic mercury compounds from emission sources. It is required to establish a standard for reliable mercury measurement method. Therefore, this study has evaluated the applicability of the new measurement method; Continuous Emission Monitoring (US EPA 30A, CEM). In addition, the reliability evaluation was conducted through Ontario Hydro Method (ASTM D6784, OHM) and Sorbent trap method (US EPA Method 30B). As a monitoring result for three months via CEM from cement kiln, the maximum mercury compounds concentration was about $600{\mu}g/Sm^3$. This is because of the various of raw materials and fuel, and the absence of mercury-control device. The mercury compounds concentrations of OHM, Sorbent trap and CEM were 13.64 $(3.33{\sim}32.41){\mu}g/Sm^3$, $13.94(5.97{\sim}23.44){\mu}g/Sm^3$ and $14.68(6.19{\sim}26.75){\mu}g/Sm^3$, respectively. The relative standard deviations (% RSD) of the three methods were 5.1~40.9%. The result of this study suggest that it is possible to apply the CEM in the cement kiln when, QA/QC such as calibration is verified.

RAPD Pattern of Radiation Induced Variants of Oyster Mushroom(Pleurotus ostreatus) (느타리(Pleurotus ostreatus)에서 방사선유기 변이주의 RAPD 양상)

  • Lee, Young-Keun;Chang, Hwa-Hyoung;Kim, Won-Rok;Kim, Jin-Kyu;Kim, Jae-Sung
    • Korean Journal of Environmental Agriculture
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    • v.17 no.3
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    • pp.195-199
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    • 1998
  • To induce the cellulolytic variants of oyster mushroom (Pleurotus ostreatus), basidiospores were irradiated at the dose of $1kGy{\sim}20kGy$ of gamma-ray. After irradiation, activities of extracellular enzymes were determined by the method of MUF residue and genetic similarity was observed by RAPD analysis of variants. Three variants of 2KG-1, 2KG-2 and 20KG-1 were clarified as highly cellulolytic isolates. It seemed that the difference of genetic similarity among variants have derived from gamma-ray radiation. It is suggested that 3 cellulolytic variants induced by gamma-ray in this experiment could play a useful role to reuse cellulosic bioresources.

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High-temperature Low-cycle Fatigue Life prediction of a Liquid Rocket Turbopump Turbine (액체로켓 터보펌프 터빈의 고열 저주기 피로수명 예측)

  • Lee, Mu-Hyoung;Jang, Byung-Wook;Jeong, Eun-Hwan;Jeon, Seong-Min;Lee, Soo-Yong;Park, Jung-Sun
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2009.05a
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    • pp.18-21
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    • 2009
  • The life of components under high thermal load is typically shorter than other components. The turbopump turbine of liquid rocket is operated under these environments like high temperature and high centrifugal dorce due to high rotating velocity during operating time. These conditions may often cause low-cycle fatigue problem in the turbopump turbine. First of all, to analyze heat stress, ABAQUS/CAE is used and Coffin-manson's equation is used to consider elasticity and plasticity strain. S.W.T's method is used to consider the mean stress effect, using strain history, low-cycle fatigue analysis is done for turbopump turbine which may have FCL(fracture critical location). In this paper, strain life method is applied to analyze low-cycle fatigue.

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Fundamental Studies on Stabilization of Shallow Slope Failure Using Lime Pile - Changes of Clayey Properties with Lime Addition - (생석회 파일을 이용한 얕은 사면 파괴의 안정화에 대한 기초 연구 - 생석회 첨가에 따른 점성토의 특성 변화 중심으로 -)

  • Kwon, Moonam;Goo, Jeungmin
    • Journal of the Korean GEO-environmental Society
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    • v.7 no.5
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    • pp.49-55
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    • 2006
  • Quick lime made from limestone that are deposited abundantly in Korea has excellent potentials for stabilization of clayey soils. If Korea is able to take advantage of its abundant supply, economical efficiency could be achieved through mass production as well as being able to take advantage of utilization of natural resources. For stabilizing of clayey soil with lime, it is necessary to determine the required quantities of lime firstly and to evaluate the degree of stabilization with lime content. In this test, the quantity of lime required for 2 clayey soils which located in Seunggok and Bugok province respectively, and for 2 clay minerals-kaolinite and montmorillonite-were determined by ASTM C 977-92 and were evaluated for solidification of each samples with changing lime contents by Atterberg limit test and pH test. It was also evaluated for the improvement of each sample with lime content and curing time. The sample which added lime content determined by ASTM C 977-92 increased plastic limit, unconfined compression strength, and decreased pH in increasing trend.

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Reproduction of Cyclic Triaxial Behavior of Unsaturated Soil using Element Simulation (요소 시뮬레이션에 의한 불포화토의 반복삼축거동 재현)

  • Lee, Chungwon
    • Journal of the Korean GEO-environmental Society
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    • v.16 no.10
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    • pp.5-14
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    • 2015
  • Suction affects the unsaturated soil as the negative pore pressure, and leads to increases of the yield stress and the plastic shear stiffness of the soil skeleton due to the growth in interparticle stress. Hence, in this study, in order to account for these effects of suction under the dynamic loading condition such as the earthquake, the element simulation of the cyclic triaxial test using induced stress-strain relation based on cyclic elasto-plastic constitutive model extended for unsaturated soil considering the $1^{st}$ and the $2^{nd}$ yield functions was conducted. Through the stress path, stress-strain relation and relation between volumetric strain and axial strain, it was seen in all the cases that the simulation results demonstrated a good agreement with the experimental results. It is expected that the results of this study possibly contribute to the accuracy improvement on the prediction of unsaturated soil behavior under the dynamic loading condition.

Study on the Physical Properties of the Artificial Lightweight Aggregate Recycled from the Dyestuff Sludge Treated Chemically With Ti and Fe Salt (Ti염 및 Fe염으로 화학처리된 염색공단 슬러지를 재활용한 인공경량골재의 물리적 특성에 관한 연구)

  • Choi, Jong-Oh;Jung, Yong-Wook
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.3 no.1
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    • pp.34-42
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    • 2015
  • The paper investigates environmental hazards and characteristics of the artificial lightweight aggregate manufactured by using dyestuff sludge from dyeing industrial complex. The dyestuff sludge used in this study is chemically treated with Ti and Fe salt for the purpose of recycling. The artificial lightweight aggregate is manufactured through 3 step; 1) Selecting the optimum moisture content by evaluating plasticity from the mixing ratio of the clay and sludge, 2) shaping round type based on the optimum mixing ratio, 3) drying and Sintering process. Based on KS F 2534 "Lightweight Aggregate for Structural concrete", the particle size, fineness modulus, the density, absorption, unit volume weight, stability and environmental hazards of the manufactured lightweight aggregate are evaluated. Experimental results show that the particle size and fineness modulus is out of the range. However, it is observed that other physical properties are within criteria. In addition, it is confirmed that the problem of the particle size and fineness modulus could be solved in the manufacturing process.

Effect of Stiffener's Web Height against Axial Compression Ultimate Strength Considering Lateral Pressure Load (횡하중을 고려한 압축최종강도에 대한 보강재 치수의 영향)

  • Oh, Young-Cheol;Ko, Jae-Yong;Oh, Dong-Ki
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.14 no.1
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    • pp.89-93
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    • 2008
  • Stiffened panels are basic strength members which have been used widely in a vessel or an offshore. They have been used often a deck, a side and a bottom structure of ship and have a number of one sided stiffener in either one or both directions called grillage. Their buckling and plastic collapse become damaged reason of the hull girder so it needs to investigate accurately buckling and ultimate strength of stiffened panels. In the present paper, using the ANSYS, a commercial finite element analysis code, we conducted the evaluation regarding buckling and post-buckling behaviour of stiffened panels, and analyzed stiffener's web height change, considering the effect of lateral pressure load against compression ultimate strength.

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