• Title/Summary/Keyword: 소성안정

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n-type 결정질 태양전지의 Si 표면과 Ag/Al 사이의 Contact formation 형태론

  • O, Dong-Hyeon;Jeon, Min-Han;Gang, Ji-Yun;Jeong, Seong-Yun;Park, Cheol-Min;Lee, Jun-Sin;Kim, Hyeon-Hu
    • Proceedings of the Korean Vacuum Society Conference
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    • 2015.08a
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    • pp.122.2-122.2
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    • 2015
  • n-type 실리콘은 p-type과 비교하여 더 높은 소수캐리어 lifetime 으로 금속 불순물에 대하여 더 좋은 내성을 갖는다. 고효율 실리콘 태양전지를 위하여 p-type 웨이퍼를 n-type으로 교체하여 빛을 조사했을 때, 광전자들이 형성되어 p-type과 비교하여 더 좋은 lifetime 안정성을 갖는다. n-type 태양전지의 전면 전극은 AgAl paste로 형성하였다. AgAl 페이스트는 소성 온도와 밀접하게 관련되어 전극의 접합 깊이에 영향을 미친다. p+ emitter 층에 파고드는 금속 접촉의 최적화된 깊이는 접촉 저항에 영향을 미치는 중요한 요소이다. 본 연구에서는 소성 조건을 변화시킴으로써, 금속 깊이의 효과적인 형성을 위한 소성 조건을 최적화하였다. $670^{\circ}C$ 이하의 온도에서 소성을 진행 하였을 때, 충분한 접촉 깊이를 형성하지 못하여 높은 접촉저항을 갖는다. 소성 온도가 증가함에 따라, 접촉 저항은 감소하였다. 최적 소성 온도 $865^{\circ}C$에서 측정된 접촉저항은 $5.99mWcm^2$이다. $900^{\circ}C$ 이상에서 contact junction은 emitter를 통과하여 실리콘과 결합하였다. 그 결과로 접촉저항 shunt가 발생한다.

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Structural analysis of liquid rocket thrust chamber regenerative cooling channel using visco-plastic model (점소성 모델을 이용한 액체로켓 연소기 재생냉각 채널 구조해석)

  • Ryu Chul-Sung;Choi Hwan-Seok
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2006.05a
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    • pp.151-155
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    • 2006
  • Elastic-viscoplastic structural analysis is performed for regenerative cooling chamber of liquid rocket thrust chamber using Bodner-Partom visco-plastic model. Strain rate test was also conducted for a copper alloy at various temperatures in order to get material constants of visco-plastic model used in the structural analysis. Material constants of visco-plastic model were obtained from strain rate test results and visco-plsstic model was incorporated into finite element program, Marc, by means of user subroutine. The structural analysis results indicate that the deformation of cooling channel is mostly caused by thermal loading rather than pressure loading and confirmed structural stability of the cooling channel under operating condition.

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Texture Evolutions in Al sheet during the deep drawing process (Al 판재의 디프 드로잉 공정에서의 집합조직 변화 고찰)

  • 조재형;최시훈;오규환
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 1997.03a
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    • pp.303-306
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    • 1997
  • $\alpha$형과 $\beta$형 섬유조직의 압연 집합조직을 초기 집합조직으로 갖는 알루미늄 판재의 디프드로잉 공정시 집합조직 변화를 고찰하였다. 플랜지 변형 단계에서는 Bs성분은 감소하 였으며, Goss, Cu, P등의 성분들은 증가하였다. 컵의 윗쪽에서는 아랫쪽에 비하여 Goss, Cu 성분은 증가하고 P성분의 변화는 적었다. 이는 컵의 윗쪽에서는 플랜지에서 받은 평면변형 의 정도가 컵의 아랫쪽에 비하여 크기 때문이다. 실제 디프드로잉 공정에서의 변형량에서는 결정들이 안정방위로의 회전경로인 $\alpha$D형의 섬유와 $\beta$D형의 섬유로 이동하게 된다.

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Study on the Mechanical Stability of Red Mud Catalysts for HFC-134a Hydrolysis Reaction (HFC-134a 가수분해를 위한 Red mud 촉매 기계적 안정성 향상에 관한 연구)

  • In-Heon Kwak;Eun-Han Lee;Sung-Chan Nam;Jung-Bae Kim;Shin-Kun Ryi
    • Clean Technology
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    • v.30 no.2
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    • pp.134-144
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    • 2024
  • In this study, the mechanical stability of red mud was improved for its commercial use as a catalyst to effectively decompose HFC-134a, one of the seven major greenhouse gases. Red mud is an industrial waste discharged from aluminum production, but it can be used for the decomposition of HFC-134a. Red mud can be manufactured into a catalyst via the crushing-preparative-compression molding-firing process, and it is possible to improve the catalyst performance and secure mechanical stability through calcination. In order to determine the optimal heat treatment conditions, pellet-shaped compressed red mud samples were calcined at 300, 600, 800 ℃ using a muffle furnace for 5 hours. The mechanical stability was confirmed by the weight loss rate before and after ultra-sonication after the catalyst was immersed in distilled water. The catalyst calcined at 800 ℃ (RM 800) was found to have the best mechanical stability as well as the most catalytic activity. The catalyst performance and durability tests that were performed for 100 hours using the RM 800 catalyst showed thatmore than 99% of 1 mol% HFC-134a was degraded at 650 ℃, and no degradation in catalytic activity was observed. XRD analysis showed tri-calcium aluminate and gehlenite crystalline phases, which enhance mechanical strength and catalytic activity due to the interaction of Ca, Si, and Al after heat treatment at 800 ℃. SEM/EDS analysis of the durability tested catalysts showed no losses in active substances or shape changes due to HFC-134a abasement. Through this research, it is expected that red mud can be commercialized as a catalyst for waste refrigerant treatment due to its high economic feasibility, high decomposition efficiency and mechanical stability.

Structural Analysis of Liquid Rocket Thrust Chamber Regenerative Cooling Channel using Bodner-Partom Viscoplastic Model (Bodner-Partom 점소성 모델을 이용한 액체로켓 연소기 재생냉각 채널 구조해석)

  • Ryu, Chul-Sung;Baek, Un-Bong;Choi, Hwan-Seok
    • Journal of the Korean Society of Propulsion Engineers
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    • v.10 no.4
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    • pp.69-76
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    • 2006
  • Elastic-viscoplastic structural analysis has been performed for regenerative cooling chamber of liquid rocket thrust chamber using Bodner-Partom visco-plastic model. Strain rate test was conducted for a copper alloy at various temperatures in order to get material constants of visco-plastic model used in the structural analysis. Material constants of visco-plastic model were obtained from strain rate test results and visco-plastic model was incorporated into finite element program, Marc, by means of a user subroutine. The structural analysis results indicated that the deformation of cooling channel is mostly caused by thermal loading rather than pressure loading and confirmed structural stability of the cooling channel under the operating condition.

Applicability of Color Bituminous Mixtures for Highway Pavement (차도용 칼라 역청 혼합물의 적용성 연구)

  • Doh, Y.S.;Oh, S.K.;Choi, Y.K.;Kim, K.W.
    • International Journal of Highway Engineering
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    • v.6 no.4 s.22
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    • pp.91-100
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    • 2004
  • This study was Performed to evaluate applicability of color flexible pavement concrete (CFPC) for motorway pavement. Color flexible pavement has been applied to non-motorway pavements, such as pedestrian and bicycle road. Two polymers were used to modify the binder and to strengthen the stiffness of pavement mixture. Waste paper was used to prevent the asphalt of gap-grade mixture from draining. Marshall properties, indirect tensile strength(ITS), tensile strength ratio(TSR) before and after freezing-and-thawing treatment and artificial aging, permanent deformation and fatigue life were measured. Color bituminous concrete mixtures used this study had nearly the same quality in mechanical properties when compared with conventional asphalt concrete mixtures manufactured with AP-3 and all mixtures satisfied with domestic specification for motorway pavement. Therefore, it is proved that the color bituminous concrete used this study can be applied for motorway pavement.

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Realistic Cloth Simulation using Plastic Deformation (소성변형특성을 이용한 사실적인 직물 시뮬레이션)

  • Oh Dong-Hoon;Jung Moon-Ryul;Song Chang-Geun;Lee Jong-Wan
    • Journal of KIISE:Computing Practices and Letters
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    • v.12 no.3
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    • pp.208-217
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    • 2006
  • This paper presents a cloth simulation technique that implements plastic deformation. Plasticity is the property that material does not restore completely to the original state once deformed, in contrast to elasticity. We model cloth using a particle model, and posit two kinds of connections between particles, i.e. the sequential connections between immediate neighbors, and the interlaced connections between every other neighbors. The sequential connections represent the compression and tension of cloth, and the interlaced connections the bending in cloth. The sequential connections are modeled by elastic springs, and the interlaced connections by elastic or plastic spring depending on the amount of the current deformation of the connections. Our model is obtained by adding plastic springs to the existing elastic particle model of cloth. Using the new model, we have been able to simulate bending wrinkles, permanently deformed wrinkles, and small wrinkles widely distributed over cloth. When constructing elastic and plastic spring models for sequential and interlaced connections, we took pain to prevent the stiffness matrix of the whole cloth system from being indefinite, in order to help achieve physical stability of the cloth motion equation and to improve the effectiveness of the numerical method.

J2-bounding Surface Plasticity Model with Zero Elastic Region (탄성영역이 없는 J2-경계면 소성모델)

  • Shin, Hosung;Oh, Seboong;Kim, Jae-min
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.43 no.4
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    • pp.469-476
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    • 2023
  • Soil plasticity models for cyclic and dynamic loads are essential in non-linear numerical analysis of geotechnical structures. While a single yield surface model shows a linear behavior for cyclic loads, J2-bounding surface plasticity model with zero elastic region can effectively simulate a nonlinearity of the ground response with the same material properties. The radius of the yield surface inside the boundary surface converged to 0 to make the elastic region disappear, and plastic hardening modulus and dilatancy define plastic strain increment. This paper presents the stress-strain incremental equation of the developed model, and derives plastic hardening modulus for the hyperbolic model. The comparative analyses of the triaxial compression test and the shallow foundation under the cyclic load can show stable numerical convergence, consistency with the theoretical solution, and hysteresis behavior. In addition, plastic hardening modulus for the modified hyperbolic function is presented, and a methodology to estimate model variables conforming 1D equivalent linear model is proposed for numerical modeling of the multi-dimensional behavior of the ground.

Nonlinear Dynamic Analysis of Space Steel Frames (공간 강뼈대 구조물의 비선헝 동적 해석)

  • Kim Seung-Eock;Cuong Ngo-Huu;Lee Dong-Ho
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.18 no.4 s.70
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    • pp.395-404
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    • 2005
  • This paper presents a reliable numerical procedure for nonlinear time-history analysis of space steel frames subjected to dynamic loads. Geometric nonlinearities of member (P-$\delta$) and frame (P-$\Delta$) are taken into account by the use of stability functions in framed stiffness matrix formulation. The gradual yielding along the member length and over the cross section is included by using a tangent modulus concept and a softening plastic hinge model based on the New-Orbison yield surface. A computer program utilizing the average acceleration method for the integration scheme is developed to numerically solve the equation of motion of framed structure formulated in an incremental form. The results of several numerical examples are compared with those derived from using beam element model of ABAQUS program to illustrate the accuracy and the computational efficiency of the proposed procedure.

Characteristics of Artificial Soils Produced from Sludge (슬러지를 이용하여 생산한 인공토양의 특성)

  • Yoon, Chun-Gyeong;Kim, Sun-Joo;Kwun, Tae-Young;Lee, Nam-Chool
    • Korean Journal of Environmental Agriculture
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    • v.17 no.3
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    • pp.200-204
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    • 1998
  • Physical and chemical properties of artificial soil produced by firing process were analyzed and compared with normal dry field soil and soil quality standards. Material used for production was water and wastewater treatment sludge, chabizite, and lime. The mixed material was thermally treated in the firing kiln at about $300^{\circ}C$ and $1,000^{\circ}C$, respectively, as per designed process. General properties of the artificial soil were classified as sand by unified soil classification method and similar to the dry-field soil, and even soil conditioning effect were expected when it is mixed properly with normal soil. The artificial soil is high in pH and permeability compared to the dry-field soil. Heavy metal concentrations of the artificial soil met the soil quality standards for the farmland. Overall, the artificial soil was thought to be an appropriate soil which can be returned safely to the nature without significant adverse effect. The cost for the artificial soil production process needs to be lowered for practical application as a sludge treatment, therefore, commercializing of the artificial soil is under review.

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