• 제목/요약/키워드: 소성거동

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Synthesis and characterization of thermally stable pink-red inorganic pigment for digital color (디지털 컬러용 pink-red 고온발색 무기안료의 합성 및 특성평가)

  • Lee, Won-Jun;Hwang, Hae-Jin;Kim, Jin-Ho;Cho, Woo-Suk;Han, Kyu-Sung
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.24 no.4
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    • pp.169-175
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    • 2014
  • Digital ink-jet printing system has many advantages such as fast and fine printing of various images, high efficiency and low cost process. Generally digital ink-jet printing requires ceramic pigments of cyan, magenta, yellow and black with thermal and glaze stability above $1000^{\circ}C$ for the application of porcelain product design. In this study, pink-red colored $CaO-SnO_2-Cr_2O_3-SiO_2$ pigment was synthesized using solid state reaction. The synthesis conditions of $Ca(Cr,Sn)SiO_5$ pigment such as annealing temperature, amount of mineralizer and non-stoichiometric composition were optimized. Crystal structure and morphology of the obtained $Ca(Cr,Sn)SiO_5$ pigment were analyzed using XRD, SEM, PSA, FT-IR and effect of Cr substitution on the pigment color was analyzed using Uv-vis. spectrophotometer and CIE $L^*a^*b^*$ measurement.

Field Investigation and Stability Analysis of a Volcanic Rock Slope at the Song-Gok site, Wan-Do (완도 송곡지구 화산암류 비탈면의 현장조사 및 안정성 검토 사례 연구)

  • Kim, Hong-Gyun;Ok, Young-Seok;Kim, Seung-Hyun;Koo, Ho-Bon
    • The Journal of Engineering Geology
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    • v.23 no.2
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    • pp.149-160
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    • 2013
  • Volcanic activity commonly creates a highly complicated volcanic complex due to the admixture of lava flow and sedimentation of volcanic ash. The Song-Gok site is composed of volcanic rocks that collapsed at the lower part of the slope, in combination with several discontinuities in and around a fault. The results of projection analysis indicated the possibility of plane, wedge, and toppling failure in the failure section. The results of discontinuity modeling using the Distinct Element Method (DEM) revealed a total displacement of 207 mm and a joint shear displacement of 114 mm. The yield surface zone was verified at the fault plane of the failure section. In geotechnical terms, volcanic rock slopes are characteristically vulnerable to failure because of differential weathering among the various rock types, the effect of groundwater based on the permeability of the rocks, and the presence of systematic joints generated by the cooling and contraction of lava. When considering the stability of a volcanic rock slope, it is necessary to consider data such as the geological features of the rock, as obtained through detailed geological survey, and variations in discontinuities and rock blocks.

Characterization of interfacial chemistry on the coal bottom ash (저회의 계면 화학적 특성 규명)

  • Lee, Ki-Gang
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.21 no.2
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    • pp.92-97
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    • 2011
  • Landfill is the main treatment method for bottom-ash because it has not only an irregular particle size and ingredients but also not proper recycling treatment. The aim of this study is to raise recycling rate of bottom-ash(nonplasticity pulverulent) and for the purpose of alternatives of clay to investigate the properties of Bottom-ash (B/A)-Hard Clay (H/C) bodies with controlled interfacial chemistry properties. After investigating the sedimentation height of suspensions with controlled pH, it was discovered that there was no hetero-polar aggregation for mixed slips because hard clay and bottom-ash had similar interfacial chemistry properties. Also, bulk density, water absorption, and microstructure properties of each pellet was observed that made by silp casting method and manufactured at $50^{\circ}C$ intervals between $1000{\sim}1250^{\circ}C$. As a result, dispersed slip of clay and bottom ash are possible for slip casting and plastic forming process because they exhibit Bingham plastic behavior. Products that made by slip with dispersed clay and bottom ash are not only suitable for KS L 4201 and KS L 1001 at $1250^{\circ}C$ but it is also possible to apply for ceramic and sanitary ware because specific gravity was about 15 % lighter than general ceramic materials.

Water absorption characteristics of artificial lightweight aggregates preparedby pre-wetting (프리웨팅된 인공경량골재의 흡수 특성)

  • Kim, Yoo-Taek;Jang, Chang-Sub;Ryu, Yug-Wang
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.21 no.2
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    • pp.82-86
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    • 2011
  • Lightweight aggregate which is composed of sintered polycrystalline materials usually has a certain portion of pores inside of it. Because of such a structural characteristics, it tends to that movement of water in aggregate shows an abnormal behavior against the change of outside environment. In general, water movement behavior is controlled by porosity, distribution of pore size; however, dense surface layer will also affect water movement behavior in case of artificially sintered aggregates. Factors affecting water movement behavior in the aggregate are pore distribution, pore shape, pre-wetting method, etc. In this study, absorption characteristics of aggregate under the pressure and absorption rate according to water dipping time are analyzed for the basis of pressure pumping of lightweight concrete. Two kinds of aggregates were used for the test: one is made by 'L' company in Germany and the other is of our own made at the pilot plant in Kyonggi University. Absorption rate of aggregate is measured according to water dipping time, vacuum pressure, and quenching condition. Absorption rate of aggregate with $300^{\circ}C$ quenching is higher than that of aggregate with 24 hr water dipping. Generally the more vacuum the higher water absorption rate. Water absorption rate of 'L' aggregate under -300 mmHg is 54 % higher than that of aggregate with 24 hr water dipping; however, only 2 % increase in water absorption was measured for the K622 and K73 which were of our own.

Evaluation of Applicability of Apparent Track Stiffness Measured by Light-Weight Deflectometer as a Ballasted Track Condition Index (소형동평판재하시험기로 측정한 궤도 겉보기 강성의 자갈궤도 상태평가 지표로서의 적용성 고찰)

  • Choi, Yeong-Tae;Hwang, Sung Ho;Jang, Seung Yup;Park, Bongsik;Shim, Gwang Seop
    • Journal of the Korean GEO-environmental Society
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    • v.19 no.2
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    • pp.37-44
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    • 2018
  • Ballasted track has been widely used due to its flexibility. However, the plastic deformation of ballasted track causes the evolution of track geometrical errors, and hence it requires continuous maintenance; increase in number of trains, weight, and speed expedites maintenance frequency and cost as well. Ballast stiffness is well-known as an indicator of design and maintenance. In this regard, this paper aims to suggest the method to measure ballast track stiffness using light-weight deflectometer (LWD) and thus verify its applicability as a maintenance measure. Preliminary field tests determined simple field testing protocol to measure track stiffness. The apparent ballast stiffness by LWD shows good corelation with TQI (Track Quality Index) and maintenance length. That is, as average of apparent stiffness increase, TQI and tamping length decrease exponentially. Therefore, apparent stiffness can be used as an index for ballast condition assessment.

Comparison of Quantitative Interfacial Adhesion Energy Measurement Method between Copper RDL and WPR Dielectric Interface for FOWLP Applications (FOWLP 적용을 위한 Cu 재배선과 WPR 절연층 계면의 정량적 계면접착에너지 측정방법 비교 평가)

  • Kim, Gahui;Lee, Jina;Park, Se-hoon;Kang, Sumin;Kim, Taek-Soo;Park, Young-Bae
    • Journal of the Microelectronics and Packaging Society
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    • v.25 no.2
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    • pp.41-48
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    • 2018
  • The quantitative interfacial adhesion energy measurement method of copper redistribution layer and WPR dielectric interface were investigated using $90^{\circ}$ peel test, 4-point bending test, double cantilever beam (DCB) measurement for FOWLP Applications. Measured interfacial adhesion energy values of all three methods were higher than $5J/m^2$, which is considered as a minimum criterion for reliable Cu/low-k integration with CMP processes without delamination. Measured energy values increase with increasing phase angle, that is, in order of DCB, 4-point bending test, and $90^{\circ}$ peel test due to increasing roughness-related shielding and plastic energy dissipation effects, which match well interfacial fracture mechanics theory. Considering adhesion specimen preparation process, phase angle, measurement accuracy and bonding energy levels, both DCB and 4-point bending test methods are recommended for quantitative adhesion energy measurement of RDL interface depending on the real application situations.

Structural Capacity Evaluation of Hybrid Precast Concrete Beam-Column Connections Subjected to Cyclic Loading (반복하중을 받는 하이브리드 프리캐스트 보-기둥 접합부의 성능평가)

  • Choi, Hyun-Ki;Yoo, Chang-Hee;Choi, Yun-Cheul;Choi, Chang-Sik
    • Journal of the Korea Concrete Institute
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    • v.22 no.3
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    • pp.325-333
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    • 2010
  • In this study, new moment-resisting precast concrete beam-column joint made up of hybrid steel concrete was developed and tested. This beam-column joint is proposed for use in moderate seismic regions. It has square hollow tubular section in concrete column and connecting plate in precast U-beam. The steel elements in column and beam members were connected using bolt. Furthermore, in order to prevent the premature failure of concrete in hybrid steel-concrete connection, ECC(engineered cementitious composite) was used. An experimental study was carried out investigating the joint behavior subjected to reversed cyclic loading and constant axial compressive load. Two precast beam-column joint specimens and monolithic reinforced concrete joint specimen were tested. The variables for interior joints were cast-in-situ concrete area and transverse reinforcement within the joint. Tests were carried out under displacement controlled reverse cyclic load with a constant axial load. Joint performance is evaluated on the basis of connection strength, stiffness, energy dissipation, and displacement capacity. The test results showed that significant differences in structural behavior between the two types of connection because of different bonding characteristics between steel and concrete; steel and ECC. The proposed joint detail can induce to move the plastic hinge out of the ECC and steel plate. And proposed precast connection showed better performance than the monolithic connection by providing sufficient moment-resisting behavior suitable for applications in moderate seismic regions.

Comparison of Pollutant Removal Efficiency in Road Sediment with Media Using Filter Separator (필터 분리기를 이용한 여재별 도로퇴적물의 오염물질 제거효율 비교)

  • Bang, Ki-Woong;Lee, Jun-Ho;Choi, Chang-Su;Lee, Sang-Ill
    • Journal of Korean Society of Environmental Engineers
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    • v.29 no.3
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    • pp.332-340
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    • 2007
  • Storm runoff from road contains significant loads of particulate and dissolved solids, organic constituents and metal elements. Micro particle is important when considering pollution mitigation because pollutant metal and organics have similar behavior with particles. The objective of this research is to evaluate the hydrodynamic filter separator performance for road storm runoff treatment. A various types of media such as perlite, granular activated carbon, zeolite were used for column test packing media and filter separator, and to determine the removal efficiency with various surface loading rate. As the results of column test, the highest SS removal efficiency was using mixed media(granular activated carbon, zeolite and perlite), and granular activated carbon mixed with zeolite has higher heavy metal removal efficiency than perlite. In laboratory scale hydrodynamic filter separator study, the operation ranges of surface loading rates were from 192 to 1,469 $m^3/m^2/day$. The estimated overall removal efficiencies of hydrodynamic filter separator for typical storm runoff were SS 48.1%, BOD 31.9%, COD 32.6%, TN 15.5%, and TP 17.3%, respectively. For the case of heavy metals, overall removal efficiencies were Fe 26.0%, Cu 19.4%, Cr 25.7, Zn 16.6%, and Pb 15.0%, respectively. The most appropriate medium for hydrodynamic filter separator was perlite mixed with granular activated carbon to treatment of road storm runoff.

Crystallization of Neodymium carbonate from Neodymium Chloride Solution (염화네오디뮴 수용액으로부터 탄산네오디뮴 결정화)

  • Kim, Chul-Joo;Yoon, Ho-Sung;Kim, Joon-Soo;Lee, Seung-Won
    • Resources Recycling
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    • v.16 no.2 s.76
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    • pp.23-31
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    • 2007
  • In this study, the crystallization of neodymium carbonate from neodymium chloride solution by addition of ammonium bicarbonate was investigated. The concentration of reactants such as neodymium chloride and ammonium bicarbonate, and reaction temperature play an important part in order to obtain the crystal of neodymium carbonate. It seemed that amorphous neodymium carbonate was prepared by aggregation of primary particles formed through nucleation. If reaction rate was increased by increasing the concentration of reactants and reaction temperature, then neodymium carbonate crystal could be obtained. Lanthanite-type neodymium carbonate[$Nd_2(CO_3)_3{\cdot}8H_2O$] and tengerite-type neodymium carbonate[$Nd_2(CO_3)_3{\cdot}2.5H_2O$] could be obtained with reaction renditions. Lanthanite-type neodymium carbonate was sensitive to temperature. The thermal decomposition of neodymium carbonate contained the processes or dehydration, decarbonation and crystalization of $Nd_2O_3$. The shape of lanthanite-type neodymium carbonate was irregular lump type, and tengerite-type neodymium carbonate had the shape of needle type. The shape of $Nd_2O_3$ was affected by the shape of neodymium carbonate.

Effect of Different Energy Frames on the Impact Velocity of Strain Energy Frame Impact Machine (에너지 프레임 종류에 따른 변형에너지 프레임 충격시험장치의 충격속도)

  • PARK, Seung Hun;PARK, Jun Kil;TRAN, Tuan Kiet;KIM, Dong Joo
    • Journal of the Korea Concrete Institute
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    • v.27 no.4
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    • pp.363-375
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    • 2015
  • This research investigated the effects of diameter and material of energy frame on the impact velocity or strain rate of Strain Energy Frame Impact Machine (SEFIM). The impact speed of SEFIM have been clearly affected by changing the diameter and material of the energy frame. The reduced diameter of the energy frame clearly increased the impact velocity owing to the higher strain at the moment of coupler breakage. And, titanium alloy energy frame produced the fastest speed of impact among three materials including steel, aluminum and titanium alloys because titanium alloy has faster wave velocity than steel. But, aluminium energy frame was broken during impact tests. In addition, the tensile stress versus strain response of high performance fiber reinforced cementitious composites at higher and wider strain rates between 10 and 72 /sec was successfully obtained by using four different energy frames.