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http://dx.doi.org/10.6111/JKCGCT.2014.24.4.169

Synthesis and characterization of thermally stable pink-red inorganic pigment for digital color  

Lee, Won-Jun (Icheon Branch, Korea Institute of Ceramic Engineering & Technology (KICET))
Hwang, Hae-Jin (School of Material Science and Engineering, Inha University)
Kim, Jin-Ho (Icheon Branch, Korea Institute of Ceramic Engineering & Technology (KICET))
Cho, Woo-Suk (Icheon Branch, Korea Institute of Ceramic Engineering & Technology (KICET))
Han, Kyu-Sung (Icheon Branch, Korea Institute of Ceramic Engineering & Technology (KICET))
Abstract
Digital ink-jet printing system has many advantages such as fast and fine printing of various images, high efficiency and low cost process. Generally digital ink-jet printing requires ceramic pigments of cyan, magenta, yellow and black with thermal and glaze stability above $1000^{\circ}C$ for the application of porcelain product design. In this study, pink-red colored $CaO-SnO_2-Cr_2O_3-SiO_2$ pigment was synthesized using solid state reaction. The synthesis conditions of $Ca(Cr,Sn)SiO_5$ pigment such as annealing temperature, amount of mineralizer and non-stoichiometric composition were optimized. Crystal structure and morphology of the obtained $Ca(Cr,Sn)SiO_5$ pigment were analyzed using XRD, SEM, PSA, FT-IR and effect of Cr substitution on the pigment color was analyzed using Uv-vis. spectrophotometer and CIE $L^*a^*b^*$ measurement.
Keywords
Ceramic pigment; Ink-jet printing; $Ca(Cr,Sn)SiO_5$; Solid state reaction;
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