• Proceedings of the Korean Vacuum Society Conference
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• 2015.08a
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• pp.190.2-190.2
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• 2015

최근에 최적의 모체 결정과 활성제 이온을 선택하여 우수한 발광과 흡광 특성을 갖는 산화물 형광체를 합성하여 디스플레이, 고체 레이저, 백색 발광 소자를 제작하는데 관심이 고조되고 있다. 본 연구에서는 열 및 화학적으로 안정한 $Gd_2MoO_6$를 모체 결정으로 선택하고 $Eu^{3+}$, $Sm^{3+}$ 이온을 활성제 이온으로 각각 도핑하여 다양한 종류의 색을 구현하는 새로운 종류의 형광체를 제조하고자 한다. 비교적 간단한 장비로 구성되고 볼밀 작업을 통하여 쉽게 초기 물질을 혼합 분쇄하고 소결할 수 있는 고상반응법을 사용하여 합성하였다. 특히, 모체 결정에 주입되는 활성제 이온을 둘러싸고 있는 국소적인 환경이 반전 대칭에서 벗어나는 정도를 파악하여 활성제 이온의 발광 파장의 세기가 최대가 되는 최적의 조건을 규명하고자 한다. $Eu^{3+}$ 이온이 도핑된 $Gd_2MoO_6$ 형광체의 발광 스펙트럼은 $Eu^{3+}$ 이온의 함량에 관계없이 모든 시료에서 전형적인 $Eu^{3+}$ 이온의 $^5D_0-^7F_j$ (j=1-4) 전이에 의한 발광 스펙트럼을 나타내었고, 가장 강한 적색 발광 파장은 611 nm에서 관측되었다. $Sm^{3+}$ 이온이 도핑된 $Gd_2MoO_6$ 형광체의 경우에, $Sm^{3+}$ 이온의 함량에 관계없이 모든 시료에서 $Sm^{3+}$ 이온의 $^4G_{5/2}-^6H_j$ (j=5/2, 7/2, 9/2) 전이에 의한 발광 스펙트럼을 나타내었고, 가장 강한 발광 파장은 616 nm에서 관측되었다. 이외에도, 결정 입자와 발광 세기의 상관 관계를 조사하였다.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2009.06a
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• pp.190-190
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• 2009

전자산업에의 필수인 커패시터는 소형화, 저저항, 고전압을 향한 추세가 늘고 있으며, 이외에도 고전압 전원, 고전압 회로 등 중전기기에 필요한 고전압, 고용량 커패시터가 사용되고 있다. 중전기기에 사용되는 커패시터는 기기에 따라 틀리지만 내전압이 보통 10kV 이상이고 정전용량이 500pF 안팎이며, 대부분 외국에서 수입에 의존하고 있는 실정이다. 본 연구에서는 $Nb_2O_5$를 2mol% 첨가한 $BaTiO_3$를 일반적인 고상 소결법으로 제조하고 성형 시 crack을 방지하기 위해 binder 및 plasticizer를 사용하였으며, binder 첨가량에 따른 성형밀도를 측정하여 최적의 binder양을 선택하였다. 성형 밀도가 떨어짐에 따라 절연파괴강도가 낮아지기 때문에 성형 밀도를 높이기 위해 CIP를 하였으며, 소결후 capacitance와 d-factor를 측정하여 수치가 허용 범위에 들어 올 경우 전극을 형성하고 표면파괴를 방지하기 위하여 epoxy로 표면코팅을 하였다. DC 60kV용 Hi-pot tester를 사용하여 15kV까지 선형적으로 증가시켜 내전압 테스트를 실시하였으며, 제조 된 커패시터 중 몇 개의 sample을 SEM 및 XRD를 사용하여 미세구조와 결정상을 조사하였다.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.9 no.4
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• pp.892-898
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• 2008

3D rapid prototyping is the manufacturing technology to fabricate a prototype with the data stored in a computer, which differs from conventional casting technology in terms of an additive process. Various 3D rapid prototyping techniques such as stereolithograpy. fused deposition modeling. selective laser sintering, laminated object manufacturing have been developed but among them, 3D inkjet printing has a unique feature that materials could be jetted to directly form the body of a prototype, which could be a finished product functionally and structurally. However, this needs ink with a high solid content, which tends to increase the dynamic viscosity of ink. The increase of ink viscositytends to restrict the jettable range of ink and hence the jetting conditions should be optimized. The intrinsic speed of sound in a hot melt ink with ceramic nanoparticles dispersed is one of key components to determine the jettable range of ink. In this paper, the way to measure the intrinsic speed of sound in a hot melt ceramic ink is proposed and its influence on the jetting condition is discussed.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 1995.10a
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• pp.204-209
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• 1995

The implementation of rapid prototyping technologies has been developed for automotive engineering by utilizing concurrent engineering principes integrated with slective laser sintering. The Selective Laser Sintering, in which a part is generated in layers form powder using a computer-controlled laser scanning apparatus and power feed system. An over view of the basic principles of SLS Machine operation is given. Binding mechanisms are described for power which becomes thermally activated bye the scanning laser beam; viscous flow and melting of a low-melting-point phase in powder. The production of parts from metal is described, including post processing to improve structural integrity and induce a transformation.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.24 no.3 s.174
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• pp.769-776
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• 2000

RP(Rapid Prototyping) technology is gaining its popularity in building a prototype in all industries. SLS(Slective Laser Sintering) is one of RP technologies, which is focused on tooling processes as well as three dimension solid model. There are several factors, the length and the cross-sectional area of a part, that have an effect on build setup in SLS process. In this paper, the computation on geometrical relationship is used to slice STL file and to estimate these factors. Based on these values, the build setup parameters such as the heating temperature, the laser power, and the powder cartridge feed rate are determined by neural network approaches. The test results show that the computation time is saved and the neural network approach is able to apply to get the optimal parameters of build process within an acceptable error rate.

• Electrical & Electronic Materials
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• v.2 no.2
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• pp.109-116
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• 1989

PSN-PT-PZ 삼성분계 압전세라믹의 상도로부터 유전적, 압전적 특성이 가장 양호한 MPB부근의 조성을 선택하여 MnO$_{2}$를 0-2[wt.%]첨가하였으며 일반소성법으로 시편을 제작하였다. 소결온도는 1,200-1,280[.deg.C], 시간은 0.5-3[hr]까지 변화시켰으며 MnO$_{2}$의 첨가가 시편의 유전적, 압전적 특성에 미치는 영향을 고찰하였다. 제작된 시편의 비유전상수는 MnO$_{2}$의 첨가량에 따라 증가하였으며 MnO$_{2}$가 2[wt.%]첨가된 시편 S-15(PSN:PT:PZ, 15:48:37)의 경우 605.41, 큐리온도는 MnO$_{2}$의 첨가량이 증가할수록 선형적으로 감소하였다. 각 시편의 전기기계 결합계수와 유전손실은 MnO$_{2}$의 첨가량이 0.5-1.5[wt.%]범위에서 양호한 특성을 나타내었으며 MnO$_{2}$가 0.5[wt.%] 첨가된 시편 S-5(PSN:PT:PZ, 5:48:47)의 경우 전기기계 결합계수는 0.425로 가장 높은 값을 나타내었다. MnO$_{2}$가 1[wt.%] 첨가된 시편 S-10(PSN:PT:PZ, 10:48:42)에서 공진주파수의 온도의존성이 가장 양호하게 나타났으며 각 시편에 대한 MnO$_{2}$의 첨가량이 증가할수록 결정립 크기는 감소하였다.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.21 no.5
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• pp.218-224
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• 2011

LAS ($Li_2O-Al_2O_3-SiO_2$) ceramics were sintered by a solid-state reaction. $CaCO_3$ and $ZrO_2$ were added to the ${\beta}$-spodumene ($Li_2O-Al_2O_3-4SiO_2$) composition of the LAS system for enhancement of sintering behavior and mechanical strength, respectively. We have investigated the sintering characteristics, microstructures, mechanical properties and thermal expansion characteristics according to the change of the amount of additive and sintering temperature of the ${\beta}$-spodumene. At 0.1 mol% $CaCO_3$, the densification of ${\beta}$-spodumene was significantly improved. At 0.04 mol% $ZrO_2$, the strength of ${\beta}$-spodumene was also improved. For all the selected all compositions, the thermal expansion coefficient was measured by a dilatometer, which revealed 1.2 to $1.7{\times}10^6/^{\circ}C$.

• Proceedings of the KSME Conference
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• 2000.04a
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• pp.860-865
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• 2000

This Paper Proposes the test pieces of X, Y and Z axes to compensate the shape distortion of Selective Laser Sintering(SLS) parts resulting from the phase change during the sintering process. In no case of the proposed compensation test pieces of X, Y axes the accurate rates of shrinkage can be measured with the reduction of curling which is obtained from adjustment of build orientation and the formula used to get scale factors are proposed with the shrinkage rates of them. The scale factors of X, Y and Z axes are generated by building up proposed compensation test pieces. The generated scale iactors are required to satisfy the dimensional accuracy even if there are changes of the build position and the size of SLS parts in the build chamber. For this reason, it is proposed that the build positions and the size be considered to be noise factors against the compensation test pieces and a method is also proposed that scale factors be selected to robustly maintain the dimensional accuracy of SLS parts under the actual operating conditions with the application of the Taguchi Method.

• Journal of the Korean Society for Precision Engineering
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• v.17 no.7
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• pp.124-131
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• 2000

Rapid Prototyping(RP) models are no longer used only for design verification. Currently, parts built utilizing layer manufacturing technology can be employed as functional prototypes and as patterns or tools for different manufacturing processes such as vacuum casting, investment casting, injection molding, precise casting and sand casting. This trend of Rapid Prototyping application meets the requirement of concurrent engineering and its range covers a more spreaded area. The aim of this paper is saving the manufacturing lead time and cost of plastic parts having hollow space shapes used by prototype-car. Using rapid prototype patterns, made by the Selective Laser Sintering(SLS) technique, a new approach of manufacturing resin-based blow mold is discussed. It has a great potential fur making prototype-car parts with the batch size of under 200 parts, in case of rapid modification due to a subsequent design changes in developing stage. So, the process proposed in this research shows reduction of process time and manufacturing cost when compared with the conventional process such as a Zinc Alloy fur Stamping(ZAS) mold.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2003.06a
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• pp.1869-1872
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• 2003

As SLA(Sterealithography), SLS(Selective Laser Sintering), LOM(Laminated Object Manufacturing), FDM(Fused Deposition Modeling) etc. The FDM system the heart of a study and is developed by Stratasys co. ltd, in US., is small and cheap R.P. The material filament is heated until the material reaches a near-liquid state, it is pumped through a nozzle and become hand with a shape required, and this nozzle move pumping on the previously deposited material. Such FDM system that choice deposition type with X-Y plouter obtain in the thin continue layer by decreasing amount of extrusion or to central the injection amount when the head slow down at the corner, but in the process that fusion wax or resin become hand, deformation occur and it will affect the shape accuracy and the surface roughness. Such effect will depreciate quality and reliability of the product. Therefore, when the product made in actuality, the fundamental study on the basis geometry(surface, volume, line, angle) must be preceded and it have been research by many Free Form Fabrication. So, this basic object study purpose to obtain the fundamental geometry data and to enhance the surface roughness of the shape. And an operant can use the data for the progress of the surface roughness. This study research the estimation and application of the prototype surface roughness by adjustment the injection amount. And basie of this research, describe the pattern of prototype surface roughness and also used the result to estimate the surface of prototype.