Browse > Article
http://dx.doi.org/10.6111/JKCGCT.2011.21.5.218

Sintered body characteristics of LAS by addition of CaCO3 and ZrO2 using a solid-state reaction  

Kim, Sang-Hun (KICET Icheon Branch)
Kang, Eun-Tae (School of Nano and Advanced Materials Engineering Gyeongsang National University)
Kim, Ung-Soo (KICET Icheon Branch)
Hwang, Kwang-Taek (KICET Icheon Branch)
Cho, Woo-Seok (KICET Icheon Branch)
Abstract
LAS ($Li_2O-Al_2O_3-SiO_2$) ceramics were sintered by a solid-state reaction. $CaCO_3$ and $ZrO_2$ were added to the ${\beta}$-spodumene ($Li_2O-Al_2O_3-4SiO_2$) composition of the LAS system for enhancement of sintering behavior and mechanical strength, respectively. We have investigated the sintering characteristics, microstructures, mechanical properties and thermal expansion characteristics according to the change of the amount of additive and sintering temperature of the ${\beta}$-spodumene. At 0.1 mol% $CaCO_3$, the densification of ${\beta}$-spodumene was significantly improved. At 0.04 mol% $ZrO_2$, the strength of ${\beta}$-spodumene was also improved. For all the selected all compositions, the thermal expansion coefficient was measured by a dilatometer, which revealed 1.2 to $1.7{\times}10^6/^{\circ}C$.
Keywords
Low thermal expansion; LAS ($Li_2O-Al_2O_3-SiO_2$); Sintering characteristics;
Citations & Related Records
Times Cited By KSCI : 9  (Citation Analysis)
연도 인용수 순위
1 E.S. Lee, H. Park and D.H. Kim, "The study of sintering characteristics in LAS system", J. Kor. Ceram. Soc. 29 (1992) 127.   과학기술학회마을
2 F.A. Hummel, "Thermal expansion properties of some synthetic lithia materials", J. Am. Ceram. Soc. 34 (1951) 235.   DOI
3 Edward J. Smoke, "Ceramic compositions having negative linear thermal expansion", J. Am. Ceram. Soc. 34[3] (1951) 87.   DOI
4 S.M. Kang, J.H. Shin, J.W. Han, J.K. Choi, B.S. Jeon and K.K. Orr, "Spodumene single crystal growth by FZ method", J. Kor. Cryst and Cryst. Tech. 3[2] (1993) 162.   과학기술학회마을
5 M.F. Hochella Jr. and G. Brown Jr., "Structural mechanism of anomalous thermal expansion of cordierite-beryl and other framework silicate", J. Am. Ceram. Soc. 69[1] (1986) 13.   DOI   ScienceOn
6 S.J. Lee and K.S. Cho, "Characteristics of cordierite ceramics filled with alumina platelets", J. Kor. Cryst and Cryst. Tech. 12[6] (2002) 292.   과학기술학회마을
7 Y. Ohya and Z.E. Nakagawa, "Cracking healing and bending strength of aluminum titanate ceramics at high temperature", J. Am. Ceram. Soc. 70[8] (1988) C-232.
8 R. Roy, D.M. Roy and E.F. Osborn, "Compositional and stability relationship among the lithium aluminosilicate: Eucryptite, spodumene and petalite", J. Am. Ceram. Soc. 33[5] (1950) 152   DOI
9 W. Ostrtag, G.R. Fisher and J.P. Williams, "Thermal expansion of synthetic ${\beta}$-spodumene and ${\beta}$-spodumenesilica solid solutions", J. Am. Ceram. Soc. 51[11] (1968) 651.   DOI
10 H. Scheidler and E. Rodek, "$Li_{2}O-Al_{2}O_{3}-SiO_{2} $glass-cermics", J. Am. Ceram. Soc. Bull. 68[11] (1989) 1926.
11 D.M. Choi, J.K. You and E.S. Lee, "Thermal, mechanical properties of LAS with the addition of mullite", J. Kor. Ceram. Soc. 30[5] (1993) 381.   과학기술학회마을
12 W.H. Kang, "The study on the crystallization and properties of adding alkaline earth oxide in low expansion glass-ceramics", Collection of Dissertations 27 (1993) 606.
13 A.M. Hu, M. Li and D.L. Mao, "Growth behavior, morphology and properties of lithium aluminosilicate glass ceramics with different amount of CaO, MgO and $TiO_{2}$ additive", Ceram. Int. 34[6] (2008) 1393.   DOI   ScienceOn
14 K.L. Choy, P. Duplock, P.S. Rogers, J. Churchman- Davies and M.T. Pirzada, "The mechanical behaviour of glass and glass-ceramic matrix composites", Mat. Sci & Eng. 278[1-2] (1999) 187.
15 D.I. Jeon, J.W. Kim and E.S. Lee, "A study on the thermal resistance strength with the formation of the zircon phase in LAS system", J. Kor. Ceram. Soc. 29[12] (1992) 935.   과학기술학회마을
16 J.H. Park, H.M. Kim and H.S. Lee, "A study on the microstructural control of LAS ceramics(II): Influence of $Li_{2}O$. $4B_{2}O_{3}$ frit addition on the microstructure and thermal expansion of ${\beta}$-spodumene", J. Kor. Ceram. Soc. 29[7] (1992) 533.   과학기술학회마을
17 H.S. Park, K.S. Cho and C.S. Mun, "The study on fabrication of LAS system ceramics for thermal shock resistance from silicate minerals: (II) Preparation of spodumene powders with sillimanite, kaolin and pyrophyllite group minerals", J. Kor. Ceram. Soc. 31[7] (1994) 784.   과학기술학회마을
18 Y.J. Kwon, Y.T. Kim, K.G. Lee and Y.J. Kim, "Lightweight aggregate bloating mechanism of clay/incinerated ash/additive system", J. Kor. Ceram. Soc. 38[9] (2001) 811.   과학기술학회마을
19 E.S. Lee, S.C. Choi, H. Park and W.S. Cho, "The thermally resistance strength of LAS ($Li_{2}O-Al_{2}O_{3}-SiO_{2} $) system (I)", J. Kor. Ceram. Soc. 27[2] (1990) 283.   과학기술학회마을
20 H. Rawson, "Properties and applications of glass", (Elsevier SCI. Pub. Co., Amsterdam, 1980) p. 83.