• Journal of Energy Engineering
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• v.9 no.1
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• pp.1-9
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• 2000

공정연계를 최소호하는 IGCC 시스템에 대한 개념설계를 수행하였다. 공정분석은 상용코드인 ASPEN PLUS를 이용하였다. 가스화기의 적절한 운전조건을 찾기위하여 가스화기를 경계조건으로 하는 액서지 민감도분석을 통하여 투입되는 슬러리와 산소의 조건을 결정하였다. 또한 , 생성가스 냉각시 현열을 최대한 회수학 ldn하여 , 열교환망을 통하여 급수를 에열하고 가스화플랜트의 각 부분에 공급하도록 공정을 구성하였다. 여분의 가열된 급수는 갑압증발시켜 복합사이클에서 동력을 생성시키는데 사용되어진다. 이와 같은 시스템은 , 가스터빈 -ASU-가스화플랜트의 공기에 의한 공정연계와, HRSG-가스냉각 및 정제시스템 간의 증기연계를 가능한 적게함으로써 공정의 운전성과 경제성을 최적으로 유지할 수 있다. 본 연구에서 제시하는 공정의 경우에, 열효율이 약 39%(고위발열량 기준)으로 나타났으며, 단위 기기 및 단위공정들의 최적화를 통하여 40%의 효율달성이 가능할 것이다.

• Journal of Energy Engineering
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• v.6 no.1
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• pp.104-113
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• 1997

This study aims to develop an analysis model using a commercial process simulator-ASPEN PLUS for an IGCC (Integrated Gasification Combined Cycle) system consisting a dry coal feeding, oxygen-blown entrained gasification process by Shell, a low temperature gas clean up process, a General Electric MS7001FA gas turbine, a three pressure, natural recirculation heat recovery steam generator, a regenerative, condensing steam turbine and a cryogenic air separation unit. The comparison between those results of this study and reference one done by other engineer at design conditions shows consistency which means the soundness of this model. The greater moisture contents in Illinois#6 coal causes decreasing gasifier temperature and the greater ash and sulfur content hurt system efficiency due to increased heat loss. As the results of sensitivity analysis using developed model for the parameters of gasifier operating pressure, steam/coal ratio and oxygen/coal ratio, the gasifier temperature increases while combustible gases (CO＋H2) decreases throughout the pressure going up. In the steam/coal ratio analysis, when the feeding steam increases the maximum combustible gas generation point moves to lower oxygen/coal ratio feeding condition. Finally, for the oxygen/coal ratio analysis, it shows oxygen/coal ratio 0.77 as a optimum operating condition at steam/coal feeding ratio 0.2.

• Korean Chemical Engineering Research
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• v.46 no.3
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• pp.561-566
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• 2008

Gasification plant using petroleum coke for refinery and power generation process is increased from considering petroleum coke as a valuable fuel. In this study, gasification of petroleum coke was performed to utilize petroleum coke and to develop essential technology using 1T/D coal gasification system. In case of petroleum coke gasification, because of lower reactivity, consumption of oxygen is higher than coal gasification. The calorific value of syngas from petroleum coke mixed with coal at a mass ratio of 1:1 shows about $6.7{\sim}7.2MJ/Nm^3$. Although carbon conversion could reach more than 92% according to oxygen amount, cold gas efficiency shows lower value than the case of coal. Therefore, it was shown that complemental study in burner design to atomize slurry droplet is required to elevate gasification performance of petroleum coke which has lower reactivity than coal.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 2000.04a
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• pp.19-22
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• 2000

• 한국신재생에너지학회:학술대회논문집
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• 2010.06a
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• pp.116.2-116.2
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• 2010

석유의 고갈과 고유가 시대에 직면한 현재 전 세계적으로 매장량이 풍부하고 안정적으로 공급이 가능한 석탄 활용에 대한 관심이 급격히 증가하고 있다. 석탄의 활용 분야 중 석탄 가스화(Coal gasifier)에서 유도된 합성가스를 이용하여 합성천연가스(SNG) 생산을 할 수 있는 메탄화(Methanation) 공정에서는 대부분 Ni계열 촉매를 사용하고 있는데, 촉매를 설계하는 관점에서 담체(Support), 조촉매(Promoter), Ni의 함량 등과 같은 설계 변수에 따라 촉매의 활성과 함께 메탄 수율이 결정된다. 본 연구에서는 다양한 담체상에 Ni를 담지 하여 20bar 압력에서 SNG 반응에 높은 활성을 보일 수 있는 촉매를 확보하고자 실험을 수행하였으며, 그 결과 $NiO/SiO_2-Al_2O_3$ 촉매가 가장 우수한 활성을 보이는 것을 알 수 있었다. 또한 $NiO/SiO_2-Al_2O_3$ 상에 Cerium, Ferric oxide 조촉매를 첨가하여 SNG 반응 활성 평가를 수행하였다.

• Journal of Energy Engineering
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• v.11 no.2
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• pp.81-89
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• 2002

IGCC (Integrated Coal Gasification Combined Cycle) is a technology that generates electric power using coal gasification and gasified fuel. Carbon conversion value of IGCC is higher and the influence on the environment is lower than the pulverized coal power plant. Especially, in the nations where the weight of fossil fuel for power generation is remarkably high like in Korea, IGCC stands out as an alternative plan to cope with sudden limitation for the emissions. In this paper, system design study for the commercial IGCC system which the introduction is imminent to Korea was performed. Two cases of entrained gasification process are adapted, one is FHR(full heat recovery) type IGCC system for high efficiency and the other is Quench type IGCC system for low cost. System simulations using common codes like AspenPlus were performed for each system. In the case of Quench system, system option study and sensitivity analysis of the air extraction rate was performed. Thermal performance result for the FHR system is 42.6% (HHV, Net) and for the quench system is 40% (HHV, net) when 75% air is extracted.

• Korean Chemical Engineering Research
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• v.48 no.1
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• pp.80-87
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• 2010

Lignite of low rank coal and petroleum coke of high sulfur content can be high potential energy sources for coal gasification process because of their plentiful supply. The kinetic study of steam gasification has been performed in an atmospheric thermobalance with wood chip, lignite, bituminous, anthracite, pet-coke. The effects of gasification temperature($600{\sim}850^{\circ}C$) and partial pressure of steam(30~90 kPa) on the gasification rate have been investigated. The modified volumetric reaction model was applied to the experimental data to describe the behavior of carbon conversion and to evaluate the needed kinetic parameters. Lignite and wood chip with high volatile content showed high average gasification rates comparing to other fuel and thus they might be proper fuel for gasification processes. The activation energies for wood chip, lignite, bituminous, anthracite, and pet-coke through Arrhenius plot were found to be 260.3, 167.9, 134.6, 82.2, 168.9 kJ/mol, respectively. The expression of apparent reaction rates for steam gasification of various chars have been proposed as basic information for the design of coal gasification processes.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 1993.05a
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• pp.132-139
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• 1993

석탄가스화 공정과 복합발전 사이클을 결합한 IGCC 발전 시스템은 기존의 석탄연소 발전방식에 비해 열효율이나 공해배출 문제 등에서 월등히 우수한 특성을 가지므로 차세대 발전개념으로 크게 각광받고 있다. 이러한 이유로 선진공업국들은 70년대 석유 파동이래 IGCC 기술을 중점 개발하여 왔고, 머지않아 상업화에 도달할 전망이다. 국내적으로도 전기수요량의 급격한 증가와 엄격한 환경규제 등의 현실적 요인으로 인해 IGCC 발전에 관심이 집중되고 있으며, 이와 더불어 우리실정에 맞는 IGCC 공정기술의 개발이 시급한 실정이다.

• Clean Technology
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• v.20 no.3
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• pp.218-225
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• 2014

Catalytic gasification of raw coals at mild condition is not realized yet mainly due to deactivation of catalysts via their irreversible interaction with mineral matters in coal. In this work, the gasification behavior of ash-free coal (AFC) was compared with that of the parent raw coal. In order to modify the gasification conditions, the raw coal gasified with fixed variables (water supply, space velocity, temperature, catalysts) in a fixed bed reactor. When catalysts are added by physical mixing method with coal, $K_2CO_3$ was the most effective additives for steam gasification of coal. However, the activity of ash-free coal (AFC) was much less reactive than raw coal due to high temperature extraction in a 1-methylnaphthalene under 30bar at $370^{\circ}C$ for 1 h, almost removed oxygen functional groups, and increased carbonization. The addition of $K_2CO_3$ in AFC achieved higher conversion rate at low temperature ($700^{\circ}C$). At that time, the molar ratio of gases ($H_2/CO$ and $CO_2/CO$) was increased because of water-gas shift reaction (WGSR) by addition of catalysts. This shows that catalytic steam gasification of AFCs is achievable for economic improvement of gasification process at mild temperature.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 2000.11a
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• pp.33-38
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• 2000

IGCC(Integrated Gasification Combined Cycle) BSU(Bench Scale Unit) 석탄 가스화공정은 정상상태 조업시 약 145$0^{\circ}C$, 25기압의 고온 및 고압의 조건하에서 운전되기 때문에 설정된 운전조건을 안정하게 유지하기 위해서 이러한 조건에 상응하는 안정된 제어로직의 구성은 매우 중요한 요소이다.(중략)