• Title/Summary/Keyword: 석유화학 공정

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Elastic Wave Characteristics of Austenitic STS202 with Subzero Treatment (서브제로 처리한 오스테나이트계 STS202의 탄성파 특성)

  • Choi, Seong-Won;Choi, Byoung-Chul;Nam, Ki-Woo
    • Journal of the Korean Society of Industry Convergence
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    • v.24 no.3
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    • pp.295-300
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    • 2021
  • This study investigated the dominant frequency of the elastic waves from the tensile test. The specimen was rolled with five different rolling degrees (10, 22, 33, 42 and 50%), which was treated subzero. The specimen was rolled at room temperature, which was transformed from austenite to martensite (only α'-martensite). The dominant frequency increased with an increase in the rolling degree regardless of the subzero temperature, and decreased after 33% of the rolling degree. On the other hand, higher frequency band was obtained at lower temperature and long time. The dominant frequency increased when the amount of α'-martensite increased and decreased with the α'-martensite amount between 50-65%. The lower subzero treatment temperature increased the amount of α'-martensite, which resulted in the higher dominant frequency. The longer treatment time at the same subzero temperature led to an increase in the amount of α'-martensite, leading to high dominant frequency.

Elastic Wave Characteristics of Incoloy 825 with Different Solution Treatment Temperature and Aging Time (용체화처리 온도 및 시효 시간이 다른 Incoloy 825의 탄성파 특성)

  • Lee, Seong-Gu;Choi, Byoung-Chul;Nam, Ki-Woo
    • Journal of the Korean Society of Industry Convergence
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    • v.24 no.3
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    • pp.261-269
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    • 2021
  • This study was evaluated the elastic wave properties according to tension of Incoloy 825 alloy with different solution treatment temperature and aging time. Solution treatment was carried out at 700, 800, 900, and 1000 ℃ for 1 hour, and aging was carried out at 700 ℃ for 1, 5, 10, and 30 hours. As the solution treatment temperature increased, the tensile strength decreased and the elongation increased. However, as the aging time increased, the tensile strength increased and the elongation decreased. The dominant frequency decreased as the solution treatment temperature increased, but increased as the aging time increased. The dominant frequency according to the solution treatment and aging time increased as the tensile strength increased, but increased despite the decrease in elongation.

Effect of Carbon on the Micro Structure and Hardness of Internally Hardened Ductile Cast Iron Roll (내부 경화형 구상흑연주철 롤 동체와 넥의 미세조직과 경도에 미치는 탄소 영향)

  • Sang-Mook Lee;Ki-Hang Shin;Byung-Chul Choi;Ki-Woo Nam
    • Journal of the Korean Society of Industry Convergence
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    • v.26 no.1
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    • pp.79-86
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    • 2023
  • This study was investigated the effect of carbon on the micro-structure and hardness of ductile cast iron roll with internal curing capacity. Spheroidal graphite existed at roll body with rapid cooling, but granular graphite existed at roll neck with slow cooling. The volume fraction of graphite increased at roll body with rapid cooling, That of roll neck with slow cooling decreased, but graphite size increased. The volume fraction of cementite decreased, but volume fraction increased. The cementite size was larger at roll neck than roll body. The hardness was decreased at roll body and roll neck due to volume fraction of cementite. The hardness of roll body was higher than roll neck.

Evaluation of Harmless Crack Size according to Residual Stress Depth of Induction Hardened SCM440 Steel (유도경화한 SCM440 강의 잔류응력 깊이에 따르는 무해화 균열 크기 평가 )

  • Jong-Kyu Park;Ki-Hang Shin;Byoung-Chul Choi;In-Duck Park;Ki-Woo, Nam
    • Journal of the Korean Society of Industry Convergence
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    • v.26 no.4_2
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    • pp.571-576
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    • 2023
  • In this study, the harmless crack size(ahml) according to the residual stress depth was evaluated using the fatigue limit of SCM440 steel by quenching-tempering(QT) and induction hardening(IH), and threshold stress intensity factor of QT steel. Because the residual stress increased rapidly as the crack depth increased, ahml was determined at the depth of all the crack aspect ratio(As) regardless of Type I-III, and ahml also increased according to the residual stress depth. ahml was minimal at As=1.0 and maximal at As=0.1, but was almost similar on each Type. ahml was small the dependence on As.

A method of human error management in chemical process industries (화학공정산업의 인적오류 제어 방법)

  • Jo Young-Do;Park Kyo-Shik;Park Heui-Joon
    • Journal of the Korean Institute of Gas
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    • v.7 no.2 s.19
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    • pp.42-47
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    • 2003
  • To prevent major accident from toxic gas release, explosion, or fire in chemical processes, it needs dynamic control of human error with mechanical failure. Although most of major accidents occur with a coupling of human error and mechanical failure, numbers of researches have studied human error and mechanical reliability independently, but no where cross each other, to reduce the risk in the process. This work focuses on the coincidence of human error and mechanical failure for management of human error, and on some important performance shaping factors to propose a method for improving safety effectively of the process industries.

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Optimization Study for the Design of Deethanizer Column (탈에탄탑 설계를 위한 공정 최적화에 대한 연구)

  • Cho, Jung-Ho;Kim, Young-Woo
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.10 no.12
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    • pp.3755-3760
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    • 2009
  • In this study, we have completed the simulation and optimization work for the deethanizer column which was used for natural gas processing plant or saturated gas plant in a petrochemical process. An optimal feed stage location which minimizes the reboiler heat duty was determined. For the modeling of deethanizer, PRO/II with PROVISION was used and Soave modified Redlich-Kwong equation of state model was selected. Through this study, we have found that the minimum number of stage and minimum reflux ratio for separation were 9.03 and 0.62437, respectively and the theoretical stage number was 12, optimal feed stage location was 9 and minimum reboiler heat duty was $12.7470{\times}10^6\;KJ/hr$.

Applications of Mathematical Optimization Method for Chemical Industries (화학 산업에서 수학적 최적화 기법을 적용한 사례)

  • Kim, Eun-Yong;Heo, Soon-Ki;Lee, Kyu-Hwang;Lee, Hokyung
    • Korean Chemical Engineering Research
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    • v.58 no.2
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    • pp.209-223
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    • 2020
  • Executions of SCM in a chemical company of which divisions produce petrochemicals, compounds, batteries, IT material and medicine directly affect their own profit. Execution level of SCM or optimization is very important. This work presents activities of SCM and optimization of inefficient issues in several industrial divisions using mathematical optimization method. The meaning is not only academic research but also making a useful tool which active partner deals with in his work. It is explained how to do beforehand and afterward optimization problem. The benefits are mentioned in the sections. The first of examples would be cover supply plan optimization, optimal profit business plan, and scheduling of a stretching process of polarizer based on minimizing raw material loss in polarizer production. The second example would be cover the optimization of production/packaging plans to maximize productivity of Poly Olefin processes, and the third example is minimization of transition loss in the production of battery electrodes. The fourth example would be cover scheduling of vessel approaching to berth. Because transportation of large portion of raw material and products of petrochemical industry is dealt with vessel, scheduling of vessel approaching to berth is important at the shore of large difference of tide. The final example would be scheduling problem to minimization of change over time of ABS semi products.

Analysis of Total Petroleum Hydrocarbon in Domestic Distribution Petroleum (국내 유통 중인 석유제품 내 석유계 총 탄화수소화합물(TPH) 분석)

  • Lim, Young-Kwan;Kim, Jeong-Min;Kim, Jong-Ryeol;Kwon, Min-Jeong;Lee, Kyoung-Heum;Ryu, Seong-Hyun
    • Applied Chemistry for Engineering
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    • v.27 no.5
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    • pp.546-550
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    • 2016
  • Over 60~70% of the domestic soil contamination have occurred by petroleum products. B T E X including benzene, toluene, ethylbenzene, xylene and total petroleum hydrocarbon (TPH) have to be inspected for the contaminated soil by petroleum products. An accurate contamination analysis is necessary to estimate the are of contaminated soil and also establish an appropriate purification scheme. In this study, we analyzed a sectional TPH pattern for current domestic distributed petroleum products. Also, the TPH content was analyzed by compensating the defect of current Korea standard analytic methods for soil where the analytic range is just for $C_8{\sim}C_{40}$. The light distillate petroleum products such as gasoline and solvent 1 showed the maximum of 85% difference in the TPH content between the standard analytic and improved methods.

Measurement of Flash Point for Binary Mixtures of 2-Butanol, 2,2,4-Trimethylpentane, Methylcyclohexane, and Toluene at 101.3 kPa (2-Butanol, 2,2,4-Trimethylpentane, Methylcyclohexane 그리고 Toluene 이성분 혼합계에 대한 101.3 kPa에서의 인화점 측정)

  • Hwang, In Chan;In, Se Jin
    • Clean Technology
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    • v.26 no.3
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    • pp.161-167
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    • 2020
  • For the design of the prevention and mitigation measures in process industries involving flammable substances, reliable safety data are required. An important property used to estimate the risk of fire and explosion for a flammable liquid is the flash point. Flammability is an important factor to consider when developing safe methods for storing and handling solids and liquids. In this study, the flash point data were measured for the binary systems {2-butanol + 2,2,4-trimethylpentane}, {2-butanol + methylcyclohexane} and {2-butanol + toluene} at 101.3 kPa. Experiments were performed according to the standard test method (ASTM D 3278) using a Stanhope-Seta closed cup flash point tester. A minimum flash point behavior was observed in the binary systems as in the many cases for the hydrocarbon and alcohol mixture that were observed. The measured flash points were compared with the predicted values calculated via the following activity coefficient (GE) models: Wilson, Non-Random Two-Liquid (NRTL), and UNIversal QUAsiChemical (UNIQUAC) models. The predicted data were only adequate for the data determined by the closed-cup test method and may not be appropriate for the data obtained from the open-cup test method because of its deviation from the vapor liquid equilibrium. The predicted results of this work can be used to design safe petrochemical processes, such as the identification of safe storage conditions for non-ideal solutions containing flammable components.

A study on the corrosion resistance of the SB410 steel sheet using teflon(PTFE) synthetic coating (Teflon(PTFE) Synthetic Coating을 이용한 SB410 강판의 내식성 향상 연구)

  • Han, Su-Min;Yu, Geun-U;Gwon, Jae-Beom;Kim, Jun-Seop
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2015.05a
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    • pp.164-165
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    • 2015
  • 보일러 및 압력 용기용 강판으로 사용되는 SB410은 고 항복 강도 및 좋은 용접성의 특성을 가진 재질로서 주로 고압력, 내열성 및 내식성이 필요한 석유플랜트, 액화물 저장 탱크, 화력 발전 보일러 등의 제조에 주로 사용되어지는 탄소 강재이다. 그러나, 최근에는 조선소, 해양 플랜트, 석유화학 플랜트 등 사용환경에 따른 관련 분야에서의 내식성 요구치가 높아지고 있다. 이와 관련하여 현재 보편적으로 사용되어지는 Marin paint coating을 적용한 SB410 강재의 경우에도 사용환경의 가혹화가 증가됨에 따라 요구되는 내식성에 비하여 불량 현상이 증가하는 추세이며 해당 분야에서 본 재질의 표면처리 개선에 대한 연구 개발이 진행되고 있다. 본 연구에서는 Teflon(PTFE) synthetic coating solution을 이용한 SB410 소재 상의 표면처리 공정 최적화를 수행하였으며, 상기 표면처리에 대한 내식성을 검토하기 위하여 Marin paint coating sample, Teflon(PTFE) synthetic coating sample들에 대한 갈바닉 부식 분석 비교를 통하여 내식성에 대한 비교 검증을 수행하였다.

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