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Evaluating The Water Resistance of Wood Adhesives Formulated with Chicken Feather Produced from Poultry Industry (도계부산물인 닭털을 이용한 목재접착제의 내수성 평가)

  • Park, Dae-Hak;Yang, In;Choi, Won-Sil;Oh, Sei Chang;Ahn, Dong-uk;Han, Gyu-Seong
    • Journal of the Korean Wood Science and Technology
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    • v.45 no.1
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    • pp.126-138
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    • 2017
  • This study was conducted to investigate the potential of chicken feather (CF), which is a by-product in poultry industry, as a raw material of wood adhesives. For the purpose, adhesive resins were formulated with NaOH- and $H_2SO_4$-hydrolyzed CF as well as crosslinkers, and then the properties and water resistance of the adhesive resins against hot water were measured. CF was made of mainly keratin-type protein, and no or very low content of heavy metals was detected. Hydrolysis rate of CF increased as NaOH concentration in hydrolysis solutions increased. However, in order to minimize the loss of adhesive property of protein itself by the severe hydrolysis of CF and to seek its proper hydrolysis conditions, NaOH concentrations in hydrolysis solution determined to adjust to 5%, 7.5% and 10%. In the NaOH-hydrolyzed CF, $H_2SO_4$-hydrolyzed CF as a hardener and crosslinker were added to formulate CF-based adhesive resins. Solid content of the resins ranged from 28.3% to 44.8% depending on hydrolysis conditions and type of crosslinker. Viscosity of the resins at $25^{\circ}C$ was very high. However, when the temperature of the resins was increased to $50^{\circ}C$, the viscosity decreased greatly and thus the resins could be applied as a sprayable resin. Retention rate measured to evaluate the water resistance of adhesive resins was the highest in the cured resin formulated with 5% NaOH-hydrolyzed CF and 5% $H_2SO_4$-hydrolyzed CF of 10% based on the solid weight as a hardener. Retention rate depending on crosslinkers added into adhesive resins was the highest phenol-formaldehyde (PF) followed by melamine-urea-formaldehyde (MUF) and formalin. The retention rate of CF-based adhesives formulated with 5% NaOH-hydrolyzed CF, PF and $H_2SO_4$-hydrolyzed CF of 10% and over did not differ statistically from that of commercial MUF resins. All of CF-based adhesives formulated with PF as a crosslinker and one with 5% NaOH-hydrolyzed CF of 55%, 5% $H_2SO_4$-hydrolyzed CF of 15%, and MUF of 30% on the basis of solid weight could be substituted for commercial urea-formaldehyde resins, From the results, CF can be used as a raw material of wood adhesives if hydrolyzed in proper conditions.

A Survey on Kitchen Facilities and Present Meal Situation in the Chungnam Farm Village and Fishing Village (충남지역 농어촌의 부엌시설과 식사현황에 관한 실태조사)

  • 김영인;김기숙
    • Korean Journal of Rural Living Science
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    • v.3
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    • pp.37-44
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    • 1992
  • 본 연구는 충남지역 농어촌의 부엌설비 및 식사현황의 실태를 조사하여 농어촌 부엌설비 연구의 기초자료로 삼고자 1992년 3월 16일부터 2주간에 걸쳐 설문지 조사법에 의해 조사되었고 빈도(N)와 백분율(%), 그리고 변인간의 상관관계는 x$^2$-test로 통계적 유의성을 검증하였다. 1. 부엌의 구조 및 설비 1) 본 연구대상 농어촌 가정의 부엌 구조는 입식인 경우가 43.9%로서 아직까지도 재래식 구조가 많이 남아있고 부엌의 형태는 일자형(34.1%)과 자형(32.1%)이 가장 많았는데 일자형은 동선이 길고 자형은 면적을 많이 차지하는 단점을 지닌다고 하겠다. 2) 부엌 바닥의 재료는 흙바닥을 그대로 이용하는 경우(38.6%)와 콘크리트로 부엌 바닥을 마감한 경우(39.8%)가 대부분을 차지하였다. 부엌구조가 점차 입식으로 이양되면서 합성수지 제품도 이용(18.7%)되기는 했으나 흙바닥은 어떤 형태로든지 마감처리를 해야 할 것으로 본다. 3) 취사용 열원으로 가장 많이 쓰이고 있는 것은 프로판가스(57.6%)이고 그 다음으로는 연탄(16.5%)과 전기(14.9%)로서 장작과 석유의 이용율은 점차 줄어들고 있었다. 4) 상수도와 하수도시설이 부엌 내에 갖추어져 있는 비율은 각각 64.7%와 48.9%로서 아직도 미흡한 상태라고 할 수 있겠고, 정수기의 사용율은 2.9%로 관심도가 극히 낮은 편이었다. 5) 쓰레기를 분리해서 처리하는 경우는 21.8%로서 분리처리에 대한 실천이 잘 안되고 있었으며 젖은오물 처리시 비닐봉지를 사용하는 경우는 61.4%로서 과반수 이상으로 나타났다. 6) 부엌설비 중 부엌바닥재료와 취사용 열원은 가정의 수입과 positive(+)의 상관이 있는 것으로 나타났다. 2. 가족의 식사현황 1) 주부가 식사를 담당하는 비율은 89.0%로서 높은 비율을 차지하였는데 이는 가족의 영양과 건강유지를 위하여 바람직한 일로 생각된다. 2) 식사장소로서 가장 많이 이용되는 곳은 안방(81.7%)이었으며 미비하기는 하나 그 다음으로는 부엌식당(15.6%)이었다. 이는 아직까지 농어촌지역에서 침식분리가 제대로 되어지지 않고 있다는 것을 시사해준다. 3) 가족이 모두 일주일에 5~7회 정도 식사를 함께 하는 경우가 아침식사시에는 55.1%, 저녁식사시에는 65.7%로 나타나 비교적 가족이 식사시간에 함께 모일 수 있는 여건이 마련되어 있는 것으로 여겨진다. 4) 가족의 외식횟수는 극히 적은편으로서 한달에 한번도 없거나 있어도 한번 정도인 경우가 대부분인 것(95.0%)으로 나타났다. 5) 가정내의 가공식품 이용도는 가끔 이용한다가 67.9%로 가장 많았고 주부의 직업이나 가정의 수입과는 negative(-)의 상관을 보임으로써 값싼 주식의 대용품이 많이 이용되는 것으로 사료된다. 이와 같이, 농어촌 가정의 부엌설비와 가족의 식사현황 문제를 조사해 본 결과 과거에 비해서는 좀더 합리적으로 변모하고 있다고 할 수 있겠으나 아직도 개선해야 할 점은 많은 것으로 사료된다. 그리고 앞으로 구체적이고도 현실적인 연구가 계속 이루어져야 할 것으로 기대해 본다.

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A Study on the Safety Improvement in a Venting System from the HCl Release Accident of a Petrochemical Company (석유화학공장의 염화수소 누출사고를 통한 대기벤트 시스템의 안전성 향상 방안)

  • Ma, Byung-Chol;Lee, Keun-Won;Im, Ji-Pyo;Kim, Young-Chul
    • Journal of the Korean Institute of Gas
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    • v.16 no.4
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    • pp.38-43
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    • 2012
  • The purpose of this study is to carry out the consequence analysis of an accident related to the release of Hydrogen chloride occurred in a petrochemical company in Korea and suggest the measures to prevent similar accidents from happening again. The total amount released through the safety valve of HCl Column was calculated based on the rated capacity of the safety valve, the ideal gas equation and mechanical energy balance, respectively. As a result of the calculation, we found that the amount of HCl released through the safety valve was at least 76.8 kg. Also, we predicted the dispersion concentration at the position of the injured workers(more than 350 m away from the accident location) using simulation programs such as PHAST. The results of ALOHA and K-CARM are 304 ppm and 1,700 ppm respectively. However, PHAST calculation indicated that the concentration is less than l ppm. From these results, we can understand that workers were injured by HCl gas released from the safe valve and the concentration of gas might be less than 1 ppm. Also, it is important for toxic gases such as HCl to be vented safely to the atmosphere after scrubbing.

Cognitive Perception of an Eco-friendly Public Transportation : Using Principal Component Analysis (친환경 대중교통 수단에 대한 인지적 특성 비교 분석 : 주성분분석을 활용하여)

  • Kwon, Yeongmin;Kim, Suji;Byun, Jihye
    • The Journal of The Korea Institute of Intelligent Transport Systems
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    • v.19 no.1
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    • pp.71-82
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    • 2020
  • The existing transportation system, which is based on internal combustion engines, is rapidly being converted to electrification. Thus, eco-friendly public transportation with high transportation efficiency will continue to spread throughout the market in the near future. The purpose of this study is to compare and analyze the cognitive characteristics of passengers redgarding the technical and social factors of various public transportation means to help a successful introduction of eco-friendly public transit. Through a survey questionnaire (N=485), seven factors of seven transportation modes were evaluated and analyzed using principal component analysis. As a result, it is confirmed that potential passengers have high expectations for the eco-friendliness and city image of the eco-friendly buses. Also, it is confirmed that eco-friendly buses are superior in cleanliness and ride comfort than diesel buses. Given the study's results, this study identifies the cognitive characteristics of passengers regarding eco-friendly public transportation. We hope that these results will be used as basic information for image positioning and improved service with the use of eco-friendly transportation.

초순수 제조공정 현황

  • 이창소
    • Proceedings of the Membrane Society of Korea Conference
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    • 1996.06a
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    • pp.91-120
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    • 1996
  • 경제발전과 더불어 산업의 많은 분야에서 순수 및 초순순의 사용이 증가하고 있으나, 환경오염에 의한 원수의 오염에 따라 순수 및 초순순제조의 장치비와 처리비용의 증가가 야기되고 있다. 현재 국내에는 화력, 원자력발전소를 비롯하여 열병합발전소, 석유화학공장, 제약회사, 전기 전자부품회사, 반도체회사 및 철강회사 등 많은 분야에서 순수 및 초순수 제조장치의 구성과 성능이 많은 차이를 나타내고 있다. 국내의 초순수 제조장치는 90% 이상이 이온교환수지를 사용하는 이온교환법과 UF, R/O System과 같은 Membrane을 사용하는 Membrane System을 병행하여 적용하고 있다. 국내 초순수처리 Plant에서는 통상 전처리 System과 1차 순수제조 System 및 초순수 System이 상호 연결되어 Plant가 구성 운영되고 있다. 전처리 System에는 응집침전, 여과 흡착, 살균 등이 적용되고 있으며 여과 System에 Membrane을 적용할 수 있으나 국내에서는 특별한 경우를 제외하고 대부분 전처리 여과 System에 Media Filter를 사용한다. 전처리 System도 순수처리 장치의 전처리로는 없어서는 안되는 System이지만 여기에는 전처리 System을 제외하고 국내에서 적용하고 있는 초순수처리 System의 공정현황과 각 System별 특징을 설명하고 있다. 초순순 System에는 요구 수질에 따라 다소 차이가 있지만 반도체 공업에서 사용되는 초순수 System이 이중 최고의 Grade로 반도체공업에서 적용되고 있는 System을 기준하였다. 특히 Membrane을 적용한 초순수제조 System이 증가하고 있어 R/O, ED, EDR, CDI, (EDI)와 같은 Membrane System의 특성과 원리를 검토하였다.대적으로 높은 산소확산계수와 물에 대해서는 낮은 투과도를 가져야 한다. 높은 산소확산계수는 반응을 빠르게 하는 잇점이 있으며 물에 대한 낮은 투과도는 센서내의 전해질 물질을 유지보호하는 역할을 한다. 분리막이 산소전극에 이용될 경우 높은 산소 확산계수 이외에도 적절한 기계적 강도, 열적 안정성 등이 요구된다. 몰입이 가능하여 임계치가 저하된 것으로 여겨진다. 또한 광학적 이득의 존재는 이 구조에 의한 극단파장 반도체 레이저다이오드의 실현 가능성을 나타내는 것이다.548 mL에 비해 통계학적으로 의의 있게 적었다(p<0.05). 결론: 관상동맥우회로 조성수술에서 전방온혈심정지액을 사용할 때 희석되지 많은 고농도 포타슘은 fliud overload와 수혈을 피하고 delivery kit를 사용하지 않음으로써 효과적이고 만족할 만한 심근보호 효과를 보였다.를 보였다.4주까지에서는 비교적 폐포는 정상적 구조를 유지하면서 부분적으로 소폐동맥 중막의 비후와 간질에 호산구 침윤의 소견이 특징적으로 관찰되었다. 결론: 분리 폐 관류는 정맥주입 방법에 비해 고농도의 cisplatin 투여로 인한 다른 장기에서의 농도 증가 없이 폐 조직에 약 50배 정도의 고농도 cisplatin을 투여할 수 있었으며, 또한 분리 폐 관류 시 cisplatin에 의한 직접적 폐 독성은 발견되지 않았다이 낮았으나 통계학적 의의는 없었다[10.0%(4/40) : 8.2%(20/244), p>0.05]. 결론: 비디오흉강경술에서 재발을 낮추기 위해 수술시 폐야 전체를 관찰하여 존재하는 폐기포를 놓치지 않는 것이 중요하며, 폐기포를 확인하지 못한 경우와 이차성 자연기흉에 대해서는 흉막유착술에 더 세심한 주의가 필요하다는 것을 확인하였다. 비디오흉강경수술은 통증이 적고, 입원기간이 짧고, 사회

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Seismic Anisotropy Physical Modeling with Vertical Transversely Isotropic Media (VTI 매질의 탄성파 이방성 축소모형실험)

  • Ha, Young-Soo;Shin, Sung-Ryul
    • Geophysics and Geophysical Exploration
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    • v.13 no.4
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    • pp.307-314
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    • 2010
  • Although conventional seismic data processing is based on the assumption that the media are isotropic, the subsurface is often anisotropy in shale formation or carbonate with cracks and fractures. This paper presents the anisotropic parameter and seismic modeling in transversely isotropic media with a vertical symmetry axis using seismic physical modeling. The experiment was successfully carried out with VTI media, laminated bakelite material, using contact transducer of p and s-wave transmission. The variation of velocities with angle of incidence was clearly shown in anisotropic material. Comparing these velocities with the calculated phase velocities, the (P) and (S)-wave velocity observed in anisotropic material was a very good agreement with the calculated values. Anisotropic parameter ${\varepsilon}$, ${\delta}$, ${\gamma}$ was estimated by using Lame's constant calculated from the observed velocity. For the purpose of testing (S)-wave polarization, a birefringence experiment was carried out. The higher velocity was associated with the polarization parallel to the fracture, and the lower velocity was associated with the polarization perpendicular to the fracture.

Effects of the Addition Pro-oxidant on the Physical Properties and Degradation of the Petroleum- derived Plastic Film (산화촉진제 첨가가 플라스틱 필름의 물성과 분해에 미치는 영향)

  • Kihyeon, Ahn;Jae-Suk, Choi;Roun, Lee;Jung-Gu, Han;Tae-Hoon, Ro;Hyung Woo, Park
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.28 no.3
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    • pp.165-170
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    • 2022
  • If petroleum- derived plastic like a bio-based plastic was degradation, awareness like a global warming and environmental disasters will be decreased. Plastic film was produced by adding ferric ions according to concentration by using a pro-oxidant in polyolefin resin. Changes in tensile strength, elongation, and molecular weight were evaluated according to the UV irradiation time. Increasing the amount of ferric ions resulted in more significant declines of physical properties, and also resulted in greater changes in molecular weight. After 100 hours of UV irradiation, tensile strength declined significantly in the film containing pro-oxidant as compared to the control. A similar effect was also observed in terms of elongation. The film containing pro-oxidant showed a 73.8% decrease in molecular weight after 100 hours of UV irradiation. The appropriate use of pro-oxidant can not only degrade plastic film but also control the time of degradation at the petroleum-derived plastic films. Further studies are necessary to investigate the conditions of plastic film degradation.

Effect on the Physical Properties of Bio-Plastic Sheet Adding Corn Husk Which was Byproduct of Food Assets (식량자산 부산물인 옥수수 피 첨가가 바이오 플라스틱 시트의 물성에 미치는 영향)

  • Ahn, Kihyeon;Choi, Jae-Suk;Han, Jung-Gu;Park, UoonSeon;Lee, Roun;Park, Hyung Woo;Chung, SungTaek
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.28 no.2
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    • pp.97-104
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    • 2022
  • This study investigated the characteristics for the optimal concentration of addition of the mixing solution through the corn husk pulverization and surface modification of biomass byproducts adding mixed solution between ESO and silane. And surveyed the specific surface area, water absorption, particle size and physical properties of bio- degradable plastic sheet. The specific surface area was 1.105 m2/g, particle size was the highest at 19 ㎛. The impact strength, tensile strength, elongation and hardness of plastic sheet showed the highest at the 1% concentration among the mixing solutions. The flexural strength and modulus was high according to the increasing the mixing solution. The results above showed that it was the best the adding 1% of mixed solution after silane treatment of corn husks for its manufacture as a bio-based plastic sheet.

Properties of Plywood Bonded with Adhesive Resins Formulated with Enzymatically-Hydrolyzed Rapeseed Flour (유채박의 효소 가수분해물로 조제한 접착제를 사용한 합판의 접착특성)

  • Yang, In;Han, Gyu-Seong;Choi, In-Gyu;Kim, Yong-Hyun;Ahn, Sye-Hee;Oh, Sei-Chang
    • Journal of the Korean Wood Science and Technology
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    • v.40 no.3
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    • pp.164-176
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    • 2012
  • In the present study, rapeseed flour (RSF), which is a by-product from the production of edible oil and biodiesel extracted from rapeseed, was used to develop alternative adhesives for the production of plywood panels. To examine the effects of the enzyme on the adhesive properties and formaldehyde emission of the RSF-based adhesive resins, three enzymes, such as cellulase (CEL), pectinase (PEC) and protease (ALC), were used either separately or together. As a crosslinking agent, PF prepolymers, which were prepared with 1.5, 1.8 and 2.1 mole formaldehyde and 1 mol phenol (1.8-, 2.1- and 2.4-PF), were added into the RSF hydrolyzates. The adhesive resins formulated with CEL- or CEL-PEC-RSF hydrolyzates and 1.8-F/P PF prepolymers exhibited excellent adhesive strengths and formaldehyde emission. The tensile shear strength and formaldehyde emission of the plywood panels bonded with the formulate resins were satisfied with the minimum requirement of the KS standard for ordinary plywood panels (0.6 N/$mm^2$). In addition, formaldehyde emissions of the plywood panels approached to that of E0 specified in the KS standard (0.5 mg/${\ell}$), and even had much better than those of commercial UF glue mixes. Overall, the use of RSF-based adhesive resins for the production of plywood panels might provide durable adhesive properties and an environmentally friendly substitute for petroleum-based adhesive resins. However, further researches - the increase of solid content of RSF-based adhesives for reducing press time and the microscopic observation of plywood specimen for identifying the relationship between tensile shear strength and the penetration of adhesives into wood structure - are required to commercialize the RSF-based adhesives.

Biodegradation of Phenol by Comamonas testosteroni DWB-1-8 Isolated from the Activated Sludge of Textile Wastewater (섬유 폐수 활성 슬러지에서 분리한 Comamonas testosteroni의 생물학적 페놀 분해)

  • Kwon, Hae Jun;Choi, Doo Ho;Kim, Mi Gyeong;Kim, Dong-Hyun;Kim, Young Guk;Yoon, Hyeokjun;Kim, Jong-Guk
    • Journal of Life Science
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    • v.30 no.2
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    • pp.156-161
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    • 2020
  • Since industrialization, the production and utilization of various chemicals has contributed to improving the quality of our lives, but the subsequent discharge of massive waste is inevitable, and environmental pollution is becoming more serious every day. Exposure to chemicals as a result of environmental pollution is having a negative effect on human health and the ecosystem, and cleaning up the polluted environment that can affect our lives is a very important issue. Toxic aromatic compounds have been detected frequently in soil, groundwater, and wastewater because of the extensive use of oil products, and phenol, which is used to produce synthetic resins, textiles, and dyes, is one of the major pollutants, along with insecticides and preservatives. Phenol can cause dyspnea, headache, vomiting, mutation, and carcinogenesis. Phenol-degrading bacterium DWB-1-8 was isolated from the activated sludge of textile wastewater; this strain was identified as Comamonas testosteroni by 16S rRNA gene sequencing. The optimal culture conditions for the cell growth and degradation of phenol were 0.7% K2HPO4, 0.6% NaH2PO4, 0.1% NH4NO3, 0.015% MgSO4·7H2O, 0.001% FeSO4·7H2O, an initial pH of 7, and a temperature of 30℃. The strain was also able to grow by using other toxic compounds, such as benzene, toluene, or xylene (BTX), as the sole source of carbon.