• Title/Summary/Keyword: 생성열

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Study on the crystallization of quartz glass crucibles for preparation of single crystal silicon (단결정 실리콘 제조용 석영유리도가니의 결정화에 대한 연구)

  • Lim, Jong Won;Kim, Tae Huei;Park, Kyung Bong
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.28 no.3
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    • pp.99-105
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    • 2018
  • In order to avoid un-uniform crystallization on the surface of a quartz glass crucible that is known to affect the production yield of the single crystal silicon, Ba (barium) was selected as a crystallization promotor and the inner surface of the crucible was coated using Ba (barium hydroxide octahydrate)-solution by the spray pyrolysis method. For un-coated crucible, it was found that the crystallization of its surface started at $1350^{\circ}C$, and at $1450^{\circ}C$ the surface was uniformly crystallized with ${\beta}$-cristobalite phase. It was found that the crucible coated with Ba began to be crystallized from $1000^{\circ}C$ and was uniformly crystallized on the crucible surface at $1300^{\circ}C$. In this case, ${\alpha}$-cristobalite and needle-shaped $BaSi_2O_5$ phase were created and disappeared as a crystal phase, and the ${\beta}$-cristobalite phase was eventually evenly distributed over the Ba-coated crucible surface.

Development of flood inundation area GIS database for Samsung-1 drainage sector, Seoul, Korea (서울 삼성 1분구에 대한 침수면적 GIS 데이터베이스 구축)

  • Oh, Minkwan;Lee, Dongryul;Kwon, Hyunhan;Kim, Dongkyun
    • Journal of Korea Water Resources Association
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    • v.49 no.12
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    • pp.981-993
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    • 2016
  • This study explains the GIS database of flood inundation area developed for Samsung-1 Drainage Sector, Seoul, Korea. The XP-SWMM dual drainage model was developed for the study area, and the time series observed at the watershed outlet was used to obtain the watershed time of concentration and to calibrate the XP-SWMM model. The rainfall scenario was developed by dividing the 40 minute watershed time of concentration into two 20-minute time steps and then applying the gradually increasing 5 mm/hr interval rainfall intensity to each of the time step up to 200 mm/hr, which is the probable maximum precipitation of the study area. The developed rainfall scenarios was used as the input of the XP-SWMM model to obtain the database of the flood inundation area. The analysis on the developed GIS database revealed that: (1) For the same increment of the rainfall, the increase of the flooded area can be different, and this was caused by topographic characteristics and spatial formation of pipe network of the study area; (2) For the same flooded area, the spatial extent can be significantly different depending on the temporal distribution of rainfall; and (3) For the same amount of the design rainfall, the flood inundation area and the extent can be significantly different depending on the temporal distribution of rainfall.

Implementaion of status information and protocol integration system at marine transportation facilities (해양교통시설의 상태정보 안내 및 프로토콜 통합 시스템 구현)

  • Jang, Hyun-Young;Jang, Jong-Wook
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2015.10a
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    • pp.190-193
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    • 2015
  • The current sea route sign system based on an electronic marine chart only has a data manufacture specification for uses at ECDIS. Therefore, it has a limitation in expressing various sea route data and falls short of productivity as it is frozen to prevent being changed for a long time. Also, it cannot satisfy requirements from high tech such as lattice structure data and time series information. Currently, although it builds each independent operation system based S-57, it has been found that it is the most important requirement from consumers that the entire monitoring system can mutually interwork by standardizing and uniting formats of all protocols. In addition, current status information and alarm system is using AIS, TRS, WCDMA telecommunication and processing all the data after saving it into each different server. Lighthouse lantern which currently has used was utilized to do a performance test of a developed system. All of created data was trasmitted through the RS-232, It is clear that the data was received by a situation monitoring system. In addition, when the data was transmitted after saving in a database, same data was ordinarily received. In this thesis, we will implemented the status information and alarm system of Marine transportation facilities which is a sea route sign system based on S-63 electronic marine chart, S/W, after uniting each different protocol and making combined system.

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Catalytic Carbonization of Biomass and Nonisothermal Combustion Reactivity of Torrefied Biomass (바이오매스 촉매 탄화 및 반탄화 바이오매스의 비등온 연소 반응 특성)

  • Bak, Young-Cheol;Choi, Joo-Hong
    • Korean Chemical Engineering Research
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    • v.56 no.5
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    • pp.725-731
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    • 2018
  • The effects of catalysts addition on the carbonization reaction of biomass have been studied in a thermogravimetric analyzer (TGA). The sample biomasses were Bamboo and Pine. The catalysts tested were K, Zn metal compounds. The carbonization reactions were tested in the nonisothermal condition from the room temperature to $850^{\circ}C$ at a heating rate $1{\sim}10^{\circ}C/min$ on the flowing of $N_2$ purge gases. Also, the effects of catalyst on the torrefaction were tested in the temperature condition of 220, 250, $280^{\circ}C$ at 30 min. Combustion characteristic for the torrefied catalyst biomass were studied in the nonisothermal conditions of $200{\sim}850^{\circ}C$. As the results, the initial decomposition temperatures of the volatile matters ($T_i$) and the temperature of maximum reaction rate ($T_{max}$) were decreased with increasing the catalyst amounts in the sample biomass. The char amounts remained after carbonization at $400^{\circ}C$ increased with the catalyst amounts. Therefore catalysts addition can be decreased the energy for carbonization process and improved the heating value of product char. The catalysts reduced the optimum torrefaction conditions from $250^{\circ}C$ to $220^{\circ}C$. The torrefied catalyst biomass have lower activated energy from 46.5~58.7 kJ/mol to 25.1~27.0 kJ/mol in the nonisothermal combustion reaction.

Clustering of Web Objects with Similar Popularity Trends (유사한 인기도 추세를 갖는 웹 객체들의 클러스터링)

  • Loh, Woong-Kee
    • The KIPS Transactions:PartD
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    • v.15D no.4
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    • pp.485-494
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    • 2008
  • Huge amounts of various web items such as keywords, images, and web pages are being made widely available on the Web. The popularities of such web items continuously change over time, and mining temporal patterns in popularities of web items is an important problem that is useful for several web applications. For example, the temporal patterns in popularities of search keywords help web search enterprises predict future popular keywords, enabling them to make price decisions when marketing search keywords to advertisers. However, presence of millions of web items makes it difficult to scale up previous techniques for this problem. This paper proposes an efficient method for mining temporal patterns in popularities of web items. We treat the popularities of web items as time-series, and propose gapmeasure to quantify the similarity between the popularities of two web items. To reduce the computation overhead for this measure, an efficient method using the Fast Fourier Transform (FFT) is presented. We assume that the popularities of web items are not necessarily following any probabilistic distribution or periodic. For finding clusters of web items with similar popularity trends, we propose to use a density-based clustering algorithm based on the gap measure. Our experiments using the popularity trends of search keywords obtained from the Google Trends web site illustrate the scalability and usefulness of the proposed approach in real-world applications.

Cooling and Antisolvent Crystallization of Potassium Bicarbonate in the Presence of Sterically Hindered Alkanolamines (입체 장애 알카놀아민 혼합 수용액에서 중탄산칼륨 결정의 냉각 반용매 결정화)

  • Jo, Chang Sin;Jung, Taesung;Yoon, Hyoung Chul;Kim, Jong-Nam;Rhee, Young Woo
    • Clean Technology
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    • v.20 no.4
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    • pp.383-389
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    • 2014
  • $CO_2$ absorption processes have a good potential for large scale capture of $CO_2$ but a large amount of absorbing solution has to be regenerated, undesirably increasing the consumption of energy such as sensible heat and latent heat of vaporization. In this study, a cooling crystallization process which would separate the $CO_2$-rich potassium bicarbonate crystals from $CO_2$-lean water was developed to reduce the energy penalty. Sterically hindered alkanolamine additives were used to enhance the $CO_2$ removal efficiency and their antisolvent effect on the crystallization was found in a continuous cooling crystallizer. The production yields of crystals were increased in the sequence of 2-amino-2-methyl-1-propanol (AMP) < 2-amino-2-methyl-1,3-propanediol (AMPD) < 2-amino-2-hydroxymethyl-1,3-propanediol (AHPD), which are related to the number of hydroxyl groups in the additive molecules. Using $^{13}carbon$ nuclear magnetic resonance, the additives favored the formation of bicarbonate ions by steric hindrance effect and increased the supersaturation of $KHCO_3$. It is shown that the additives increase the mean size of crystals and crystal growth rate by increasing supersaturation. The additives are promising for enhancing the $CO_2$ removal efficiency and reducing the regeneration energy cost of $CO_2$ absorbing solution by promoting $KHCO_3$ crystallization.

A Study on the Experimental Measurements and Its Recovery for the Rate of Boil-Off Gas from the Storage Tank of the CO2 Transport Ship (CO2 수송선 저장탱크의 BOG 측정 실험 및 회수에 관한 연구)

  • Park, Jin-Woo;Kim, Dong-Sun;Ko, Min-Su;Cho, Jung-Ho
    • Clean Technology
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    • v.20 no.1
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    • pp.1-6
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    • 2014
  • $CO_2$ is generated by the combustion reaction, when getting the energy from fossil fuel. If the carbon dioxide emissions increases more, the global warming problem will become more serious. CCS (carbon capture storage) needs to be developed for the prevention of this. When liquefied $CO_2$ is transported, BOG (boil-off gas) is generated because of several problems. In the study, by injecting liquefied $CO_2$ in two tanks which contains $40m^3$each, the amount of BOG and its composition were measured during 30 days when generating pressure changes and external heat, loading, unloading. In result, 16,040 kg of BOG was generated and the composition has been found out to be 99.95% $CO_2$ and 0.05 % $N_2$. Also, we conducted simulation process for reliquefaction of generated BOG with vapor compression cycle using the PRO/II with PROVISION version 9.2. As a result, the refrigeration cycle of the total circulation flow rate was 42.07 kg/h and the condenser utility consumption was 48.85 kg/h.

Assessment of the Quality Characteristics of Mixed-grain Nuruk Made with Different Fungal Strains (곰팡이 균종을 달리하여 제조한 혼합 곡류 누룩의 품질특성)

  • Baek, Seong-Yeol;Kim, Joo-Yeon;Choi, Ji-Ho;Choi, Jeong-Sil;Choi, Han-Seok;Jeong, Seok-Tae;Yeo, Soo-Hwan
    • Journal of the East Asian Society of Dietary Life
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    • v.22 no.1
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    • pp.103-108
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    • 2012
  • Nuruk is a fermented ingredient used for production of traditional Korean rice wine. In this study, quality characteristics of mixed-grain nuruk was made by brewing with different fungal strains was analyzed. Quality elements including enzyme activity and organic acids constituents were measured. The fermentation time of the nuruk did not make a significant difference in terms of its pH, but the acidity and amino acid content for nuruk made from a mixture of two fungal strains was higher than that seen with a single fungal strain. Overall, the enzyme activity for two fungal strain nuruk was higher than that observed for single fungal strain nuruk, with ${\alpha}$-amylase and acidic protease activity in the mixed strain nuruk observed to be more than twice that of the single strain. The major organic acids observed in the manufactured nuruk were identified as acetic, citric, formic, fumaric, lactic, malic and oxalic acids. The total amount of organic acids contained in the nuruk made with the two fungal strain was (2,116.3 mg%). The fungal strains used were A. kawachii SC60 nuruk (1,608.5 mg%) and A. oryzae RIB1353 nuruk (1,146.7 mg%).

Study on the Polymerization Characteristics of Isoprene through Nitroxide Mediated Controlled/"living" Radical Polymerization Techniques (Nitroxide 매개 리빙라디칼 중합법에 의한 isoprene의 중합특성에 관한 연구)

  • Hong, Sung-Chul
    • Elastomers and Composites
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    • v.44 no.1
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    • pp.55-62
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    • 2009
  • In this study, investigation on the polymerization characteristics of isoprene through nitroxide mediated controlled/"living" radical polymerization techniques was attempted. In the presence of acetol, linear increase of isoprene conversion with time and low polydispersities of the resulting polymers ($M_w/M_n$ < 1.5) were observed, which suggest successful controlled/"living" radical polymerization of isoprene. The microstructure of the resulting polyisoprene was composed of $\sim$ 22% of 3, 4, $\sim$30% of 1, 4-cis and $\sim$ 48% of 1, 4-trans. The optimum polymerization temperature was 145 $^{circ}C$, below which no significant polymerization behavior was observed. Non-cyclic nitroxide, such as di-tert-butyl nitroxide (DTBN) could not mediate the polymerization, whereas cyclic nitroxides (2, 2, 6, 6-tetramethyl-1-peperidine 1-oxyl (TEMPO) and 4-oxo-2, 2, 6, 6-tetramethyl-1-peperidine 1-oxyl (oxoTEMPO)) were successfully employed for the polymerization. However, isoprene dimerization reaction through Diels-Alder process was also observed at the given polymerization condition, which afforded a significant amount of limonene. Isoprene thermal autoinitiation was also possible, which was, however, considered to be not significant under the given polymerization condition.

Antimicrobial & Physiological Characteristics of Ethanol Extract from Pinus rigida Miller Leaves (리기다소나무 잎 에탄올 추출물의 항균 및 생리특성)

  • Oh, Byung-Tae;Choi, Sung-Gil;Cho, Sung-Hwan
    • Food Science and Preservation
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    • v.13 no.5
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    • pp.629-633
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    • 2006
  • Pinus rigida Miller leaf extract (PRLE) showed antimicrobial activity remarkably against food pathogenic and spoilage bacteria at concentrations of $100{\sim}250{\mu}g/mL$. Alcohol-soluble PRLE had higher antimicrobial activity against Staphylococcus aureus and E-coli than any other-soluble PRLE such as butanol, ethyl acetate, ether and water. As PRLE concentration increased alcohol-soluble PRLE increased the remarkable inhibitory zone of microbial growth on the microbial media. PRLE showed good stability against temperature and pH in the range of $40{\sim}150^{\circ}C$ and $4{\sim}11$, respectively. This may indicate that PRLE can be a potential anti-microbial agent for industrial application. In addition, SEM of Listeria monocytogenes suggested that it antimicrobial component would perturb the functions of microbial cell membranes synergistically. In the feeding experiment the formaldehyde content in the serum of formalin-fed and PRLE-treated me decreased remarkably due to the lysis of formaldehyde and the rate of hemoglobin biosynthesis was recovered to the orignal state within a short breeding time.